Showing 1–50 of 61 results for author: Zeng, S

The Emergence of Prebiotic Chemistry in the ISM

Authors: Izaskun Jimenez-Serra, Giuliana Cosentino, Francisco Montenegro-Montes, Laura Colzi, Victor M. Rivilla, Miguel Sanz-Novo, Marta Rey-Montejo, David San Andres, Sergio Martin, Shaoshan Zeng, Amelie Godard Palluet, Miguel A. Requena-Torres, German Molpeceres, Pamela Klassen, Doug Johnston, Francesco Fontani, Silvia Spezzano, Elena Redaelli, Juris Kalvans, Yuri Aikawa, Belen Tercero, Pablo de Vicente, Serena Viti, Emilio J. Cocinero, Aran Insausti

Abstract: Contrary to popular belief, the interstellar medium (ISM) is not empty; it is filled with atoms, dust particles, and molecules. Some of these molecules may have been the very building blocks of life that, delivered to Earth via comets and meteorites, could have given rise to Life itself. A large-area single-dish telescope with superb sensitivity, field-of-view and multi-band instruments will allow… ▽ More Contrary to popular belief, the interstellar medium (ISM) is not empty; it is filled with atoms, dust particles, and molecules. Some of these molecules may have been the very building blocks of life that, delivered to Earth via comets and meteorites, could have given rise to Life itself. A large-area single-dish telescope with superb sensitivity, field-of-view and multi-band instruments will allow us to explore the limits of chemical complexity in the interstellar medium, across our Galaxy and in external galaxies, determining whether amino acids, sugars, or RNA/DNA nucleobases can form in space. △ Less

Submitted 16 December, 2025; originally announced December 2025.

Comments: This white paper was submitted to ESO Expanding Horizons in support of AtLAST

The role of supernova remnants for the emergence of pre-biotic chemistry in molecular clouds

Authors: Giuliana Cosentino, Izaskun Jiménez-Serra, Laura Colzi, Víctor Rivilla, Francisco Montenegro-Montes, Miguel Sanz-Novo, Marta Rey-Montejo, Andrés Megías, David San Andrés, Sergio Martín, Shaoshan Zeng, Amelie Godard, Miguel Requena-Torres, Juris Kalvāns

Abstract: There is growing evidence that the Sun might have formed within a nebula impacted by at least one SNR. In this scenario, ejecta and shocks from SNRs may have provided the elements on which life as we know it is based. Investigating the chemical complexity of molecular clouds impacted by SNRs is therefore essential to unveil the star formation process and how life appeared on Earth. In this paper,… ▽ More There is growing evidence that the Sun might have formed within a nebula impacted by at least one SNR. In this scenario, ejecta and shocks from SNRs may have provided the elements on which life as we know it is based. Investigating the chemical complexity of molecular clouds impacted by SNRs is therefore essential to unveil the star formation process and how life appeared on Earth. In this paper, we exploit this scientific questions and describe which technical specifications will drive in future generation telescopes. △ Less

Submitted 16 December, 2025; originally announced December 2025.

Comments: This white paper was submitted to ESO Expanding Horizons in support of AtLAST

Sulfur-Bearing Cyclic Hydrocarbons in Space

Authors: Mitsunori Araki, Miguel Sanz-Novo, Christian P. Endres, Paola Caselli, Víctor M. Rivilla, Izaskun Jiménez-Serra, Laura Colzi, Shaoshan Zeng, Andrés Megías, Álvaro López-Gallifa, Antonio Martínez-Henares, David San Andrés, Sergio Martín, Miguel A. Requena-Torres, Juan García de la Concepción, Valerio Lattanzi

Abstract: Molecules harbouring sulfur are thought to have played a key role in the biological processes of life on Earth. We report the first astronomical detection of a sulfur-bearing cyclic 1hydrocarbon in interstellar space. Observations of the Galactic center molecular cloud G+0.693-0.027 reveal the presence of 2,5-cyclohexadien-1-thione - a structural isomer of thiophenol ($c$-C$_6$H$_6$S). To allow th… ▽ More Molecules harbouring sulfur are thought to have played a key role in the biological processes of life on Earth. We report the first astronomical detection of a sulfur-bearing cyclic 1hydrocarbon in interstellar space. Observations of the Galactic center molecular cloud G+0.693-0.027 reveal the presence of 2,5-cyclohexadien-1-thione - a structural isomer of thiophenol ($c$-C$_6$H$_6$S). To allow the astronomical identification, we first performed precise laboratory measurements of the thiophenol discharge products system. These measurements, conducted in the radio band using a chirped-pulse Fourier transform microwave spectrometer, enabled us to characterize this highly polar molecular species and provided unambiguous fingerprints needed to identify this organosulfur compound in space, which now ranks as the largest interstellar sulfur-bearing molecule. These results herald the discovery of a new family of prebiotically relevant sulfur-bearing species, potentially acting as a bridge between the chemical inventory of the interstellar medium and the composition of the minor bodies of the Solar System. △ Less

Submitted 5 December, 2025; v1 submitted 28 November, 2025; originally announced November 2025.

Comments: Submitted

Observation of CH$_{3}$$^{17}$OH and CH$_{3}$$^{18}$OH in Orion KL: A New Tool to Study Star-Formation History

Authors: Yoshimasa Watanabe, Takahiro Oyama, Akemi Tamanai, Shaoshan Zeng, Nami Sakai

Abstract: Methanol is a seed species of complex organic molecules that is of fundamental importance in astrochemistry. Although various isotopologues of CH$_3$OH have been detected in the interstellar medium (ISM), CH$_{3}$$^{17}$OH is only tentatively detected in Sgr~B2. To confirm the presence of CH$_{3}$$^{17}$OH in the ISM and to investigate its abundance, we search for its emission lines in the Orion~K… ▽ More Methanol is a seed species of complex organic molecules that is of fundamental importance in astrochemistry. Although various isotopologues of CH$_3$OH have been detected in the interstellar medium (ISM), CH$_{3}$$^{17}$OH is only tentatively detected in Sgr~B2. To confirm the presence of CH$_{3}$$^{17}$OH in the ISM and to investigate its abundance, we search for its emission lines in the Orion~KL region. We have obtained image cubes covering the frequency ranges 236.40~GHz-236.65~GHz and 231.68~GHz-231.88~GHz using ALMA archival data observed toward the Orion~KL region. The column densities of CH$_3$$^{17}$OH and CH$_3$$^{18}$OH are estimated under the assumption of local thermodynamic equilibrium condition with fixed excitation temperatures at the two CH$_3$$^{18}$OH peaks, MeOH1 and MeOH2,. We have identified six emission lines of CH$_{3}$$^{17}$OH in MeOH1 and MeOH2 and confirmed that the line profiles and spatial distributions are consistent with those of CH$_3$$^{18}$OH. The abundance ratios of CH$_3$$^{18}$OH/CH$_3$$^{17}$OH are evaluated to be $\sim 3.4-3.5$ and are similar to the canonical value of $^{18}$O/$^{17}$O $\sim 3-4$ derived from CO observations in the Orion~KL region. We have compared the results with the previous study of CH$_3$OH and evaluated CH$_3$$^{16}$OH/CH$_3$$^{17}$OH ratios to be $\sim 2300-2500$ at a resolution of $\sim 4$~arcsec. The ratios are close to the $^{16}$O/$^{17}$O ratio in the local ISM. This result indicates that the CH$_3$OH isotopologues can serve as new tracers of oxygen isotope ratios in star-forming regions because the opacity of CH$_3$OH can be evaluated using transition lines spanning a wide range of line intensities. Moreover, this method enables us to study the star-formation history of our Galaxy with the aid of the Galactic chemical evolution models. △ Less

Submitted 9 October, 2025; originally announced October 2025.

Comments: Accepted for publication in Astronomy & Astrophysics, 8 pages, 4 figures

Origin of Pulsed Radio Emission from Magnetars

Authors: Shuzhe Zeng, Alexander Philippov, James Juno, Andrei M. Beloborodov, Elena Popova

Abstract: Extended periods of radio pulsations have been observed for six magnetars, displaying characteristics different from those of ordinary pulsars. In this Letter, we argue that radio emission is generated in a closed, twisted magnetic flux bundle originating near the magnetic pole and extending beyond 100 km from the magnetar. The electron-positron flow in the twisted bundle has to carry electric cur… ▽ More Extended periods of radio pulsations have been observed for six magnetars, displaying characteristics different from those of ordinary pulsars. In this Letter, we argue that radio emission is generated in a closed, twisted magnetic flux bundle originating near the magnetic pole and extending beyond 100 km from the magnetar. The electron-positron flow in the twisted bundle has to carry electric current and, at the same time, experiences a strong drag by the radiation field of the magnetar. This combination forces the plasma into a ``radiatively locked'' state with a sustained two-stream instability, generating radio emission. We demonstrate this mechanism using novel first-principles simulations that follow the plasma behavior by solving the relativistic Vlasov equation with the discontinuous Galerkin method. First, using one-dimensional simulations, we demonstrate how radiative drag induces the two-stream instability, sustaining turbulent electric fields. When extended to two dimensions, the system produces electromagnetic waves, including superluminal modes capable of escaping the magnetosphere. We measure their frequency and emitted power, and incorporate the local simulation results into a global magnetospheric model. The model explains key features of observed radio emission from magnetars: its appearance after an X-ray outburst, wide pulse profiles, luminosities $\sim 10^{30}{\rm{erg/s}}$, and a broad range of frequencies extending up to $\sim 100\, \mathrm{GHz}$. △ Less

Submitted 16 December, 2025; v1 submitted 16 September, 2025; originally announced September 2025.

Comments: 17 pages, 8 figures, accepted to ApJL

High-energy interstellar isomers: cis-N-methylformamide in the G+0.693-0.027 molecular cloud

Authors: S. Zeng, V. M. Rivilla, M. Sanz-Novo, M. Melosso, I. Jiménez-Serra, L. Colzi, A. Megías, D. San Andrés, A. López-Gallifa, A. Martínez-Hernares, S. Martín

Abstract: Isomerism in complex organic molecules provides key insights into the formation mechanisms and physical conditions of the interstellar medium (ISM). Among the C$_2$H$_5$NO isomers, only acetamide and trans-N-methylformamide (trans-NMF) have been detected in space. The recent detection of higher-energy isomers in other chemical families raises questions about the formation and abundance of less sta… ▽ More Isomerism in complex organic molecules provides key insights into the formation mechanisms and physical conditions of the interstellar medium (ISM). Among the C$_2$H$_5$NO isomers, only acetamide and trans-N-methylformamide (trans-NMF) have been detected in space. The recent detection of higher-energy isomers in other chemical families raises questions about the formation and abundance of less stable isomers. We used ultra-sensitive wide-band spectral surveys obtained with the Yebes 40 m and IRAM 30 m telescopes to search for cis-NMF towards the Galactic Centre molecular cloud G+0.693-0.027. We present the first detection of cis-NMF in the ISM, with 55 unblended or slightly blended transitions, 44 of which were new transitions identified based on extrapolated spectroscopic data. Due to the lack of collisional rate coefficients, a quasi-non-LTE analysis, which separated the transitions into different K$_a$ ladders, was used to determine the excitation conditions. The resulting trans/cis-NMF isomeric ratio of 2.9$\pm$0.6 deviates significantly from thermodynamic expectations, suggesting that kinetic non-equilibrium processes and stereospecific chemical pathways are responsible for the formation of cis-NMF in this environment. The detection of cis-NMF expands the known inventory of interstellar C$_2$H$_5$NO isomers and challenges the assumption that isomer abundances strictly correlate with thermodynamic stability. Laboratory and theoretical studies propose formation via CH$_3$NCO hydrogenation or spin-forbidden reactions involving CH$_2$ and NH$_2$CHO, though these may not reflect typical ISM conditions. This finding highlights the need for further investigation into isomerisation mechanisms and constrains astrochemical models of complex organic molecules. △ Less

Submitted 15 September, 2025; originally announced September 2025.

Comments: 10 pages, 2 figures, 2 tables. Accepted for publication in A&A

Measuring metal sulfides in interstellar dust with PRIMA

Authors: Izaskun Jiménez-Serra, Shaoshan Zeng, Yao-Lun Yang, Angèle Taillard, Marta Rey-Montejo, Laura Colzi, Nami Sakai, Asunción Fuente

Abstract: Sulfur is known to undergo severe depletion when moving from diffuse clouds to the denser regimes of the interstellar medium in molecular clouds. The form in which sulfur gets depleted onto dust grains, however, remains a mystery. One possibility is that sulfur gets locked in interstellar dust in the form of sulfide minerals. Recently, metal sulfides such as NaS and MgS have been detected in a sho… ▽ More Sulfur is known to undergo severe depletion when moving from diffuse clouds to the denser regimes of the interstellar medium in molecular clouds. The form in which sulfur gets depleted onto dust grains, however, remains a mystery. One possibility is that sulfur gets locked in interstellar dust in the form of sulfide minerals. Recently, metal sulfides such as NaS and MgS have been detected in a shocked molecular cloud in the Galactic Center, suggesting that these molecules could represent an important reservoir of sulfur in dust grains. In this contribution, we discuss the prospect of observing metal sulfides such as MgS and FeS in absorption experiments carried out with the FIRESS instrument onboard PRIMA using its low resolution observing mode. Our estimates show that the molecular bands of MgS and FeS found between 20 and 50 $μ$m could be detected in absorption with S/N ${\geq}$ 5 for sources brighter than 200 mJy in just 1 h of observing time against low-mass protostellar objects. This science case, therefore, has the potential to unveil the main reservoir of sulfur in interstellar dust, constraining in what form sulfur is incorporated into minor bodies of our solar system. △ Less

Submitted 2 September, 2025; originally announced September 2025.

Comments: This paper is part of the JATIS special issue focused on the PRobe Infrared Mission for Astrophysics (PRIMA) probe mission concept. The issue is edited by Matt Griffin and Naseem Rangwala (JATIS VOL. 11, NO. 3, July 2025). Published, 11 pages, 5 figures

Chemical templates of the Central Molecular Zone. Shock and protostellar object signatures under Galactic Center conditions

Authors: Katarzyna M. Dutkowska, Gijs Vermariën, Serena Viti, Izaskun Jiménez-Serra, Laura Colzi, Laura A. Busch, Víctor M. Rivilla, Elisabeth A. C. Mills, Sergio Martín, Christian Henkel, Pablo García, Xing Lu, Miriam G. Santa-Maria, Jairo Armijos-Abendaño, Yue Hu, Jürgen Ott, Kai Smith, Fengwei Xu, Shaoshan Zeng, Álvaro Sánchez-Monge, Anika Schmiedeke, Jaime E. Pineda, Steven N. Longmore, Thanja Lamberts

Abstract: (Abridged) The Central Molecular Zone (CMZ) of the Milky Way exhibits extreme conditions, including high gas densities, elevated temperatures, enhanced cosmic-ray ionization rates, and large-scale dynamics. Large-scale molecular surveys reveal increasing chemical and physical complexity in the CMZ. A key step to interpreting the molecular richness found in the CMZ is to build chemical templates ta… ▽ More (Abridged) The Central Molecular Zone (CMZ) of the Milky Way exhibits extreme conditions, including high gas densities, elevated temperatures, enhanced cosmic-ray ionization rates, and large-scale dynamics. Large-scale molecular surveys reveal increasing chemical and physical complexity in the CMZ. A key step to interpreting the molecular richness found in the CMZ is to build chemical templates tailored to its diverse conditions. The combined impact of high ionization, elevated temperatures, and dense gas remains insufficiently explored for observable tracers. In this study, we utilized UCLCHEM, a gas-grain time-dependent chemical model, to link physical conditions with their corresponding molecular signatures and identify key tracers of temperature, density, ionization, and shock activity. We ran a grid of models of shocks and protostellar objects representative of typical CMZ conditions, focusing on twenty-four species, including complex organic molecules. Shocked and protostellar environments show distinct evolutionary timescales ($\lesssim 10^4$ vs. $\gtrsim 10^4$ years), with 300 K emerging as a key temperature threshold for chemical differentiation. We find that cosmic-ray ionization and temperature are the main drivers of chemical trends. HCO$^+$, H$_2$CO, and CH$_3$SH trace ionization, while HCO, HCO$^+$, CH$_3$SH, CH$_3$NCO, and HCOOCH$_3$ show consistent abundance contrasts between shocks and protostellar regions over similar temperature ranges. While our models underpredict some complex organics in shocks, they reproduce observed trends for most species, supporting scenarios involving recurring shocks in Galactic Center clouds and enhanced ionization towards Sgr B2(N2). Future work should assess the role of shock recurrence and metallicity in shaping chemistry. △ Less

Submitted 14 August, 2025; originally announced August 2025.

Comments: Accepted for publication in A&A. 23 pages, 12 figures

Journal ref: A&A 703, A46 (2025)

Determining the methanol deuteration in the disk around V883 Orionis with laboratory measured spectroscopy

Authors: Shaoshan Zeng, Jae-Hong Jeong, Takahiro Oyama, Jeong-Eun Lee, Yao-Lun Yang, Nami Sakai

Abstract: Deuterium fractionation, as studied through mono-deuterated methanol, is frequently used as a diagnostic tool to trace the physical conditions and chemical evolution of interstellar sources. This study investigates methanol deuteration in the disk around V883 Ori, utilising recent laboratory spectroscopic data for CH$_2$DOH and CH$_3$OD along with ALMA observations. The derived column densities fo… ▽ More Deuterium fractionation, as studied through mono-deuterated methanol, is frequently used as a diagnostic tool to trace the physical conditions and chemical evolution of interstellar sources. This study investigates methanol deuteration in the disk around V883 Ori, utilising recent laboratory spectroscopic data for CH$_2$DOH and CH$_3$OD along with ALMA observations. The derived column densities for CH$_2$DOH and CH$_3$OD are (5.14$\pm$0.08) $\times $10$^{16}$ cm$^{-2}$ and (4.22$\pm$0.06) $\times$ 10$^{16}$ cm$^{-2}$, respectively. The analysis demonstrates the influence of spectroscopic data on determining molecular column density, excitation temperature, and, most importantly, the inferred D/H ratio. The D/H ratio for CH$_2$DOH is calculated to be (7.3$\pm$1.5) $\times$ 10$^{-3}$ after applying a statistical correction, whilst the D/H ratio for CH$_3$OD is (1.79$\pm$0.36) $\times$ 10$^{-2}$. The discovery of an unexpectedly low CH$_2$DOH/CH$_3$OD ratio (1.22$\pm$0.02) in V883 Ori, however, raises further questions about the synthesis and chemical processes involved in CH$_3$OD formation. Overall, this study underscores the importance of accurate spectroscopic data for studies of isotopic fractionation and provides new insights into methanol deuteration chemistry in star-forming regions. Future research, combining updated spectroscopy and chemical modelling, will help further constrain these processes across different masses and evolutionary stages. △ Less

Submitted 9 June, 2025; originally announced June 2025.

Comments: 15 pages, 4 figures, 4 tables, Accepted for publication in ApJ

Linear Analysis and Simulations of the Cosmic-Ray Streaming Instability: the Importance of Oblique Waves

Authors: Shuzhe Zeng, Xue-Ning Bai, Xiaochen Sun

Abstract: Cosmic-ray (CR) streaming instability (CRSI) is believed to play an important role in CR transport and CR feedback to galaxies. It drives the growth of magnetohydrodynamic (MHD) waves that scatter CRs, and leads to energy/momentum exchange between CRs and interstellar medium. Despite extensive research on CRSI, its dependence on the thermodynamic state of the gas and its multidimensional effects h… ▽ More Cosmic-ray (CR) streaming instability (CRSI) is believed to play an important role in CR transport and CR feedback to galaxies. It drives the growth of magnetohydrodynamic (MHD) waves that scatter CRs, and leads to energy/momentum exchange between CRs and interstellar medium. Despite extensive research on CRSI, its dependence on the thermodynamic state of the gas and its multidimensional effects have not been systematically studied. In this study, we derive the dispersion relation of the CRSI for three types of MHD waves including their dependence on propagation direction and plasma $β$ (the ratio of thermal pressure to magnetic pressure). We verify the analytical dispersion relation with one-dimensional and two-dimensional magnetohydrodynamic particle-in-cell simulations. Furthermore, we use 2D simulations to investigate the role of oblique MHD waves in scattering CRs, and find that these waves are important in helping low-energy particles overcome the 90-degree pitch angle barrier. While magnetosonic waves tend to be damped by transit time damping under typical conditions, oblique Alfvén waves likely play an important role in low-$β$ plasmas. △ Less

Submitted 9 June, 2025; v1 submitted 22 March, 2025; originally announced March 2025.

On the abiotic origin of dimethyl sulfide: discovery of DMS in the Interstellar Medium

Authors: Miguel Sanz-Novo, Víctor M. Rivilla, Christian P. Endres, Valerio Lattanzi, Izaskun Jiménez-Serra, Laura Colzi, Shaoshan Zeng, Andrés Megías, Álvaro López-Gallifa, Antonio Martínez-Henares, David San Andrés, Belén Tercero, Pablo de Vicente, Sergio Martín, Miguel A. Requena-Torres, Paola Caselli, Jesús Martín-Pintado

Abstract: Following the discovery of dimethyl sulfide (CH$_3$SCH$_3$, DMS) signatures in comet 67P/Churyumov-Gerasimenko, we report the first detection of this organosulfur species in the interstellar medium, during the exploration of an ultradeep molecular line survey performed toward the Galactic Center molecular cloud G+0.693-0.027 with the Yebes 40$\,$m and IRAM 30$\,$m telescopes. We derive a molecular… ▽ More Following the discovery of dimethyl sulfide (CH$_3$SCH$_3$, DMS) signatures in comet 67P/Churyumov-Gerasimenko, we report the first detection of this organosulfur species in the interstellar medium, during the exploration of an ultradeep molecular line survey performed toward the Galactic Center molecular cloud G+0.693-0.027 with the Yebes 40$\,$m and IRAM 30$\,$m telescopes. We derive a molecular column density of $N$ = (2.6 $\pm$ 0.3)$\times$10$^{13}$ cm$^{-2}$, yielding a fractional abundance relative to H$_2$ of $\sim$1.9$\times$10$^{-10}$. This implies that DMS is a factor of $\sim$1.6 times less abundant than its structural isomer CH$_3$CH$_2$SH and $\sim$30 times less abundant than its O-analogue dimethyl ether (CH$_3$OCH$_3$) toward this cloud, in excellent agreement with previous results on various O/S pairs. Furthermore, we find a remarkable resemblance between the relative abundance of DMS/CH$_3$OH in G+0.693-0.027 ($\sim$1.7$\times$10$^{-3}$) and in the comet ($\sim$1.3$\times$10$^{-3}$). Although the chemistry of DMS beyond Earth is yet to be fully disclosed, this discovery provides conclusive observational evidence on its efficient abiotic production in the interstellar medium, casting doubts about using DMS as a reliable biomarker in exoplanet science. △ Less

Submitted 3 February, 2025; v1 submitted 15 January, 2025; originally announced January 2025.

Comments: Accepted in ApJL

Interaction between the Supernova Remnant W44 and the Infrared Dark Cloud G034.77-00.55: shock induced star formation?

Authors: G. Cosentino, I. Jiménez-Serra, A. T. Barnes, J. C. Tan, F. Fontani, P. Caselli, J. D. Henshaw, C. Y. Law, S. Viti, R. Fedriani, C. -J. Hsu, P. Gorai, S. Zeng, M. De Simone

Abstract: How Supernova Remnant (SNR) shocks impact nearby molecular clouds is still poorly observationally constrained. It is unclear if SNRs can positively or negatively affect clouds star formation potential. We have studied the dense gas morphology and kinematics toward the Infrared Dark Cloud (IRDC) G034.77-00.55, shock-interacting with the SNR W44, to identify evidence of early stage star formation in… ▽ More How Supernova Remnant (SNR) shocks impact nearby molecular clouds is still poorly observationally constrained. It is unclear if SNRs can positively or negatively affect clouds star formation potential. We have studied the dense gas morphology and kinematics toward the Infrared Dark Cloud (IRDC) G034.77-00.55, shock-interacting with the SNR W44, to identify evidence of early stage star formation induced by the shock. We have used high-angular resolution N2H+(1-0) images across G034.77-00.55, obtained with ALMA. N2H+ is a well known tracer of dense and cold material, optimal to identify gas with the highest potential to harbour star formation. The N2H+ emission is distributed into two elongated structures, one toward the dense ridge at the edge of the source and one toward the inner cloud. Both elongations are spatially associated with well-defined mass-surface density features. The velocities of the gas in the two structures i.e., 38-41 km s-1 and 41-43 km s-1 are consistent with the lowest velocities of the J- and C-type parts of the SNR-driven shock, respectively. A third velocity component is present at 43-45.5 km s-1. The dense gas shows a fragmented morphology with core-like fragments of scales consistent with the Jeans lengths, masses $\sim$1-20 M$_{\odot}$, densities (n(H$_2$)$\geq$10$^5$ cm$^{-3}$) sufficient to host star formation in free-fall time scales (few 10$^4$ yr) and with virial parameters that hint toward possible collapse. The W44 driven shock may have swept up the encountered material which is now seen as a dense ridge, almost detached from the main cloud, and an elongation within the inner cloud, well constrained in both N2H+ emission and mass surface density. This shock compressed material may have then fragmented into cores that are either in a starless or pre-stellar stage. Additional observations are needed to confirm this scenario and the nature of the cores. △ Less

Submitted 25 November, 2024; originally announced November 2024.

Comments: 12 pages, 8 figures, accepted for publication in A&A

Journal ref: A&A 693, A199 (2025)

Excitation and spatial study of a prestellar cluster towards G+0.693-0.027 in the Galactic centre

Authors: L. Colzi, J. Martín-Pintado, S. Zeng, I. Jiménez-Serra, V. M. Rivilla, M. Sanz-Novo, S. Martín, Q. Zhang, X. Lu

Abstract: Star formation in the central molecular zone (CMZ) is suppressed with respect to that of the Galactic disk, and this is likely related to its high turbulent environment. This turbulence impedes the potential detection of prestellar cores. We present the temperature, density, and spatial structure of the CMZ molecular cloud G+0.693-0.027, which has been proposed to host a prestellar cluster in the… ▽ More Star formation in the central molecular zone (CMZ) is suppressed with respect to that of the Galactic disk, and this is likely related to its high turbulent environment. This turbulence impedes the potential detection of prestellar cores. We present the temperature, density, and spatial structure of the CMZ molecular cloud G+0.693-0.027, which has been proposed to host a prestellar cluster in the Sgr B2 region. We analysed multiple HC$_{3}$N rotational transitions that were observed with the IRAM 30m, APEX, Yebes 40m, and GBT radio telescopes, together with SMA+APEX spatially resolved maps. The spectral shape of HC$_{3}$N lines shows three velocity components: a broad component with a line width of 23 km s$^{-1}$ (C1), and two narrow components with line widths of 7.2 and 8.8 km s$^{-1}$ (C2 and C3). This suggests that a fraction of the molecular gas in this cloud is undergoing turbulence dissipation. From a non-local thermodynamic equilibrium analysis we have found H$_{2}$ densities of 2$\times$10$^{4}$ cm$^{-3}$, 5$\times$10$^{4}$ cm$^{-3}$, and 4$\times$10$^{5}$ cm$^{-3}$ and kinetic temperatures of 140 K, 30 K, and 80 K for C1, C2, and C3, respectively. The spatially resolved maps confirm that the colder and high-density condensations C2 and C3, which peak in the 70-85 km s$^{-1}$ velocity range, are embedded in a more diffuse and warmer gas (C1). The larger-scale structure of the Sgr B2 region shows a hole at 40-50 km s$^{-1}$ that is likely due to a small cloud that shocked the Sgr B2 region and is spatially related with a massive cloud at 60-80 km s$^{-1}$. We propose that the impacting small cloud sequentially triggered the formation of Sgr B2(M), (N), and (S) and the condensations in G+0.693-0.027 during its passage. Based on the analysis of the masses of the two condensations and on the virial parameters, C2 might expand, while C3 might further fragment or collapse. △ Less

Submitted 30 August, 2024; originally announced August 2024.

Comments: 21 pages, 16 figures, 5 tables, 4 appendix - Accepted for publication in A&A

The factors that influence protostellar multiplicity I: Gas temperature, density, and mass in Perseus with Nobeyama

Authors: N. M. Murillo, C. M. Fuchs, D. Harsono, N. Sakai, A. Hacar, D. Johnstone, R. Mignon-Risse, S. Zeng, T. -H. Hsieh, Y. -L. Yang, J. J. Tobin, M. V. Persson

Abstract: Protostellar multiplicity is common at all stages and mass ranges. However, the factors that determine the multiplicity of protostellar systems have not been systematically characterized through their molecular gas. Nobeyama 45m Radio Observatory OTF maps of HCN, HNC, HCO$^+$, and N$_2$H$^+$ (J = 1--0) toward five subregions in Perseus, complemented with single pointing APEX observations of HNC (J… ▽ More Protostellar multiplicity is common at all stages and mass ranges. However, the factors that determine the multiplicity of protostellar systems have not been systematically characterized through their molecular gas. Nobeyama 45m Radio Observatory OTF maps of HCN, HNC, HCO$^+$, and N$_2$H$^+$ (J = 1--0) toward five subregions in Perseus, complemented with single pointing APEX observations of HNC (J = 4--3) are used to derive physical parameters of the dense gas. Both observations have angular resolutions of $\sim$18", equivalent to $\sim$5000 AU scales at the distance of Perseus. Kinetic gas temperature is derived from the $I$(HCN)/$I$(HNC) J = 1--0 ratio, and H$_2$ density is obtained from the HNC J=4--3/J=1--0 ratio. These parameters are used to obtain the N$_2$H$^+$ and HCO$^+$ gas masses. The inferred and derived parameters are compared to source parameters. Inferred mean kinetic gas temperature ($I$(HCN)/$I$(HNC) J=1--0 ratio; ranging between 15 and 26 K), and H$_2$ volumetric density (HNC J=4--3/J=1--0; 10$^5$ -- 10$^6$ cm$^{-3}$) do not show correlations with multiplicity in Perseus. The derived gas and dust masses, 1.3 to 16 $\times~10^{-9}$ M$_{\odot}$ for the N$_2$H$^+$ gas mass, 0.1 to 25 M$_{\odot}$ for envelope dust masses (850 $μ$m), and 0.8 to 10 $\times~10^{-10}$ M$_{\odot}$ for the HCO$^+$ gas mass, are correlated to multiplicity and number of protostellar components. The warm gas masses are a factor of 16 lower than the cold gas masses. This work shows that gas and dust mass is correlated to multiplicity at $\sim$5000 AU scales in Perseus. Higher order multiples tend to have higher gas and dust masses in general, while close binaries (separations $\leq$7") and single protostars have similar gas and dust mass distributions. On the other hand, H$_2$ density and kinetic gas temperature do not show any correlation with multiplicity. △ Less

Submitted 19 July, 2024; originally announced July 2024.

Comments: 25 pages, 12 figures, 3 appendices. Accepted for publication in A&A. The abstract has been modified to comply with arXiv's character limit

Journal ref: A&A 689, A267 (2024)

Discovery of MgS and NaS in the Interstellar Medium and tentative detection of CaO

Authors: M. Rey-Montejo, I. Jimenez-Serra, J. Martin-Pintado, V. M. Rivilla, A. Megias, D. San Andres, M. Sanz-Novo, L. Colzi, S. Zeng, A. Lopez-Gallifa, A. Martinez-Henares, S. Martin, B. Tercero, P. de Vicente, M. Requena-Torres

Abstract: We report the first detection of the metal-bearing molecules sodium sulfide (NaS) and magnesium sulfide (MgS) and the tentative detection of calcium monoxide (CaO) in the interstellar medium (ISM) towards the Galactic Center molecular cloud G+0.693-0.027. The derived column densities are (5.0+-1.1) x 10$^{10}$ cm$^{-2}$, (6.0+-0.6) x $^{10}$ cm$^{-2}$, and (2.0+-0.5) x $^{10}$ cm$^{-2}$, respectiv… ▽ More We report the first detection of the metal-bearing molecules sodium sulfide (NaS) and magnesium sulfide (MgS) and the tentative detection of calcium monoxide (CaO) in the interstellar medium (ISM) towards the Galactic Center molecular cloud G+0.693-0.027. The derived column densities are (5.0+-1.1) x 10$^{10}$ cm$^{-2}$, (6.0+-0.6) x $^{10}$ cm$^{-2}$, and (2.0+-0.5) x $^{10}$ cm$^{-2}$, respectively. This translates into fractional abundances with respect to H$_2$ of (3.7+-1.0) x $10^{-13}$, (4.4+-0.8) x $10^{-13}$, and (1.5+-0.4) x $10^{-13}$, respectively. We have also searched for other Na-, Mg- and Ca-bearing species towards this source but none of them have been detected and thus we provide upper limits for their abundances. We discuss the possible chemical routes involved in the formation of these molecules containing metals under interstellar conditions. Finally, we compare the ratio between sulfur-bearing and oxygen-bearing molecules with and without metals, finding that metal-bearing sulfur molecules are much more abundant than metal-bearing oxygen ones, in contrast with the general trend found in the ratios between other non metal- oxygen- and sulfur-bearing molecules. This further strengthen the idea that sulfur may be little depleted in G+0.693-0.027 as a result of the low velocity shocks present in this source sputtering large amounts of material from dust grains. △ Less

Submitted 26 August, 2024; v1 submitted 10 July, 2024; originally announced July 2024.

Comments: 18 pages, 7 tables and 7 figures, final version accepted by ApJ

CH_3OH and Its Deuterated Species in the Disk/Envelope System of the Low-Mass Protostellar Source B335

Authors: Yuki Okoda, Yoko Oya, Nami Sakai, Yoshimasa Watanabe, Ana López-Sepulcre, Takahiro Oyama, Shaoshan Zeng, Satoshi Yamamoto

Abstract: Deuterium fractionation in the closest vicinity of a protostar is important in understanding its potential heritage to a planetary system. Here, we have detected the spectral line emission of CH3OH and its three deuterated species, CH2DOH, CHD2OH, and CH3OD, toward the low-mass protostellar source B335 at a resolution of 0.''03 (5 au) with Atacama Large Millimeter/submillimeter Array. They have a… ▽ More Deuterium fractionation in the closest vicinity of a protostar is important in understanding its potential heritage to a planetary system. Here, we have detected the spectral line emission of CH3OH and its three deuterated species, CH2DOH, CHD2OH, and CH3OD, toward the low-mass protostellar source B335 at a resolution of 0.''03 (5 au) with Atacama Large Millimeter/submillimeter Array. They have a ring distribution within the radius of 24 au with the intensity depression at the continuum peak. We derive the column densities and abundance ratios of the above species at 6 positions in the disk/envelope system as well as the continuum peak. The D/H ratio of CH3OH is ~[0.03-0.13], which is derived by correcting the statistical weight of 3 for CH2DOH. The [CHD2OH]/[CH2DOH] ratio is derived to be higher ([0.14-0.29]). On the other hand, the [CH2DOH]/[CH3OD] ratio ([4.9-15]) is higher than the statistical ratio of 3, and is comparable to those reported for other low-mass sources. We study the physical structure on a few au scale in B335 by analyzing the CH3OH (183,15-182,16, A) and HCOOH (120,12-110,11) line emission. Velocity structures of these lines are reasonably explained as the infalling-rotating motion. The protostellar mass and the upper limit to centrifugal barrier are thus derived to be 0.03-0.07 M_{\odot} and <7 au, respectively, showing that B335 harbors a young protostar with a tiny disk structure. Such youth of the protostar may be related to the relatively high [CH2DOH]/[CH3OH] ratio. △ Less

Submitted 26 May, 2024; originally announced May 2024.

First detection in space of the high-energy isomer of cyanomethanimine: H2CNCN

Authors: David San Andrés, Víctor M. Rivilla, Laura Colzi, Izaskun Jiménez-Serra, Jesús Martín-Pintado, Andrés Megías, Álvaro López-Gallifa, Antonio Martínez-Henares, Sarah Massalkhi, Shaoshan Zeng, Miguel Sanz-Novo, Belén Tercero, Pablo de Vicente, Sergio Martín, Miguel A. Requena-Torres, Germán Molpeceres, Juan García de la Concepción

Abstract: We report the first detection in the interstellar medium of $N$-cyanomethanimine (H$_2$CNCN), the stable dimer of HCN of highest energy, and the most complex organic molecule identified in space containing the prebiotically relevant NCN backbone. We have identified a plethora of $a$-type rotational transitions with 3 $\leq J_\text{up} \leq$ 11 and $K_\text{a} \leq$ 2 that belong to this species to… ▽ More We report the first detection in the interstellar medium of $N$-cyanomethanimine (H$_2$CNCN), the stable dimer of HCN of highest energy, and the most complex organic molecule identified in space containing the prebiotically relevant NCN backbone. We have identified a plethora of $a$-type rotational transitions with 3 $\leq J_\text{up} \leq$ 11 and $K_\text{a} \leq$ 2 that belong to this species towards the Galactic Center G+0.693-0.027 molecular cloud, the only interstellar source showing the three cyanomethanimine isomers (including the $Z$- and $E$- isomers of $C$-cyanomethanimine, HNCHCN). We have derived a total column density for H$_2$CNCN of (2.9$\, \pm \,$0.1)$\times$10$^{12}$ cm$^{-2}$, which translates into a total molecular abundance with respect to H$_2$ of (2.1$\, \pm \,$0.3)$\times$10$^{-11}$. We have also revisited the previous detection of $E$- and $Z$-HNCHCN, and found a total $C/N$-cyanomethanimine abundance ratio of 31.8$\, \pm \,$1.8 and a $Z/E$-HNCHCN ratio of 4.5$\, \pm \,$0.2. While the latter can be explained on the basis of thermodynamic equilibrium, chemical kinetics are more likely responsible for the observed $C/N$-cyanomethanimine abundance ratio, where the gas-phase reaction between methanimine (CH$_2$NH) and the cyanogen radical (CN) arises as the primary formation route. △ Less

Submitted 9 April, 2024; v1 submitted 4 April, 2024; originally announced April 2024.

Comments: 22 pages, 8 figures, 3 tables, 2 appendix - Accepted for publication in The Astrophysical Journal

Discovery of thionylimide, HNSO, in space: the first N-, S- and O-bearing interstellar molecule

Authors: Miguel Sanz-Novo, Víctor M. Rivilla, Holger S. P. Müller, Izaskun Jiménez-Serra, Jesús Martín-Pintado, Laura Colzi, Shaoshan Zeng, Andrés Megías, Álvaro López-Gallifa, Antonio Martínez-Henares, Belén Tercero, Pablo de Vicente, David San Andrés, Sergio Martín, Miguel A. Requena-Torres

Abstract: We present the first detection in space of thionylimide (HNSO) toward the Galactic Center molecular cloud G+0.693-0.027, thanks to the superb sensitivity of an ultradeep molecular line survey carried out with the Yebes 40$\,$m and IRAM 30$\,$m telescopes. This molecule is the first species detected in the interstellar medium containing, simultaneously, N, S and O. We have identified numerous $K$… ▽ More We present the first detection in space of thionylimide (HNSO) toward the Galactic Center molecular cloud G+0.693-0.027, thanks to the superb sensitivity of an ultradeep molecular line survey carried out with the Yebes 40$\,$m and IRAM 30$\,$m telescopes. This molecule is the first species detected in the interstellar medium containing, simultaneously, N, S and O. We have identified numerous $K$$_a$ = 0, 1 and 2 transitions belonging to HNSO covering from $J$$_{\rm up}$ = 2 to $J$$_{\rm up}$ = 10, including several completely unblended features. We derive a molecular column density of $N$ = (8 $\pm$ 1)$\times$10$^{13}$ cm$^{-2}$, yielding a fractional abundance relative to H$_2$ of $\sim$6$\times$10$^{-10}$, which is about $\sim$37 and $\sim$4.8 times less abundant than SO and SO2, respectively. Although there are still many unknowns in the interstellar chemistry of NSO-bearing molecules, we propose that HNSO is likely formed through the reaction of the NSO radical and atomic H on the surface of icy grains, with alternative routes also deserving exploration. Finally, HNSO appears as a promising link between N- , S- and O- interstellar chemistry and its discovery paves the route to the detection of a new family of molecules in space. △ Less

Submitted 1 April, 2024; originally announced April 2024.

Comments: Forthcoming paper in The Astrophysical Journal Letters (in press)

Interstellar detection of O-protonated carbonyl sulfide, HOCS+

Authors: Miguel Sanz-Novo, Víctor M. Rivilla, Izaskun Jiménez-Serra, Jesús Martín-Pintado, Laura Colzi, Shaoshan Zeng, Andrés Megías, Álvaro López-Gallifa, Antonio Martínez-Henares, Sarah Massalkhi, Belén Tercero, Pablo de Vicente, David San Andrés, Sergio Martín, Miguel A. Requena-Torres

Abstract: We present the first detection in space of O-protonated carbonyl sulfide (\ch{HOCS+}), in the midst of an ultradeep molecular line survey toward the G+0.693-0.027 molecular cloud. From the observation of all $K$$_a$ = 0 transitions ranging from $J$$_{lo}$ = 2 to $J$$_{lo}$ = 13 of \ch{HOCS+} covered by our survey, we derive a column density of $N$ = (9 $\pm$ 2)$\times$10$^{12}$ cm$^{-2}$, translat… ▽ More We present the first detection in space of O-protonated carbonyl sulfide (\ch{HOCS+}), in the midst of an ultradeep molecular line survey toward the G+0.693-0.027 molecular cloud. From the observation of all $K$$_a$ = 0 transitions ranging from $J$$_{lo}$ = 2 to $J$$_{lo}$ = 13 of \ch{HOCS+} covered by our survey, we derive a column density of $N$ = (9 $\pm$ 2)$\times$10$^{12}$ cm$^{-2}$, translating into a fractional abundance relative to H$_2$ of $\sim$7$\times$10$^{-11}$. Conversely, the S-protonated \ch{HSCO+} isomer remains undetected, and we derive an upper limit to its abundance with respect to H$_2$ of $\leq$3$\times$10$^{-11}$, a factor of $\geq$2.3 less abundant than \ch{HOCS+}. We obtain a \ch{HOCS+}/OCS ratio of $\sim$2.5$\times$10$^{-3}$, in good agreement with the prediction of astrochemical models. These models show that one of the main chemical routes to the interstellar formation of \ch{HOCS+} is likely the protonation of OCS, which appears to be more efficient at the oxygen end. Also, we find that high values of cosmic-ray ionisation rates (10$^{-15}$-10$^{-14}$ s$^{-1}$) are needed to reproduce the observed abundance of \ch{HOCS+}. In addition, we compare the O/S ratio across different interstellar environments. G+0.693-0.027 appears as the source with the lowest O/S ratio. We find a \ch{HOCO+}/\ch{HOCS+} ratio of $\sim$31, in accordance with other O/S molecular pairs detected toward this region and also close to the O/S solar value ($\sim$37). This fact indicates that S is not significantly depleted within this cloud due to the action of large-scale shocks, unlike in other sources where S-bearing species remain trapped on icy dust grains. △ Less

Submitted 23 February, 2024; originally announced February 2024.

Comments: Forthcoming paper in The Astrophysical Journal (in press)

Real-time Monitoring for the Next Core-Collapse Supernova in JUNO

Authors: Angel Abusleme, Thomas Adam, Shakeel Ahmad, Rizwan Ahmed, Sebastiano Aiello, Muhammad Akram, Abid Aleem, Fengpeng An, Qi An, Giuseppe Andronico, Nikolay Anfimov, Vito Antonelli, Tatiana Antoshkina, Burin Asavapibhop, João Pedro Athayde Marcondes de André, Didier Auguste, Weidong Bai, Nikita Balashov, Wander Baldini, Andrea Barresi, Davide Basilico, Eric Baussan, Marco Bellato, Marco Beretta, Antonio Bergnoli , et al. (606 additional authors not shown)

Abstract: The core-collapse supernova (CCSN) is considered one of the most energetic astrophysical events in the universe. The early and prompt detection of neutrinos before (pre-SN) and during the supernova (SN) burst presents a unique opportunity for multi-messenger observations of CCSN events. In this study, we describe the monitoring concept and present the sensitivity of the system to pre-SN and SN neu… ▽ More The core-collapse supernova (CCSN) is considered one of the most energetic astrophysical events in the universe. The early and prompt detection of neutrinos before (pre-SN) and during the supernova (SN) burst presents a unique opportunity for multi-messenger observations of CCSN events. In this study, we describe the monitoring concept and present the sensitivity of the system to pre-SN and SN neutrinos at the Jiangmen Underground Neutrino Observatory (JUNO), a 20 kton liquid scintillator detector currently under construction in South China. The real-time monitoring system is designed to ensure both prompt alert speed and comprehensive coverage of progenitor stars. It incorporates prompt monitors on the electronic board as well as online monitors at the data acquisition stage. Assuming a false alert rate of 1 per year, this monitoring system exhibits sensitivity to pre-SN neutrinos up to a distance of approximately 1.6 (0.9) kiloparsecs and SN neutrinos up to about 370 (360) kiloparsecs for a progenitor mass of 30 solar masses, considering both normal and inverted mass ordering scenarios. The pointing ability of the CCSN is evaluated by analyzing the accumulated event anisotropy of inverse beta decay interactions from pre-SN or SN neutrinos. This, along with the early alert, can play a crucial role in facilitating follow-up multi-messenger observations of the next galactic or nearby extragalactic CCSN. △ Less

Submitted 4 December, 2023; v1 submitted 13 September, 2023; originally announced September 2023.

Comments: 24 pages, 9 figures, accepted for the publication at JCAP

The first detection of SiC$_2$ in the interstellar medium

Authors: S. Massalkhi, I. Jiménez-Serra, J. Martín-Pintado, V. M. Rivilla, L. Colzi, S. Zeng, S. Martín, B. Tercero, P. de Vicente, M. A. Requena-Torres

Abstract: We report the first detection of SiC$_2$ in the interstellar medium. The molecule was identified through six rotational transitions toward G\,+0.693$-$0.027, a molecular cloud located in the Galactic center. The detection is based on a line survey carried out with the GBT, the Yebes 40m, and the IRAM 30m telescopes covering a range of frequencies from 12 to 276 GHz. We fit the observed spectra ass… ▽ More We report the first detection of SiC$_2$ in the interstellar medium. The molecule was identified through six rotational transitions toward G\,+0.693$-$0.027, a molecular cloud located in the Galactic center. The detection is based on a line survey carried out with the GBT, the Yebes 40m, and the IRAM 30m telescopes covering a range of frequencies from 12 to 276 GHz. We fit the observed spectra assuming local thermodynamic equilibrium and derive a column density of ($1.02\pm0.04)\times10^{13}$ cm$^{-2}$, which gives a fractional abundance of $7.5\times10^{-11}$ with respect to H$_2$, and an excitation temperature of $5.9\pm0.2$ K. We conclude that SiC$_2$ can be formed in the shocked gas by a reaction between the sputtered atomic silicon and C$_2$H$_2$, or it can be released directly from the dust grains due to disruption. We also search for other Si-bearing molecules and detect eight rotational transitions of SiS and four transitions of Si$^{18}$O. The derived fractional abundances are $3.9\times10^{-10}$ and $2.1\times10^{-11}$, respectively. All Si-bearing species toward G\,+0.693$-$0.027 show fractional abundances well below what is typically found in late-type evolved stars. △ Less

Submitted 6 October, 2023; v1 submitted 18 August, 2023; originally announced August 2023.

Comments: 8 pages, 5 figures

Journal ref: A&A 678, A45 (2023)

First glycine isomer detected in the interstellar medium: glycolamide (NH$_2$C(O)CH$_2$OH)

Authors: Víctor M. Rivilla, Miguel Sanz-Novo, Izaskun Jiménez-Serra, Jesús Martín-Pintado, Laura Colzi, Shaoshan Zeng, Andrés Megías, Álvaro López-Gallifa, Antonio Martínez-Henares, Sarah Massalkhi, Belén Tercero, Pablo de Vicente, Sergio Martín, David San Andrés, Miguel A. Requena-Torres, José Luis Alonso

Abstract: We report the first detection in the interstellar medium of a C$_2$H$_5$O$_2$N isomer: $syn$-glycolamide (NH$_2$C(O)CH$_2$OH). The exquisite sensitivity at sub-mK levels of an ultra-deep spectral survey carried out with the Yebes 40m and IRAM 30m telescopes towards the G+0.693-0.027 molecular cloud have allowed us to unambiguously identify multiple transitions of this species. We derived a column… ▽ More We report the first detection in the interstellar medium of a C$_2$H$_5$O$_2$N isomer: $syn$-glycolamide (NH$_2$C(O)CH$_2$OH). The exquisite sensitivity at sub-mK levels of an ultra-deep spectral survey carried out with the Yebes 40m and IRAM 30m telescopes towards the G+0.693-0.027 molecular cloud have allowed us to unambiguously identify multiple transitions of this species. We derived a column density of (7.4 $\pm$ 0.7)$\times$10$^{12}$ cm$^{-2}$, which implies a molecular abundance with respect to H$_2$ of 5.5$\times$10$^{-11}$. The other C$_2$H$_5$O$_2$N isomers, including the higher-energy $anti$ conformer of glycolamide, and two conformers of glycine, were not detected. The upper limit derived for the abundance of glycine indicates that this amino acid is surely less abundant than its isomer glycolamide in the ISM. The abundances of the C$_2$H$_5$O$_2$N isomers cannot be explained in terms of thermodynamic equilibrium, and thus chemical kinetics need to be invoked. While the low abundance of glycine might not be surprising, based on the relative low abundances of acids in the ISM compared to other compounds (e.g. alcohols, aldehydes or amines), several chemical pathways can favour the formation of its isomer glycolamide. It can be formed through radical-radical reactions on the surface of dust grains. The abundances of these radicals can be significantly boosted in an environment affected by a strong ultraviolet field induced by cosmic rays, such as that expected in G+0.693-0.027. Therefore, as shown by several recent molecular detections towards this molecular cloud, it stands out as the best target to discover new species with carbon, oxygen and nitrogen with increasing chemical complexity. △ Less

Submitted 11 August, 2023; v1 submitted 21 July, 2023; originally announced July 2023.

Comments: Accepted in The Astrophysical Journal Letters

Discovery of the elusive carbonic acid (HOCOOH) in space

Authors: Miguel Sanz-Novo, Víctor M. Rivilla, Izaskun Jiménez-Serra, Jesús Martín-Pintado, Laura Colzi, Shaoshan Zeng, Andrés Megías, Álvaro López-Gallifa, Antonio Martínez-Henares, Sarah Massalkhi, Belén Tercero, Pablo de Vicente, Sergio Martín, David San Andrés, Miguel A. Requena-Torres

Abstract: After a quarter century since the detection of the last interstellar carboxylic acid, acetic acid (CH$_3$COOH), we report the discovery of a new one, the cis-trans form of carbonic acid (HOCOOH), toward the Galactic Center molecular cloud G+0.693-0.027. HOCOOH stands as the first interstellar molecule containing three oxygen atoms and also the third carboxylic acid detected so far in the interstel… ▽ More After a quarter century since the detection of the last interstellar carboxylic acid, acetic acid (CH$_3$COOH), we report the discovery of a new one, the cis-trans form of carbonic acid (HOCOOH), toward the Galactic Center molecular cloud G+0.693-0.027. HOCOOH stands as the first interstellar molecule containing three oxygen atoms and also the third carboxylic acid detected so far in the interstellar medium. Albeit the limited available laboratory measurements (up to 65 GHz), we have also identified several pairs of unblended lines directly in the astronomical data (between 75-120 GHz), which allowed us to slightly improve the set of spectroscopic constants. We derive a column density for cis-trans HOCOOH of $N$ = (6.4 $\pm$ 0.4) $\times$ 10$^{12}$ cm$^{-2}$, which yields an abundance with respect to molecular H$_2$ of 4.7 $\times$ 10$^{-11}$. Meanwhile, the extremely low dipole moment (about fifteen times lower) of the lower-energy conformer, cis-cis HOCOOH, precludes its detection. We obtain an upper limit to its abundance with respect to H$_2$ of $\leq$ 1.2 $\times$10$^{-9}$, which suggests that cis-cis HOCOOH might be fairly abundant in interstellar space, although it is nearly undetectable by radio astronomical observations. We derive a cis-cis/cis-trans ratio $\leq$ 25, consistent with the smaller energy difference between both conformers compared with the relative stability of trans- and cis-formic acid (HCOOH). Finally, we compare the abundance of these acids in different astronomical environments, further suggesting a relationship between the chemical content found in the interstellar medium and the chemical composition of the minor bodies of the Solar System, which could be inherited during the star formation process. △ Less

Submitted 18 July, 2023; v1 submitted 17 July, 2023; originally announced July 2023.

Comments: Accepted for publication in The Astrophysical Journal

Journal ref: ApJ, 954 3, 2023

JUNO sensitivity to the annihilation of MeV dark matter in the galactic halo

Authors: JUNO Collaboration, Angel Abusleme, Thomas Adam, Shakeel Ahmad, Rizwan Ahmed, Sebastiano Aiello, Muhammad Akram, Abid Aleem, Tsagkarakis Alexandros, Fengpeng An, Qi An, Giuseppe Andronico, Nikolay Anfimov, Vito Antonelli, Tatiana Antoshkina, Burin Asavapibhop, João Pedro Athayde Marcondes de André, Didier Auguste, Weidong Bai, Nikita Balashov, Wander Baldini, Andrea Barresi, Davide Basilico, Eric Baussan, Marco Bellato , et al. (581 additional authors not shown)

Abstract: We discuss JUNO sensitivity to the annihilation of MeV dark matter in the galactic halo via detecting inverse beta decay reactions of electron anti-neutrinos resulting from the annihilation. We study possible backgrounds to the signature, including the reactor neutrinos, diffuse supernova neutrino background, charged- and neutral-current interactions of atmospheric neutrinos, backgrounds from muon… ▽ More We discuss JUNO sensitivity to the annihilation of MeV dark matter in the galactic halo via detecting inverse beta decay reactions of electron anti-neutrinos resulting from the annihilation. We study possible backgrounds to the signature, including the reactor neutrinos, diffuse supernova neutrino background, charged- and neutral-current interactions of atmospheric neutrinos, backgrounds from muon-induced fast neutrons and cosmogenic isotopes. A fiducial volume cut, as well as the pulse shape discrimination and the muon veto are applied to suppress the above backgrounds. It is shown that JUNO sensitivity to the thermally averaged dark matter annihilation rate in 10 years of exposure would be significantly better than the present-day best limit set by Super-Kamiokande and would be comparable to that expected by Hyper-Kamiokande. △ Less

Submitted 13 September, 2023; v1 submitted 15 June, 2023; originally announced June 2023.

Comments: 25 pages, 9 figures, matches the publised version

Journal ref: JCAP 09 (2023) 001

Deuterium Fractionation across the Infrared Dark Cloud G034.77-00.55 interacting with the Supernova Remnant W44

Authors: G. Cosentino, J. C. Tan, I. Jiménez-Serra, F. Fontani, P. Caselli, J. D. Henshaw, A. T. Barnes, C. -Y. Law, S. Viti, R. Fedriani, C. -J. Hsu, P. Gorai, S. Zeng

Abstract: Supernova remnants (SNRs) may regulate star formation in galaxies. For example, SNR-driven shocks may form new molecular gas or compress pre-existing clouds and trigger the formation of new stars. To test this scenario, we measure the deuteration of $N_2H^+$, $D_{frac}^{N_2H^+}$, a well-studied tracer of pre-stellar cores, across the Infrared Dark Cloud (IRDC) G034.77-00.55, known to be experienci… ▽ More Supernova remnants (SNRs) may regulate star formation in galaxies. For example, SNR-driven shocks may form new molecular gas or compress pre-existing clouds and trigger the formation of new stars. To test this scenario, we measure the deuteration of $N_2H^+$, $D_{frac}^{N_2H^+}$, a well-studied tracer of pre-stellar cores, across the Infrared Dark Cloud (IRDC) G034.77-00.55, known to be experiencing a shock interaction with the SNR W44. We use N$_2$H$^+$ and N$_2$D$^+$ J=1-0 single pointing observations obtained with the 30m antenna at the Instituto de Radioastronomia Millimetrica to infer $D_{frac}^{N_2H^+}$ toward five positions across the cloud, namely a massive core, different regions across the shock front, a dense clump and ambient gas. We find $D_{frac}^{N_2H^+}$ in the range 0.03-0.1, several orders of magnitude larger than the cosmic D/H ratio ($\sim$10$^{-5}$). Across the shock front, $D_{frac}^{N_2H^+}$ is enhanced by more than a factor of 2 ($D_{frac}^{N_2H^+}\sim$0.05-0.07) with respect to the ambient gas ($\leq$0.03) and similar to that measured generally in pre-stellar cores. Indeed, in the massive core and dense clump regions of this IRDC we measure $D_{frac}^{N_2H^+}$}$\sim$0.1. We find enhanced deuteration of $N_2H^+$ across the region of the shock, at a level that is enhanced with respect to regions of unperturbed gas. It is possible that this has been induced by shock compression, which would then be indirect evidence that the shock is triggering conditions for future star formation. However, since unperturbed dense regions also show elevated levels of deuteration, further, higher-resolution studies are needed to better understand the structure and kinematics of the deuterated material in the shock region, e.g., if it still in relatively diffuse form or already organised in a population of low-mass pre-stellar cores. △ Less

Submitted 5 June, 2023; originally announced June 2023.

Comments: Accepted for publication on A&A; 8 pages, 5 figures

Journal ref: A&A 675, A190 (2023)

Amides inventory towards the G+0.693-0.027 molecular cloud

Authors: S. Zeng, V. M. Rivilla, I. Jiménez-Serra, L. Colzi, J. Martín-Pintado, B. Tercero, P. de Vicente, S. Martín, M. A. Requena-Torres

Abstract: Interstellar amides have attracted significant attentions as they are potential precursors for a wide variety of organics essential to life. However, our current understanding of their formation in space is heavily based on observations in star-forming regions and hence the chemical networks lack the constraints on their early origin. In this work, unbiased sensitive spectral surveys with IRAM 30m… ▽ More Interstellar amides have attracted significant attentions as they are potential precursors for a wide variety of organics essential to life. However, our current understanding of their formation in space is heavily based on observations in star-forming regions and hence the chemical networks lack the constraints on their early origin. In this work, unbiased sensitive spectral surveys with IRAM 30m and Yebes 40m telescopes are used to systematically study a number of amides towards a quiescent Galactic Centre molecular cloud, G+0.693-0.027. We report the first detection of acetamide (CH3C(O)NH2) and trans-N-methylformamide (CH3NHCHO) towards this cloud. In addition, with the wider frequency coverage of the survey, we revisited the detection of formamide (NH2CHO) and urea (carbamide; NH2C(O)NH2), which had been reported previously towards G+0.693-0.027. Our results are compared with those present in the literature including recent laboratory experiments and chemical models. We find constant abundance ratios independently of the evolutionary stages, suggesting that amides related chemistry is triggered in early evolutionary stages of molecular cloud and remain unaffected by the warm-up phase during the star formation process. Although a correlation between more complex amides and NH2CHO have been suggested, alternative formation routes involving other precursors such as acetaldehyde (CH3CHO), methyl isocyanate (CH3NCO) and methylamine (CH3NH2) may also contribute to the production of amides. Observations of amides together with these species towards a larger sample of sources can help to constrain the amide chemistry in the interstellar medium. △ Less

Submitted 29 May, 2023; originally announced May 2023.

Comments: 16 pages, 8 figures, 3 tables, accepted for publication in Monthly Notices of the Royal Astronomical Society

FacetClumps: A Facet-based Molecular Clump Detection Algorithm

Authors: Yu Jiang, Zhiwei Chen, Sheng Zheng, Zhibo Jiang, Yao Huang, Shuguang Zeng, Xiangyun Zeng, Xiaoyu Luo

Abstract: A comprehensive understanding of molecular clumps is essential for investigating star formation. We present an algorithm for molecular clump detection, called FacetClumps. This algorithm uses a morphological approach to extract signal regions from the original data. The Gaussian Facet model is employed to fit the signal regions, which enhances the resistance to noise and the stability of the algor… ▽ More A comprehensive understanding of molecular clumps is essential for investigating star formation. We present an algorithm for molecular clump detection, called FacetClumps. This algorithm uses a morphological approach to extract signal regions from the original data. The Gaussian Facet model is employed to fit the signal regions, which enhances the resistance to noise and the stability of the algorithm in diverse overlapping areas. The introduction of the extremum determination theorem of multivariate functions offers theoretical guidance for automatically locating clump centers. To guarantee that each clump is continuous, the signal regions are segmented into local regions based on gradient, and then the local regions are clustered into the clump centers based on connectivity and minimum distance to identify the regional information of each clump. Experiments conducted with both simulated and synthetic data demonstrate that FacetClumps exhibits great recall and precision rates, small location error and flux loss, a high consistency between the region of detected clump and that of simulated clump, and is generally stable in various environments. Notably, the recall rate of FacetClumps in the synthetic data, which comprises $^{13}CO$ ($J = 1-0$) emission line of the MWISP within $11.7^{\circ} \leq l \leq 13.4^{\circ}$, $0.22^{\circ} \leq b \leq 1.05^{\circ}$ and 5 km s$^{-1}$ $\leq v \leq$ 35 km s$^{-1}$ and simulated clumps, reaches 90.2%. Additionally, FacetClumps demonstrates satisfactory performance when applied to observational data. △ Less

Submitted 2 June, 2023; v1 submitted 29 May, 2023; originally announced May 2023.

Comments: Accepted for ApJS

H2CN/H2NC abundance ratio: a new potential temperature tracer for the interstellar medium

Authors: David San Andrés, Laura Colzi, Víctor M. Rivilla, Juan García de la Concepción, Mattia Melosso, Jesús Martín-Pintado, Izaskun Jiménez-Serra, Shaoshan Zeng, Sergio Martín, Miguel A. Requena-Torres

Abstract: The ${\rm H_2NC}$ radical is the high-energy metastable isomer of ${\rm H_2CN}$ radical, which has been recently detected for the first time in the interstellar medium towards a handful of cold galactic sources, besides a warm galaxy in front of the PKS 1830-211 quasar. These detections have shown that the ${\rm H_2CN}$/${\rm H_2NC}$ isomeric ratio, likewise the HCN/HNC ratio, might increase with… ▽ More The ${\rm H_2NC}$ radical is the high-energy metastable isomer of ${\rm H_2CN}$ radical, which has been recently detected for the first time in the interstellar medium towards a handful of cold galactic sources, besides a warm galaxy in front of the PKS 1830-211 quasar. These detections have shown that the ${\rm H_2CN}$/${\rm H_2NC}$ isomeric ratio, likewise the HCN/HNC ratio, might increase with the kinetic temperature ($T_{\rm kin}$), but the shortage of them in warm sources still prevents us to confirm this hypothesis and shed light about their chemistry. In this work, we present the first detection of ${\rm H_2CN}$ and ${\rm H_2NC}$ towards a warm galactic source, the G+0.693-0.027 molecular cloud (with $T_{\rm kin} > 70 \, {\rm K}$), using IRAM 30m observations. We have detected multiple hyperfine components of the $N_{K_\text{a}K_\text{c}} = 1_{01} - 0_{00}$ and $2_{02} - 1_{01}$ transitions. We derived molecular abundances with respect to ${\rm H_2}$ of (6.8$\pm$1.3)$\times 10^{-11}$ for ${\rm H_2CN}$ and of (3.1$\pm$0.7)$\times 10^{-11}$ for ${\rm H_2NC}$, and a ${\rm H_2CN}$/${\rm H_2NC}$ abundance ratio of 2.2$\pm$0.5. These detections confirm that the ${\rm H_2CN}$/${\rm H_2NC}$ ratio is $\gtrsim$2 for sources with $T_{\rm kin} > 70 \, {\rm K}$, larger than the $\sim$1 ratios previously found in colder cores ($T_{\rm kin}\sim10 \, {\rm K}$). This isomeric ratio dependence with temperature cannot be fully explained with the currently proposed gas-phase formation and destruction pathways. Grain surface reactions, including the ${\rm H_2NC} \rightarrow {\rm H_2CN}$ isomerization, deserve consideration to explain the higher isomeric ratios and ${\rm H_2CN}$ abundances observed in warm sources, where the molecules can be desorbed into the gas phase through thermal and/or shock-induced mechanisms. △ Less

Submitted 5 June, 2023; v1 submitted 8 May, 2023; originally announced May 2023.

Comments: 12 pages, 5 figures, 3 tables, 2 appendix - Accepted for publication in Monthly Notices of the Royal Astronomical Society

Model Independent Approach of the JUNO $^8$B Solar Neutrino Program

Authors: JUNO Collaboration, Jie Zhao, Baobiao Yue, Haoqi Lu, Yufeng Li, Jiajie Ling, Zeyuan Yu, Angel Abusleme, Thomas Adam, Shakeel Ahmad, Rizwan Ahmed, Sebastiano Aiello, Muhammad Akram, Abid Aleem, Tsagkarakis Alexandros, Fengpeng An, Qi An, Giuseppe Andronico, Nikolay Anfimov, Vito Antonelli, Tatiana Antoshkina, Burin Asavapibhop, João Pedro Athayde Marcondes de André, Didier Auguste, Weidong Bai , et al. (579 additional authors not shown)

Abstract: The physics potential of detecting $^8$B solar neutrinos will be exploited at the Jiangmen Underground Neutrino Observatory (JUNO), in a model independent manner by using three distinct channels of the charged-current (CC), neutral-current (NC) and elastic scattering (ES) interactions. Due to the largest-ever mass of $^{13}$C nuclei in the liquid-scintillator detectors and the {expected} low backg… ▽ More The physics potential of detecting $^8$B solar neutrinos will be exploited at the Jiangmen Underground Neutrino Observatory (JUNO), in a model independent manner by using three distinct channels of the charged-current (CC), neutral-current (NC) and elastic scattering (ES) interactions. Due to the largest-ever mass of $^{13}$C nuclei in the liquid-scintillator detectors and the {expected} low background level, $^8$B solar neutrinos would be observable in the CC and NC interactions on $^{13}$C for the first time. By virtue of optimized event selections and muon veto strategies, backgrounds from the accidental coincidence, muon-induced isotopes, and external backgrounds can be greatly suppressed. Excellent signal-to-background ratios can be achieved in the CC, NC and ES channels to guarantee the $^8$B solar neutrino observation. From the sensitivity studies performed in this work, we show that JUNO, with ten years of data, can reach the {1$σ$} precision levels of 5%, 8% and 20% for the $^8$B neutrino flux, $\sin^2θ_{12}$, and $Δm^2_{21}$, respectively. It would be unique and helpful to probe the details of both solar physics and neutrino physics. In addition, when combined with SNO, the world-best precision of 3% is expected for the $^8$B neutrino flux measurement. △ Less

Submitted 6 March, 2024; v1 submitted 15 October, 2022; originally announced October 2022.

Comments: 19 pages, 7 figures, accepted version to appear in The Astrophysical Journal. Yufeng Li and Jiajie Ling are corresponding authors

Journal ref: Astrophysical Journal 965 (2024) 122

Estimating Atmospheric Parameters from LAMOST Low-Resolution Spectra with Low SNR

Authors: Xiangru Li, Si Zeng, Zhu Wang, Bing Du, Xiao Kong, Caixiu Liao

Abstract: Large Sky Area Multi-Object Fiber Spectroscopic Telescope (LAMOST) acquired tens of millions of low-resolution stellar spectra. The large amount of the spectra result in the urgency to explore automatic atmospheric parameter estimation methods. There are lots of LAMOST spectra with low signal-to-noise ratios (SNR), which result in a sharp degradation on the accuracy of their estimations. Therefore… ▽ More Large Sky Area Multi-Object Fiber Spectroscopic Telescope (LAMOST) acquired tens of millions of low-resolution stellar spectra. The large amount of the spectra result in the urgency to explore automatic atmospheric parameter estimation methods. There are lots of LAMOST spectra with low signal-to-noise ratios (SNR), which result in a sharp degradation on the accuracy of their estimations. Therefore, it is necessary to explore better estimation methods for low-SNR spectra. This paper proposed a neural network-based scheme to deliver atmospheric parameters, LASSO-MLPNet. Firstly, we adopt a polynomial fitting method to obtain pseudo-continuum and remove it. Then, some parameter-sensitive features in the existence of high noises were detected using Least Absolute Shrinkage and Selection Operator (LASSO). Finally, LASSO-MLPNet used a Multilayer Perceptron network (MLPNet) to estimate atmospheric parameters $T_{\mathrm{eff}}$, log $g$ and [Fe/H]. The effectiveness of the LASSO-MLPNet was evaluated on some LAMOST stellar spectra of the common star between APOGEE (The Apache Point Observatory Galactic Evolution Experiment) and LAMOST. it is shown that the estimation accuracy is significantly improved on the stellar spectra with $10<\mathrm{SNR}\leq80$. Especially, LASSO-MLPNet reduces the mean absolute error (MAE) of the estimation of $T_{\mathrm{eff}}$, log $g$ and [Fe/H] from (144.59 K, 0.236 dex, 0.108 dex) (LASP) to (90.29 K, 0.152 dex, 0.064 dex) (LASSO-MLPNet) on the stellar spectra with $10<\mathrm{SNR}\leq20$. To facilitate reference, we release the estimates of the LASSO-MLPNet from more than 4.82 million stellar spectra with $10<\mathrm{SNR}\leq80$ and 3500 < SNR$g$ $\leq$ 6500 as a value-added output. △ Less

Submitted 13 July, 2022; originally announced July 2022.

Comments: 14 pages, 12 figures, 5 tables

Journal ref: MNRAS,514(3): 4588-4600,2022

Molecular precursors of the RNA-world in space: new nitriles in the G+0.693-0.027 molecular cloud

Authors: Víctor M. Rivilla, Izaskun Jiménez-Serra, Jesus Martín-Pintado, Laura Colzi, Belén Tercero, Pablo de Vicente, Shaoshan Zeng, Sergio Martín, Juan García de la Concepción, Luca Bizzocchi, Mattia Melosso, Fernando Rico-Villas, Miguel A. Requena-Torres

Abstract: Nitriles play a key role as molecular precursors in prebiotic experiments based on the RNA-world scenario for the origin of life. These chemical compounds could have been partially delivered to the young Earth from extraterrestrial objects, stressing the importance of establishing the reservoir of nitriles in the interstellar medium. We report here the detection towards the molecular cloud G+0.693… ▽ More Nitriles play a key role as molecular precursors in prebiotic experiments based on the RNA-world scenario for the origin of life. These chemical compounds could have been partially delivered to the young Earth from extraterrestrial objects, stressing the importance of establishing the reservoir of nitriles in the interstellar medium. We report here the detection towards the molecular cloud G+0.693-0.027 of several nitriles, including cyanic acid (HOCN), and three C$_4$H$_3$N isomers (cyanoallene, CH$_2$CCHCN; propargyl cyanide, HCCCH$_2$CN; and cyanopropyne (CH$_3$CCCN), and the tentative detections of cyanoformaldehyde (HCOCN), and glycolonitrile (HOCH$_2$CN). We have also performed the first interstellar search of cyanoacetaldehyde (HCOCH$_2$CN), which was not detected. Based on the derived molecular abundances of the different nitriles in G+0.693-0.027 and other interstellar sources, we have discussed their formation mechanisms in the ISM. We propose that the observed HOCN abundance in G+0.693-0.027 is mainly due to surface chemistry and subsequent shock-induced desorption, while HCOCN might be mainly formed through gas-phase chemistry. In the case of HOCH$_2$CN, several grain-surface routes from abundant precursors could produce it. The derived abundances of the three C$_4$H$_3$N isomers in G+0.693-0.027 are very similar, and also similar to those previously reported in the dark cold cloud TMC-1. This suggests that the three isomers are likely formed through gas-phase chemistry from common precursors, possibly unsaturated hydrocarbons (CH$_3$CCH and CH$_2$CCH$_2$) that react with the cyanide radical (CN). The rich nitrile feedstock found towards G+0.693-0.027 confirms that interstellar chemistry is able to synthesize in space molecular species that could drive the prebiotic chemistry of the RNA-world. △ Less

Submitted 2 June, 2022; originally announced June 2022.

Comments: Accepted in Frontiers in Astronomy and Space Sciences

Prospects for Detecting the Diffuse Supernova Neutrino Background with JUNO

Authors: JUNO Collaboration, Angel Abusleme, Thomas Adam, Shakeel Ahmad, Rizwan Ahmed, Sebastiano Aiello, Muhammad Akram, Fengpeng An, Qi An, Giuseppe Andronico, Nikolay Anfimov, Vito Antonelli, Tatiana Antoshkina, Burin Asavapibhop, João Pedro Athayde Marcondes de André, Didier Auguste, Nikita Balashov, Wander Baldini, Andrea Barresi, Davide Basilico, Eric Baussan, Marco Bellato, Antonio Bergnoli, Thilo Birkenfeld, Sylvie Blin , et al. (577 additional authors not shown)

Abstract: We present the detection potential for the diffuse supernova neutrino background (DSNB) at the Jiangmen Underground Neutrino Observatory (JUNO), using the inverse-beta-decay (IBD) detection channel on free protons. We employ the latest information on the DSNB flux predictions, and investigate in detail the background and its reduction for the DSNB search at JUNO. The atmospheric neutrino induced n… ▽ More We present the detection potential for the diffuse supernova neutrino background (DSNB) at the Jiangmen Underground Neutrino Observatory (JUNO), using the inverse-beta-decay (IBD) detection channel on free protons. We employ the latest information on the DSNB flux predictions, and investigate in detail the background and its reduction for the DSNB search at JUNO. The atmospheric neutrino induced neutral current (NC) background turns out to be the most critical background, whose uncertainty is carefully evaluated from both the spread of model predictions and an envisaged \textit{in situ} measurement. We also make a careful study on the background suppression with the pulse shape discrimination (PSD) and triple coincidence (TC) cuts. With latest DSNB signal predictions, more realistic background evaluation and PSD efficiency optimization, and additional TC cut, JUNO can reach the significance of 3$σ$ for 3 years of data taking, and achieve better than 5$σ$ after 10 years for a reference DSNB model. In the pessimistic scenario of non-observation, JUNO would strongly improve the limits and exclude a significant region of the model parameter space. △ Less

Submitted 13 October, 2022; v1 submitted 18 May, 2022; originally announced May 2022.

Comments: 29 pages, 11 figures, final published version in JCAP

Journal ref: JCAP 10 (2022) 033

Precursors of fatty alcohols in the ISM: Discovery of n-propanol

Authors: Izaskun Jimenez-Serra, Lucas F. Rodriguez-Almeida, Jesus Martin-Pintado, Victor M. Rivilla, Mattia Melosso, Shaoshan Zeng, Laura Colzi, Yoshiyuki Kawashima, Eizi Hirota, Cristina Puzzarini, Belen Tercero, Pablo de Vicente, Fernando Rico-Villas, Miguel A. Requena-Torres, Sergio Martin

Abstract: Theories on the origins of life propose that early cell membranes were synthesized from amphiphilic molecules simpler than phospholipids such as fatty alcohols. The discovery in the interstellar medium (ISM) of ethanolamine, the simplest phospholipid head group, raises the question whether simple amphiphilic molecules are also synthesized in space. We investigate whether precursors of fatty alcoho… ▽ More Theories on the origins of life propose that early cell membranes were synthesized from amphiphilic molecules simpler than phospholipids such as fatty alcohols. The discovery in the interstellar medium (ISM) of ethanolamine, the simplest phospholipid head group, raises the question whether simple amphiphilic molecules are also synthesized in space. We investigate whether precursors of fatty alcohols are present in the ISM. For this, we have carried out a spectral survey at 7, 3, 2 and 1 mm toward the Giant Molecular Cloud G+0.693-0.027 located in the Galactic Center using the IRAM 30m and Yebes 40m telescopes. Here, we report the detection in the ISM of the primary alcohol n-propanol (in both conformers Ga-n-C3H7OH and Aa-n-C3H7OH), a precursor of fatty alcohols. The derived column densities of n-propanol are (5.5+-0.4)x10^13 cm^-2 for the Ga conformer and (3.4+-0.3)x10^13 cm^-2 for the Aa conformer, which imply molecular abundances of (4.1+-0.3)x10^-10 for Ga-n-C3H7OH and of (2.5+-0.2)x10^-10 for Aa-n-C3H7OH. We also searched for the AGa conformer of n-butanol (AGa-n-C4H9OH) without success yielding an upper limit to its abundance of <4.1x10^-11. The inferred CH3OH:C2H5OH:C3H7OH:C4H9OH abundance ratios go as 1:0.04:0.006:<0.0004 toward G+0.693-0.027, i.e. they decrease roughly by one order of magnitude for increasing complexity. We also report the detection of both syn and anti conformers of vinyl alcohol, with column densities of (1.11+-0.08)x10^14 cm^-2 and (1.3+-0.4)x10^13 cm^-2, and abundances of (8.2+-0.6)x10^-10 and (9.6+-3.0)x10^-11, respectively. The detection of n-propanol, together with the recent discovery of ethanolamine in the ISM, opens the possibility that precursors of lipids according to theories of the origin of life, could have been brought to Earth from outer space. △ Less

Submitted 18 April, 2022; originally announced April 2022.

Comments: 15 pages, 10 figures, accepted for A&A

Journal ref: A&A 663, A181 (2022)

Estimation of stellar atmospheric parameters from LAMOST DR8 low-resolution spectra with 20$\leq$SNR$<$30

Authors: Xiangru Li, Zhu Wang, Si Zeng, Caixiu Liao, Bing Du, X. Kong, Haining Li

Abstract: The accuracy of the estimated stellar atmospheric parameter decreases evidently with the decreasing of spectral signal-to-noise ratio (SNR) and there are a huge amount of this kind observations, especially in case of SNR$<$30. Therefore, it is helpful to improve the parameter estimation performance for these spectra and this work studied the ($T_\texttt{eff}, \log~g$, [Fe/H]) estimation problem fo… ▽ More The accuracy of the estimated stellar atmospheric parameter decreases evidently with the decreasing of spectral signal-to-noise ratio (SNR) and there are a huge amount of this kind observations, especially in case of SNR$<$30. Therefore, it is helpful to improve the parameter estimation performance for these spectra and this work studied the ($T_\texttt{eff}, \log~g$, [Fe/H]) estimation problem for LAMOST DR8 low-resolution spectra with 20$\leq$SNR$<$30. We proposed a data-driven method based on machine learning techniques. Firstly, this scheme detected stellar atmospheric parameter-sensitive features from spectra by the Least Absolute Shrinkage and Selection Operator (LASSO), rejected ineffective data components and irrelevant data. Secondly, a Multi-layer Perceptron (MLP) method was used to estimate stellar atmospheric parameters from the LASSO features. Finally, the performance of the LASSO-MLP was evaluated by computing and analyzing the consistency between its estimation and the reference from the APOGEE (Apache Point Observatory Galactic Evolution Experiment) high-resolution spectra. Experiments show that the Mean Absolute Errors (MAE) of $T_\texttt{eff}, \log~g$, [Fe/H] are reduced from the LASP (137.6 K, 0.195 dex, 0.091 dex) to LASSO-MLP (84.32 K, 0.137 dex, 0.063 dex), which indicate evident improvements on stellar atmospheric parameter estimation. In addition, this work estimated the stellar atmospheric parameters for 1,162,760 low-resolution spectra with 20$\leq$SNR$<$30 from LAMOST DR8 using LASSO-MLP, and released the estimation catalog, learned model, experimental code, trained model, training data and test data for scientific exploration and algorithm study. △ Less

Submitted 13 April, 2022; originally announced April 2022.

Comments: 16 pages, 6 figures, 4 tables

Journal ref: Research in Astronomy and Astrophysics, 2022, 22:065018 (11pp)

Precursors of the RNA-world in space: Detection of ($Z$)-1,2-ethenediol in the interstellar medium, a key intermediate in sugar formation

Authors: Víctor M. Rivilla, Laura Colzi, Izaskun Jiménez-Serra, Jesús Martín-Pintado, Andrés Megías, Mattia Melosso, Luca Bizzocchi, Álvaro López-Gallifa, Antonio Martínez-Henares, Sarah Massalkhi, Belén Tercero, Pablo de Vicente, Jean-Claude Guillemin, Juan García de la Concepción, Fernando Rico-Villas, Shaoshan Zeng, Sergio Martín, Miguel A. Requena-Torres, Francesca Tonolo, Silvia Alessandrini, Luca Dore, Vincenzo Barone, Cristina Puzzarini

Abstract: We present the first detection of ($Z$)-1,2-ethenediol, (CHOH)$_2$, the enol form of glycolaldehyde, in the interstellar medium towards the G+0.693-0.027 molecular cloud located in the Galactic Center. We have derived a column density of (1.8$\pm$0.1)$\times$10$^{13}$ cm$^{-2}$, which translates into a molecular abundance with respect to molecular hydrogen of 1.3$\times$10$^{-10}$. The abundance r… ▽ More We present the first detection of ($Z$)-1,2-ethenediol, (CHOH)$_2$, the enol form of glycolaldehyde, in the interstellar medium towards the G+0.693-0.027 molecular cloud located in the Galactic Center. We have derived a column density of (1.8$\pm$0.1)$\times$10$^{13}$ cm$^{-2}$, which translates into a molecular abundance with respect to molecular hydrogen of 1.3$\times$10$^{-10}$. The abundance ratio between glycolaldehyde and ($Z$)-1,2-ethenediol is $\sim$5.2. We discuss several viable formation routes through chemical reactions from precursors such as HCO, H$_2$CO, CHOH or CH$_2$CHOH. We also propose that this species might be an important precursor in the formation of glyceraldehyde (HOCH$_2$CHOHCHO) in the interstellar medium through combination with the hydroxymethylene (CHOH) radical. △ Less

Submitted 6 April, 2022; v1 submitted 28 March, 2022; originally announced March 2022.

Comments: Accepted for publication in The Astrophysical Journal Letters

Ionise hard: interstellar PO$^{+}$ detection

Authors: Víctor M. Rivilla, Juan García de la Concepción, Izaskun Jiménez-Serra, Jesús Martín-Pintado, Laura Colzi, Belén Tercero, Andrés Megías, Álvaro López-Gallifa, Antonio Martínez-Henares, Sara Massalkhi, Sergio Martín, Shaoshan Zeng, Pablo De Vicente, Fernando Rico-Villas, Miguel A. Requena-Torres, Giuliana Cosentino

Abstract: We report the first detection of the phosphorus monoxide ion (PO$^{+}$) in the interstellar medium. Our unbiased and very sensitive spectral survey towards the G+0.693$-$0.027 molecular cloud covers four different rotational transitions of this molecule, two of which ($J$=1$-$0 and $J$=2$-$1) appear free of contamination from other species. The fit performed, assuming Local Thermodynamic Equilibri… ▽ More We report the first detection of the phosphorus monoxide ion (PO$^{+}$) in the interstellar medium. Our unbiased and very sensitive spectral survey towards the G+0.693$-$0.027 molecular cloud covers four different rotational transitions of this molecule, two of which ($J$=1$-$0 and $J$=2$-$1) appear free of contamination from other species. The fit performed, assuming Local Thermodynamic Equilibrium conditions, yields a column density of $N$=(6.0$\pm$0.7)$\times$10$^{11}$ cm$^{-2}$. The resulting molecular abundance with respect to molecular hydrogen is 4.5$\times$10$^{-12}$. The column density of PO$^{+}$ normalised by the cosmic abundance of P is larger than those of NO$^{+}$ and SO$^{+}$, normalised by N and S, by factors of 3.6 and 2.3, respectively. The $N$(PO$^{+}$)/$N$(PO) ratio is 0.12$\pm$0.03, more than one order of magnitude higher than those of $N$(SO$^{+}$)/$N$(SO) and $N$(NO$^{+}$)/$N$(NO). These results indicate that P is more efficiently ionised in the ISM than N and S. We have performed new chemical models that confirm that the PO$^+$ abundance is strongly enhanced in shocked regions with high values of cosmic-ray ionisation rates (10$^{-15}-$10$^{-14}$ s$^{-1}$), as occurs in the G+0.693$-$0.027 molecular cloud. The shocks sputter the interstellar icy grain mantles, releasing into the gas phase most of their P content, mainly in the form of PH$_3$, which is converted into atomic P, and then ionised efficiently by cosmic rays, forming P$^+$. Further reactions with O$_2$ and OH produce PO$^{+}$. The cosmic-ray ionisation of PO might also contribute significantly, which would explain the high $N$(PO$^{+}$)/$N$(PO) observed. The relatively high gas-phase abundance of PO$^{+}$ with respect to other P-bearing species stresses the relevance of this species in the interstellar chemistry of P. △ Less

Submitted 28 February, 2022; originally announced February 2022.

Comments: Accepted in Frontiers in Astronomy and Space Sciences

Deuterium fractionation as a multi-phase component tracer in the Galactic Centre

Authors: L. Colzi, J. Martín-Pintado, V. M. Rivilla, I. Jiménez-Serra, S. Zeng, L. F. Rodríguez-Almeida, F. Rico-Villas, S. Martín, M. A. Requena-Torres

Abstract: The Central Molecular Zone (CMZ) contains most of the mass of our Galaxy but its star formation rate is one order of magnitude lower than in the Galactic disc. This is likely related to the fact that the bulk of the gas in the CMZ is in a warm ($>$100 K) and turbulent phase with little material in the pre-stellar phase. We present in this Letter observations of deuterium fractionation (D/H ratios)… ▽ More The Central Molecular Zone (CMZ) contains most of the mass of our Galaxy but its star formation rate is one order of magnitude lower than in the Galactic disc. This is likely related to the fact that the bulk of the gas in the CMZ is in a warm ($>$100 K) and turbulent phase with little material in the pre-stellar phase. We present in this Letter observations of deuterium fractionation (D/H ratios) of HCN, HNC, HCO$^{+}$, and N$_{2}$H$^{+}$ towards the CMZ molecular cloud G+0.693-0.027. These observations clearly show, for the first time, the presence of a colder, denser, and less turbulent narrow component, with a line width of $\sim$9 km s$^{-1}$, in addition to the warm, less dense and turbulent broad component with a line width of $\sim$20 km s$^{-1}$. The very low D/H ratio $\le$6$\times$10$^{-5}$ for HCO$^{+}$ and N$_{2}$H$^{+}$, close to the cosmic value ($\sim$2.5$\times$10$^{-5}$), and the high D/H ratios $>$4$\times$10$^{-4}$ for HCN and HNC derived for the broad component, confirm the presence of high-temperatures deuteration routes for nitriles. For the narrow component we have derived D/H ratios $>$10$^{-4}$ and excitation temperatures of $7$ K for all molecules, suggesting kinetic temperatures $\le$30 K and H$_2$ densities $\ge$5$\times$10$^{4}$ cm$^{-3}$, at least one order of magnitude larger than for the broad component. The method presented in this Letter allows to identify clouds on the verge of star formation, i.e. under pre-stellar conditions, towards the CMZ. This method can also be used for the identification of such clouds in external galaxies. △ Less

Submitted 8 February, 2022; originally announced February 2022.

Comments: 11 pages, 4 figures, 2 tables, 2 appendix - Accepted for publication in ApJ Letters

Negative and Positive Feedback from a Supernova Remnant with SHREC: A detailed Study of the Shocked Gas in IC443

Authors: G. Cosentino, I. Jiménez-Serra, J. C. Tan, J. D. Henshaw, A. T. Barnes, C. -Y. Law, S. Zeng, F. Fontani, P. Caselli, S. Viti, S. Zahorecz, F. Rico-Villas, A. Megías, M. Miceli, S. Orlando, S. Ustamujic, E. Greco, G. Peres, F. Bocchino, R. Fedriani, P. Gorai, L. Testi, J. Martín-Pintado

Abstract: Supernova remnants (SNRs) contribute to regulate the star formation efficiency and evolution of galaxies. As they expand into the interstellar medium (ISM), they transfer vast amounts of energy and momentum that displace, compress and heat the surrounding material. Despite the extensive work in galaxy evolution models, it remains to be observationally validated to what extent the molecular ISM is… ▽ More Supernova remnants (SNRs) contribute to regulate the star formation efficiency and evolution of galaxies. As they expand into the interstellar medium (ISM), they transfer vast amounts of energy and momentum that displace, compress and heat the surrounding material. Despite the extensive work in galaxy evolution models, it remains to be observationally validated to what extent the molecular ISM is affected by the interaction with SNRs. We use the first results of the ESO-ARO Public Spectroscopic Survey SHREC, to investigate the shock interaction between the SNR IC443 and the nearby molecular clump G. We use high sensitivity SiO(2-1) and H$^{13}$CO$^+$(1-0) maps obtained by SHREC together with SiO(1-0) observations obtained with the 40m telescope at the Yebes Observatory. We find that the bulk of the SiO emission is arising from the ongoing shock interaction between IC443 and clump G. The shocked gas shows a well ordered kinematic structure, with velocities blue-shifted with respect to the central velocity of the SNR, similar to what observed toward other SNR-cloud interaction sites. The shock compression enhances the molecular gas density, n(H$_2$), up to $>$10$^5$ cm$^{-3}$, a factor of >10 higher than the ambient gas density and similar to values required to ignite star formation. Finally, we estimate that up to 50\% of the momentum injected by IC443 is transferred to the interacting molecular material. Therefore the molecular ISM may represent an important momentum carrier in sites of SNR-cloud interactions. △ Less

Submitted 9 January, 2022; originally announced January 2022.

Comments: Accepted for Publication in MNRAS; 11 pages, 7 figures

Molecular Clump Extraction Algorithm Based on Local Density Clustering

Authors: Xiaoyu Luo, Sheng Zheng, Yao Huang, Shuguang Zeng, Xiangyun Zeng, Zhibo Jiang, Zhiwei Chen

Abstract: The detection and parametrization of molecular clumps is the first step in studying them. We propose a method based on Local Density Clustering algorithm while physical parameters of those clumps are measured using the Multiple Gaussian Model algorithm. One advantage of applying the Local Density Clustering to the clump detection and segmentation, is the high accuracy under different signal-to-noi… ▽ More The detection and parametrization of molecular clumps is the first step in studying them. We propose a method based on Local Density Clustering algorithm while physical parameters of those clumps are measured using the Multiple Gaussian Model algorithm. One advantage of applying the Local Density Clustering to the clump detection and segmentation, is the high accuracy under different signal-to-noise levels. The Multiple Gaussian Model is able to deal with overlapping clumps whose parameters can be derived reliably. Using simulation and synthetic data, we have verified that the proposed algorithm could characterize the morphology and flux of molecular clumps accurately. The total flux recovery rate in $^{13}\rm CO$ (J=1-0) line of M16 is measured as 90.2\%. The detection rate and the completeness limit are 81.7\% and 20 K km s$ ^{-1} $ in $^{13}\rm CO$ (J=1-0) line of M16, respectively. △ Less

Submitted 22 October, 2021; originally announced October 2021.

Comments: Accepted for the publication in Research in Astronomy and Astrophysics (RAA). The python-based package will be available soon

Probing the chemical complexity of amines in the ISM: detection of vinylamine (C$_2$H$_3$NH$_2$) and tentative detection of ethylamine (C$_2$H$_5$NH$_2$)

Authors: Shaoshan Zeng, Izaskun Jiménez-Serra, Víctor M. Rivilla, Jesús Martín-Pintado, Lucas F. Rodríguez-Almeida, Belén Tercero, Pablo de Vicente, Fernando Rico-Villas, Laura Colzi, Sergio Martín, Miguel A. Requena-Torres

Abstract: Amines, in particular primary amines (R-NH$_2$) are closely related to the primordial synthesis of amino acids since they share the same structural backbone. However, only limited number of amines has been identified in the ISM which prevents us from studying their chemistry as well as their relation to pre-biotic species that could lead to the emergence of life. In this letter, we report the firs… ▽ More Amines, in particular primary amines (R-NH$_2$) are closely related to the primordial synthesis of amino acids since they share the same structural backbone. However, only limited number of amines has been identified in the ISM which prevents us from studying their chemistry as well as their relation to pre-biotic species that could lead to the emergence of life. In this letter, we report the first interstellar detection of vinylamine (C$_2$H$_3$NH$_2$) and tentative detection of ethylamine (C$_2$H$_5$NH$_2$) towards the Galactic Centre cloud G+0.693-0.027. The derived abundance with respect to H$_2$ is (3.3$\pm$0.4)$\times$10$^{-10}$ and (1.9$\pm$0.5)$\times$10$^{-10}$, respectively. The inferred abundance ratios of C$_2$H$_3$NH$_2$ and C$_2$H$_5$NH$_2$ with respect to methylamine (CH$_3$NH$_2$) are $\sim$0.02 and $\sim$0.008 respectively. The derived abundance of C$_2$H$_3$NH$_2$, C$_2$H$_5$NH$_2$ and several other NH$_2$-bearing species are compared to those obtained towards high-mass and low-mass star-forming regions. Based on recent chemical and laboratory studies, possible chemical routes for the interstellar synthesis of C$_2$H$_3$NH$_2$ and C$_2$H$_5$NH$_2$ are discussed. △ Less

Submitted 10 October, 2021; v1 submitted 4 October, 2021; originally announced October 2021.

Comments: 8 pages, 4 figures, 1 table, article accepted in Astrophysical Journal Letters

The $^{59}$Fe(n, γ)$^{60}$Fe Cross Section from the Surrogate Ratio Method and Its Effect on the $^{60}$Fe Nucleosynthesis

Authors: S. Q. Yan, X. Y. Li, K. Nishio, M. Lugaro, Z. H. Li, H. Makii, M. Pignatari, Y. B. Wang, R. Orlandi, K. Hirose, K. Tsukada, P. Mohr, G. S. Li, J. G. Wang, B. S. Gao, Y. L. Han, B. Guo, Y. J. Li, Y. P. Shen, T. K. Sato, Y. Ito, F. Suzaki, J. Su, Y. Y. Yang, J. S. Wang , et al. (17 additional authors not shown)

Abstract: The long-lived $^{60}$Fe (with a half-life of 2.62 Myr) is a crucial diagnostic of active nucleosynthesis in the Milky Way galaxy and in supernovae near the solar system. The neutron-capture reaction $^{59}$Fe(n,$γ$)$^{60}$Fe on $^{59}$Fe (half-life = 44.5 days) is the key reaction for the production of $^{60}$Fe in massive stars. This reaction cross section has been previously constrained by the… ▽ More The long-lived $^{60}$Fe (with a half-life of 2.62 Myr) is a crucial diagnostic of active nucleosynthesis in the Milky Way galaxy and in supernovae near the solar system. The neutron-capture reaction $^{59}$Fe(n,$γ$)$^{60}$Fe on $^{59}$Fe (half-life = 44.5 days) is the key reaction for the production of $^{60}$Fe in massive stars. This reaction cross section has been previously constrained by the Coulomb dissociation experiment, which offered partial constraint on the $E$1 $γ$-ray strength function but a negligible constraint on the $M$1 and $E$2 components. In this work, for the first time, we use the surrogate ratio method to experimentally determine the $^{59}$Fe(n,$γ$)$^{60}$Fe cross sections in which all the components are included. We derived a Maxwellian-averaged cross section of 27.5 $\pm$ 3.5 mb at $kT$= 30 keV and 13.4 $\pm$ 1.7 mb at $kT$= 90 keV, roughly 10 - 20% higher than previous estimates. We analyzed the impact of our new reaction rates in nucleosynthesis models of massive stars and found that uncertainties in the production of $^{60}$Fe from the $^{59}$Fe(n,$γ$)$^{60}$Fe rate are at most of 25%. We conclude that stellar physics uncertainties now play a major role in the accurate evaluation of the stellar production of $^{60}$Fe. △ Less

Submitted 26 September, 2021; originally announced September 2021.

Comments: 9 pages with 6 figures

First detection of C$_2$H$_5$NCO in the ISM and search of other isocyanates towards the G+0.693-0.027 molecular cloud

Authors: L. F. Rodríguez Almeida, V. M. Rivilla, I. Jiménez-Serra, M. Melosso, L. Colzi, S. Zeng, B. Tercero, P. de Vicente, S. Martín, M. A. Requena-Torres, F. Rico-Villas, J. Martín-Pintado

Abstract: Little is known about the chemistry of isocyanates (compounds with the functional group R-N=C=O) in the interstellar medium, as only four of them have been detected so far: isocyanate radical (NCO), isocyanic acid (HNCO), N-protonated isocyanic acid (H$_2$NCO$^+$) and methyl isocyanate (CH$_3$NCO). The molecular cloud G+0.693-0.027, located in the Galactic Centre, represents an excellent candidate… ▽ More Little is known about the chemistry of isocyanates (compounds with the functional group R-N=C=O) in the interstellar medium, as only four of them have been detected so far: isocyanate radical (NCO), isocyanic acid (HNCO), N-protonated isocyanic acid (H$_2$NCO$^+$) and methyl isocyanate (CH$_3$NCO). The molecular cloud G+0.693-0.027, located in the Galactic Centre, represents an excellent candidate to search for new isocyanates since it exhibits high abundances of the simplest ones, HNCO and CH$_3$NCO. After CH$_3$NCO, the next complex isocyanates are ethyl isocyanate (C$_2$H$_5$NCO) and vinyl isocyanate (C$_2$H$_3$NCO). Their detection in the ISM would enhance our understanding of the formation of these compounds in space. We have detected C$_2$H$_5$NCO and H$_2$NCO$^+$ towards G+0.693-0.027 (the former for the first time in the interstellar medium) with molecular abundances of (4.7$-$7.3)$\times$10$^{-11}$ and (1.0$-$1.5)$\times$10$^{-11}$, respectively. A ratio CH$_3$NCO / C$_2$H$_5$NCO = 8$\pm$1 is obtained; therefore the relative abundance determined for HNCO:CH$_3$NCO:C$_2$H$_5$NCO is 1:1/55:1/447, which implies a decrease by more than one order of magnitude going progressively from HNCO to CH$_3$NCO and to C$_2$H$_5$NCO. This is similar to what has been found for e.g. alcohols and thiols and suggests that C$_2$H$_5$NCO is likely formed on the surface of dust grains. In addition, we have obtained column density ratios of HNCO / NCO > 269, HNCO / H$_2$NCO$^+$ $\sim$ 2100 and C$_2$H$_3$NCO / C$_2$H$_5$NCO~<~4. A comparison of the Methyl~/~Ethyl ratios for isocyanates (-NCO), alcohols (-OH), formiates (HCOO-), nitriles (-CN) and thiols (-SH) is performed and shows that ethyl-derivatives may be formed more efficiently for the N-bearing molecules than for the O- and S-bearing molecules. △ Less

Submitted 16 September, 2021; originally announced September 2021.

Comments: 5 pages, 5 figures; accepted in A&A

Journal ref: A&A 654, L1 (2021)

Detection of the cyanomidyl radical (HNCN): a new interstellar species with the NCN backbone

Authors: V. M. Rivilla, I. Jiménez-Serra, J. García de la Concepción, J. Martín-Pintado, L. Colzi, L. F. Rodríguez-Almeida, B. Tercero, F. Rico-Villas, S. Zeng, S. Martín, M. A. Requena-Torres, P. de Vicente

Abstract: We report here the first detection in the interstellar medium of the cyanomidyl radical (HNCN). Using the Yebes 40m and the IRAM 30m telescopes, we have targeted the doublets of the $N$=2$-$1, 4$-$3, 5$-$4, 6$-$5, and 7$-$6 transitions of HNCN toward the molecular cloud G+0.693-0.027. We have detected three unblended lines of HNCN, these are the $N$=6$-$5 doublet and one line of the $N$=4$-$3 tran… ▽ More We report here the first detection in the interstellar medium of the cyanomidyl radical (HNCN). Using the Yebes 40m and the IRAM 30m telescopes, we have targeted the doublets of the $N$=2$-$1, 4$-$3, 5$-$4, 6$-$5, and 7$-$6 transitions of HNCN toward the molecular cloud G+0.693-0.027. We have detected three unblended lines of HNCN, these are the $N$=6$-$5 doublet and one line of the $N$=4$-$3 transition. Additionally we present one line of the $N$=5$-$4 transition partially blended with emission from other species. The Local Thermodynamic Equilibrium best fit to the data gives a molecular abundance of (0.91$\pm$0.05)$\times$10$^{-10}$ with respect to H$_2$. The relatively low abundance of this species in G+0.693-0.027, and its high reactivity, suggest that HNCN is possibly produced by gas-phase chemistry. Our work shows that this highly reactive molecule is present in interstellar space, and thus it represents a plausible precursor of larger prebiotic molecules with the NCN backbone such as cyanamide (NH$_2$CN), carbodiimide (HNCNH) and formamidine (NH$_2$CHNH). △ Less

Submitted 22 July, 2021; v1 submitted 17 June, 2021; originally announced June 2021.

Comments: Accepted in Monthly Notices of the Royal Astronomical Society Letters

Discovery in space of ethanolamine, the simplest phospholipid head group

Authors: Víctor M. Rivilla, Izaskun Jiménez-Serra, Jesús Martín-Pintado, Carlos Briones, Lucas F. Rodríguez-Almeida, Fernando Rico-Villas, Belén Tercero, Shaoshan Zeng, Laura Colzi, Pablo de Vicente, Sergio Martín, Miguel A. Requena-Torres

Abstract: Cell membranes are a key element of life because they keep the genetic material and metabolic machinery together. All present cell membranes are made of phospholipids, yet the nature of the first membranes and the origin of phospholipids are still under debate. We report here the first detection in space of ethanolamine, NH$_2$CH$_2$CH$_2$OH, which forms the hydrophilic head of the simplest and se… ▽ More Cell membranes are a key element of life because they keep the genetic material and metabolic machinery together. All present cell membranes are made of phospholipids, yet the nature of the first membranes and the origin of phospholipids are still under debate. We report here the first detection in space of ethanolamine, NH$_2$CH$_2$CH$_2$OH, which forms the hydrophilic head of the simplest and second most abundant phospholipid in membranes. The molecular column density of ethanolamine in interstellar space is $N$=(1.51$\pm$0.07)$\times$10$^{13}$ cm$^{-2}$, implying a molecular abundance with respect to H$_2$ of (0.9-1.4)$\times$10$^{-10}$. Previous studies reported its presence in meteoritic material but they suggested that it is synthesized in the meteorite itself by decomposition of amino acids. However, we find that the proportion of the molecule with respect to water in the interstellar medium is similar to the one found in the meteorite (10$^{-6}$). These results indicate that ethanolamine forms efficiently in space and, if delivered onto early Earth, it could have contributed to the assembling and early evolution of primitive membranes. △ Less

Submitted 24 May, 2021; originally announced May 2021.

Comments: Accepted in PNAS (Proceedings of the National Academy of Sciences of the United States of America)

Thiols in the ISM: first detection of HC(O)SH and confirmation of C$_2$H$_5$SH

Authors: Lucas F. Rodríguez-Almeida, Izaskun Jiménez-Serra, Víctor M. Rivilla, Jesús Martín-Pintado, Shaoshan Zeng, Belén Tercero, Pablo de Vicente, Laura Colzi, Fernando Rico-Villas, Sergio Martín, Miguel A. Requena-Torres

Abstract: The chemical compounds carrying the thiol group (-SH) have been considered essential in recent prebiotic studies regarding the polymerization of amino acids. We have searched for this kind of compounds toward the Galactic Centre quiescent cloud G+0.693-0.027. We report the first detection in the interstellar space of the trans-isomer of monothioformic acid (t-HC(O)SH) with an abundance of… ▽ More The chemical compounds carrying the thiol group (-SH) have been considered essential in recent prebiotic studies regarding the polymerization of amino acids. We have searched for this kind of compounds toward the Galactic Centre quiescent cloud G+0.693-0.027. We report the first detection in the interstellar space of the trans-isomer of monothioformic acid (t-HC(O)SH) with an abundance of $\sim\,$1$\,\times\,$10$^{-10}$. Additionally, we provide a solid confirmation of the gauche isomer of ethyl mercaptan (g-C$_2$H$_5$SH) with an abundance of $\sim\,$3$\,\times\,$10$^{-10}$, and we also detect methyl mercaptan (CH$_3$SH) with an abundance of $\sim\,$5$\,\times\,$10$^{-9}$. Abundance ratios were calculated for the three SH-bearing species and their OH-analogues, revealing similar trends between alcohols and thiols with increasing complexity. Possible chemical routes for the interstellar synthesis of t-HC(O)SH, CH$_3$SH and C$_2$H$_5$SH are discussed, as well as the relevance of these compounds in the synthesis of prebiotic proteins in the primitive Earth. △ Less

Submitted 19 April, 2021; v1 submitted 16 April, 2021; originally announced April 2021.

Comments: 16 pages, 6 figures, article accepted in Astrophysical Journal Letters; typos corrected

The Perseus ALMA Chemistry Survey (PEACHES). I. The Complex Organic Molecules in Perseus Embedded Protostars

Authors: Yao-Lun Yang, Nami Sakai, Yichen Zhang, Nadia M. Murillo, Ziwei E. Zhang, Aya E. Higuchi, Shaoshan Zeng, Ana López-Sepulcre, Satoshi Yamamoto, Bertrand Lefloch, Mathilde Bouvier, Cecilia Ceccarelli, Tomoya Hirota, Muneaki Imai, Yoko Oya, Takeshi Sakai, Yoshimasa Watanabe

Abstract: To date, about two dozen low-mass embedded protostars exhibit rich spectra with lines of complex organic molecule (COM). These protostars seem to possess different enrichment in COMs. However, the statistics of COM abundance in low-mass protostars are limited by the scarcity of observations. This study introduces the Perseus ALMA Chemistry Survey (PEACHES), which aims at unbiasedly characterizing… ▽ More To date, about two dozen low-mass embedded protostars exhibit rich spectra with lines of complex organic molecule (COM). These protostars seem to possess different enrichment in COMs. However, the statistics of COM abundance in low-mass protostars are limited by the scarcity of observations. This study introduces the Perseus ALMA Chemistry Survey (PEACHES), which aims at unbiasedly characterizing the chemistry of COMs toward the embedded (Class 0/I) protostars in the Perseus molecular cloud. Of 50 embedded protostars surveyed, 58% of them have emission from COMs. A 56%, 32%, and 40% of the protostars have CH$_3$OH, CH$_3$OCHO, and N-bearing COMs, respectively. The detectability of COMs depends neither on the averaged continuum brightness temperature, a proxy of the H$_2$ column density, nor on the bolometric luminosity and the bolometric temperature. For the protostars with detected COMs, CH$_3$OH has a tight correlation with CH$_3$CN, spanning more than two orders of magnitude in column densities normalized by the continuum brightness temperature, suggesting a chemical relation between CH$_3$OH and CH$_3$CN and a large chemical diversity in the PEACHES samples at the same time. A similar trend with more scatter is also found between all identified COMs, hinting at a common chemistry for the sources with COMs. The correlation between COMs is insensitive to the protostellar properties, such as the bolometric luminosity and the bolometric temperature. The abundance of larger COMs (CH$_3$OCHO and CH$_3$OCH$_3$) relative to that of smaller COMs (CH$_3$OH and CH$_3$CN) increases with the inferred gas column density, hinting at an efficient production of complex species in denser envelopes. △ Less

Submitted 16 April, 2021; v1 submitted 26 January, 2021; originally announced January 2021.

Comments: 55 pages, 9 tables, 24 figures. Updated after publication in ApJ. Figure 18 appears as a figure set in ApJ

Journal ref: ApJ, 910, 20 (2021)

Prebiotic precursors of the primordial RNA world in space: Detection of NH$_{2}$OH

Authors: Víctor M. Rivilla, Jesús Martín-Pintado, Izaskun Jiménez-Serra, Sergio Martín, Lucas F. Rodríguez-Almeida, Miguel A. Requena-Torres, Fernando Rico-Villas, Shaoshan Zeng, Carlos Briones

Abstract: One of the proposed scenarios for the origin of life is the primordial RNA world, which considers that RNA molecules were likely responsible for the storage of genetic information and the catalysis of biochemical reactions in primitive cells, before the advent of proteins and DNA. In the last decade, experiments in the field of prebiotic chemistry have shown that RNA nucleotides can be synthesized… ▽ More One of the proposed scenarios for the origin of life is the primordial RNA world, which considers that RNA molecules were likely responsible for the storage of genetic information and the catalysis of biochemical reactions in primitive cells, before the advent of proteins and DNA. In the last decade, experiments in the field of prebiotic chemistry have shown that RNA nucleotides can be synthesized from relatively simple molecular precursors, most of which have been found in space. An important exception is hydroxylamine, NH$_2$OH, which, despite several observational attempts, it has not been detected in space yet. Here we present the first detection of NH$_2$OH in the interstellar medium towards the quiescent molecular cloud G+0.693-0.027 located in the Galactic Center. We have targeted the three groups of transitions from the $J$=2$-$1, 3$-$2, and 4$-$3 rotational lines, detecting 5 transitions that are unblended or only slightly blended. The derived molecular abundance of NH$_2$OH is (2.1$\pm$0.9)$\times$10$^{-10}$. From the comparison of the derived abundance of NH$_2$OH and chemically related species, with those predicted by chemical models and measured in laboratory experiments, we favor the formation of NH$_2$OH in the interstellar medium via hydrogenation of NO on dust grain surfaces, with possibly a contribution of ice mantle NH$_3$ oxidation processes. Further laboratory studies and quantum chemical calculations are needed to completely rule out the formation of NH$_2$OH in the gas phase. △ Less

Submitted 13 August, 2020; v1 submitted 1 August, 2020; originally announced August 2020.

Comments: Accepted in the Astrophysical Journal Letters

Cloud-cloud collision as drivers of the chemical complexity in Galactic Centre molecular clouds

Authors: S. Zeng, Q. Zhang, I. Jimenez-Serra, B. Tercero, X. Lu, J. Martin-Pintado, P. de Vicente, V. M. Rivilla, S. Li

Abstract: G+0.693-0.03 is a quiescent molecular cloud located within the Sagittarius B2 (Sgr B2) star-forming complex. Recent spectral surveys have shown that it represents one of the most prolific repositories of complex organic species in the Galaxy. The origin of such chemical complexity, along with the small-scale physical structure and properties of G+0.693-0.03, remains a mystery. In this paper, we re… ▽ More G+0.693-0.03 is a quiescent molecular cloud located within the Sagittarius B2 (Sgr B2) star-forming complex. Recent spectral surveys have shown that it represents one of the most prolific repositories of complex organic species in the Galaxy. The origin of such chemical complexity, along with the small-scale physical structure and properties of G+0.693-0.03, remains a mystery. In this paper, we report the study of multiple molecules with interferometric observations in combination with single-dish data in G+0.693-0.03. Despite the lack of detection of continuum source, we find small-scale (0.2 pc) structures within this cloud. The analysis of the molecular emission of typical shock tracers such as SiO, HNCO, and CH$_3$OH unveiled two molecular components, peaking at velocities of 57 and 75 km s$^{-1}$. They are found to be interconnected in both space and velocity. The position-velocity diagrams show features that match with the observational signatures of a cloud-cloud collision. Additionally, we detect three series of class \rom{1} methanol masers known to appear in shocked gas, supporting the cloud-cloud collision scenario. From the maser emission we provide constraints on the gas kinetic temperatures ($\sim$30-150 K) and H$_2$ densities (10$^4$-10$^5$ cm$^{-2}$). These properties are similar to those found for the starburst galaxy NGC253 also using class \rom{1} methanol masers, suggested to be associated with a cloud-cloud collision. We conclude that shocks driven by the possible cloud-cloud collision is likely the most important mechanism responsible for the high level of chemical complexity observed in G+0.693-0.03. △ Less

Submitted 7 August, 2020; v1 submitted 28 July, 2020; originally announced July 2020.

Comments: 18 pages, 8 figures, 1 table, accepted for publication in MNRAS

Search For Electron-Antineutrinos Associated With Gravitational-Wave Events GW150914, GW151012, GW151226, GW170104, GW170608, GW170814, and GW170817 at Daya Bay

Authors: F. P. An, A. B. Balantekin, H. R. Band, M. Bishai, S. Blyth, G. F. Cao, J. Cao, J. F. Chang, Y. Chang, H. S. Chen, S. M. Chen, Y. Chen, Y. X. Chen, J. Cheng, Z. K. Cheng, J. J. Cherwinka, M. C. Chu, J. P. Cummings, O. Dalager, F. S. Deng, Y. Y. Ding, M. V. Diwan, T. Dohnal, J. Dove, M. Dvorak , et al. (161 additional authors not shown)

Abstract: Providing a possible connection between neutrino emission and gravitational-wave (GW) bursts is important to our understanding of the physical processes that occur when black holes or neutron stars merge. In the Daya Bay experiment, using data collected from December 2011 to August 2017, a search has been performed for electron-antineutrino signals coinciding with detected GW events, including GW1… ▽ More Providing a possible connection between neutrino emission and gravitational-wave (GW) bursts is important to our understanding of the physical processes that occur when black holes or neutron stars merge. In the Daya Bay experiment, using data collected from December 2011 to August 2017, a search has been performed for electron-antineutrino signals coinciding with detected GW events, including GW150914, GW151012, GW151226, GW170104, GW170608, GW170814, and GW170817. We used three time windows of $\mathrm{\pm 10~s}$, $\mathrm{\pm 500~s}$, and $\mathrm{\pm 1000~s}$ relative to the occurrence of the GW events, and a neutrino energy range of 1.8 to 100 MeV to search for correlated neutrino candidates. The detected electron-antineutrino candidates are consistent with the expected background rates for all the three time windows. Assuming monochromatic spectra, we found upper limits (90% confidence level) on electron-antineutrino fluence of $(1.13~-~2.44) \times 10^{11}~\rm{cm^{-2}}$ at 5 MeV to $8.0 \times 10^{7}~\rm{cm^{-2}}$ at 100 MeV for the three time windows. Under the assumption of a Fermi-Dirac spectrum, the upper limits were found to be $(5.4~-~7.0)\times 10^{9}~\rm{cm^{-2}}$ for the three time windows. △ Less

Submitted 14 September, 2020; v1 submitted 27 June, 2020; originally announced June 2020.

Comments: 16 pages, 12 figures, 9 tables

A New Comprehensive Data Set of Solar Filaments of 100 yr Interval. I

Authors: GangHua Lin, GaoFei Zhu, Xiao Yang, YongLiang Song, Mei Zhang, Suo Liu, XiaoFan Wang, JiangTao Su, Sheng Zheng, JiaFeng Zhang, DongYi Tao, ShuGuang Zeng, HaiMin Wang, Chang Liu, Yan Xu

Abstract: Filaments are very common physical phenomena on the Sun and are often taken as important proxies of solar magnetic activities. The study of filaments has become a hot topic in the space weather research. For a more comprehensive understanding of filaments, especially for an understanding of solar activities of multiple solar cycles, it is necessary to perform a combined multifeature analysis by co… ▽ More Filaments are very common physical phenomena on the Sun and are often taken as important proxies of solar magnetic activities. The study of filaments has become a hot topic in the space weather research. For a more comprehensive understanding of filaments, especially for an understanding of solar activities of multiple solar cycles, it is necessary to perform a combined multifeature analysis by constructing a data set of multiple solar cycle data. To achieve this goal, we constructed a centennial data set that covers the H$α$ data from five observatories around the world. During the data set construction, we encountered varieties of problems, such as data fusion, accurate determination of the solar edge, classifying data by quality, dynamic threshold, and so on, which arose mainly due to multiple sources and a large time span of data. But fortunately, these problems were well solved. The data set includes seven types of data products and eight types of feature parameters with which we can implement the functions of data searching and statistical analyses. It has the characteristics of better continuity and highly complementary to space observation data, especially in the wavelengths not covered by space observations, and covers many solar cycles (including more than 60 yr of high-cadence data). We expect that this new comprehensive data set as well as the tools will help researchers to significantly speed up their search for features or events of interest, for either statistical or case study purposes, and possibly help them get a better and more comprehensive understanding of solar filament mechanisms. △ Less

Submitted 16 June, 2020; originally announced June 2020.

Comments: 20 pages, 17 figures, 1 table, accepted for publication in ApJS

Journal ref: ApJS 249 (2020) 11