Showing 1–50 of 390 results for author: Li, P

Three-Dimensional Electronic Structures in Superconducting Ruddlesden-Popper Bilayer Nickelate Films

Authors: Yueying Li, Lizhi Xu, Wei Lv, Zihao Nie, Zechao Wang, Yu Miao, Jianchang Shen, Guangdi Zhou, Wenhua Song, Heng Wang, Haoliang Huang, Junfeng He, Jin-Feng Jia, Peng Li, Qi-Kun Xue, Zhuoyu Chen

Abstract: Beyond the quasi-two-dimensional (2D) paradigm of cuprates, the role of the third dimension of the Ruddlesden-Popper bilayer nickelates is essential to decoding their superconducting mechanism. Here, using angle-resolved photoemission spectroscopy (ARPES) with varied photon energies, we systematically investigate the electronic band structures in three dimensions for superconducting (La,Pr,Sm)… ▽ More Beyond the quasi-two-dimensional (2D) paradigm of cuprates, the role of the third dimension of the Ruddlesden-Popper bilayer nickelates is essential to decoding their superconducting mechanism. Here, using angle-resolved photoemission spectroscopy (ARPES) with varied photon energies, we systematically investigate the electronic band structures in three dimensions for superconducting (La,Pr,Sm)$_3$Ni$_2$O$_7$/SrLaAlO$_4$ thin films (superconducting onset temperature $T_c^{\text{onset}} \sim 48$ K) transferred via a cryogenic ultra-high vacuum suitcase. We reveal an orbital-dependent dimensionality: while the $d{x^2-y^2}$-dominant bands exhibit a quasi-2D character, the $d{z^2}$-dominant band displays a finite $k_z$ dispersion. Finite energy gaps are identified on all observed bands across multiple high-symmetry directions. Systematic temperature-dependent analysis characterizes the superconducting nature of the gap on the $d{z^2}$-derived band, revealing a large gap $Δ\sim 18$ meV and a ratio $2Δ/k_BT_c\sim 8$ exceeding the weak-coupling BCS limit. The suppression of spectral weight near the Fermi level persists above the superconducting transition temperature. Ubiquitous waterfall-like spectral features evidence the presence of electron interactions. These results underscore the role of the $d_{z^2}$ orbital and correlations, placing constraints on theoretical models for nickelate superconductivity. △ Less

Submitted 10 April, 2026; v1 submitted 9 April, 2026; originally announced April 2026.

Pumping of spin supercurrent in unitary triplet superconductors

Authors: Ping Li, Tao Yu

Abstract: One efficient mechanism for generating a charge supercurrent is Andreev reflection, in which the electric current injected from a normal metal into a conventional superconductor is converted into a supercurrent, thereby preserving charge conservation. We here propose a general principle for generating spin supercurrents in triplet superconductors by analogy with such charge transport, i.e., assumi… ▽ More One efficient mechanism for generating a charge supercurrent is Andreev reflection, in which the electric current injected from a normal metal into a conventional superconductor is converted into a supercurrent, thereby preserving charge conservation. We here propose a general principle for generating spin supercurrents in triplet superconductors by analogy with such charge transport, i.e., assuming spin conservation. We find a spin torque that is proportional to the triplet superconducting order parameter and, in the spin-conservation scenario, converts the particle spin to that of Cooper pairs. Based on this general principle, we propose an implementation to efficiently generate a spin supercurrent in unitary triplet superconductors, even though Cooper pairs carry no spin polarization at equilibrium, by the magnetization dynamics ${\bf M}(t)$ of a proximity magnetic nanostructure. The efficiency of this spin pumping is not solely limited to the $d{\bf M}/dt\times {\bf M}$ due to the emergent particle-hole symmetry, thereby going beyond the conventional spin pumping of electrons. This general principle provides an efficient approach to generating and manipulating dissipationless spin currents in many unconventional superconductors. △ Less

Submitted 29 March, 2026; originally announced March 2026.

Comments: 17 pages, 4 figures

A biomimetic feedback loop for sustaining self-lubrication and wear resistance

Authors: Fuyan Kang, Shilin Deng, Panpan Li, Rui Zhao, Xiaohong Liu, Hongxuan Li, Huidi Zhou, Jianmin Chen, Wengen Ouyang, Li Ji

Abstract: Intelligent materials that self-sense and self-regulate are an emerging frontier in sustainable technology. Here we introduce Cu(Au)/C nanocomposite films that act as bioinspired self-adjusting lubricants. In these films, frictional heating triggers melting and migration of soft metal nanoparticles (NPs) such as Cu or Au along nano-pores to the friction interface, where the metal catalyzes the in-… ▽ More Intelligent materials that self-sense and self-regulate are an emerging frontier in sustainable technology. Here we introduce Cu(Au)/C nanocomposite films that act as bioinspired self-adjusting lubricants. In these films, frictional heating triggers melting and migration of soft metal nanoparticles (NPs) such as Cu or Au along nano-pores to the friction interface, where the metal catalyzes the in-situ formation of ordered carbon nano-structures. Real-time monitoring of friction coefficient, electrical resistance(R), and metal release confirms an autonomous cycle: high friction coefficient generates heat, melting the metal NPs; the migrating metal then lowers friction coefficent by creating low-friction nanostructures, which reduces heat and arrests further migration until friction rises again. This self-limiting feedback enables stable ultra-low friction (~0.04) and an exceptional wear life (>40 km) even in high vacuum. By utilizing friction-derived heat as an intrinsic activation signal, our system establishes a general paradigm for intelligent, self-regulating materials with applications extending beyond tribology. △ Less

Submitted 16 March, 2026; originally announced March 2026.

Persistent incommensurate amorphous/crystalline meta-interfaces enable engineering-grade superlubricity

Authors: Wan Wang, Zijun Ding, Panpan Li, Wanying Ying, Hongxuan Li, Xiaohong Liu, Huidi Zhou, Jianmin Chen, Wengen Ouyang, Li Ji

Abstract: Friction dissipates a substantial portion of global energy, motivating the pursuit of superlubricity, a state of near-zero friction, in real-world systems. Conventional approaches rely on crystalline lattice mismatch to suppress periodic energy barriers, but real interfaces invariably contain defects, edges and grain boundaries that restore high-friction states. Here we introduce a materials-agnos… ▽ More Friction dissipates a substantial portion of global energy, motivating the pursuit of superlubricity, a state of near-zero friction, in real-world systems. Conventional approaches rely on crystalline lattice mismatch to suppress periodic energy barriers, but real interfaces invariably contain defects, edges and grain boundaries that restore high-friction states. Here we introduce a materials-agnostic strategy based on amorphous/crystalline heterointerfaces to achieve robust superlubricity under engineering-relevant conditions. Using diamond-like carbon (DLC) and crystalline MoS2 as a model system, we show through experiments and atomistic simulations that their interface remains incommensurate at all orientations and exhibits vanishing energy barriers during friction. In contrast, twisted MoS2 bilayers readily reorient into commensurate, high-friction states. We scale this effect by fabricating laser-patterned arrays of DLC/MoS2 meta-contacts reinforced with Ti3C2Tx MXene, forming hierarchical interfaces that sustain a friction coefficient of ~0.008 over 100000 cycles under combined extreme conditions: millimetre-scale contact size, 12.7 GPa contact pressure and RH 40% air. This unprecedented performance arises from four synergistic factors: intrinsic incommensurability at amorphous/crystalline interface, the rigidity of DLC support, MXene-based mechanical reinforcement and normalized load distribution by geometric patterning. These findings establish a general design paradigm that extends structural superlubricity from nanoscale model systems to practical technologies for sustainable engineering. △ Less

Submitted 16 March, 2026; originally announced March 2026.

Quantitative 3D imaging of highly distorted micro-crystals using Bragg ptychography

Authors: Peng Li, David Yang, Christoph Rau, Marc Allain, Felix Hofmann, Virginie Chamard

Abstract: Bragg coherent diffraction imaging (BCDI) fails to reliably retrieve phases in micro-crystals exhibiting strong strain inhomogeneities, which restricts its applicability. Here we show that three-dimensional Bragg ptychography (3DBP) overcomes this limitation by enabling stable inversion for large lattice distortions. Using a combination of experimental measurements and numerical tests, we compare… ▽ More Bragg coherent diffraction imaging (BCDI) fails to reliably retrieve phases in micro-crystals exhibiting strong strain inhomogeneities, which restricts its applicability. Here we show that three-dimensional Bragg ptychography (3DBP) overcomes this limitation by enabling stable inversion for large lattice distortions. Using a combination of experimental measurements and numerical tests, we compare the performance limits of the two approaches and demonstrate that 3DBP tolerates lattice distortions more than six times larger than BCDI. We also establish the sensitivity of both methods on a weakly distorted crystal, for which 3DBP yields smoother amplitude and phase fields with reduced short-length-scale artifacts. 3DBP thus provides a reliable route for imaging micro-crystals with large lattice distortions, expanding the scope of coherent X-ray Bragg microscopy to strongly deformed systems. △ Less

Submitted 12 March, 2026; originally announced March 2026.

Comments: 4 figures

Contribution of remote bands to orbital magnetization in twisted bilayer graphene

Authors: Pinzhuo Li, Kun Jiang, Ziqiang Wang, Jian Kang, Yi Zhang

Abstract: Motivated by recent theoretical and experimental works on orbital magnetization $M_{\mathrm{orb}}$ for the interacting system, we develop a gauge-invariant framework to compute $M_{\mathrm{orb}}$ for correlated phases of magic-angle twisted bilayer graphene within self-consistent Hartree-Fock approximation. Based on the projector formulation of the theory of orbital magnetization, we evaluate both… ▽ More Motivated by recent theoretical and experimental works on orbital magnetization $M_{\mathrm{orb}}$ for the interacting system, we develop a gauge-invariant framework to compute $M_{\mathrm{orb}}$ for correlated phases of magic-angle twisted bilayer graphene within self-consistent Hartree-Fock approximation. Based on the projector formulation of the theory of orbital magnetization, we evaluate both $M_{\mathrm{orb}}$ and the self-rotation contribution $m_{\mathrm{SR}}$ directly from the Hartree-Fock Hamiltonian. We demonstrate that, in contrast to topological invariants such as the Chern number, both $M_{\mathrm{orb}}$ and $m_{\mathrm{SR}}$ obtain substantial contributions from remote bands and thus require careful convergence with respect to the number of included remote bands. Applying this approach to correlated phases at integer fillings, we obtain converged $M_{\mathrm{orb}}$ and $m_{\mathrm{SR}}$ for time reversal symmetry broken Chern insulating states at $ν=\pm3$ and for competing correlated phases at other integer fillings. Our results establish a systematic and controlled approach for evaluating orbital magnetization in correlated moiré systems and clarify the crucial role of remote bands in determining their magnetic response. △ Less

Submitted 16 April, 2026; v1 submitted 3 March, 2026; originally announced March 2026.

Comments: 9 pages, 5 figures(main text) 10 pages, 4 figures (SM)

Sliding Ferroelectricity Induced and Switched Altermagnetism in GaSe-VPSe3-GaSe Sandwiched Heterostructure with Strong Magnetoelectric Effect

Authors: Pengqiang Dong, Hanbo Sun, Chao Wu, Ping Li

Abstract: Magnetoelectric coupling is vital for exploring fundamental science and driving the development of high-density memory and energy-efficient spintronic devices. Altermagnets, which merge the benefits of ferromagnets and antiferromagnets, pave the way for unprecedented magnetoelectric coupling effects. However, the spin splitting in altermagnets is robustly protected by spin space group symmetry, po… ▽ More Magnetoelectric coupling is vital for exploring fundamental science and driving the development of high-density memory and energy-efficient spintronic devices. Altermagnets, which merge the benefits of ferromagnets and antiferromagnets, pave the way for unprecedented magnetoelectric coupling effects. However, the spin splitting in altermagnets is robustly protected by spin space group symmetry, posing a significant challenge for external manipulation. Here, we propose to utilize the coupling between the layer degree of freedom and the altermagnet to achieve an altermagnetic multiferroic with strong magnetoelectric coupling. In the GaSe-VPSe3-GaSe sandwiched structure, the magnetic order can be switched between altermagnetic and conventional antiferromagnetic by controllably breaking and restoring the combined spatial inversion and time-reversal symmetry using sliding ferroelectricity. Moreover, our systematic investigation of all pathways revealed that the transition from a ferroelectric CB stacking, through an antiferroelectric CC stacking, to a ferroelectric BC stacking is the most favorable, with an energy barrier of only 50.13 meV/f.u.. More importantly, we reveal that the microscopic mechanism of the magnetic phase transition stems from the interlayer covalent bonding of Se-Se or Se-P atomic pairs at the interface. Our findings unveil a new form of magnetoelectric coupling and lay the groundwork for designing miniature information processing and multiferroic memory devices based on altermagnetism. △ Less

Submitted 28 February, 2026; originally announced March 2026.

Comments: 12 pages, 6 figures, Accepted Acta Materialia

Journal ref: Acta Materialia (2026)

Emergence of a symmetry-broken Chern insulator near a moiré Kondo breakdown

Authors: Wanghao Tian, Bowen Shen, Lizhong Li, Mingjie Zhang, Feng Liu, Chushan Li, Yaotian Liu, Fan Xu, Kenji Watanabe, Takashi Taniguchi, Peiling Li, Li Lu, Yang Xu, Shengwei Jiang, Tingxin Li, Jie Shan, Kin Fai Mak

Abstract: Moiré semiconductors built on angle-aligned transition metal dichalcogenide (TMD) heterobilayers provide a physical realization of the Kondo lattice model, in which one TMD layer is prepared in a Mott insulating state supporting a lattice of local magnetic moments and the other layer in a metallic state supporting itinerant carriers. The artificial Kondo lattice enables the exploration of exotic s… ▽ More Moiré semiconductors built on angle-aligned transition metal dichalcogenide (TMD) heterobilayers provide a physical realization of the Kondo lattice model, in which one TMD layer is prepared in a Mott insulating state supporting a lattice of local magnetic moments and the other layer in a metallic state supporting itinerant carriers. The artificial Kondo lattice enables the exploration of exotic states of matter near a continuously tunable Kondo breakdown. Here we report the emergence of a symmetry-broken Chern insulator at a moiré hole filling factor 4/3 in angle-aligned MoTe2/WSe2 moiré bilayers, which realize a chiral Kondo lattice. The symmetry-broken Chern insulator, which exhibits integer quantized Hall conductance at a fractional moiré filling, breaks the translational symmetry of the lattice spontaneously; it also appears only near a magnetic field-induced Kondo breakdown in the mixed-valence regime of the material. We further demonstrate that the magnetic field required to induce the Kondo breakdown and to stabilize the symmetry-broken Chern insulator is twist angle dependent. The results present new opportunities for exploring the subtle interplay between topology and Kondo interactions in moiré semiconductors. △ Less

Submitted 19 February, 2026; originally announced February 2026.

Nonlinear quadrupole topological insulators

Authors: Rujiang Li, Wencai Wang, Yongtao Jia, Ying Liu, Pengfei Li, Boris A. Malomed

Abstract: Higher-order topological insulators (HOTIs) represent a family of topological phases that go beyond the conventional bulkboundary correspondence. d-dimensional n-th order HOTIs maintain (d - n)-dimensional gapless boundary states (in particular, zero-dimensional corner states in the case of d = n = 2). HOTIs of the Wannier type cam be extended into the nonlinear regime. Another prominent class of… ▽ More Higher-order topological insulators (HOTIs) represent a family of topological phases that go beyond the conventional bulkboundary correspondence. d-dimensional n-th order HOTIs maintain (d - n)-dimensional gapless boundary states (in particular, zero-dimensional corner states in the case of d = n = 2). HOTIs of the Wannier type cam be extended into the nonlinear regime. Another prominent class of HOTIs, in the form of multipole insulators, was investigated only in the linear regime, due to the challenge of simultaneously achieving both negative hopping and strong nonlinearity. Here we propose the concept of nonlinear quadrupole topological insulators (NLQTIs) and report their experimental realization in an electric circuit lattice. Quench-initiated dynamics gives rise to nonlinear topological corner states and topologically trivial corner solitons, in weakly and strongly nonlinear regimes, respectively. Furthermore, we reveal the formation of two distinct types of bulk solitons, one existing in the middle finite gap under the action of weak nonlinearity, and another one found in the semi-infinite gap under strong nonlinearity. This work realizes another member of the nonlinear HOTI family, suggesting directions for exploring novel solitons across a broad range of topological insulators. △ Less

Submitted 6 February, 2026; originally announced February 2026.

Comments: to be published in Chaos, Solitons & Fractals

Deterministic non-local parity control and supercurrent-based detection in an Andreev molecule

Authors: Shang Zhu, Xiaozhou Yang, Mingli Liu, Min Wei, Yiping Jiao, Jiezhong He, Bingbing Tong, Junya Feng, Ziwei Dou, Peiling Li, Jie Shen, Xiaohui Song, Guangtong Liu, Zhaozheng Lyu, Dong Pan, Jianhua Zhao, Li Lu, Fanming Qu

Abstract: The ability to manipulate and detect the parity of quantum states in superconductor-semiconductor hybrid systems is pivotal to realizing the promise of topological quantum computation. However, as these architectures scale toward artificial Kitaev chains with phase-control loops, local accessibility becomes restricted, constraining conventional local parity control and detection. While Andreev mol… ▽ More The ability to manipulate and detect the parity of quantum states in superconductor-semiconductor hybrid systems is pivotal to realizing the promise of topological quantum computation. However, as these architectures scale toward artificial Kitaev chains with phase-control loops, local accessibility becomes restricted, constraining conventional local parity control and detection. While Andreev molecules offer a platform for non-local intervention, deterministic protocols for parity manipulation have yet to be experimentally established. Here, we demonstrate deterministic non-local control over the parity configuration of a quantum dot (QD) by electrically modulating the coherent hybridization with a spatially adjacent QD within an Andreev molecule. By systematically investigating three distinct joint parity configuration regimes in the elastic co-tunneling limit, we experimentally uncover the operational conditions for this non-local control. In conjunction with theoretical simulations establishing a global phase diagram, we identify a set of universal selection rules governing parity transitions, dictated by the symmetry-imposed interplay between the joint parity configuration and the dominant inter-dot coupling mechanism (elastic co-tunneling vs. crossed Andreev reflection). Furthermore, we establish the supercurrent, directly signaled by zero-bias conductance peaks, as an intrinsic, sensor-free probe of the parity configuration, obviating the need for auxiliary charge sensors. Our results provide a validated physical framework for parity engineering, offering a key building block for scalable, multi-QD superconducting architectures. △ Less

Submitted 27 January, 2026; originally announced January 2026.

Comments: 34 pages, 11 figures

Artificial Intelligence-Enabled Holistic Design of Catalysts Tailored for Semiconducting Carbon Nanotube Growth

Authors: Liu Qian, Yue Li, Ying Xie, Jian Zhang, Pai Li, Yue Yu, Zhe Liu, Feng Ding, Jin Zhang

Abstract: Catalyst design is crucial for materials synthesis, especially for complex reaction networks. Strategies like collaborative catalytic systems and multifunctional catalysts are effective but face challenges at the nanoscale. Carbon nanotube synthesis contains complicated nanoscale catalytic reactions, thus achieving high-density, high-quality semiconducting CNTs demands innovative catalyst design.… ▽ More Catalyst design is crucial for materials synthesis, especially for complex reaction networks. Strategies like collaborative catalytic systems and multifunctional catalysts are effective but face challenges at the nanoscale. Carbon nanotube synthesis contains complicated nanoscale catalytic reactions, thus achieving high-density, high-quality semiconducting CNTs demands innovative catalyst design. In this work, we present a holistic framework integrating machine learning into traditional catalyst design for semiconducting CNT synthesis. It combines knowledge-based insights with data-driven techniques. Three key components, including open-access electronic structure databases for precise physicochemical descriptors, pre-trained natural language processing-based embedding model for higher-level abstractions, and physical - driven predictive models based on experiment data, are utilized. Through this framework, a new method for selective semiconducting CNT synthesis via catalyst - mediated electron injection, tuned by light during growth, is proposed. 54 candidate catalysts are screened, and three with high potential are identified. High-throughput experiments validate the predictions, with semiconducting selectivity exceeding 91% and the FeTiO3 catalyst reaching 98.6%. This approach not only addresses semiconducting CNT synthesis but also offers a generalizable methodology for global catalyst design and nanomaterials synthesis, advancing materials science in precise control. △ Less

Submitted 17 December, 2025; originally announced December 2025.

Comments: 16 pages and 4 figures in main text

Exceptional Alkaline Methanol Electrooxidation on Bi-modified Pt3M Intermetallics: Kinetic Origins and an OH Binding Energy Descriptor

Authors: Lecheng Liang, Hengyu Li, Shao Ye, Peng Li, Kaiyang Xu, Jinhui Liang, Binwen Zeng, Bo Shen, Taisuke Ozaki, Zhiming Cui

Abstract: The exploration of advanced CO-free catalysts and clarifying the ambiguous kinetic origins and governing factors would undoubtedly open up opportunities to overcome the sluggish kinetics of methanol electrooxidation and promote the development of direct methanol fuel cells. Herein, we constructed a family of Bi-modified Pt3M intermetallic catalysts (Bi-Pt3M/C, M=Cr, Mn, Co, Zn, In, Ga, and Sn) tha… ▽ More The exploration of advanced CO-free catalysts and clarifying the ambiguous kinetic origins and governing factors would undoubtedly open up opportunities to overcome the sluggish kinetics of methanol electrooxidation and promote the development of direct methanol fuel cells. Herein, we constructed a family of Bi-modified Pt3M intermetallic catalysts (Bi-Pt3M/C, M=Cr, Mn, Co, Zn, In, Ga, and Sn) that follow CO-free dominated pathway and exhibit exceptional catalytic activity. More significantly, leveraging this platform, we have identified the pivotal factor governing the reaction kinetics in CO-free pathway, namely OH binding energy (OHBE). This arises because the rate-determining step (RDS) encompasses both C-H bond activation and water dissociation, whose respective barriers can be reflected by the OHBE. Accordingly, OHBE can act as an activity descriptor. Specifically, Bi-Pt3In/C stands out from other Bi-Pt3M/C and delivers the unprecedented mass activity of 36.7 A mgPt-1 at peak potential, far exceeding state-of-the-art Pt-based catalysts reported to date. Taking Bi-Pt3In/C as a proof of concept, we clearly elucidate the origin of enhanced MOR activity by combining theoretical calculations, kinetic isotope effects, and formaldehyde electrooxidation. Moreover, there exhibits a volcano-type trend between OHBE and the activity of Bi-Pt3M/C. Beyond the discovery of ultrahigh-performance catalysts, these findings provide a detailed mechanistic picture of RDS and offer an innovative design principle for advanced catalysts. △ Less

Submitted 12 December, 2025; originally announced December 2025.

Three-body interaction in a magnon-Andreev-superconducting qubit system: collapse-revival phenomena and entanglement redistribution

Authors: Sheng Zhao, Peng-Bo Li

Abstract: Three-body interactions are fundamental for realizing novel quantum phenomena beyond pairwise physics, yet their implementation -- particularly among distinct quantum systems -- remains challenging. Here, we propose a hybrid quantum architecture comprising a magnonic mode (in a YIG sphere), an Andreev spin qubit (ASQ), and a superconducting qubit (SCQ), to realize a strong three-body interaction a… ▽ More Three-body interactions are fundamental for realizing novel quantum phenomena beyond pairwise physics, yet their implementation -- particularly among distinct quantum systems -- remains challenging. Here, we propose a hybrid quantum architecture comprising a magnonic mode (in a YIG sphere), an Andreev spin qubit (ASQ), and a superconducting qubit (SCQ), to realize a strong three-body interaction at the single-quantum level. Leveraging the spin-dependent supercurrent and circuit-integration flexibility of the ASQ, it is possible to engineer a strong tripartite coupling that jointly excites both qubits upon magnon annihilation (or excites magnons and SCQs upon ASQ deexcitation). Through analytical and numerical studies, we demonstrate that this interaction induces synchronized collapse and revival in qubit populations when the magnon is initially prepared in a coherent state. Notably, during the collapse region -- where populations remain static -- the entanglement structure undergoes a dramatic and continuous reorganization. We show that the genuine tripartite entanglement is redistributed into bipartite entanglement between the two qubits, and vice versa, with the total entanglement conserved. These phenomena, unattainable via two-body couplings, underscore the potential of three-body interactions for exploring intrinsically new quantum effects and advancing hybrid quantum information platforms. △ Less

Submitted 10 December, 2025; originally announced December 2025.

Comments: 7+17 pages, 3+9 figures

Demonstration of on-chip all-optical switching of magnetization in integrated photonics

Authors: Pingzhi Li, Gijs W. A. Simons, Tianyu Zhang, Philip P. J. Schrinner, Sohrab Kamyar, Ronald Dekker, Diana C. Leitao, Reinoud Lavrijsen, Yuqing Jiao, Bert Koopmans

Abstract: Ultrafast all-optical magnetization switching (AOS) holds great promise for nextgeneration spintronic memory and hybrid spintronic-photonic systems. However, most implementations to date rely on bulky free-space optical setups, limiting scalability and practical integration. As a critical step toward integrated applications, we demonstrate single-pulse AOS within a silicon nitride (Si3N4) photonic… ▽ More Ultrafast all-optical magnetization switching (AOS) holds great promise for nextgeneration spintronic memory and hybrid spintronic-photonic systems. However, most implementations to date rely on bulky free-space optical setups, limiting scalability and practical integration. As a critical step toward integrated applications, we demonstrate single-pulse AOS within a silicon nitride (Si3N4) photonic integrated circuit. Using trains of femtosecond laser pulses guided through on-chip waveguides, we achieve deterministic toggle switching in a sub-micron out-of-plane Co/Gd Hall cross patterned directly atop the photonic waveguide. Electrical readout via the anomalous Hall effect reveals a switching contrast of up to 90% for 500 nm-wide devices. In larger Hall crosses, the contrast decreases and switching becomes stochastic, consistent with spatially non-uniform optical absorption as confirmed by finite-element simulations. This behavior is hypothetically attributed to domain wall relaxation and thermally assisted (de)pinning processes within partially switched regions. Our results highlight the critical role of device scaling in achieving robust on-chip AOS and establish a foundation for ultrafast, energy-efficient, and fully integrated spintronic-photonic platforms. △ Less

Submitted 4 November, 2025; originally announced November 2025.

Comments: 13 pages, 3 figures, 4 supplementary information appendices

Exchange operation of Majorana zero modes in topological insulator-based Josephson trijunctions

Authors: Yunxiao Zhang, Zhaozheng Lyu, Xiang Wang, Yukun Shi, Duolin Wang, Xiaozhou Yang, Enna Zhuo, Bing Li, Yuyang Huang, Zenan Shi, Anqi Wang, Heng Zhang, Fucong Fei, Xiaohui Song, Peiling Li, Bingbing Tong, Ziwei Dou, Jie Shen, Guangtong Liu, Fanming Qu, Fengqi Song, Li Lu

Abstract: Majorana zero modes are anyons obeying non-Abelian exchange statistics distinct from fermions or bosons. While significant progresses have been achieved in the past two decades in searching for these exotic excitations in solid-state systems, their non-Abelian nature remains unverified, as definitive proof requires braiding operations. Here, we report preliminarily experimental advances in creatin… ▽ More Majorana zero modes are anyons obeying non-Abelian exchange statistics distinct from fermions or bosons. While significant progresses have been achieved in the past two decades in searching for these exotic excitations in solid-state systems, their non-Abelian nature remains unverified, as definitive proof requires braiding operations. Here, we report preliminarily experimental advances in creating, manipulating, and exchanging the presumed Majorana zero modes in an envelope-shaped Josephson device composed of multiple trijunctions on a topological insulator surface. We observed the signatures of in-gap states migration consistent with the expectations of the Fu-Kane model, supporting the realization of an exchange operation. This work would establish a critical pathway toward ultimately braiding Majorana zero modes in the Fu-Kane scheme of topological quantum computation. △ Less

Submitted 2 November, 2025; originally announced November 2025.

Comments: 4 pages, 4 figures

Transverse and Unidirectional Spin Pumping

Authors: Ping Li, Chengyuan Cai, Tao Yu

Abstract: Conventional spin pumping, driven by magnetization dynamics, is longitudinal since the pumped spin current flows normal to the interface between the ferromagnet and the conductor. We predict \textit{Hall-type/transverse} and \textit{unidirectional} spin pumping into conductors by near-field electromagnetic radiation emitted by, \textit{e.g.}, magnetization dynamics. The joint effect of the electri… ▽ More Conventional spin pumping, driven by magnetization dynamics, is longitudinal since the pumped spin current flows normal to the interface between the ferromagnet and the conductor. We predict \textit{Hall-type/transverse} and \textit{unidirectional} spin pumping into conductors by near-field electromagnetic radiation emitted by, \textit{e.g.}, magnetization dynamics. The joint effect of the electric and magnetic fields results in a pure spin current flowing parallel to the interface, i.e., a Hall-type spin pumping, which is highly efficient due to the strong coupling to the electric field. Such a transverse spin current is unidirectional, with the spatial distribution controlled by the magnetization direction. Our finding reveals a robust approach for generating and manipulating spin currents in future low-dimensional spintronic and orbitronic devices. △ Less

Submitted 8 January, 2026; v1 submitted 30 October, 2025; originally announced October 2025.

Comments: 14 pages, 6 figures

Intrinsic Non-linearity of Josephson Junctions as an Alternative Origin of the Missing First Shapiro Step

Authors: Lei Xu, Shuhang Mai, Manzhang Xu, Xue Yang, Lihong Hu, Xinyi Zheng, Sicheng Zhou, Siyuan Zhou, Bingbing Tong, Xiaohui Song, Jie Shen, Zhaozheng Lyu, Ziwei Dou, Xiunian Jing, Fanming Qu, Peiling Li, Guangtong Liu, Li Lu

Abstract: The missing first Shapiro step in microwave-irradiated Josephson junctions has been widely interpreted as a hallmark of Majorana bound states. However, conventional mechanisms like junction underdamping or Joule heating can produce similar signatures. Here, we demonstrate that the intrinsic non-linear current-voltage characteristic of low-to-moderate transparency junctions can also suppress the fi… ▽ More The missing first Shapiro step in microwave-irradiated Josephson junctions has been widely interpreted as a hallmark of Majorana bound states. However, conventional mechanisms like junction underdamping or Joule heating can produce similar signatures. Here, we demonstrate that the intrinsic non-linear current-voltage characteristic of low-to-moderate transparency junctions can also suppress the first step, accompanied by distinctive zigzag boundaries between the zeroth and first step at intermediate driving frequencies. Microwave measurements on Al/WTe2 junctions and numerical simulations of a non-linear resistively and capacitively shunted junction model reveal the first step collapse induced by switching jumps of current, together with zigzag features absent in scenarios solely driven by finite \b{eta} or Joule heating. This zigzag signature therefore provides a crucial diagnostic tool, emphasizing the necessity of comprehensive analysis of microwave spectra before attributing the absence of the first Shapiro step to Majorana physics. △ Less

Submitted 22 October, 2025; originally announced October 2025.

Comments: 18 pages, 4 figures

Exotic Surface Stripe Orders in Correlated Kagome Metal CsCr3Sb5

Authors: Yunxing Li, Peigen Li, Taimin Miao, Rui Xu, Yongqing Cai, Neng Cai, Bo Liang, Han Gao, Hanbo Xiao, Yongzhen Jiang, Jiefeng Cao, Fangyuan Zhu, Hongkun Wang, Jincheng Xie, Jingcheng Li, Zhongkai Liu, Chaoyu Chen, Yunwei Zhang, X. J. Zhou, Dingyong Zhong, Huichao Wang, Jianwei Huang, Donghui Guo

Abstract: The newly discovered kagome superconductor CsCr3Sb5 exhibits distinct features with flat bands and unique magnetism, providing a compelling platform for exploring novel quantum states of correlated electron systems. Emergent charge order in this material is a key for understanding unconventional superconductivity, but it remains unexplored at the atomic scale and the underlying physics is elusive.… ▽ More The newly discovered kagome superconductor CsCr3Sb5 exhibits distinct features with flat bands and unique magnetism, providing a compelling platform for exploring novel quantum states of correlated electron systems. Emergent charge order in this material is a key for understanding unconventional superconductivity, but it remains unexplored at the atomic scale and the underlying physics is elusive. Here, we identify and unreported stripe orders on the surface which are distinct from the bulk and investigate the underlying bulk electronic properties using a combination of scanning tunneling microscopy (STM), angle-resolved photoemission spectroscopy (ARPES) and density functional theory (DFT) calculations. Specifically, a mixture of 2a0 * a0 and 3a0 * a0 stripe order is found on Cs-terminated surface while 4a0 * root3a0 stripe order is found on the Sb-terminated surface. The electronic spectra exhibit strongly correlated features resembling that of high temperature superconductors, with kagome flat bands lying about 330 meV above EF, suggesting that the electron correlations arise from Coulomb interactions and Hund's coupling. Moreover, a distinct electron-boson coupling mode is observed at approximately 100 meV. These findings provide new insights into the interplay between surface and bulk charge orders in this strongly correlated kagome system. △ Less

Submitted 14 October, 2025; originally announced October 2025.

Comments: 21 pages, 5 figures

Broad nonlocal spectrum in the Pb-InSb hybrid three terminals for potential realization of Kitaev chains

Authors: Guoan Li, Xiaofan Shi, Ruixuan Zhang, Yuxiao Song, Marco Rossi, Ghada Badawy, Zhiyuan Zhang, Anqi Wang, Xingchen Guo, Xiao Deng, Xiao Chen, Liangqian Xu, Bingbing Tong, Peiling Li, Xiaohui Song, Zhaozheng Lyu, Guangtong Liu, Fanming Qu, Michał P. Nowak, Paweł Wójcik, Ziwei Dou, Erik P. A. M. Bakkers, Li Lu, Jie Shen

Abstract: Hybrid superconductor-semiconductor(SC-SM) nanowires remain one of the foremost platforms for engineering topological superconductivity and Majorana zero modes(MZMs) towards fault-tolerant topological qubits, especially with the rapid development of artificial Kitaev chains. In contrast to the widely used aluminum(Al)-based hybrids, lead(Pb) offers a bulk superconducting gap of ~1.4meV and a criti… ▽ More Hybrid superconductor-semiconductor(SC-SM) nanowires remain one of the foremost platforms for engineering topological superconductivity and Majorana zero modes(MZMs) towards fault-tolerant topological qubits, especially with the rapid development of artificial Kitaev chains. In contrast to the widely used aluminum(Al)-based hybrids, lead(Pb) offers a bulk superconducting gap of ~1.4meV and a critical temperature of ~7.2K, giving rise to a proximity-induced gap that is roughly five times larger than that obtained with Al. Here we present the first three-terminal Pb-hybrid devices and perform nonlocal differential-conductance spectroscopy on this platform. The nonlocal measurement simultaneously resolves a dual-gap feature of the parent Pb gap and the large, hard, gate-tunable induced superconducting gap, distinguished by a switch between electron- and hole-like dissipation processes. Within the induced gap we observe several types of Andreev bound states(ABSs) that undergo singlet-doublet transitions. Moreover, by tuning gate voltages we achieve gate-controlled resonating sign reversals of the nonlocal conductance, identifying three distinct regimes that correspond to different configurations of quantum-dot(QD) resonances(single-resonance, double-resonance, and series-resonance). Finally, the coupling between ABSs and QDs also present and can be modulated from the weak- to strong-coupling limit, indicating the feasibility of realizing the artificial Kitaev chains. Crucially, the robust nonlocal signatures persist up to temperatures(~1K) far above the operating temperature of Al-based devices thanks to the unusually large induced gap, thereby widening the accessible parameter space greatly and underscoring the suitability of Pb-based hybrids for implementing warm temperature artificial Kitaev chains and the topological quantum devices protected by a substantially larger topological gap. △ Less

Submitted 11 October, 2025; originally announced October 2025.

Superconductivity and Electronic Structures of Nickelate Thin Film Superstructures

Authors: Zihao Nie, Yueying Li, Wei Lv, Lizhi Xu, Zhicheng Jiang, Peng Fu, Guangdi Zhou, Wenhua Song, Yaqi Chen, Heng Wang, Haoliang Huang, Junhao Lin, Jin-Feng Jia, Dawei Shen, Peng Li, Qi-Kun Xue, Zhuoyu Chen

Abstract: Ruddlesden-Popper (RP) nickelates have emerged as a crucial platform for exploring the mechanisms of high-temperature superconductivity. However, the Fermi surface topology required for superconductivity remains elusive. Here, beyond the superconducting pure bilayer (2222) phase, we report the thin film growth and ambient-pressure superconductivity of monolayer-bilayer (1212) and bilayer-trilayer… ▽ More Ruddlesden-Popper (RP) nickelates have emerged as a crucial platform for exploring the mechanisms of high-temperature superconductivity. However, the Fermi surface topology required for superconductivity remains elusive. Here, beyond the superconducting pure bilayer (2222) phase, we report the thin film growth and ambient-pressure superconductivity of monolayer-bilayer (1212) and bilayer-trilayer (2323) superstructures, together with the absence of superconductivity in monolayer-trilayer (1313) superstructure, under identical compressive epitaxial strain. The onset superconducting transition temperatures range from 46 to 50 K, exceeding the McMillan limit. Angle-resolved photoemission spectroscopy reveals key Fermi surface differences in these atomically-engineered structures. In superconducting 1212 and 2222 films, a dispersive hole-like band ($γ^{\mathrm{II}}$) forms an underlying Fermi pocket, surrounding the Brillouin zone corner. In contrast, the top of the flat band ($γ^{\mathrm{III}}$) is observed ~70 meV below $E_\text{F}$ in the non-superconducting 1313 films. Particularly, the superconducting 2323 films host both $γ^{\mathrm{II}}$ and $γ^{\mathrm{III}}$ bands. The polarization dependence of the $γ$ bands reveals their Ni $d_{z^2}$ origin. Our findings expand the family of ambient-pressure nickelate superconductors and establish a connection between structural configuration, electronic structure, and the emergence of superconductivity in nickelates. △ Less

Submitted 13 April, 2026; v1 submitted 3 September, 2025; originally announced September 2025.

Journal ref: Nature 2026

A non-invasive dry-transfer method for fabricating mesoscopic devices on sensitive materials

Authors: Zhongmou Jia, Yiwen Ma, Zhongchen Xu, Xue Yang, Jianfei Xiao, Jiezhong He, Yunteng Shi, Zhiyuan Zhang, Duolin Wang, Sicheng Zhou, Bingbing Tong, Peiling Li, Ziwei Dou, Xiaohui Song, Guangtong Liu, Jie Shen, Zhaozheng Lyu, Youguo Shi, Jiangping Hu, Li Lu, Fanming Qu

Abstract: Many materials with novel or exotic properties are highly sensitive to environmental factors such as air, solvents, and heat, which complicates device fabrication and limits their potential applications. Here, we present a universal submicron fabrication method for mesoscopic devices using a dry-transfer technique, tailored specifically for sensitive materials. This approach utilizes PMMA masks, c… ▽ More Many materials with novel or exotic properties are highly sensitive to environmental factors such as air, solvents, and heat, which complicates device fabrication and limits their potential applications. Here, we present a universal submicron fabrication method for mesoscopic devices using a dry-transfer technique, tailored specifically for sensitive materials. This approach utilizes PMMA masks, combined with a water-dissoluble coating as a sacrificial layer, to ensure that sensitive materials are processed without exposure to harmful environmental conditions. The entire fabrication process is carried out in a glove box, employing dry techniques that avoid air, solvents, and heat exposure, culminating in an encapsulation step. We demonstrate the utility of this method by fabricating and characterizing K2Cr3As3 and WTe2 devices, a one- and two-dimensional material, respectively. The results show that our technique preserves the integrity of the materials, provides excellent contact interfaces, and is broadly applicable to a range of sensitive materials. △ Less

Submitted 26 August, 2025; originally announced August 2025.

Journal ref: Appl. Phys. Lett. 126, 243504 (2025)

Josephson diode effect in nanowire-based Andreev molecules

Authors: Shang Zhu, Yiwen Ma, Jiangbo He, Xiaozhou Yang, Zhongmou Jia, Min Wei, Yiping Jiao, Jiezhong He, Enna Zhuo, Xuewei Cao, Bingbing Tong, Ziwei Dou, Peiling Li, Jie Shen, Xiaohui Song, Zhaozheng Lyu, Guangtong Liu, Dong Pan, Jianhua Zhao, Bo Lu, Li Lu, Fanming Qu

Abstract: Superconducting systems exhibit non-reciprocal current transport under certain conditions of symmetry breaking, a phenomenon known as the superconducting diode effect. This effect allows for perfect rectification of supercurrent, and has received considerable research interest. We report the observation of the Josephson diode effect (JDE) in nanowire-based Andreev molecules, where the time-reversa… ▽ More Superconducting systems exhibit non-reciprocal current transport under certain conditions of symmetry breaking, a phenomenon known as the superconducting diode effect. This effect allows for perfect rectification of supercurrent, and has received considerable research interest. We report the observation of the Josephson diode effect (JDE) in nanowire-based Andreev molecules, where the time-reversal and spatial-inversion symmetries of a Josephson junction (JJ) can be nonlocally broken by coherently coupling to another JJ. The JDE can be controlled using both non-local phase and gate voltages. Notably, the non-local phase can induce a sign reversal of the diode efficiency, a manifestation of regulating the probabilities of double elastic cotunneling and double-crossed Andreev reflection. Additionally, the diode efficiency can be further modulated by local and non-local gate voltages, exhibiting a central-peak feature in the gate-voltage space. Our theoretical calculations of the energy spectrum and the Josephson currents align well with the experimental results. These results demonstrate the non-local regulation of the JDE in Andreev molecules, offering significant implications for the control of multi-JJ devices and the development of advanced superconducting devices. △ Less

Submitted 20 August, 2025; v1 submitted 18 August, 2025; originally announced August 2025.

Comments: 24 pages, 13 figures

Journal ref: Communications Physics 8, 330 (2025)

Optimizing the depth-dependent nitrogen-vacancy center quantum sensor in diamane

Authors: Pei Li, Guanjian Hu, Xiao Yu, Bing Huang, Song Li

Abstract: Negatively charged nitrogen-vacancy (NV) center in diamond is the representative solid state defect qubit for quantum information science, offering long coherence time at room temperature. To achieve high sensitivity and spatial resolution, shallow NV center near the surface are preferred. However, shallow NV center suffers from surface states and spin noise which reduce the photostability and coh… ▽ More Negatively charged nitrogen-vacancy (NV) center in diamond is the representative solid state defect qubit for quantum information science, offering long coherence time at room temperature. To achieve high sensitivity and spatial resolution, shallow NV center near the surface are preferred. However, shallow NV center suffers from surface states and spin noise which reduce the photostability and coherence time. In this work, we systematically study the NV center in recently reported two-dimensional diamond, known as diamane--using first-principles calculations. We show that the quantum confinement in finite-layer diamane, with appropriate surface passivation, could significantly modify the band structure. In particular, we identify oxygen surface termination capable of hosting NV center in diamane while optimizing photostability compared to bulk diamond. Furthermore, layer-dependent NV center demonstrates tunable zero-phonon-line and suppressed phonon side band, while retaining long coherence time. Our findings highlight diamane as a promising platform for NV-based quantum information processing with improved optical properties and stability △ Less

Submitted 11 August, 2025; originally announced August 2025.

Comments: 8 pages, 3 figures

Density of States (Gate) - Controlled Andreev Molecule and Sensor

Authors: Xiaofan Shi, Ziwei Dou, Guoan Li, Dong Pan, Yuxiao Song, Anqi Wang, Zhiyuan Zhang, Xingchen Guo, Xiao Deng, Ruixuan Zhang, Liangqian Xu, Xiao Chen, Yupeng Li, Bingbing Tong, Xiaohui Song, Zhaozheng Lyu, Peiling Li, Fanming Qu, Guangtong Liu, Jianhua Zhao, Li Lu, Jie Shen

Abstract: Topological quantum computing typically relies on topological Andreev bound states (ABSs) engineered in hybrid superconductor-semiconductor devices, where gate control offers key advantages. While strong Zeeman fields can induce such states, an alternative approach emerges through Andreev molecules -- closely spaced, coupled ABSs, also key building-block for Kitaev chain -- that enable topological… ▽ More Topological quantum computing typically relies on topological Andreev bound states (ABSs) engineered in hybrid superconductor-semiconductor devices, where gate control offers key advantages. While strong Zeeman fields can induce such states, an alternative approach emerges through Andreev molecules -- closely spaced, coupled ABSs, also key building-block for Kitaev chain -- that enable topological behavior without high magnetic fields. However, existing Andreev molecules are controlled via magnetic flux in superconducting loops, limiting scalability. Here, we introduce a gate-controlled Andreev molecule, where electrostatic tuning of the density of states in one site nonlocally enhances the critical current of another. This eliminates superconducting loops, offering superior tunability, scalability, and sensitivity. We further extend such an Andreev molecule to a multi-site Kitaev chain, and a noninvasive sensor resolving single-Cooper-pair charge for parity readout. This platform bridges the gap between scalable ABS engineering and high-sensitivity quantum sensing, advancing the development for constructing and parity-readout in topological ABSs and long Kitaev chains towards topological qubits. △ Less

Submitted 6 August, 2025; originally announced August 2025.

Orbital-selective charge transfer drives two-step negative thermal expansion structural transitions in PbTa2Se4

Authors: Peng Li, Xiaohui Yang, Wenhua Song, Zhefeng Lou, Tongrui Li, Zhengtai Liu, Zhu'an Xu, Zhuoyu Chen, Xiao Lin, Yang Liu

Abstract: The negative thermal expansion (NTE) effect has been found generally combined with structural phase transitions. However, the charge and orbital freedoms of the NTE has not been well studied. This study employs angle-resolved photoemission spectroscopy and first-principles calculations to elucidate the charge and orbital kinetics of the anomalous two-step negative thermal expansion structural phas… ▽ More The negative thermal expansion (NTE) effect has been found generally combined with structural phase transitions. However, the charge and orbital freedoms of the NTE has not been well studied. This study employs angle-resolved photoemission spectroscopy and first-principles calculations to elucidate the charge and orbital kinetics of the anomalous two-step negative thermal expansion structural phase transitions in PbTa2Se4. As the temperature decreases, each transition undergoes a similar block-layer sliding, although the charge transfer behaviors differ significantly. During the first transition, charge is mainly transferred from the Pb 6pz orbital to an M-shaped band below the Fermi level, barely altering the Fermi surface. In contrast, the second transition involves modifications to both the Fermi surface and charge-transfer orbitals, with charge selectively transferred from Pb 6px/py orbitals to Ta 5dz2 orbitals and a decrease of the Fermi pockets formed by Pb 6px/py orbitals. Furthermore, a small pressure can easily tune the base structure phase among the three phases and the corresponding superconductivity. Therefore, our findings reveal that the orbital-selective charge transfer drives the unusual structure transition in PbTa2Se4, offering new insights into the NTE mechanisms and providing a unique window to study the pressure-tuned superconductivity in this metal-intercalated transition chalcogenides. △ Less

Submitted 29 July, 2025; originally announced July 2025.

Comments: 4 figures

Atomic-Scale Heterogeneity of Hydrogen in Metal Hydrides Revealed by Electron Ptychography

Authors: Pengcheng Li, Chenglin Pua, Zehao Dong, Zhengxiong Su, Tao Liu, Chao Cai, Huahai Shen, Lin Gu, Zhen Chen

Abstract: Hydrogen plays critical roles in materials science, particularly for advancing technologies in hydrogen storage and phase manipulation, while also posing challenges like hydrogen embrittlement. Understanding its behavior, vital for improving material properties, requires precise determination of atomic-scale distribution-a persistent challenge due to hydrogen's weak electron scattering and high mo… ▽ More Hydrogen plays critical roles in materials science, particularly for advancing technologies in hydrogen storage and phase manipulation, while also posing challenges like hydrogen embrittlement. Understanding its behavior, vital for improving material properties, requires precise determination of atomic-scale distribution-a persistent challenge due to hydrogen's weak electron scattering and high mobility, as well as the limitations of conventional transmission electron microscopy. We demonstrate that multislice electron ptychography (MEP) overcomes these constraints through three key advances: exceptional sensitivity for hydrogen occupancy, three-dimensional quantification, and picometer-level precision in atomic positioning. Experimentally, MEP resolves heterogeneous hydrogen distributions and quantifies hydrogen-induced lattice displacements with picometer precision in multi-principal-element alloy hydrides. This work demonstrates MEP as a transformative method for directly probing hydrogen atoms in solids, unlocking fundamental understanding of hydrogen's impact on material properties. △ Less

Submitted 24 July, 2025; originally announced July 2025.

Comments: 32 pages, 4 main figures, and 13 SI figures

An eco-friendly universal strategy via ribavirin to achieve highly efficient and stable perovskite solar cells

Authors: Xianhu Wu, Gaojie Xia, Guanglei Cui, Jieyu Bi, Nian Liu, Jiaxin Jiang, Jilong Sun, Luyang Liu, Ping Li, Ning Lu, Zewen Zuo, Min Gu

Abstract: The grain boundaries of perovskite films prepared by the solution method are highly disordered, with a large number of defects existing at the grain boundaries. These defect sites promote the decomposition of perovskite. Here, we use ribavirin obtained through bacillus subtilis fermentation to regulate the crystal growth of perovskite, inducing changes in the work function and energy level structu… ▽ More The grain boundaries of perovskite films prepared by the solution method are highly disordered, with a large number of defects existing at the grain boundaries. These defect sites promote the decomposition of perovskite. Here, we use ribavirin obtained through bacillus subtilis fermentation to regulate the crystal growth of perovskite, inducing changes in the work function and energy level structure of perovskite, which significantly reduces the defect density. Based on density functional theory calculations, the defect formation energies of VI, VMA, VPb, and PbI in perovskite are improved. This increases the open-circuit voltage of perovskite solar cells (PSCs) (ITO/PEDOT:PSS/perovskite/PCBM/BCP/Ag) from 1.077 to 1.151 V, and the PCE increases significantly from 17.05% to 19.86%. Unencapsulated PSCs were stored in the environment (humidity approximately 35+-5%) for long-term stability testing. After approximately 900 hours of storage, the PCE of the ribavirin-based device retains 84.33% of its initial PCE, while the control-based device retains only 13.44% of its initial PCE. The PCE of PSCs (ITO/SnO2/perovskite/Spiro-OMETAD/Ag) is increased from 20.16% to 22.14%, demonstrating the universality of this doping method. This universal doping strategy provides a new approach for improving the efficiency and stability of PSCs using green molecular doping strategies. △ Less

Submitted 2 July, 2025; originally announced July 2025.

Gap reopening as signature of coupling between Majorana zero modes in Sn-(Bi,Sb)2(Te,S)3-based Josephson trijunctions

Authors: Duolin Wang, Xiang Zhang, Yunxiao Zhang, Heng Zhang, Fucong Fei, Xiang Wang, Bing Li, Xiaozhou Yang, Yukun Shi, Zhongmou Jia, Enna Zhuo, Yuyang Huang, Anqi Wang, Zenan Shi, Zhaozheng Lyu, Xiaohui Song, Peiling Li, Bingbing Tong, Ziwei Dou, Jie Shen, Guangtong Liu, Fanming Qu, Fengqi Song, Li Lu

Abstract: In the past two decades, enormous efforts have been made to search for possible platforms and schemes to implement topological quantum computation (TQC). In exploring the Fu-Kane scheme of TQC based on Josephson trijunctions constructed on topological insulators, the expected Majorana phase diagram of a single trijunction has been experimentally verified. If Majorana zero modes indeed exist in thi… ▽ More In the past two decades, enormous efforts have been made to search for possible platforms and schemes to implement topological quantum computation (TQC). In exploring the Fu-Kane scheme of TQC based on Josephson trijunctions constructed on topological insulators, the expected Majorana phase diagram of a single trijunction has been experimentally verified. If Majorana zero modes indeed exist in this kind of trijunctions, coupling between them in multiple trijunction devices would be further expected. In this study, we fabricated Josephson devices containing two adjacent Josephson trijunctions on the surface of Sn-(Bi,Sb)2(Te,S)3, and observed that the minigap reopens for both trijunctions in their phase spaces where a closure would otherwise be expected if the trijunctions existed independently. Our findings would provide new experimental support for the validity of the Fu-Kane theory and instill further confidence in advancing along the TQC scheme proposed by Fu and Kane. △ Less

Submitted 8 July, 2025; originally announced July 2025.

Comments: 3 figures

Quantized conductance in a CVD-grown nanoribbon with hidden Rashba effect

Authors: Jianfei Xiao, Yiwen Ma, Congwei Tan, Kui Zhao, Yunteng Shi, Bingbing Tong, Peiling Li, Ziwei Dou, Xiaohui Song, Guangtong Liu, Jie Shen, Zhaozheng Lyu, Li Lu, Hailin Peng, Fanming Qu

Abstract: Quantized conductance in quasi-one-dimensional systems not only provides a hallmark of ballistic transport, but also serves as a gateway for exploring quantum phenomena. Recently, a unique hidden Rashba effect attracts tremendous attention, which arises from the compensation of opposite spin polarizations of a Rashba bilayer in inversion symmetric crystals with dipole fields, such as bismuth oxyse… ▽ More Quantized conductance in quasi-one-dimensional systems not only provides a hallmark of ballistic transport, but also serves as a gateway for exploring quantum phenomena. Recently, a unique hidden Rashba effect attracts tremendous attention, which arises from the compensation of opposite spin polarizations of a Rashba bilayer in inversion symmetric crystals with dipole fields, such as bismuth oxyselenide ($\mathrm{Bi}_{2}\mathrm{O}_{2}\mathrm{Se}$). However, investigating this effect utilizing conductance quantization is still challenging. Here we report the conductance quantization observed in a chemical vapor deposition (CVD)-grown high-mobility $\mathrm{Bi}_{2}\mathrm{O}_{2}\mathrm{Se}$ nanoribbon, where quantized conductance plateaus up to $44\cdot 2e^{2}/{h}$ ($e$ is the elementary charge, $h$ is the Planck constant, and the factor $2$ results from spin degeneracy) are achieved at zero magnetic field. Due to the hidden Rashba effect, the quantized conductance remains in multiples of $2e^{2}/{h}$ without Zeeman splitting even under magnetic field up to $12$ T. Moreover, within a specific range of magnetic field, the plateau sequence exhibits the Pascal triangle series, namely $(1,3,6,10,15\dots )\cdot 2e^{2}/{h}$, reflecting the interplay of size quantization in two transverse directions. These observations are well captured by an effective hidden Rashba bilayer model. Our results demonstrate $\mathrm{Bi}_{2}\mathrm{O}_{2}\mathrm{Se}$ as a compelling platform for spintronics and the investigation of emergent phenomena. △ Less

Submitted 7 July, 2025; originally announced July 2025.

Comments: 16 pages, 4 figures

Journal ref: Phys. Rev. Lett. 136, 046302 (2026)

Type III Valley Polarization and Anomalous Valley Hall Effect in Two-Dimensional Non-Janus and Janus Altermagnet Fe2WS2Se2

Authors: Yanchao She, Yiding Wang, Hanbo Sun, Chao Wu, Weixi Zhang, Ping Li

Abstract: Exploiting the valley degree of freedom introduces a novel paradigm for advancing quantum information technology. Currently, the investigation on spontaneous valley polarization mainly focuses on two major types of systems. One type magnetic systems by breaking the time-reversal symmetry, the other is ferroelectric materials through breaking the inversion symmetry. Might there be additional scenar… ▽ More Exploiting the valley degree of freedom introduces a novel paradigm for advancing quantum information technology. Currently, the investigation on spontaneous valley polarization mainly focuses on two major types of systems. One type magnetic systems by breaking the time-reversal symmetry, the other is ferroelectric materials through breaking the inversion symmetry. Might there be additional scenarios? Here, we propose to realize spontaneous valley polarization by breaking the mirror symmetry in the altermagnets, named type III valley polarization. Through symmetry analysis and first-principles calculations, we confirm that this mechanism is feasible in Non-Janus Fe2WS2Se2. Monolayer Non-Janus and Janus Fe2WS2Se2 are stable Neel-type antiferromagnetic state with the direct band gap semiconductor. More interestingly, their magnetic anisotropy energy exhibits the rare biaxial anisotropy and a four-leaf clover shape in the xy plane, while the xz and yz planes show the common uniaxial anisotropy. This originated from the fourth-order single ion interactions. More importantly, the valley splitting is spontaneously generated in the Non-Janus Fe2WS2Se2 due to the Mxy symmetry breaking, without requiring the SOC effect. Both the Non-Janus and Janus Fe2WS2Se2 exhibit diverse valley polarization and anomalous valley Hall effect properties. In addition, the magnitude and direction of valley polarization can be effectively tuned by the biaxial strain and magnetic field. Our findings not only expand the realization system of spontaneous valley polarization, but also provide a theoretical basis for the high-density storage of valley degrees of freedom. △ Less

Submitted 11 June, 2025; originally announced June 2025.

Comments: 10 pages, 7 figures

Enhanced and modulable induced superconducting gap and effective Landé g-factor in Pb-InSb hybrid devices

Authors: Guoan Li, Xiaofan Shi, Ziwei Dou, Guang Yang, Jiayu Shi, Marco Rossi, Ghada Badawy, Yuxiao Song, Ruixuan Zhang, Yupeng Li, Zhiyuan Zhang, Anqi Wang, Xingchen Guo, Xiao Deng, Bingbing Tong, Peiling Li, Zhaozheng Lyu, Guangtong Liu, Fanming Qu, Erik P. A. M. Bakkers, Michał P. Nowak, Paweł Wójcik, Li Lu, Jie Shen

Abstract: The hybrid system of a conventional superconductor (SC) on a semiconductor (SM) nanowire with strong spin-orbit coupling (SOC) represents a promising platform for achieving topological superconductivity and Majorana zero modes (MZMs) towards topological quantum computation. While aluminum (Al)-based hybrid nanowire devices have been widely utilized, their limited superconducting gap and intrinsic… ▽ More The hybrid system of a conventional superconductor (SC) on a semiconductor (SM) nanowire with strong spin-orbit coupling (SOC) represents a promising platform for achieving topological superconductivity and Majorana zero modes (MZMs) towards topological quantum computation. While aluminum (Al)-based hybrid nanowire devices have been widely utilized, their limited superconducting gap and intrinsic weak SOC as well as small Landé g-factor may hinder future experimental advancements. In contrast, we demonstrate that lead (Pb)-based hybrid quantum devices exhibit a remarkably large and hard proximity-induced superconducting gap, exceeding that of Al by an order of magnitude. By exploiting electrostatic gating to modulate wavefunction distribution and SC-SM interfacial coupling, this gap can be continuously tuned from its maximum value (~1.4 meV, matching the bulk Pb gap) down to nearly zero while maintaining the hardness. Furthermore, magnetic-field-dependent measurements reveal a radial evolution of the gap structure with anti-crossing feature, indicative of strong SOC and huge effective g-factors up to 76. These findings underscore the superior functionality of Pb-based hybrid systems, significantly advancing their potential for realizing and stabilizing MZMs and the further scalable topological quantum architectures. △ Less

Submitted 4 June, 2025; originally announced June 2025.

Magnon blockade in spin-magnon systems with frequency detuning

Authors: Sheng Zhao, Ya-Long Ren, Xin-Lei Hei, Xue-Feng Pan, Peng-Bo Li

Abstract: Magnon blockade is a physical mechanism for the preparation of a single-magnon source, which has important applications in quantum information processing. Here we propose a scheme for generating an optimal magnon blockade in the spin-magnon quantum system. By introducing frequency detuning between the magnon and the spin qubit of the NV center, the conventional magnon blockade and the unconvention… ▽ More Magnon blockade is a physical mechanism for the preparation of a single-magnon source, which has important applications in quantum information processing. Here we propose a scheme for generating an optimal magnon blockade in the spin-magnon quantum system. By introducing frequency detuning between the magnon and the spin qubit of the NV center, the conventional magnon blockade and the unconventional magnon blockade can be obtained under both strong and weak coupling, relaxing the requirements for coupling strength. Moreover, the conventional and unconventional magnon blockade can occur simultaneously when both the magnon and the spin qubit are driven. This allows the equal-time second-order correlation function to reach $10^{-8}$, about five orders of magnitude lower than that in previous works. Additionally, the time-delayed second-order correlation function avoids oscillation. Our study demonstrates the impact of frequency detuning on the magnon blockade and proposes methods to enhance the magnon blockade and relax the requirements for coupling strength through frequency detuning. △ Less

Submitted 27 May, 2025; originally announced May 2025.

Comments: 10 pages, 8 figures, to appear in PRA

Circuit-level-configurable Zero-field Superconducting Diodes: A Universal Platform Beyond Intrinsic Symmetry Breaking

Authors: Xiaofan Shi, Ziwei Dou, Dong Pan, Guoan Li, Yupeng Li, Anqi Wang, Zhiyuan Zhang, Xingchen Guo, Xiao Deng, Bingbing Tong, Zhaozheng Lyu, Peiling Li, Fanming Qu, Guangtong Liu, Jianhua Zhao, Jiangping Hu, Li Lu, Jie Shen

Abstract: Modern industry seeks next-generation microelectronics with ultra-low dissipation and noise beyond semiconducting systems, where the superconducting electronics offer promise. Its physical foundation is the superconducting diode effect (SDE) with nonreciprocal supercurrent. SDE has hitherto mainly relied on material-specific intrinsic symmetry breaking in superconductors, suffering from low yield,… ▽ More Modern industry seeks next-generation microelectronics with ultra-low dissipation and noise beyond semiconducting systems, where the superconducting electronics offer promise. Its physical foundation is the superconducting diode effect (SDE) with nonreciprocal supercurrent. SDE has hitherto mainly relied on material-specific intrinsic symmetry breaking in superconductors, suffering from low yield, controllability, and compatibility with further functional extension - an undesirable aspect for applications. Here, we demonstrated a field-free SDE due to the chemical potential shift from external circuit line resistance, which is generic and challenges the previous interpretations of the intrinsic symmetry breaking in superconductivity for zero-field SDE. Moreover, this SDE is circuit-level configurable since it can be electrically switched on/off with its polarity and efficiency precisely modulated via gate voltage and circuit reconfiguration, facilitating functional extension. Such a generic, controllable and extensible SDE addresses critical challenges in dissipationless circuit towards application, and thus establishes a robust platform for scalable superconducting electronics. △ Less

Submitted 23 May, 2025; originally announced May 2025.

Procedure of tuning up a three-site artificial Kitaev chain based on transmon measurements

Authors: Xiaozhou Yang, Zhaozheng Lyu, Xiang Wang, Enna Zhuo, Yunxiao Zhang, Duolin Wang, Yukun Shi, Yuyang Huang, Bing Li, Xiaohui Song, Peiling Li, Bingbing Tong, Ziwei Dou, Jie Shen, Guangtong Liu, Fanming Qu, Li Lu

Abstract: Artificial Kitaev chains (AKCs), formed of quantum dot-superconductor linear arrays, provide a promising platform for hosting Majorana bound states (MBSs) and implementing topological quantum computing. The main challenges along this research direction would include the tuning up of AKCs for hosting MBSs and the readout of the parity of the chains. In this work, we present a step-by-step procedure… ▽ More Artificial Kitaev chains (AKCs), formed of quantum dot-superconductor linear arrays, provide a promising platform for hosting Majorana bound states (MBSs) and implementing topological quantum computing. The main challenges along this research direction would include the tuning up of AKCs for hosting MBSs and the readout of the parity of the chains. In this work, we present a step-by-step procedure for tuning up a three-site AKC to its sweet spots based on the spectra of a transmon circuit which is integrated with the chain for the purpose of reading out the parity of the chain. The signatures of the transmon's plasma modes in each step, particular those related to the appearance of MBSs in the chain, will be given. We find that the sweet spots in a three-site AKC can be classified into three types based on the relative strengths of elastic cotunneling (ECT) and crossed Andreev reflection (CAR): ECT-dominated sweet spots, genuine sweet spots and CAR-dominated sweet spots. We show that the ECT-dominated and CAR-dominated sweet spots can be more conveniently accessed and utilized in transmon-based measurements. △ Less

Submitted 21 May, 2025; originally announced May 2025.

Unconventional band splitting of CeSb in the devil's staircase transition

Authors: Tongrui Li, Zhanfeng Liu, Peng Li, Yuzhe Wang, Zhisheng Zhao, Shiwu Su, Zhicheng Jiang, Yuhao Hong, Hui Tian, Xin Zheng, Yi Liu, Yilin Wang, Zhengtai Liu, Dawei Shen, Zhe Sun, Yang Liu, Juan Jiang, Donglai Feng

Abstract: The interplay between magnetism and electronic band structure is a central theme in condensed matter physics. CeSb, with its complex devil's staircase antiferromagnetic transition, offers a unique opportunity to explore this interplay. Using angle-resolved photoemission spectroscopy (ARPES), we investigate the electronic structure evolution across the devil's staircase transition. Upon entering th… ▽ More The interplay between magnetism and electronic band structure is a central theme in condensed matter physics. CeSb, with its complex devil's staircase antiferromagnetic transition, offers a unique opportunity to explore this interplay. Using angle-resolved photoemission spectroscopy (ARPES), we investigate the electronic structure evolution across the devil's staircase transition. Upon entering the antiferromagnetic phase, we observe an intriguing band splitting of the electron pocket around the X point. The energy separation between the split bands changes abruptly with temperature, consistent with the characteristics of the first-order phase transition. However, their respective spectral weights behave gradually with temperature. Combined with our density functional theory (DFT) calculations, we suggest that this atypical behavior deviates from conventional magnetically induced band splitting and potentially arises from the intricate modulation of paramagnetic and antiferromagnetic layers within the devil's staircase transition. Our results provide insights into the complex relationship between electronic structure and magnetism in correlated electron systems. △ Less

Submitted 18 May, 2025; originally announced May 2025.

Comments: 13 pages, 4 figures

Journal ref: Communications Materials volume 6, Article number: 97 (2025)

Controllable creation of topological boundary states in topological-insulator-based Josephson corner junctions

Authors: Xiang Wang, Duolin Wang, Yunxiao Zhang, Xiaozhou Yang, Yukun Shi, Bing Li, Enna Zhuo, Yuyang Huang, Anqi Wang, Zhaozheng Lyu, Xiaohui Song, Peiling Li, Bingbing Tong, Ziwei Dou, Jie Shen, Guangtong Liu, Fanming Qu, Li Lu

Abstract: Majorana zero modes (MZMs) in condensed matter systems have attracted great attention in the past two decades, due to their interesting physics and potential application in topological quantum computing (TQC). However, the topologically protected nature of MZMs still need more experimental verifications. In this study, we have realized controllable creation of a topological boundary state at the c… ▽ More Majorana zero modes (MZMs) in condensed matter systems have attracted great attention in the past two decades, due to their interesting physics and potential application in topological quantum computing (TQC). However, the topologically protected nature of MZMs still need more experimental verifications. In this study, we have realized controllable creation of a topological boundary state at the corner of topological insulator (TI)-based Josephson corner junctions. This state demonstrates protected existence across a broad region in parametric space, and exhibits a non-2π-period but 4π-period-compatible energy-phase relation. Our study suggests that TI-based Josephson junctions, as proposed in the Fu-Kane scheme of TQC, may provide a promising platform for hosting and braiding MZMs. △ Less

Submitted 13 May, 2025; originally announced May 2025.

Comments: 5 pages, 4 figures

BOOM: Benchmarking Out-Of-distribution Molecular Property Predictions of Machine Learning Models

Authors: Evan R. Antoniuk, Shehtab Zaman, Tal Ben-Nun, Peggy Li, James Diffenderfer, Busra Sahin, Obadiah Smolenski, Tim Hsu, Anna M. Hiszpanski, Kenneth Chiu, Bhavya Kailkhura, Brian Van Essen

Abstract: Data-driven molecular discovery leverages artificial intelligence/machine learning (AI/ML) and generative modeling to filter and design novel molecules. Discovering novel molecules requires accurate out-of-distribution (OOD) predictions, but ML models struggle to generalize OOD. Currently, no systematic benchmarks exist for molecular OOD prediction tasks. We present $\mathbf{BOOM}$, $\mathbf{b}$en… ▽ More Data-driven molecular discovery leverages artificial intelligence/machine learning (AI/ML) and generative modeling to filter and design novel molecules. Discovering novel molecules requires accurate out-of-distribution (OOD) predictions, but ML models struggle to generalize OOD. Currently, no systematic benchmarks exist for molecular OOD prediction tasks. We present $\mathbf{BOOM}$, $\mathbf{b}$enchmarks for $\mathbf{o}$ut-$\mathbf{o}$f-distribution $\mathbf{m}$olecular property predictions: a chemically-informed benchmark for OOD performance on common molecular property prediction tasks. We evaluate over 150 model-task combinations to benchmark deep learning models on OOD performance. Overall, we find that no existing model achieves strong generalization across all tasks: even the top-performing model exhibited an average OOD error 3x higher than in-distribution. Current chemical foundation models do not show strong OOD extrapolation, while models with high inductive bias can perform well on OOD tasks with simple, specific properties. We perform extensive ablation experiments, highlighting how data generation, pre-training, hyperparameter optimization, model architecture, and molecular representation impact OOD performance. Developing models with strong OOD generalization is a new frontier challenge in chemical ML. This open-source benchmark is available at https://github.com/FLASK-LLNL/BOOM △ Less

Submitted 19 December, 2025; v1 submitted 3 May, 2025; originally announced May 2025.

Tripartite hybrid quantum systems: Skyrmion-mediated quantum interactions between single NV centers and superconducting qubits

Authors: Xue-Feng Pan, Peng-Bo Li

Abstract: Nitrogen-vacancy (NV) centers in diamond and superconducting qubits are two promising solid-state quantum systems for quantum science and technology, but the realization of controlled interfaces between individual solid-state spins and superconducting qubits remains fundamentally challenging. Here, we propose and analyze a hybrid quantum system consisting of a magnetic skyrmion, an NV center, and… ▽ More Nitrogen-vacancy (NV) centers in diamond and superconducting qubits are two promising solid-state quantum systems for quantum science and technology, but the realization of controlled interfaces between individual solid-state spins and superconducting qubits remains fundamentally challenging. Here, we propose and analyze a hybrid quantum system consisting of a magnetic skyrmion, an NV center, and a superconducting qubit, where the solid-state qubits are both positioned in proximity to the skyrmion structure in a thin magnetic disk. We show that it is experimentally feasible to achieve strong magnetic (coherent or dissipative) coupling between the NV center and the superconducting qubit by using the \textit{quantized gyration mode of the skyrmion} as an intermediary. This allows coherent information transfer and nonreciprocal responses between the NV center and the superconducting qubit at the single quantum level with high controllability. The proposed platform provides a scalable pathway for implementing quantum protocols that synergistically exploit the complementary advantages of spin-based quantum memories, microwave-frequency superconducting circuits, and topologically protected magnetic excitations. △ Less

Submitted 30 April, 2025; originally announced May 2025.

Comments: 20 pages,13 figures

Valley Polarization and Anomalous Valley Hall Effect in Altermagnet Ti2Se2S with Multipiezo Properties

Authors: Xin Hu, Weihang Zhao, Wenjun Xia, Hanbo Sun, Chao Wu, Yin-Zhong Wu, Ping Li

Abstract: Recently, altermagnets demonstrate numerous newfangle physical phenomena due to their inherent antiferromagnetic coupling and spontaneous spin splitting, that are anticipated to enable innovative spintronic devices. However, the rare two-dimensional altermagnets have been reported, making it difficult to meet the requirements for high-performance spintronic devices on account of the growth big dat… ▽ More Recently, altermagnets demonstrate numerous newfangle physical phenomena due to their inherent antiferromagnetic coupling and spontaneous spin splitting, that are anticipated to enable innovative spintronic devices. However, the rare two-dimensional altermagnets have been reported, making it difficult to meet the requirements for high-performance spintronic devices on account of the growth big data. Here, we predict a stable monolayer Ti2Se2S with out-of-plane altermagnetic ground state and giant valley splitting. The electronic properties of altermagnet Ti2Se2S are highly dependent on the onsite electron correlation. Through symmetry analysis, we find that the valleys of X and Y points are protected by the mirror Mxy symmetry rather than the time-reversal symmetry. Therefore, the multipiezo effect, including piezovalley and piezomagnetism, can be induced by the uniaxial strain. The total valley splitting of monolayer Ti2Se2S can be as high as ~500 meV. Most interestingly, the direction of valley polarization can be effectively tuned by the uniaxial strain, based on this, we have defined logical "0", "+1", and "-1" states for data transmission and storage. In addition, we have designed a schematic diagram for observing the anomalous Hall effect in experimentally. Our findings have enriched the candidate materials of two-dimensional altermagnet for the ultra-fast and low power consumption device applications. △ Less

Submitted 25 April, 2025; originally announced April 2025.

Comments: 7 pages, 6 figures

MatterTune: An Integrated, User-Friendly Platform for Fine-Tuning Atomistic Foundation Models to Accelerate Materials Simulation and Discovery

Authors: Lingyu Kong, Nima Shoghi, Guoxiang Hu, Pan Li, Victor Fung

Abstract: Geometric machine learning models such as graph neural networks have achieved remarkable success in recent years in chemical and materials science research for applications such as high-throughput virtual screening and atomistic simulations. The success of these models can be attributed to their ability to effectively learn latent representations of atomic structures directly from the training dat… ▽ More Geometric machine learning models such as graph neural networks have achieved remarkable success in recent years in chemical and materials science research for applications such as high-throughput virtual screening and atomistic simulations. The success of these models can be attributed to their ability to effectively learn latent representations of atomic structures directly from the training data. Conversely, this also results in high data requirements for these models, hindering their application to problems which are data sparse which are common in this domain. To address this limitation, there is a growing development in the area of pre-trained machine learning models which have learned general, fundamental, geometric relationships in atomistic data, and which can then be fine-tuned to much smaller application-specific datasets. In particular, models which are pre-trained on diverse, large-scale atomistic datasets have shown impressive generalizability and flexibility to downstream applications, and are increasingly referred to as atomistic foundation models. To leverage the untapped potential of these foundation models, we introduce MatterTune, a modular and extensible framework that provides advanced fine-tuning capabilities and seamless integration of atomistic foundation models into downstream materials informatics and simulation workflows, thereby lowering the barriers to adoption and facilitating diverse applications in materials science. In its current state, MatterTune supports a number of state-of-the-art foundation models such as ORB, MatterSim, JMP, and EquformerV2, and hosts a wide range of features including a modular and flexible design, distributed and customizable fine-tuning, broad support for downstream informatics tasks, and more. △ Less

Submitted 14 April, 2025; originally announced April 2025.

Realization of a non-Hermitian Haldane model in circuits

Authors: Rujiang Li, Wencai Wang, Xiangyu Kong, Bo Lv, Yongtao Jia, Huibin Tao, Pengfei Li, Ying Liu

Abstract: The Haldane model is the simplest yet most powerful topological lattice model exhibiting various phases, including the Dirac semimetal phase and the anomalous quantum Hall phase (also known as the Chern insulator). Although considered unlikely to be physically directly realizable in condensed matter systems, it has been experimentally demonstrated in other physical settings such as cold atoms, whe… ▽ More The Haldane model is the simplest yet most powerful topological lattice model exhibiting various phases, including the Dirac semimetal phase and the anomalous quantum Hall phase (also known as the Chern insulator). Although considered unlikely to be physically directly realizable in condensed matter systems, it has been experimentally demonstrated in other physical settings such as cold atoms, where Hermiticity is usually preserved. Extending this model to the non-Hermitian regime with energy non-conservation can significantly enrich topological phases that lack Hermitian counterparts; however, such exploration remains experimentally challenging due to the lack of suitable physical platforms. Here, based on electric circuits, we report the experimental realization of a genuine non-Hermitian Haldane model with asymmetric next-nearest-neighbor hopping. We observe two previously uncovered phases: a non-Hermitian Chern insulator and a non-Hermitian semimetal phase, both exhibiting boundary-dependent amplifying or dissipative chiral edge states. Our work paves the way for exploring non-Hermiticity-induced unconventional topological phases in the Haldane model. △ Less

Submitted 31 March, 2025; originally announced March 2025.

Comments: to be published in Frontiers of Physics

Flexible BiSel/NiO-based X-ray synapses bridging the functions of detection and memory

Authors: Qiao Wang, Pengfei Li, Yushou Song, Jalu Li, Haiying Xiao, Yuqing Wang, Guoliang Ma, Hsu-Sheng Tsai, Ping-An Hu

Abstract: Currently, the X-ray detectors are widely used in medical imaging, industrial inspection, aerospace, and other fields, as the market demand for high-efficiency, flexible, and low-power detectors is increased. Although the traditional inorganic X-ray detection materials have achieved great success and effectiveness, they have their own limitations and let alone flexibility/bendability and memory fu… ▽ More Currently, the X-ray detectors are widely used in medical imaging, industrial inspection, aerospace, and other fields, as the market demand for high-efficiency, flexible, and low-power detectors is increased. Although the traditional inorganic X-ray detection materials have achieved great success and effectiveness, they have their own limitations and let alone flexibility/bendability and memory function. In this study, we present the design of a BiSeI/NiO-based X-ray synaptic detector and its application in the simulation of biological synaptic processes. Herein, the BiSeI, a quasi-1D inorganic semiconductor, stands out as an ideal choice for the X-ray detectors, especially for flexible and portable devices due to its large atomic number, large photoelectric absorption coefficient, and mechanical plasticity. Meanwhile, the NiO-based materials provide the memory function required for the intelligent detection systems. Moreover, our devices offer notable advantages in terms of low power consumption, compared with traditional X-ray detectors. The BiSeI/NiO detectors demonstrate advanced features with an ultrahigh sensitivity, an ultralow detection limit, and include the paired-pulse facilitation (PPF) and the transition from short- to long-term memory, maintaining the functionality on flexible substrates. This design represents a significant step toward the development of intelligent and flexible X-ray detectors. △ Less

Submitted 5 December, 2025; v1 submitted 18 March, 2025; originally announced March 2025.

Direct-Write Printed Contacts to Layered and 2D Materials

Authors: Sharadh Jois, Erica Lee, Philip Li, Tsegereda Esatu, Jason Fleischer, Edwin Quinn, Genda Gu, Vadym Kulichenko, Luis Balicas, Son T. Le, Samuel W. LaGasse, Aubrey T. Hanbicki, Adam L. Friedman

Abstract: Advancements in fabrication methods have shaped new computing device technologies. Among these methods, depositing electrical contacts to the channel material is fundamental to device characterization. Novel layered and two-dimensional (2D) materials are promising for next-generation computing electronic channel materials. Direct-write printing of conductive inks is introduced as a surprisingly ef… ▽ More Advancements in fabrication methods have shaped new computing device technologies. Among these methods, depositing electrical contacts to the channel material is fundamental to device characterization. Novel layered and two-dimensional (2D) materials are promising for next-generation computing electronic channel materials. Direct-write printing of conductive inks is introduced as a surprisingly effective, significantly faster, and cleaner method to contact different classes of layered materials, including graphene (semi-metal), MoS2 (semiconductor), Bi-2212 (superconductor), and Fe5GeTe2 (metallic ferromagnet). Based on the electrical response, the quality of the printed contacts is comparable to what is achievable with resist-based lithography techniques. These devices are tested by sweeping gate voltage, temperature, and magnetic field to show that the materials remain pristine post-processing. This work demonstrates that direct-write printing is an agile method for prototyping and characterizing the electrical properties of novel layered materials. △ Less

Submitted 10 April, 2025; v1 submitted 6 March, 2025; originally announced March 2025.

Nonlinear Tripartite Coupling of Single Electrons on Solid Neon with Magnons in a Hybrid Quantum System

Authors: Xue-Feng Pan, Peng-Bo Li

Abstract: Coherent nonlinear tripartite interactions are critical for advancing quantum simulation and information processing in hybrid quantum systems, yet they remain experimentally challenging and still evade comprehensive exploration. Here, we predict a nonlinear tripartite coupling mechanism in a hybrid setup comprising a single electron trapped on a solid neon surface and a nearby micromagnet. The tri… ▽ More Coherent nonlinear tripartite interactions are critical for advancing quantum simulation and information processing in hybrid quantum systems, yet they remain experimentally challenging and still evade comprehensive exploration. Here, we predict a nonlinear tripartite coupling mechanism in a hybrid setup comprising a single electron trapped on a solid neon surface and a nearby micromagnet. The tripartite coupling here leverages the electron's intrinsic charge (motional) and spin degrees of freedom interacting with the magnon modes of the micromagnet. Thanks to the large spatial extent of the electron zero-point motion, we show that it is possible to obtain a tunable and strong spin-magnon-motion coupling at the single quantum level, with two phonons simultaneously interacting with a single spin and magnon excitation. This enables, for example, dissipative interactions between the electron's charge and spin degrees of freedom, permitting controlled phonon addition/subtraction in the electron's motional state and the preparation of steady-state non-Gaussian motional states. This protocol can be readily implemented with the well-developed techniques in electron traps and may open new avenues for general applications in quantum simulations and information processing based on strongly coupled hybrid quantum systems. △ Less

Submitted 11 March, 2025; originally announced March 2025.

Comments: 7 pages, 3 figures

Revealing the electron-spin fluctuation coupling by photoemission in CaKFe4As4

Authors: Peng Li, Yuzhe Wang, Yabin Liu, Jianghao Yao, Zhisheng Zhao, Zhengtai Liu, Dawei Shen, Huiqian Luo, Guanghan Cao, Juan Jiang, Donglai Feng

Abstract: Electron-boson coupling in unconventional superconductors is one of the key parameters in understanding the superconducting pairing symmetry. Here, we report definitive photoemission evidence of electron-spin exciton coupling in the iron-based superconductor CaKFe4As4, obtained via high-resolution ARPES. Our study identifies a distinct kink structure on the α band, observable only in the supercond… ▽ More Electron-boson coupling in unconventional superconductors is one of the key parameters in understanding the superconducting pairing symmetry. Here, we report definitive photoemission evidence of electron-spin exciton coupling in the iron-based superconductor CaKFe4As4, obtained via high-resolution ARPES. Our study identifies a distinct kink structure on the α band, observable only in the superconducting phase and closely linked with the superconductivity, indicative of strong electron-boson interactions. Notably, this kink structure corresponds to two distinct bosonic modes at 11 meV and 13 meV, aligning with spin resonance modes previously observed in inelastic neutron scattering experiments. This alignment underscores the significant role of antiferromagnetic fluctuations in the pairing mechanism of this superconductor. Furthermore, the unique momentum-dependent and orbital-selective properties of the coupling revealed by ARPES provide profound insights into the pairing symmetry, suggesting predominantly s_+- wave pairing facilitated by spin fluctuations. Our findings not only highlight the pivotal role of spin resonance in the superconductivity of CaKFe4As4 but also enhance understanding of the electron-spin exciton interactions in unconventional superconductors. △ Less

Submitted 5 March, 2025; originally announced March 2025.

Comments: Phys. Rev. X - Accepted 4 March, 2025

Coexisting Triferroic and Multiple Types of Valley Polarization by Structural Phase Transition in Two-Dimensional Materials

Authors: Chao Wu, Hanbo Sun, Pengqiang Dong, Yin-Zhong Wu, Ping Li

Abstract: The multiferroic materials, which coexist magnetism, ferroelectric, and ferrovalley, have broad practical application prospects in promoting the miniaturization and integration of spintronic and valleytronic devices. However, it is rare that there are triferroic orders and multiple types of valley polarization in a real material. Here, we propose a mechanism to realize triferroic order coexistence… ▽ More The multiferroic materials, which coexist magnetism, ferroelectric, and ferrovalley, have broad practical application prospects in promoting the miniaturization and integration of spintronic and valleytronic devices. However, it is rare that there are triferroic orders and multiple types of valley polarization in a real material. Here, we propose a mechanism to realize triferroic order coexistence and multiple types of valley polarization by structural phase transition in two-dimensional (2D) materials. The 1T and 2H phase OsBr2 monolayers exhibit non-magnetic semiconductor and ferromagnetic semiconductor with valley polarization up to 175.49 meV, respectively. Interestingly, the 1T phase OsBr2 bilayer shows the tri-state valley polarization due to lattice symmetry breaking, while the valley polarization of 2H phase bilayer originates from the combined effect of time-reversal symmetry breaking and spin-orbit coupling. Furthermore, the valley polarization and ferroelectric polarization of 1T phase AB stackings and 2H phase AA stackings can be manipulated via interlayer sliding. Importantly, we have verified that the 2H phase can be transformed to 1T phase by Li+ ion intercalation, while the 2H phase can occur the structural phase transition into the 1T phase by infrared laser induction. Our work provides a feasible strategy for manipulating valley polarization and a design idea for nano-devices with nonvolatile multiferroic properties. △ Less

Submitted 25 February, 2025; originally announced February 2025.

Comments: 10 pages, 7 figures

Multifield Induced Antiferromagnet Transformation into Altermagnet and Realized Anomalous Valley Hall Effect in Two-dimensional Materials

Authors: Hanbo Sun, Pengqiang Dong, Chao Wu, Ping Li

Abstract: Altermagnetism, as a new category of collinear magnetism distinct from traditional ferromagnetism and antiferromagnetism, exhibits the spin splitting without net magnetization. Currently, researchers are focus on searching three-dimensional altermagnetism and exploring its novel physical properties. However, there is a lack of understanding of the physical origin of two-dimensional altermagnetic e… ▽ More Altermagnetism, as a new category of collinear magnetism distinct from traditional ferromagnetism and antiferromagnetism, exhibits the spin splitting without net magnetization. Currently, researchers are focus on searching three-dimensional altermagnetism and exploring its novel physical properties. However, there is a lack of understanding of the physical origin of two-dimensional altermagnetic emergent behavior. Here, we propose an approach to realize the transition from Neel antiferromagnetism to altermagnetism in two-dimensional system using an electric field, Janus structure, and ferroelectric substrate. In monolayer VPSe3, we demonstrate that multiple-physical-fields cause the upper and lower Se atoms unequal to break PT symmetry, resulting in altermagnetic spin splitting. Noted that monolayer VPSe3 produces a spontaneous valley splitting of 2.91 meV at the conduction band minimum. The electric field can effectively tune the valley splitting magnitude, while the Janus structure not only changes the valley splitting magnitude, but also alters the direction. More interestingly, when the ferroelectric polarization of Al2S3 is upward, the direction of valley polarization is switched and the magnitude is almost unchanged. However, the valley splitting sigfinicantly increases under the downward. It is worth noting that the ferroelectric polarization can switch altermagnetic effect and realize anomalous valley Hall effect. Besides, we reveal the microscopic mechanism of valley splitting by an effective Hamiltonian. Our findings not only provide a method to designing altermagnet, but also enriches the valley physics. △ Less

Submitted 25 February, 2025; originally announced February 2025.

Comments: 8 pages, 5 figures

Stacking, Strain-Engineering Induced Altermagnetism, Multipiezo Effect, and Topological State in Two-Dimensional Materials

Authors: Wei Xun, Xin Liu, Youdong Zhang, Yin-Zhong Wu, Ping Li

Abstract: Altermagnetism, as a newly identified form of unconventional antiferromagnetism, enables the removal of spin degeneracy in the absence of net magnetization that provides a platform for the low power consumption and ultra-fast device applications. However, the rare attention has been paid to the relationship between stacking, strain and altermagnet, multipiezo effect and topological state. Here, we… ▽ More Altermagnetism, as a newly identified form of unconventional antiferromagnetism, enables the removal of spin degeneracy in the absence of net magnetization that provides a platform for the low power consumption and ultra-fast device applications. However, the rare attention has been paid to the relationship between stacking, strain and altermagnet, multipiezo effect and topological state. Here, we propose a mechanism to realize the altermagnet, multipiezo effect, and topological state in two-dimensional materials by the stacking and strain engineering. Based on the analysis of symmetry, we find that the spin splitting feature related to the Ut, PTt, MzUt, or MzPTt symmetries in altermagnet multilayers. In addition, we find that the stacking engineering can effectively realize the transform from antiferromagnetism to altermagnetism and semiconductor to metal for the Jauns bilayer V2SeTeO. More interestingly, the strain not only induces an intriguing multipiezo effect, encompassing the piezovalley, piezomagnetism and piezoelectric, but also achieves the abundant topological phase. Our findings offer a generalized direction for manipulating the spin splitting, valley polarization, and topological states, promoting practical application of valleytronic and spintronic devices based on two-dimensional altermagnets. △ Less

Submitted 25 February, 2025; originally announced February 2025.

Comments: 8 pages, 5 figures

Nodeless superconducting gap and electron-boson coupling in (La,Pr,Sm)$_{3}$Ni$_2$O$_7$ films

Authors: Jianchang Shen, Guangdi Zhou, Yu Miao, Peng Li, Zhipeng Ou, Yaqi Chen, Zechao Wang, Runqing Luan, Hongxu Sun, Zikun Feng, Xinru Yong, Yueying Li, Lizhi Xu, Wei Lv, Zihao Nie, Heng Wang, Haoliang Huang, Yu-Jie Sun, Qi-Kun Xue, Junfeng He, Zhuoyu Chen

Abstract: The discovery of superconductivity in Ruddlesden-Popper (RP) bilayer nickelate films under ambient pressure provides an unprecedented opportunity to directly investigate electronic energy scales of the superconducting state and the pairing mechanism. Here, we report angle-resolved photoemission spectroscopy measurements of superconducting (La,Pr,Sm)$_{3}$Ni$_2$O$_7$ thin films epitaxially grown on… ▽ More The discovery of superconductivity in Ruddlesden-Popper (RP) bilayer nickelate films under ambient pressure provides an unprecedented opportunity to directly investigate electronic energy scales of the superconducting state and the pairing mechanism. Here, we report angle-resolved photoemission spectroscopy measurements of superconducting (La,Pr,Sm)$_{3}$Ni$_2$O$_7$ thin films epitaxially grown on SrLaAlO$_4$ substrates by developing an ultra-high vacuum low-temperature quenching and transfer technique. A finite superconducting gap of ~18 meV with pronounced coherence peak is observed along the Brillouin zone diagonal direction. Remarkably, the finite superconducting gap persists across the entire Brillouin zone of the underlying Fermi surfaces, revealing the absence of gap nodes. An abrupt band renormalization, manifested as a kink in the energy-momentum dispersion at ~70 meV below the Fermi level, indicates an electron-boson coupling in the system. The simultaneous observation of a nodeless superconducting gap and electron-boson coupling provides crucial insights into the pairing symmetry and gluing mechanism in high-T$_c$ RP bilayer nickelates. △ Less

Submitted 9 July, 2025; v1 submitted 24 February, 2025; originally announced February 2025.

Quantum fluctuations-driven Melting Transitions in Two-dimensional Superconductors

Authors: Dong Qiu, Yuting Zou, Chao Yang, Dongxing Zheng, Chenhui Zhang, Deju Zhang, Yuhang Wu, Gaofeng Rao, Peng Li, Yuqiao Zhou, Xian Jian, Haoran Wei, Zhigang Cheng, Xixiang Zhang, Yanning Zhang, Haiwen Liu, Jingbo Qi, Yanrong Li, Jie Xiong

Abstract: Quantum fluctuations are pivotal in driving quantum phase transitions, exemplified by the quantum melting of Wigner crystals into Fermi liquids in electron systems. However, their impact on superconducting systems near zero temperature, particularly in the superconductor-insulator/metal transition, remains poorly understood. In this study, through electric transport measurements on the two-dimensi… ▽ More Quantum fluctuations are pivotal in driving quantum phase transitions, exemplified by the quantum melting of Wigner crystals into Fermi liquids in electron systems. However, their impact on superconducting systems near zero temperature, particularly in the superconductor-insulator/metal transition, remains poorly understood. In this study, through electric transport measurements on the two-dimensional (2D) superconductor (SnS)1.17NbS2, we demonstrate that quantum fluctuations induce vortex displacement from their mean position, leading to the quantum melting of vortex solid near zero temperature. Quantitative analysis reveals the magnetic field-induced anomalous metal originates from this quantum melting transition, with energy dissipation governed by quantum fluctuations-driven vortex displacements. Remarkably, further extending this analysis to various 2D superconductors yields the same results, and many properties of anomalous metal can be qualitatively understood within the framework of quantum melting. The connection between the quantum melting of vortex solids and dissipative anomalous metal opens a novel pathway towards understanding quantum phase transitions through vortex dynamics, providing new insights on both fields. △ Less

Submitted 20 February, 2025; originally announced February 2025.

Report number: https://journals.aps.org/prresearch/abstract/10.1103/wbvb-r19q