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Condensed Matter > Materials Science

arXiv:2011.12874 (cond-mat)
[Submitted on 25 Nov 2020]

Title:Effect of pseudo-cubic (111)-oriented orthorhombic substrate facets on perovskite oxide thin film synthesis

Authors:K. Kjærnes, T. Bolstad, D. M. Evans, E. Lysne, B. A. D. Williamson, D. Meier, S. M. Selbach, T. Tybell
View a PDF of the paper titled Effect of pseudo-cubic (111)-oriented orthorhombic substrate facets on perovskite oxide thin film synthesis, by K. Kj{\ae}rnes and 7 other authors
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Abstract:Strain engineering with different substrate facets is promising for tuning functional properties of thin film perovskite oxides. By choice of facet, different surface symmetries and chemical bond directions for epitaxial interfaces can be tailored. Here, preparation of well-defined pseudo-cubic (111)-oriented orthorhombic substrates of DyScO3 , GdScO3 , and NdGaO3 is reported. The choice of orthorhombic facet, (011)o or (101)o , both corresponding to pseudo-cubic (111)pc , gives vicinal surfaces with single or double (111pc layer terrace step heights, respectively, impacting subsequent thin film growth. Orthorhombic LaFeO3 epitaxy on the (101)o facet reveals a distinction between alternating (111)pc layers, both during and after growth. The observed differences are explained based on the oxygen octahedral tilt pattern relative to the two orthorhombic (111)pc surfaces. This robust structural detail in the orthorhombic perovskite oxides enables utilisation of different (111)pc facets for property engineering, through polyhedral connectivity control and cation coordination at epitaxial interfaces.
Subjects: Materials Science (cond-mat.mtrl-sci)
Cite as: arXiv:2011.12874 [cond-mat.mtrl-sci]
  (or arXiv:2011.12874v1 [cond-mat.mtrl-sci] for this version)
  https://doi.org/10.48550/arXiv.2011.12874
arXiv-issued DOI via DataCite

Submission history

From: Thomas Tybell [view email]
[v1] Wed, 25 Nov 2020 16:52:03 UTC (3,879 KB)
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