Showing 1–50 of 73 results for author: Yan, C

Probing Quantum Geometric Phases via Scanning Tunneling Microscopy

Authors: Chao Yan, Mu-Wei Gao, Yue Zhao, Jia-Xin Yin

Abstract: The quantum geometric phase intrinsically dictates the geometry, topology, and many-body correlations of electronic wave functions. While quantum geometric phases are conventionally inferred through momentum-space probes or macroscopic transport measurements, their direct visualization and quantification in real space have historically been restricted by the spatial averaging of bulk techniques. S… ▽ More The quantum geometric phase intrinsically dictates the geometry, topology, and many-body correlations of electronic wave functions. While quantum geometric phases are conventionally inferred through momentum-space probes or macroscopic transport measurements, their direct visualization and quantification in real space have historically been restricted by the spatial averaging of bulk techniques. Scanning tunneling microscopy and spectroscopy (STM/STS) circumvent this limitation, leveraging atomic-scale spatial resolution and high energy sensitivity to resolve local electronic phase profiles directly. This review highlights recent progress across four representative methodologies: probing the Aharonov-Bohm (AB) geometric phase via nanoscale real space interferometry; extracting the Berry phase from defect-induced quasiparticle interference and wavefront dislocations; reconstructing the complex phase structure in symmetric systems, such as magic-angle graphene, using order parameter decomposition; and mapping the phase textures and topological defects of pair density wave (PDW) and charge density wave (CDW) in unconventional superconductors utilizing the numerical 2D lock-in technique. Together, these developments show how quantum phases can be translated onto real space and locally resolvable observables. Phase-resolved STM imaging provides stringent constraints on topological states of matter, symmetry-breaking patterns, and strong electronic correlations, outlining a robust framework for in situ phase engineering in quantum materials. △ Less

Submitted 5 July, 2026; v1 submitted 28 June, 2026; originally announced June 2026.

Journal ref: Acta Physica Sinica. 2026, 75(12): 120701

Resolving support-mismatch by local basis rotation in variational Monte Carlo

Authors: Jia-Lin Chen, Zhen Fan, Canhui Yan, Yantao Wu, Tao Xiang

Abstract: Real-time dynamics after a local quench by a charged operator encodes the response functions measured in spectroscopic experiments, yet they have long posed a challenge for variational Monte Carlo calculations. The obstacle is a support mismatch: the projective action by a charged local operator forces an exponentially large number of configurations to vanish, but these configurations may still co… ▽ More Real-time dynamics after a local quench by a charged operator encodes the response functions measured in spectroscopic experiments, yet they have long posed a challenge for variational Monte Carlo calculations. The obstacle is a support mismatch: the projective action by a charged local operator forces an exponentially large number of configurations to vanish, but these configurations may still contribute to the dynamics, biasing the estimators and freezing the evolution at the very first step. This difficulty is an artifact of the chosen sampling basis, and the support mismatch generated by a charged local operator is itself local. We demonstrate that the missing support can be restored by a local rotation of the sampling basis, without changing the underlying variational dynamics. We propose a local basis-rotation sampling scheme that resolves the support-mismatch problem and can be readily incorporated into existing variational Monte Carlo algorithms. Benchmarks show that rotation sampling accurately captures long-time quantum dynamics, enabling variational Monte Carlo calculations of dynamical structure factors in one dimension and unbiased local-operator quench dynamics in two dimensions. We also show that this resolution of the support-mismatch problem extends beyond real-time dynamics, and may also be helpful for ground state variational Monte Carlo calculations. △ Less

Submitted 22 June, 2026; originally announced June 2026.

Oxygen Vacancies at Dislocation Core Modulate Plasticity in Strontium Titanate

Authors: Min-Chul Kang, Chunxu Yan, Alexander Frisch, Xufei Fang, Liming Xiong, Lin Zhou

Abstract: Dislocation core chemistry in oxides critically influences mechanical behavior and functionality; yet the evolution of core chemistry during the dislocation motion in them has not been directly observed. Here, using SrTiO3 as a model material, we combine aberration-corrected scanning transmission electron microscopy and electron energy-loss spectroscopy with atomic-level molecular dynamics (MD) si… ▽ More Dislocation core chemistry in oxides critically influences mechanical behavior and functionality; yet the evolution of core chemistry during the dislocation motion in them has not been directly observed. Here, using SrTiO3 as a model material, we combine aberration-corrected scanning transmission electron microscopy and electron energy-loss spectroscopy with atomic-level molecular dynamics (MD) simulations to correlate the <110>{1-10} dislocation core structure, oxygen vacancy density, charge state, and mobility with each other. We find that the mechanically induced dislocation loops exhibit dissociated cores, whose oxygen vacancy density depends on the gliding distance: short loops are Ti-reduced and oxygen-deficient at the edge dislocation core, whereas longer loops remain close to stoichiometry in both the edge and screw components. MD simulations reveal that kink-assisted edge dislocation glide in SrTiO3 leaves oxygen-deficient trails behind, modulating the oxygen content inside the edge core. These results demonstrate that oxygen-vacancy evolution at the dislocation core intrinsically couples with plasticity in ionic crystals, suggesting a mechanism for oxygen vacancy-dependent dislocation mobility in plastically deformed oxides. △ Less

Submitted 1 May, 2026; originally announced May 2026.

Journal ref: Acta Materialia, 2026, 313: 122283

Coordination Engineering of Dual-Atom Catalysts for Overall Water Splitting: Mechanistic Insights from Constant-Potential First-Principles and Machine Learning

Authors: Jiahang Li, Suhang Li, Chong Yan, Jiajun Yu, Qinzhuang Liu, Ruo-Ya Wang, Dongwei Ma

Abstract: The rational design of bifunctional electrocatalysts for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is essential for achieving efficient and cost-effective overall water splitting. Atomically dispersed transition-metal catalysts, including single-atom catalysts and dual-atom catalysts (DACs), have emerged as a prominent class of heterogeneous catalysts, in which coor… ▽ More The rational design of bifunctional electrocatalysts for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is essential for achieving efficient and cost-effective overall water splitting. Atomically dispersed transition-metal catalysts, including single-atom catalysts and dual-atom catalysts (DACs), have emerged as a prominent class of heterogeneous catalysts, in which coordination engineering plays a decisive role in tuning catalytic performance. Herein, we explore coordination-engineered bifunctional overall water splitting electrocatalysts using graphene-supported DACs (TM1TM2-C6-xNx) as model systems. By tuning C/N coordination and dual-metal combinations (Fe, Co, Ni, and Cu), a library of 228 structures was constructed. A three-step screening strategy, combining constant-charge and constant-potential density functional theory with kinetic analysis of proton-coupled electron transfer (PCET), identifies 24 highly active candidates (TM1TM2 = CoNi, CoCu and Co2) with mixed C/N coordination for OER. These catalysts exhibit overpotentials comparable to that of IrO2 and low PCET barriers (lower than 0.40 eV), among which 22 also show high HER activity. Machine learning reveals clear coordination-dependent structure-performance relationships. Such bifunctionality arises from coordination engineering that enables the simultaneous optimization of OER intermediate adsorption and the hydrogen binding strength for HER. This work establishes coordination engineering as an effective strategy for designing high-performance bifunctional dual-atom electrocatalysts for overall water splitting. △ Less

Submitted 1 May, 2026; originally announced May 2026.

Interband optical conductivities in two-dimensional tilted Dirac bands revisited within the tight-binding model

Authors: Chao-Yang Tan, Jian-Tong Hou, Xin Chen, Ling-Zhi Bai, Jie Lu, Yong-Hong Zhao, Chang-Xu Yan, Hao-Ran Chang, Hong Guo

Abstract: Within the framework of linear response theory, we theoretically investigated the interband longitudinal optical conductivities (LOCs) in two-dimensional (2D) tilted Dirac bands using a tight-binding (TB) model, incorporating the effects of band tilting and Dirac-point shifting. We identified three characteristic critical frequencies in the interband LOCs of the TB model: the partner frequencies,… ▽ More Within the framework of linear response theory, we theoretically investigated the interband longitudinal optical conductivities (LOCs) in two-dimensional (2D) tilted Dirac bands using a tight-binding (TB) model, incorporating the effects of band tilting and Dirac-point shifting. We identified three characteristic critical frequencies in the interband LOCs of the TB model: the partner frequencies, the sharp- peak frequency, and the cutoff frequency. In contrast to conventional critical frequencies, these three types are consistently absent in the corresponding linearized $k\cdot p$ model. Notably, the sharp-peak frequency and cutoff frequency remain robust against variations in band tilting and Dirac-point shifting. By employing analytical expressions derived via the Lagrange multiplier method, we elucidate the origins of the conventional critical frequencies and their partner counterparts. In contrast, the sharp-peak frequency and cutoff frequency are associated with interband optical transitions at high-symmetry points of the energy bands, arising from the Pauli exclusion principle and the finite boundaries of the Brillouin zone. Our theoretical predictions are intended to guide future experimental studies on tilt-dependent optical phenomena in 2D tilted Dirac systems. △ Less

Submitted 7 April, 2026; originally announced April 2026.

Comments: 11 pages main text with 5 figures, 11 pages supplemental materials

Journal ref: Front. Phys. 21(9), 095205 (2026)

Electrically tunable circular photocurrent via local-field induced symmetry breaking at a metal-MoTe2 interface

Authors: Butian Zhang, Kexin Wang, Jun-Tao Ma, Yiya Guo, Chengyu Yan, Xin Yi, Luojun Du, Youwei Zhang, Hua-Hua Fu, Shun Wang

Abstract: Transition metal dichalcogenides (TMDCs) constitute a promising platform for symmetry-engineered responses to circularly polarized light. The high crystal symmetry of centrosymmetric 2H-phase TMDCs inherently forbids the circular photogalvanic effect, thereby necessitating external stimuli such as electric fields or strain to lower the symmetry for its activation. While Schottky junctions provide… ▽ More Transition metal dichalcogenides (TMDCs) constitute a promising platform for symmetry-engineered responses to circularly polarized light. The high crystal symmetry of centrosymmetric 2H-phase TMDCs inherently forbids the circular photogalvanic effect, thereby necessitating external stimuli such as electric fields or strain to lower the symmetry for its activation. While Schottky junctions provide a ubiquitous built-in field for potentially inducing circular photocurrents, the mechanism for the generation and control of circular photocurrents in TMDCs is not understood. In this study, we fabricated a localized gold-MoTe2 heterostructure and demonstrate a pronounced circular photocurrent at the interface under normal incidence. The photocurrent is attributed to circular photogalvanic effect governed by the strength and direction of the built-in electric field, enabling continuous modulation via an external bias. First-principles calculations show that the gold interface induces a spin splitting in the valence bands of MoTe2, establishing a valley-dependent spin ordering. The observed circular photocurrent from multilayer 2H-MoTe2 under normal incidence indicates the breaking of C3 rotational symmetry by the local in-plane field. These results establish an effective strategy for developing voltage-tunable circularly polarized photodetectors and valleytronic devices. △ Less

Submitted 5 March, 2026; originally announced March 2026.

Origin of anomalous p-type conductivity in monolayer Fe-doped MoS2

Authors: Xiangning Quan, Xiaoqiu Yuan, Junwei Zhang, Xuebing Peng, Helin Mei, Cheng Yan, Hong Zhang, Hongli Li, Daqiang Gao, Yongjian Wang, Mingsu Si, Lili Zhang, Anmin Zhang, Zongyuan Zhang, Lei Shan, Yong Peng

Abstract: Substitutional doping effectively modulates carrier polarity of semiconducting two-dimensional (2D) transition metal dichalcogenides (TMDs) like MoS2. Although Fe doping typically induces n-type conductivity in monolayer MoS2, anomalous p-type behavior has also been experimentally reported, the origin of which remains unresolved. Here, we prove that this anomalous p-type conductivity originates fr… ▽ More Substitutional doping effectively modulates carrier polarity of semiconducting two-dimensional (2D) transition metal dichalcogenides (TMDs) like MoS2. Although Fe doping typically induces n-type conductivity in monolayer MoS2, anomalous p-type behavior has also been experimentally reported, the origin of which remains unresolved. Here, we prove that this anomalous p-type conductivity originates from defect associates formed through interactions between Fe dopants and S atoms, which consists of three Fe substituting Mo (FeMo) point defects arranged into an equilateral triangle with a central S atom, denoted as 3FeMo-S associate. Its p-type effect is directly verified through scanning tunneling microscopy/scanning tunneling spectroscopy (STM/STS) measurement, in sharp contrast to the n-type behavior induced by isolated FeMo point defects, and the conclusion is further supported by electrical transport measurements and first-principles calculations. Similar 3FeW-S associates and their p-type doping effect are also identified in monolayer Fe-doped WS2. This work resolves a longstanding controversy and highlights the critical role of defect associates in modulating properties of 2D TMDs. △ Less

Submitted 28 February, 2026; originally announced March 2026.

Comments: Main: 22 pages, 5 figures. SI: 24 pages, 17 figures, 1 Table

From Literature to Lab: Closed-Loop Advancement of Perovskite Solar Cells via Domain Knowledge Guided LLM

Authors: Penglei Sun, Shuyan Chen, Xiang Liu, Longhan Zhang, Huajie You, Chang Yan, Yongqi Zhang, Xiaowen Chu, Tong-yi Zhang

Abstract: Perovskite solar cells (PSCs) have been considered as a next-generation disruptive photovoltaic technology, yet their advancement is constrained by the complexity of perovskite recipe with high-dimensional material and process design space. Despite the impressive general reasoning of Large Language Models (LLMs), they struggle with two limitations for application in PSCs: an inability to align gen… ▽ More Perovskite solar cells (PSCs) have been considered as a next-generation disruptive photovoltaic technology, yet their advancement is constrained by the complexity of perovskite recipe with high-dimensional material and process design space. Despite the impressive general reasoning of Large Language Models (LLMs), they struggle with two limitations for application in PSCs: an inability to align general semantics with the perovskite domain knowledge, and an inefficiency in navigating high-dimensional perovskite material and recipe design spaces. To address these limitations, we introduce a domain-knowledge-guided framework PVK-LLM, a specialized model to serve as an expert to bridge general semantics with perovskite domain knowledge. By integrating this domain knowledge into a hierarchical Bayesian Optimization workflow, our approach efficiently navigates the high-dimension design space on a solar cell simulator platform. The domain knowledge resolves cold-start problems while dynamically adapting to simulator feedback. Moreover, in an individual wet-lab experiment aimed at maximizing power conversion efficiency (PCE), our framework autonomously proposes a novel synergistic four-component recipe comprising specialized organic passivation recipe (3MTPAI, PDAI2, EDAI2, and PipDI) which has not been reported in existing literature. This AI-designed recipe effectively achieves a champion PCE value of over 26.0 %, approaching world records achieved through extensive expert trial-and-error. Our approach can effectively enable LLM comprehend the domain knowledge, which can efficiently navigate in a high-dimensional, capable to accelerate the advancement in real-world perovskite as well as other material science development. △ Less

Submitted 3 February, 2026; originally announced February 2026.

Potential-Induced Dynamic Coordination of Nonmetal Atoms Directly Bound to Metal Centers in Graphene-Embedded Single-Atom Catalysts and Its Implications

Authors: Jiahang Li, Suhang Li, Chong Yan, Qinzhuang Liu, Jiajun Yu, Dongwei Ma

Abstract: Electrode-potential-induced dynamic coordination is an essential factor governing the performance of graphene-embedded single-atom catalysts (SACs). While previous studies have primarily centered on structural dynamics at the metal site, the response of its coordinated nonmetal atoms remains largely unexplored. Here, using Ni SACs with mixed nitrogen/carbon coordination (NiN4-xCx) as representativ… ▽ More Electrode-potential-induced dynamic coordination is an essential factor governing the performance of graphene-embedded single-atom catalysts (SACs). While previous studies have primarily centered on structural dynamics at the metal site, the response of its coordinated nonmetal atoms remains largely unexplored. Here, using Ni SACs with mixed nitrogen/carbon coordination (NiN4-xCx) as representatives, we investigate potential-driven hydrogenation of metal-center-coordinated nonmetallic atoms through constant-potential density functional theory and ab initio molecular dynamics. We find that the C sites directly bound to Ni undergo potential-driven hydrogenation, whereas hydrogenation at N sites is thermodynamically unfavorable. Taking NiNC3 as a representative system, we demonstrate that these hydrogenation processes proceed with accessible kinetic barriers and obey the Brønsted-Evans-Polanyi relation. The resulting dynamic coordination reshapes the Ni 3d and dz2 orbitals, modulates the stability of the active center, and weakens molecular adsorption through combined electronic and steric effects. These findings reveal that electrode potential and solvent not only regulate the metal center but also dynamically reconfigure its coordination environment, offering novel mechanistic insights into potential-induced coordination dynamics and guiding the rational design of coordination-engineered SACs. △ Less

Submitted 4 February, 2026; originally announced February 2026.

Comments: 35 pages, 5 figures

Electric-Switchable Chiral Magnons in PT-Symmetric Antiferromagnets

Authors: Jinyang Ni, Congzhe Yan, Peiyuan Cui, Zhijun Jiang, Yuanjun Jin, Guoqing Chang

Abstract: The magnons in antiferromagnetic insulators (AFIs) exhibit dual chirality, each carrying opposite spin angular momentum. However, in PT-symmetric AFIs, the magnon bands remain degenerate. In this work, we introduce a new class of PT-preserving AFIs in which the giant chiral splitting of magnons can be induced and controlled by an external electric field. Unlike conventional cases, such AFIs host a… ▽ More The magnons in antiferromagnetic insulators (AFIs) exhibit dual chirality, each carrying opposite spin angular momentum. However, in PT-symmetric AFIs, the magnon bands remain degenerate. In this work, we introduce a new class of PT-preserving AFIs in which the giant chiral splitting of magnons can be induced and controlled by an external electric field. Unlike conventional cases, such AFIs host a hidden dipole coupled to the antiferromagnetic order, which allows an external electric field to break the magnon sublattice symmetry and thereby largely lift the band degeneracy. Group theoretical analysis identifies the possible magnetic layer groups, while first-principles calculations and spin-wave theory reveal band splittings up to 20meV in Cr2CCl2 and Cr2CBr2 under the electric field of 0.2 V/Å, corresponding to an effective magnetic field of 200T. In addition, the electrically controlled magnon chiral splitting enables reversible switching of magnon-mediated spin currents. These findings open a new route toward nonvolatile spintronics based on magnons. △ Less

Submitted 22 May, 2026; v1 submitted 22 January, 2026; originally announced January 2026.

A Symmetric Superconducting Dome Hosts Non-Fermi Liquid Behavior at Optimal Doping in MoS2

Authors: Qiao Chen, Chengyu Yan, Dino Novko, Changshuai Lan, Huiqin Jian, Yi Yan, Xinming Zhao, Yihang Li, Huai Guan, Bo Gao, Zhong Wan, Shun Wang

Abstract: The similarities between the phase diagrams of ionic liquid-gated transition metal dichalcogenides (TMDCs) and high-temperature superconductors have garnered considerable interest due to the presence of a superconducting dome with a non-monotonic dependence of the superconducting order parameter as a function of charge carrier density. However, the lack of a complete superconducting dome and insig… ▽ More The similarities between the phase diagrams of ionic liquid-gated transition metal dichalcogenides (TMDCs) and high-temperature superconductors have garnered considerable interest due to the presence of a superconducting dome with a non-monotonic dependence of the superconducting order parameter as a function of charge carrier density. However, the lack of a complete superconducting dome and insights into the normal state in ionic liquid-gated TMDCs prevents a detailed mapping between the two systems. In this work, we obtain a symmetric superconducting dome that extends from deep underdoped regime all the way to deep overdoped regime in ionic liquid gated MoS2 with a refined gating protocol. We demonstrate that the dome is anticorrelated with the evolution of non-Fermi liquid behavior in the normal states. The scattering rate in the non-Fermi liquid regime can reach Planckian limit. The results may shed light on the emergence of superconductivity in TMDCs. △ Less

Submitted 25 May, 2026; v1 submitted 23 December, 2025; originally announced December 2025.

Many-body electronic structure in pyrochlore superconductor CsBi2 and spin liquid Pr2Ir2O7

Authors: Wei Song, Guowei Liu, Hanbin Deng, Tianyu Yang, Yongkai Li, Xiao-Yu Yan, Ruoxing Liao, Qianming Wang, Jiayu Xu, Chao Yan, Yuanyuan Zhao, Hailang Qin, Da Wang, Wenchuan Jing, Dawei Shen, Kosuke Nakayama, Takafumi Sato, Chandan Setty, Desheng Wu, Boqing Song, Tianping Ying, Zhaoming Tian, Akito Sakai, Satoru Nakatsuji, Harish Kumar , et al. (4 additional authors not shown)

Abstract: The pyrochlore lattice materials can exhibit geometrical frustration, while the related many-body electronic states remain elusive. In this work, we performed scanning tunneling microscopy measurements on the pyrochlore superconductor CsBi2 and spin liquid Pr2Ir2O7 at 0.3 K. For the first time, we obtained atomically resolved images of their (111) surfaces, revealing a hexagonal lattice or a kagom… ▽ More The pyrochlore lattice materials can exhibit geometrical frustration, while the related many-body electronic states remain elusive. In this work, we performed scanning tunneling microscopy measurements on the pyrochlore superconductor CsBi2 and spin liquid Pr2Ir2O7 at 0.3 K. For the first time, we obtained atomically resolved images of their (111) surfaces, revealing a hexagonal lattice or a kagome lattice. Tunneling spectroscopy in CsBi2 reveals a nearly fully opened superconductivity gap. The ratio of 2Δ/kBTC = 4.7 suggests relatively strong coupling superconductivity, as compared with that in kagome superconductors AV3Sb5 (A = K, Rb, Cs). In contrast to the previous study categorizing CsBi2 as a type-I superconductor, the applied magnetic field induces a hexagonal vortex lattice in which each vortex core exhibits an intriguing three-fold symmetry state. In Pr2Ir2O7, we observed a spatially homogeneous Kondo-lattice resonance, which is compared with that in the kagome Kondo-lattice material CsCr6Sb6. We further discover that the Kondo resonance exhibits a spatial modulation with three-fold symmetry, and the applied magnetic field induces a Zeeman splitting of the Kondo resonance with intriguing atomic site dependence. We discuss the relations of these many-body electronic phenomena with the pyrochlore lattice geometry and its charge or spin frustration. Our systematic observations offer atomic-scale insights into the many-body electronic structures of the geometrically frustrated pyrochlore superconductors and spin liquids. △ Less

Submitted 22 November, 2025; originally announced November 2025.

Comments: To appear in PRB

Journal ref: Phys. Rev. B 112, 245131 2025

Interband optical conductivity in two-dimensional semi-Dirac bands tilting along the quadratic dispersion

Authors: Xin Chen, Jian-Tong Hou, Long Liang, Jie Lu, Hong Guo, Chang-Xu Yan, Hao-Ran Chang

Abstract: Two-dimensional (2D) semi-Dirac materials feature a unique anisotropic band structure characterized by quadratic dispersion along one spatial direction and linear dispersion along the other, effectively hybridizing ordinary and Dirac fermions. The anisotropy of energy dispersion can be further modulated through band tilting along either spatial direction of the wave vector. We propose a new defini… ▽ More Two-dimensional (2D) semi-Dirac materials feature a unique anisotropic band structure characterized by quadratic dispersion along one spatial direction and linear dispersion along the other, effectively hybridizing ordinary and Dirac fermions. The anisotropy of energy dispersion can be further modulated through band tilting along either spatial direction of the wave vector. We propose a new definition of tilt parameter to characterize Lifshitz phases in 2D semi-Dirac bands tilting along the quadratically dispersing direction. Using linear response theory, we theoretically investigate the interband optical conductivity of 2D tilted semi-Dirac bands. Our analytical zero-temperature results reveal pronounced distinctions from Dirac and semi-Dirac systems tilting along the linearly dispersing direction. Notably, we find that spectral fixed point emerges in the optical conductivity over a specific range of the tilt parameter, a phenomenon explained by the corresponding behavior of the joint density of states. These findings provide a robust theoretical framework for identifying and characterizing 2D tilted semi-Dirac materials and establish clear spectral fingerprints that distinguish different kinds of 2D semi-Dirac bands and Dirac bands. Our predictions can guide future experimental studies of anisotropic band engineering and tilt-dependent phenomena. △ Less

Submitted 7 October, 2025; originally announced October 2025.

Comments: 15 pages, 5 figures

Defect migration in supercrystalline nanocomposites

Authors: Dmitry Lapkin, Cong Yan, Emre Gürsoy, Hadas Sternlicht, Alexander Plunkett, Büsra Bor, Young Yong Kim, Dameli Assalauova, Fabian Westermeier, Michael Sprung, Tobias Krekeler, Surya Snata Rout, Martin Ritter, Satishkumar Kulkarni, Thomas F. Keller, Gerold A. Schneider, Gregor B. Vonbun-Feldbauer, Robert H. Meissner, Andreas Stierle, Ivan A. Vartanyants, Diletta Giuntini

Abstract: Supercrystalline nanocomposites (SCNCs) are nanostructured hybrid materials with unique emergent functional properties. Given their periodically arranged building blocks, they also offer interesting parallelisms with crystalline materials. They can be processed in multiple forms and at different scales, and crosslinking their organic ligands via heat treatment leads to a remarkable boost of their… ▽ More Supercrystalline nanocomposites (SCNCs) are nanostructured hybrid materials with unique emergent functional properties. Given their periodically arranged building blocks, they also offer interesting parallelisms with crystalline materials. They can be processed in multiple forms and at different scales, and crosslinking their organic ligands via heat treatment leads to a remarkable boost of their mechanical properties. This study shows, via X-ray and in-situ scanning transmission (STEM) electron microscopy analyses, how each of these processing steps plays a distinct role in the generation, migration, interaction and healing of supercrystalline defects. Pressing of SCNCs into bulk pellets leads to a distortion of the otherwise fcc superlattice, while emulsion-templated self-assembly yields supraparticles (SPs) with stacking faults and size-dependent symmetries. Interestingly, heat treatment at the same temperatures as those applied for the organic crosslinking has significant effects on planar defects. Stacking faults migrate and get healed, as also confirmed via molecular dynamics simulations, and inter-supercrystalline 'grain' boundaries undergo structural changes. These rearrangements of defects at the supercrystalline scale (tens of nm) in nanocomposites with such remarkable mechanical properties (compressive strength of 100-500 MPa) provide new insights into the formation and evolution of ordered assemblies of functionalized nanoparticles. △ Less

Submitted 28 July, 2025; originally announced July 2025.

Dual-mode superconducting diode effect enabled by in-plane and out-of-plane magnetic field

Authors: Chengyu Yan, Huai Guan, Zhenyu Zhang, Yiheng Sun, Qiao Chen, Xinming Zhao, Chuanwen Zhao, James Jun He, Shun Wang

Abstract: The discovery of the superconducting diode effect (SDE) has been cherished as a milestone in developing superconducting electronics. Tremendous efforts are being dedicated to realizing SDE in a wide variety of material platforms. Despite the diversity in the hosting materials and device designs, SDE is usually operated in a single mode which is enabled by either out-of-plane or in-plane magnetic f… ▽ More The discovery of the superconducting diode effect (SDE) has been cherished as a milestone in developing superconducting electronics. Tremendous efforts are being dedicated to realizing SDE in a wide variety of material platforms. Despite the diversity in the hosting materials and device designs, SDE is usually operated in a single mode which is enabled by either out-of-plane or in-plane magnetic field/magnetization. In this work, we report the realization of a dual-mode SDE in 2H-$\mathrm{NbS_2}$/2H-$\mathrm{NbSe_2}$ heterostructures where both the out-of-plane magnetic field $B_{\perp}$ and in-plane magnetic field $B_{||}$ can independently generate and manipulate SDE. The two modes share similar diode efficiency but differ in two aspects: 1. $B_{\perp}$-induced SDE is activated by a field on the order of 1 mT while $B_{||}$-induced SDE requires a field on the order of 100 mT; 2. $η$ of $B_{\perp}$-induced SDE exhibits a square-root like temperature dependence while $η$ of $B_{||}$-induced SDE takes a more linear-like one. We demonstrate that the dual-mode SDE is most likely a result of mirror symmetry breaking along multiple orientations. Thanks to the two orders difference in the operational field for the two modes, we propose a dual-functionality device scheme to showcase the potential of the dual-mode SDE in realizing advanced superconducting architecture, where fast polarity-switching functionality is implemented with $B_{\perp}$-induced SDE and high-fidelity functionality is enabled with $B_{\perp}$-induced SDE. △ Less

Submitted 8 June, 2025; originally announced June 2025.

Journal ref: Commun Phys 9, 180 (2026)

Evolution of quantum criticality in underdoped cuprates

Authors: Changshuai Lan, Chengyu Yan, Yihang Li, Qiao Chen, Huai Guan, Xinming Zhao, Dong Wu, Butian Zhang, Youwei Zhang, Shun Wang

Abstract: Quantum criticality, with both static and dynamic information of the system intrinsically encoded in characteristic length scales, serves as one of the most sensitive and universal probes to monitor quantum phase transition. Qualitatively different quantum criticality behaviours have been widely observed even in the same condensed matter system. The discrepancy is attributed to sample specificity… ▽ More Quantum criticality, with both static and dynamic information of the system intrinsically encoded in characteristic length scales, serves as one of the most sensitive and universal probes to monitor quantum phase transition. Qualitatively different quantum criticality behaviours have been widely observed even in the same condensed matter system. The discrepancy is attributed to sample specificity but has not been systemically addressed. Here we report a single-parameter driven three-stage evolution of quantum criticality unveiled in superconductor-insulator transition in underdoped Bi2Sr2CaCu2O8+δ flakes. The evolution starts with a single quantum critical point emerging at the boundary between the superconducting and antiferromagnetic phases, then evolving into anomalous quantum Griffiths singularity at the medium doping levels and eventually being replaced by quantum Griffiths singularity in the deep superconducting regime. A puddle model that incorporates the developments of antiferromagnetic correlation can capture the evolution. The results offer a new aspect to examine previous seemingly sample-specific quantum critical behavior and lay the foundation for further exploring complex quantum criticality in strongly correlated systems; meanwhile they shed light on the detailed interaction between superconductivity and antiferromagnetism in cuprates. △ Less

Submitted 28 April, 2025; originally announced April 2025.

Comments: 13 pages, 5 figures

Enhanced Backgate Tunability on Interfacial Carrier Concentration in Ionic Liquid-Gated MoS2 Devices

Authors: Qiao Chen, Chengyu Yan, Changshuai Lan, Qiyang Song, Yi Yan, Shun Wang

Abstract: The periodic spatial modulation potential arising from the zig-zag distribution of ions at large gate voltage in an ionic liquid gated device may enable functionalities in a similar way as nanopatterning and moiré engineering. However, the inherent coupling between periodic modulation potential and carrier concentration in ionic liquid devices has hindered further exploration. Here, we demonstrate… ▽ More The periodic spatial modulation potential arising from the zig-zag distribution of ions at large gate voltage in an ionic liquid gated device may enable functionalities in a similar way as nanopatterning and moiré engineering. However, the inherent coupling between periodic modulation potential and carrier concentration in ionic liquid devices has hindered further exploration. Here, we demonstrate the feasibility of decoupling manipulation on periodic modulation potential and carrier density in an ionic liquid device by using a conventional backgate. The backgate is found to have a tunability on carrier concentration comparable to that of ionic gating, especially at large ionic liquid gate voltage, by activating the bulk channels mediated back tunneling between the trapped bands and interfacial channel. △ Less

Submitted 25 April, 2025; originally announced April 2025.

Comments: 14 pages, 4 figures

Journal ref: Small, 2025

A Topological Superconductor Tuned by Electronic Correlations

Authors: Haoran Lin, Christopher L. Jacobs, Chenhui Yan, Gillian M. Nolan, Gabriele Berruto, Patrick Singleton, Khanh Duy Nguyen, Yunhe Bai, Qiang Gao, Xianxin Wu, Chao-Xing Liu, Gangbin Yan, Suin Choi, Chong Liu, Nathan P. Guisinger, Pinshane Y. Huang, Subhasish Mandal, Shuolong Yang

Abstract: A topological superconductor, characterized by either a chiral order parameter or a chiral topological surface state in proximity to bulk superconductivity, is foundational to topological quantum computing. As in other topological phases of matter, electronic correlations can tune topological superconductivity via modifications of the low-energy Fermiology. Such tuning has not been realized so far… ▽ More A topological superconductor, characterized by either a chiral order parameter or a chiral topological surface state in proximity to bulk superconductivity, is foundational to topological quantum computing. As in other topological phases of matter, electronic correlations can tune topological superconductivity via modifications of the low-energy Fermiology. Such tuning has not been realized so far. Here we uncover a unique topological superconducting phase in competition with electronic correlations in 10-unit-cell thick FeTe$_{x}$Se$_{1-x}$ films grown on SrTiO$_{3}$ substrates. When the Te content $x$ exceeds $0.7$, we observe a rapid increase of the effective mass for the Fe $d_{xy}$ band, with the emergence of a superconducting topological surface state confirmed by high-resolution angle-resolved photoemission spectroscopy; however, near the FeTe limit, the system enters an incoherent regime where the topological surface state becomes unidentifiable and superconductivity is suppressed. Theory suggests that the electron-electron interactions in the odd-parity $xy^-$ band with a strong $d_{xy}$ character lead to an orbital-selective correlated phase. Our work establishes FeTe$_{x}$Se$_{1-x}$ thin films as a unique platform where electronic correlations sensitively modulate topological superconductivity, suggesting opportunities to use tunable electron-electron interactions to engineer new topological phases in a broad class of materials. △ Less

Submitted 28 March, 2025; originally announced March 2025.

State-dependent friction for a moving liquid contact line over rough solid surfaces

Authors: Caishan Yan, Penger Tong, Qin Xu

Abstract: Solid friction between two rough surfaces is often observed to increase logarithmically over time due to contact creeping. An intriguing question is whether a similar aging effect occurs in contact line (CL) friction over rough substrates. Here, we report a systematic experimental study of CL friction using a hanging-fiber atomic force microscope (AFM) to measure the frictional force as a liquid C… ▽ More Solid friction between two rough surfaces is often observed to increase logarithmically over time due to contact creeping. An intriguing question is whether a similar aging effect occurs in contact line (CL) friction over rough substrates. Here, we report a systematic experimental study of CL friction using a hanging-fiber atomic force microscope (AFM) to measure the frictional force as a liquid CL moves across a fiber surface with different coatings under a well-controlled time protocol. State- (or time-)dependent CL friction is observed for the fiber surface with different textures in both the advancing and receding directions. The experimental findings are explained by a phenomenological model that links mesoscale CL friction to the microscopic relaxation of metastable air bubbles or liquid droplets trapped in the interstices of a rough surface. This model offers a general aging mechanism relevant to a wide range of liquid-solid interfaces. △ Less

Submitted 4 March, 2025; originally announced March 2025.

Orbital Fulde-Ferrell-Larkin-Ovchinnikov state in 2H-NbS2 flakes

Authors: Xinming Zhao, Guoliang Guo, Chengyu Yan, Noah F. Q. Yuan, Chuanwen Zhao, Huai Guan, Changshuai Lan, Yihang Li, Xin Liu, Shun Wang

Abstract: Symmetry breaking in a layered superconductor with Ising spin-orbit coupling has offered an opportunity to realize unconventional superconductivity. To be more specific, orbital Fulde-Ferrell-Larkin-Ovchinnikov (FFLO) state, exhibiting layer-dependent finite-momentum pairing, may emerge in transition metal dichalcogenides materials (TMDC) in the presence of an in-plane magnetic field. Orbital FFLO… ▽ More Symmetry breaking in a layered superconductor with Ising spin-orbit coupling has offered an opportunity to realize unconventional superconductivity. To be more specific, orbital Fulde-Ferrell-Larkin-Ovchinnikov (FFLO) state, exhibiting layer-dependent finite-momentum pairing, may emerge in transition metal dichalcogenides materials (TMDC) in the presence of an in-plane magnetic field. Orbital FFLO state can be more robust against the magnetic field than the conventional superconducting state with zero-momentum pairing. This feature renders its potential in field-resilient superconducting functionality. Although, orbital FFLO state has been reported in NbSe2 and MoS2, it is not yet clear if orbital FFLO state can be extended to other TMDC superconductor. Here, we report the observation of orbital FFLO state in 2H-NbS2 flakes and its dependence on the thickness of flake. We conclude that the relatively weak interlayer coupling is instrumental in stabilizing orbital FFLO state at higher temperature with respect to the critical temperature and lower magnetic field with respect to paramagnetic limit in NbS2 in comparison to its NbSe2 counterpart. △ Less

Submitted 26 May, 2025; v1 submitted 13 November, 2024; originally announced November 2024.

Journal ref: Phys. Rev. B 112, 174503 (2025)

Distinguishing Surface and Bulk Electromagnetism via Their Dynamics in an Intrinsic Magnetic Topological Insulator

Authors: Khanh Duy Nguyen, Woojoo Lee, Jianchen Dang, Tongyao Wu, Gabriele Berruto, Chenhui Yan, Chi Ian Jess Ip, Haoran Lin, Qiang Gao, Seng Huat Lee, Binghai Yan, Chaoxing Liu, Zhiqiang Mao, Xiao-Xiao Zhang, Shuolong Yang

Abstract: The indirect exchange interaction between local magnetic moments via surface electrons has been long predicted to bolster the surface ferromagnetism in magnetic topological insulators (MTIs), which facilitates the quantum anomalous Hall effect. This unconventional effect is critical to determining the operating temperatures of future topotronic devices. However, the experimental confirmation of th… ▽ More The indirect exchange interaction between local magnetic moments via surface electrons has been long predicted to bolster the surface ferromagnetism in magnetic topological insulators (MTIs), which facilitates the quantum anomalous Hall effect. This unconventional effect is critical to determining the operating temperatures of future topotronic devices. However, the experimental confirmation of this mechanism remains elusive, especially in intrinsic MTIs. Here we combine time-resolved photoemission spectroscopy with time-resolved magneto-optical Kerr effect measurements to elucidate the unique electromagnetism at the surface of an intrinsic MTI MnBi2Te4. Theoretical modeling based on 2D Ruderman-Kittel-Kasuya-Yosida interactions captures the initial quenching of a surface-rooted exchange gap within a factor of two but over-estimates the bulk demagnetization by one order of magnitude. This mechanism directly explains the sizable gap in the quasi-2D electronic state and the nonzero residual magnetization in even-layer MnBi2Te4. Furthermore, it leads to efficient light-induced demagnetization comparable to state-of-the-art magnetophotonic crystals, promising an effective manipulation of magnetism and topological orders for future topotronics. △ Less

Submitted 28 June, 2024; originally announced July 2024.

Comments: 19 pages, 4 figures

Preservation of Topological Surface States in Millimeter-Scale Transferred Membranes

Authors: Chi Ian Jess Ip, Qiang Gao, Khanhy Du Nguyen, Chenhui Yan, Gangbin Yan, Eli Hoenig, Thomas S. Marchese, Minghao Zhang, Woojoo Lee, Hossein Rokni, Ying Shirley Meng, Chong Liu, Shuolong Yang

Abstract: Ultrathin topological insulator membranes are building blocks of exotic quantum matter. However, traditional epitaxy of these materials does not facilitate stacking in arbitrary orders, while mechanical exfoliation from bulk crystals is also challenging due to the non-negligible interlayer coupling therein. Here we liberate millimeter-scale films of topological insulator Bi$_2$Se$_3$, grown by mol… ▽ More Ultrathin topological insulator membranes are building blocks of exotic quantum matter. However, traditional epitaxy of these materials does not facilitate stacking in arbitrary orders, while mechanical exfoliation from bulk crystals is also challenging due to the non-negligible interlayer coupling therein. Here we liberate millimeter-scale films of topological insulator Bi$_2$Se$_3$, grown by molecular beam epitaxy, down to 3 quintuple layers. We characterize the preservation of the topological surface states and quantum well states in transferred Bi$_{2}$Se$_{3}$ films using angle-resolved photoemission spectroscopy. Leveraging the photon-energy-dependent surface sensitivity, the photoemission spectra taken with $6$ eV and $21.2$ eV photons reveal a transfer-induced migration of the topological surface states from the top to the inner layers. By establishing clear electronic structures of the transferred films and unveiling the wavefunction relocation of the topological surface states, our work paves the physics foundation crucial for the future fabrication of artificially stacked topological materials with single-layer precision. △ Less

Submitted 21 May, 2024; originally announced May 2024.

Comments: 4 figures

Journal ref: Nano Letters 2024

Circular Photocurrents in Centrosymmetric Semiconductors with Hidden Spin Polarization

Authors: Kexin Wang, Butian Zhang, Chengyu Yan, Luojun Du, Shun Wang

Abstract: Centrosymmetric materials with site inversion asymmetries possess hidden spin polarization, which remains challenging to be converted into spin currents because the global inversion symmetry is still conserved. This study demonstrates the spin-polarized DC circular photocurrents (CPC) in centrosymmetric transition metal dichalcogenides (TMDCs) at normal incidence without applying electric bias. Th… ▽ More Centrosymmetric materials with site inversion asymmetries possess hidden spin polarization, which remains challenging to be converted into spin currents because the global inversion symmetry is still conserved. This study demonstrates the spin-polarized DC circular photocurrents (CPC) in centrosymmetric transition metal dichalcogenides (TMDCs) at normal incidence without applying electric bias. The global inversion symmetry is broken by using a spatially-varying circularly polarized light beam, which could generate spin gradient owing to the hidden spin polarization. The dependences of the CPC on electrode configuration, illumination position, and beam spot size indicate an emergence of circulating electric current under spatially inhomogeneous light, which is associated with the deflection of spin-polarized current through the inverse spin Hall effect (ISHE). The CPC is subsequently utilized to probe the spin polarization and ISHE under different excitation wavelengths and temperatures. The results of this study demonstrate the feasibility of using centrosymmetric materials with hidden spin polarization and non-vanishing Berry curvature for spintronic device applications. △ Less

Submitted 20 May, 2024; v1 submitted 19 April, 2024; originally announced April 2024.

Visualizing orbital angular momentum induced single wavefront dislocation in graphene

Authors: Yi-Wen Liu, Yu-Chen Zhuang, Ya-Ning Ren, Chao Yan, Xiao-Feng Zhou, Qian Yang, Qing-Feng Sun, Lin He

Abstract: Phase singularities are phase-indeterminate points where wave amplitudes are zero, which manifest as phase vertices or wavefront dislocations. In the realm of optical and electron beams, the phase singularity has been extensively explored, demonstrating a profound connection to orbital angular momentum. Direct local imaging of the impact of orbital angular momentum on phase singularities at the na… ▽ More Phase singularities are phase-indeterminate points where wave amplitudes are zero, which manifest as phase vertices or wavefront dislocations. In the realm of optical and electron beams, the phase singularity has been extensively explored, demonstrating a profound connection to orbital angular momentum. Direct local imaging of the impact of orbital angular momentum on phase singularities at the nanoscale, however, remains a challenge and has yet to be achieved. Here, we study the role of orbital angular momentum in phase singularities in graphene, particularly at the atomic level, through scanning tunneling microscopy and spectroscopy. Our experiments demonstrate that the scatterings between different orbital angular momentum states, which are induced by local rotational symmetry-breaking potentials, can generate additional phase singularity, and result in robust single wavefront dislocation in real space. Our results pave the way for exploring the effects of orbital degree of freedom on quantum phases in quasiparticle interference processes. △ Less

Submitted 28 March, 2024; originally announced March 2024.

Comments: 28 pages, 3 figures, 10 extended figures

Elasticity-Controlled Jamming Criticality in Soft Composite Solids

Authors: Yiqiu Zhao, Haitao Hu, Yulu Huang, Hanqing Liu, Caishan Yan, Chang Xu, Rui Zhang, Yifan Wang, Qin Xu

Abstract: Soft composite solids are made of inclusions dispersed within soft matrices. They are ubiquitous in nature and form the basis of many biological tissues. In the field of materials science, synthetic soft composites are promising candidates for building various engineering devices due to their highly programmable features. However, when the volume fraction of the inclusions increases, predicting th… ▽ More Soft composite solids are made of inclusions dispersed within soft matrices. They are ubiquitous in nature and form the basis of many biological tissues. In the field of materials science, synthetic soft composites are promising candidates for building various engineering devices due to their highly programmable features. However, when the volume fraction of the inclusions increases, predicting the mechanical properties of these materials poses a significant challenge for the classical theories of composite mechanics. The difficulty arises from the inherently disordered, multi-scale interactions between the inclusions and the matrix. To address this challenge, we systematically investigated the mechanics of densely filled soft elastomers containing stiff microspheres. We experimentally demonstrated how the strain-stiffening response of the soft composites is governed by the critical scalings in the vicinity of a shear-jamming transition of the included particles. The proposed criticality framework quantitatively connects the overall mechanics of a soft composite with the elasticity of the matrix and the particles, and captures the diverse mechanical responses observed across a wide range of material parameters. The findings uncover a novel design paradigm of composite mechanics that relies on engineering the jamming properties of the embedded inclusions. △ Less

Submitted 13 June, 2024; v1 submitted 4 August, 2023; originally announced August 2023.

Report number: LA-UR-23-28837

Journal ref: Nat Commun 15, 1691 (2024)

Thickness-dependent magnetic properties in Pt[CoNi]n multilayers with perpendicular magnetic anisotropy

Authors: Chunjie Yan, Lina Chen, Kaiyuan Zhou, Liupeng Yang, Qingwei Fu, Wenqiang Wang, Wen-Cheng Yue, Like Liang, Zui Tao, Jun Du, Yong-Lei Wang, Ronghua Liu

Abstract: We systematically investigated the Ni and Co thickness-dependent perpendicular magnetic anisotropy (PMA) coefficient, magnetic domain structures, and magnetization dynamics of Pt(5 nm)/[Co(t_Co nm)/Ni(t_Ni nm)]5/Pt(1 nm) multilayers by combining the four standard magnetic characterization techniques. The magnetic-related hysteresis loops obtained from the field-dependent magnetization M and anomal… ▽ More We systematically investigated the Ni and Co thickness-dependent perpendicular magnetic anisotropy (PMA) coefficient, magnetic domain structures, and magnetization dynamics of Pt(5 nm)/[Co(t_Co nm)/Ni(t_Ni nm)]5/Pt(1 nm) multilayers by combining the four standard magnetic characterization techniques. The magnetic-related hysteresis loops obtained from the field-dependent magnetization M and anomalous Hall resistivity (AHR) \r{ho}_xy found that the two serial multilayers with t_Co = 0.2 and 0.3 nm have the optimum PMA coefficient K_U well as the highest coercivity H_C at the Ni thickness t_Ni = 0.6 nm. Additionally, the magnetic domain structures obtained by Magneto-optic Kerr effect (MOKE) microscopy also significantly depend on the thickness and K_U of the films. Furthermore, the thickness-dependent linewidth of ferromagnetic resonance is inversely proportional to K_U and H_C, indicating that inhomogeneous magnetic properties dominate the linewidth. However, the intrinsic Gilbert damping constant determined by a linear fitting of frequency-dependent linewidth does not depend on Ni thickness and K_U. Our results could help promote the PMA [Co/Ni] multilayer applications in various spintronic and spin-orbitronic devices. △ Less

Submitted 18 April, 2023; originally announced April 2023.

Comments: 17 pages, 4 figures

Journal ref: Chinese Phys. B 32 (2023) 017503

Efficient characteristics of exchange coupling and spin-flop transition in Py/Gd bilayer using anisotropic magnetoresistance

Authors: Kaiyuan Zhou, Xiang Zhan, Zishuang Li, Haotian Li, Chunjie Yan, Lina Chen, Ronghua Liu

Abstract: The interlayer antiferromagnetic coupling rare-earth/transition-metal bilayer ferrimagnet systems have attracted much attention because they present variously unusual temperature-and field-dependent nontrivial magnetic states and dynamics. These properties and the implementation of their applications in spintronics highly depend on the significant temperature dependence of the magnetic exchange st… ▽ More The interlayer antiferromagnetic coupling rare-earth/transition-metal bilayer ferrimagnet systems have attracted much attention because they present variously unusual temperature-and field-dependent nontrivial magnetic states and dynamics. These properties and the implementation of their applications in spintronics highly depend on the significant temperature dependence of the magnetic exchange stiffness constant A. Here, we quantitatively determine the temperature dependence of magnetic exchange stiffness A_{Py-Gd} and A_{Gd} in the artificially layered ferrimagnet consisting of a Py/Gd bilayer, using a measurement of anisotropic magnetoresistance (AMR) of the bilayer thin film at different temperatures and magnetic fields. The obtained temperature dependence of A_{Py-Gd} and A_{Gd} exhibit a scaling power law with the magnetization of Gd. The critical field of spin-flop transition and its temperature dependence can also be directly obtained by this method. Additionally, the experimental results are well reproduced by micromagnetic simulations with the obtained parameters A_{Py-Gd} and A_{Gd}, which further confirms the reliability of this easily accessible technique. △ Less

Submitted 18 April, 2023; originally announced April 2023.

Comments: 5 pages, 4 figures

Journal ref: Applied Physics Letters 122 (2023) 102403

Exploring the interfacial coupling between graphene and the antiferromagnetic insulator MnPSe$_3$

Authors: Xin Yi, Qiao Chen, Kexin Wang, Yuanyang Yu, Yi Yan, Xin Jiang, Chengyu Yan, Shun Wang

Abstract: Interfacial coupling between graphene and other 2D materials can give rise to intriguing physical phenomena. In particular, several theoretical studies predict that the interplay between graphene and an antiferromagnetic insulator could lead to the emergence of quantum anomalous Hall phases. However, such phases have not been observed experimentally yet, and further experimental studies are needed… ▽ More Interfacial coupling between graphene and other 2D materials can give rise to intriguing physical phenomena. In particular, several theoretical studies predict that the interplay between graphene and an antiferromagnetic insulator could lead to the emergence of quantum anomalous Hall phases. However, such phases have not been observed experimentally yet, and further experimental studies are needed to reveal the interaction between graphene and antiferromagnetic insulators. Here, we report the study in heterostructures composed of graphene and the antiferromagnetic insulator MnPSe$_3$. It is found that the MnPSe$_3$ has little impact on the quantum Hall phases apart from doping graphene via interfacial charge transfer. However, the magnetic order can contribute indirectly via process like Kondo effect, as evidenced by the observed minimum in the temperature-resistance curve between 20-40 K, far below the Néel temperature (70 K). △ Less

Submitted 2 June, 2023; v1 submitted 12 April, 2023; originally announced April 2023.

Highly anisotropic optical conductivities in two-dimensional tilted semi-Dirac bands

Authors: Chang-Xu Yan, Chao-Yang Tan, Hong Guo, Hao-Ran Chang

Abstract: Within linear response theory, the absorptive part of highly anisotropic optical conductivities are analytically calculated for distinct tilts in two-dimensional (2D) tilted semi-Dirac bands (SDBs). The transverse optical conductivities always vanish. The interband longitudinal optical conductivities (LOCs) in 2D tilted SDBs differ qualitatively in the power-law scaling of $ω$ as… ▽ More Within linear response theory, the absorptive part of highly anisotropic optical conductivities are analytically calculated for distinct tilts in two-dimensional (2D) tilted semi-Dirac bands (SDBs). The transverse optical conductivities always vanish. The interband longitudinal optical conductivities (LOCs) in 2D tilted SDBs differ qualitatively in the power-law scaling of $ω$ as $\mathrm{Re}σ_{\perp}^{\mathrm{IB}}(ω)\proptoσ_0\sqrtω$ and $\mathrm{Re}σ_{\parallel}^{\mathrm{IB}}(ω)\proptoσ_0/\sqrtω$. By contrast, the intraband LOCs in 2D tilted SDBs depend on $μ$ in the power-law scaling as $\mathrm{Re}σ_{\perp}^{\mathrm{D}}(ω)\proptoσ_0μ\sqrtμ$ and $\mathrm{Re}σ_{\parallel}^{\mathrm{D}}(ω)\proptoσ_0μ/\sqrtμ$. The tilt-dependent behaviors of LOCs could qualitatively characterize distinct impact of band tilting in 2D tilted SDBs. In particular, for arbitrary tilt $t$ satisfying $0<t\le 2$, the interband LOCs always possess a robust fixed point at $ω=2μ$. The power-law scalings and tilt-dependent behaviors further dictate significant differences in the asymptotic background values and angular dependence of LOCs. Our theoretical predictions should be valid for a broad class of 2D tilted SDB materials, and can also be used to fingerprint 2D tilted SDB from 2D untilted SDB as well as tilted Dirac bands. △ Less

Submitted 23 November, 2023; v1 submitted 31 March, 2023; originally announced March 2023.

Comments: 19 pages, 5 figures

Journal ref: Phys. Rev. B 108, 195427 (2023)

A composite electrodynamic mechanism to reconcile spatiotemporally resolved exciton transport in quantum dot superlattices

Authors: Rongfeng Yuan, Trevor D. Roberts, Rafaela M. Brinn, Alexander A. Choi, Ha H. Park, Chang Yan, Justin C. Ondry, Siamak Khorasani, David J. Masiello, Ke Xu, A. Paul Alivisatos, Naomi S. Ginsberg

Abstract: Quantum dot (QD) solids are promising optoelectronic materials; further advancing their device functionality depends on understanding their energy transport mechanisms. The commonly invoked near-field Förster resonance energy transfer (FRET) theory often underestimates the exciton hopping rate in QD solids, yet no consensus exists on the underlying cause. In response, we use time-resolved ultrafas… ▽ More Quantum dot (QD) solids are promising optoelectronic materials; further advancing their device functionality depends on understanding their energy transport mechanisms. The commonly invoked near-field Förster resonance energy transfer (FRET) theory often underestimates the exciton hopping rate in QD solids, yet no consensus exists on the underlying cause. In response, we use time-resolved ultrafast stimulated emission depletion (TRUSTED) microscopy, an ultrafast transformation of stimulated emission depletion (STED) microscopy to spatiotemporally resolve exciton diffusion in tellurium-doped CdSe-core/CdS-shell QD superlattices. We measure the concomitant time-resolved exciton energy decay due to excitons sampling a heterogeneous energetic landscape within the superlattice. The heterogeneity is quantified by single-particle emission spectroscopy. This powerful multimodal set of observables provides sufficient constraints on a kinetic Monte Carlo simulation of exciton transport to elucidate a composite transport mechanism that includes both near-field FRET and previously-neglected far-field emission/reabsorption contributions. Uncovering this mechanism offers a much-needed unified framework in which to characterize transport in QD solids and additional principles for device design. △ Less

Submitted 24 September, 2023; v1 submitted 21 February, 2023; originally announced February 2023.

Comments: 48 pages, including supplement

Journal ref: Science Advances, Vol 9, Issue 42, eadh241 (2023)

Breakdown of self-cleaning mechanism for nanoscale interfacial substances in tiny-angle twisted bilayer graphene

Authors: Chao Yan, Ya-Xin Zhao, Yi-Wen Liu, Lin He

Abstract: Realization of high-quality van der Waals (vdW) heterostructures with tailored properties by stacking two-dimensional (2D) layers requires atomically clean interfaces. Because of strong adhesion between the constituent layers, the vdW forces could drive trapped contaminants together into submicron-size bubbles, which leaves large interfacial areas atomically clean. Such a phenomenon is dubbed self… ▽ More Realization of high-quality van der Waals (vdW) heterostructures with tailored properties by stacking two-dimensional (2D) layers requires atomically clean interfaces. Because of strong adhesion between the constituent layers, the vdW forces could drive trapped contaminants together into submicron-size bubbles, which leaves large interfacial areas atomically clean. Such a phenomenon is dubbed self-cleaning mechanism in 2D systems. Here, we demonstrate the breakdown of self-cleaning mechanism for nanoscale interfacial bubbles in tiny-angle twisted bilayer graphene (TBG). In the tiny-angle TBG, there is a triangular network of domain boundaries due to structural reconstruction. Our experiments indicate that the bubbles will mainly move along the triangular network of domain boundaries when the sizes of the bubbles are comparable to that of an AA-stacking region in the TBG. When the size of the bubble is smaller than that of an AA-stacking region, the bubble becomes motionless and is fixed in the AA-stacking region because of its large out-of-plane corrugation. Our results reveal a substantial influence of the moiré superlattice on the motion of nanoscale interfacial substances. △ Less

Submitted 11 February, 2023; originally announced February 2023.

Comments: 4 figures in main text

Layer-by-layer disentanglement of Bloch states via frequency-domain photoemission

Authors: Woojoo Lee, Sebastian Fernandez-Mulligan, Hengxin Tan, Chenhui Yan, Yingdong Guan, Seng Huat Lee, Ruobing Mei, Chaoxing Liu, Binghai Yan, Zhiqiang Mao, Shuolong Yang

Abstract: Layer-by-layer material engineering has enabled exotic quantum phenomena such as interfacial superconductivity and the quantum anomalous Hall effect. Meanwhile, deciphering electronic states layer-by-layer remains a fundamental scientific challenge. This is exemplified by the difficulty in understanding the layer origins of topological electronic states in magnetic topological insulators, which is… ▽ More Layer-by-layer material engineering has enabled exotic quantum phenomena such as interfacial superconductivity and the quantum anomalous Hall effect. Meanwhile, deciphering electronic states layer-by-layer remains a fundamental scientific challenge. This is exemplified by the difficulty in understanding the layer origins of topological electronic states in magnetic topological insulators, which is key to understanding and controlling topological quantum phases. Here, we report a layer-encoded frequency-domain ARPES experiment on a magnetic topological insulator (MnBi2Te4)(Bi2Te3) to characterize the layer origins of electronic states. Infrared laser excitations launch coherent lattice vibrations with the layer index encoded by the vibration frequency; photoemission spectroscopy tracks the electron dynamics, where the layer information is decoded in the frequency domain. This layer-frequency correspondence reveals a surprising wavefunction relocation of the topological surface state from the top magnetic layer into the buried second layer, reconciling the controversy over the vanishing broken-symmetry energy gap in (MnBi2Te4)(Bi2Te3) and its related compounds. The layer-frequency correspondence can be harnessed to disentangle electronic states layer-by-layer in a broad class of van der Waals superlattices. △ Less

Submitted 3 January, 2023; originally announced January 2023.

Nanoindentation creep of supercrystalline nanocomposites

Authors: Cong Yan, Büsra Bor, Alexander Plunkett, Berta Domènech, Verena Maier-Kiener, Diletta Giuntini

Abstract: Supercrystalline nanocomposites (SCNCs) are inorganic-organic hybrid materials with a unique periodic nanostructure, and as such they have been gaining growing attention for their intriguing functional properties and parallelisms with hierarchical biomaterials. Their mechanical behavior remains, however, poorly understood, even though its understanding and control are of paramount importance to al… ▽ More Supercrystalline nanocomposites (SCNCs) are inorganic-organic hybrid materials with a unique periodic nanostructure, and as such they have been gaining growing attention for their intriguing functional properties and parallelisms with hierarchical biomaterials. Their mechanical behavior remains, however, poorly understood, even though its understanding and control are of paramount importance to allow SCNCs implementation into devices. An important aspect that has not been tackled yet is their time-dependent deformation behavior, which is nevertheless expected to play an important role in materials containing such a distribution of organic phase. Hereby, we report on the creep of ceramic-organic SCNCs with varying degrees of organic crosslinking, as assessed via nanoindentation. Creep strains and their partial recoverability are observed, hinting at the co-presence of viscoelasticity and viscoplasticity, and a clear effect of crosslinking in decreasing the overall material deformability. We rationalize our experimental observations with the analysis of stress exponent and activation volume, resulting in a power-law breakdown behavior and governing deformation mechanisms occurring at the organic sub-nm interfaces scale, in terms of organic ligands rearrangement. The set of results is reinforced by the evaluation of the strain rate sensitivity via strain rate jump tests, and the assessment of the effect of oscillations during continuous stiffness measurement mode. △ Less

Submitted 22 December, 2022; v1 submitted 20 December, 2022; originally announced December 2022.

Vortex-driven periodic and aperiodic magnetoresistance oscillations in cuprates

Authors: Changshuai Lan, Chuanwen Zhao, Xin Yi, Qiao Chen, Xinming Zhao, Dong Wu, Chengyu Yan, Shun Wang

Abstract: The study of the interaction between superconductivity and charge ordering is helpful to resolve the pairing mechanism in high-temperature superconductors. Recently, several resistance oscillations studies trigger the speculation that a long-range charge ordering, with an enormous mesh size of several tens of nanometer, can possibly emerge in underdoped high Tc superconductor. However, spectroscop… ▽ More The study of the interaction between superconductivity and charge ordering is helpful to resolve the pairing mechanism in high-temperature superconductors. Recently, several resistance oscillations studies trigger the speculation that a long-range charge ordering, with an enormous mesh size of several tens of nanometer, can possibly emerge in underdoped high Tc superconductor. However, spectroscopy studies have not traced this kind of long-range charge ordering. Here, we clarify the disagreement between the transport and spectroscopy studies on the mysterious long-range charge ordering by investigating the magneto-oscillations in underdoped Bi2Sr2CaCu2O8+δ flakes. Inspired by the observation that the oscillations evolve from a periodic to an aperiodic one with decreasing doping level, we conclude that the magneto-oscillations can be generated by the interaction between vortices and superconducting loops that enclose randomly distributed underdoped puddles while an assumption of long-range charge ordering is not necessary. △ Less

Submitted 7 December, 2022; originally announced December 2022.

Journal ref: PhysRevB.109.115133 (2024)

Competing multiferroic phases in monolayer and few-layer NiI$_{2}$

Authors: Nanshu Liu, Cong Wang, Changlin Yan, Changsong Xu, Jun Hu, Yanning Zhang, Wei Ji

Abstract: A recent experiment reported type-II multiferroicity in monolayer (ML) NiI$_{2}$ based on a presumed spiral magnetic configuration (Spiral-B), which is, as we found here, under debate in the ML limit. Freestanding ML NiI$_{2}$ breaks its C$_{3}$ symmetry, as it prefers a striped antiferromagnetic order (AABB-AFM) along with an intralayer antiferroelectric (AFE) order. However, substrate confinemen… ▽ More A recent experiment reported type-II multiferroicity in monolayer (ML) NiI$_{2}$ based on a presumed spiral magnetic configuration (Spiral-B), which is, as we found here, under debate in the ML limit. Freestanding ML NiI$_{2}$ breaks its C$_{3}$ symmetry, as it prefers a striped antiferromagnetic order (AABB-AFM) along with an intralayer antiferroelectric (AFE) order. However, substrate confinement may preserve the C$_{3}$ symmetry and/or apply tensile strain to the ML. This leads to another spiral magnetic order (Spiral-$IV^X$), while 2L shows a different order (Spiral-$V^Y$) and Spiral-B dominates in thicker layers. Thus, three multiferroic phases, namely, Spiral-B+FE, Spiral-$IV^X$ +FE, Spiral-$V^Y$+FE, and an anti-multiferroic AABB-AFM+AFE one, show layer-thickness-dependent and geometry-dependent dominance, ascribed to competitions among thickness-dependent Kitaev, biquadratic, and Heisenberg spin-exchange interactions and single-ion magnetic anisotropy. Our theoretical results clarify the debate on the multiferroicity of ML NiI$_{2}$ and shed light on the role of layer-stacking-induced changes in noncollinear spin-exchange interactions and magnetic anisotropy in thickness-dependent magnetism. △ Less

Submitted 3 June, 2024; v1 submitted 25 November, 2022; originally announced November 2022.

Comments: 48 pages, 21 figures

Journal ref: Physical Review B 109, 195422 (2024)

Anomalous acoustic plasmons in two-dimensional over-tilted Dirac bands

Authors: Chang-Xu Yan, Furu Zhang, Chao-Yang Tan, Hao-Ran Chang, Jianhui Zhou, Yugui Yao

Abstract: The over-tilting of Dirac cones has led to various fascinating quantum phenomena. Here we find that two anomalous acoustic plasmons (AAPs) are dictated by the distinct geometry of two-dimensional (2D) type-II Dirac cones, far beyond the conventional $\sqrt{q}$ plasmon. One AAP originates from the strong hybridization of two pockets with large velocity anisotropy at one Dirac point, whereas the oth… ▽ More The over-tilting of Dirac cones has led to various fascinating quantum phenomena. Here we find that two anomalous acoustic plasmons (AAPs) are dictated by the distinct geometry of two-dimensional (2D) type-II Dirac cones, far beyond the conventional $\sqrt{q}$ plasmon. One AAP originates from the strong hybridization of two pockets with large velocity anisotropy at one Dirac point, whereas the other is attributed to the significant enhancement of the band correlation around the open Fermi surface. Remarkably, the plasmons exhibit valley-dependent chirality along the tilting direction due to the chiral electron dispersion. Meanwhile, we discuss the tunability of plasmon dispersion and lifetime by tuning the gap and dielectric substrate. Our work provides a promising way to generate the novel plasmons in Dirac materials. △ Less

Submitted 7 April, 2026; v1 submitted 21 November, 2022; originally announced November 2022.

Comments: 5 pages main text with 5 figures, 7 supplemental materials with 5 figures, references added

Journal ref: Chinese Physics Letters. 43, 040707 (2026)

Josephson Effect in NbS$_{2}$ van der Waals Junctions

Authors: Chuanwen Zhao, Xin Yi, Qiao Chen, Chengyu Yan, Shun Wang

Abstract: Van der Waals (vdW) Josephson junctions can possibly accelerate the development of advanced superconducting device that utilizes the unique properties of two-dimensional (2D) transition metal dichalcogenide (TMD) superconductors such as spin-orbit coupling, spin-valley locking. Here, we fabricate vertically stacked NbS$_{2}$/NbS$_{2}$ Josephson junctions using a modified all-dry transfer technique… ▽ More Van der Waals (vdW) Josephson junctions can possibly accelerate the development of advanced superconducting device that utilizes the unique properties of two-dimensional (2D) transition metal dichalcogenide (TMD) superconductors such as spin-orbit coupling, spin-valley locking. Here, we fabricate vertically stacked NbS$_{2}$/NbS$_{2}$ Josephson junctions using a modified all-dry transfer technique and characterize the device performance via systematic low-temperature transport measurements. The experimental results show that the superconducting transition temperature of the NbS$_{2}$/NbS$_{2}$ Josephson junction is 5.84 K, and the critical current density reaches 3975 A/cm$^{2}$ at 2K. Moreover, we extract a superconducting energy gap $Δ=0.58$ meV, which is considerably smaller than that expected from the single band s-wave Bardeen-Cooper-Schrieffer (BCS) model ($Δ=0.89$ meV). △ Less

Submitted 3 November, 2022; originally announced November 2022.

Effects of spatial dimensionality and band tilting on the longitudinal optical conductivities in Dirac bands

Authors: Jian-Tong Hou, Chang-Xu Yan, Chao-Yang Tan, Zhi-Qiang Li, Peng Wang, Hong Guo, Hao-Ran Chang

Abstract: We report a unified theory based on linear response, for analyzing the longitudinal optical conductivity (LOC) of materials with tilted Dirac cones. Depending on the tilt parameter $t$, the Dirac electrons have four phases: untilted, type-I, type-II, and type-III; the Dirac dispersion can be isotropic or anisotropic; the spatial dimension of the material can be one-, two-, or three-dimensions (1D,… ▽ More We report a unified theory based on linear response, for analyzing the longitudinal optical conductivity (LOC) of materials with tilted Dirac cones. Depending on the tilt parameter $t$, the Dirac electrons have four phases: untilted, type-I, type-II, and type-III; the Dirac dispersion can be isotropic or anisotropic; the spatial dimension of the material can be one-, two-, or three-dimensions (1D, 2D and 3D). The interband LOCs and intraband LOCs in $d$ dimension (with $d\ge2$) are found to scale as $σ_{0}ω^{d-2}$ and $σ_{0}μ^{d-1}δ(ω)$, respectively, where $ω$ is the frequency and $μ$ the chemical potential. The interband LOC vanishes in 1D due to lack of extra spatial dimension. In contrast, the interband LOCs in 2D and 3D are nonvanishing and share many similar properties. A universal and robust fixed point of interband LOCs appears at $ω=2μ$ no matter $d=2$ or $d=3$, which can be intuitively understood by the geometric structures of Fermi surface and energy resonance contour. The intraband LOCs and the carrier density for 2D and 3D tilted Dirac bands are both closely related to the geometric structure of Fermi surface and the cutoff of integration. The angular dependence of LOCs is found to characterize both spatial dimensionality and band tilting and the constant asymptotic background values of LOC reflect features of Dirac bands. The LOCs in the anisotropic tilted Dirac cone can be connected to its isotropic counterpart by a ratio that consists of Fermi velocities for both 2D and 3D. Most of the findings are universal for tilted Dirac materials and hence valid for a great many Dirac materials in the spatial dimensions of physical interest. △ Less

Submitted 24 November, 2023; v1 submitted 19 October, 2022; originally announced October 2022.

Comments: 22 pages, 7 figures

Journal ref: Phys. Rev. B 108, 035407 (2023)

Coexistence of Reconstructed and Unreconstructed Structures in Structural Transition Regime of Twisted Bilayer Graphene

Authors: Xiao-Feng Zhou, Yi-Wen Liu, Chen-Yue Hao, Chao Yan, Qi Zheng, Ya-Ning Ren, Ya-Xin Zhao, Kenji Watanabe, Takashi Taniguchi, Lin He

Abstract: In twisted bilayer graphene (TBG), a twist-angle-dependent competition between interlayer stacking energy and intralayer elastic energy results in flat rigid layers at large twist angles and lattice reconstruction at small twist angles. Despite enormous scientific interest and effort in the TBG, however, an experimental study of evolution from the rigid lattice to the reconstructed lattice as a fu… ▽ More In twisted bilayer graphene (TBG), a twist-angle-dependent competition between interlayer stacking energy and intralayer elastic energy results in flat rigid layers at large twist angles and lattice reconstruction at small twist angles. Despite enormous scientific interest and effort in the TBG, however, an experimental study of evolution from the rigid lattice to the reconstructed lattice as a function of twist angle is still missing. Here we present a scanning tunneling microscopy and spectroscopy study to reveal the twist-angle-dependent lattice reconstruction in the TBG. Our experiment demonstrates that there is a transition regime between the rigid regime and the relaxed regime and, unexpectedly, the reconstructed and unreconstructed structures coexist in the transition regime. The coexistence of the two distinct structures in this regime may arise from subtle balance between the interlayer stacking energy and intralayer elastic energy in the TBG with intermediate moiré sizes. △ Less

Submitted 29 September, 2022; originally announced September 2022.

Comments: 4 Figures in main text

Enhancement of spin-orbit torque efficiency by tailoring interfacial spin-orbit coupling in Pt-based magnetic multilayers

Authors: Wenqiang Wang, Kaiyuan Zhou, Xiang Zhan, Zui Tao, Qingwei Fu, Like Liang, Zishuang Li, Lina Chen, Chunjie Yan, Haotian Li, Tiejun Zhou, Ronghua Liu

Abstract: We study inserting Co layer thickness-dependent spin transport and spin-orbit torques (SOTs) in the Pt/Co/Py trilayers by spin-torque ferromagnetic resonance. The interfacial perpendicular magnetic anisotropy energy density ($K_s = 2.7~erg/cm^2$), which is dominated by interfacial spin-orbit coupling (ISOC) in the Pt/Co interface, total effective spin-mixing conductance (… ▽ More We study inserting Co layer thickness-dependent spin transport and spin-orbit torques (SOTs) in the Pt/Co/Py trilayers by spin-torque ferromagnetic resonance. The interfacial perpendicular magnetic anisotropy energy density ($K_s = 2.7~erg/cm^2$), which is dominated by interfacial spin-orbit coupling (ISOC) in the Pt/Co interface, total effective spin-mixing conductance ($G_{eff,tot} = 0.42 {\times} 10^{15}~Ω^{-1} m^{-2}$) and two-magnon scattering ($β_{TMS} = 0.46~nm^2$) are first characterized, and the damping-like torque ($ξ_{DL}$ = 0.103) and field-like torque ($ξ_{FL}$ = -0.017) efficiencies are also calculated quantitatively by varying the thickness of the inserting Co layer. The significant enhancement of $ξ_{DL}$ and $ξ_{FL}$ in Pt/Co/Py than Pt/Py bilayer system originates from the interfacial Rashba-Edelstein effect due to the strong ISOC between Co-3d and Pt-5d orbitals at the Pt/Co interface. Additionally, we find a considerable out-of-plane spin polarization SOT, which is ascribed to the spin anomalous Hall effect and possible spin precession effect due to IPMA-induced perpendicular magnetization at the Pt/Co interface. Our results demonstrate that the ISOC of the Pt/Co interface plays a vital role in spin transport and SOTs-generation. Our finds offer an alternative approach to improve the conventional SOTs efficiencies and generate unconventional SOTs with out-of-plane spin polarization to develop low power Pt-based spintronic via tailoring the Pt/FM interface. △ Less

Submitted 6 September, 2022; originally announced September 2022.

Comments: 17 pages, 4 figures

Journal ref: Chin. Phys. B 31, 097504 (2022)

Molecular Collapse States in Elliptical Graphene/WSe2 Heterostructure Quantum Dots

Authors: Qi Zheng, Yu-Chen Zhuang, Ya-Ning Ren, Chao Yan, Qing-Feng Sun, Lin He

Abstract: In relativistic physics, both atomic collapse in heavy nucleus and Hawking radiation in black hole are predicted to occur through Klein tunneling process that couples particles and antiparticles. Recently, atomic collapse states (ACSs) were explicitly realized in graphene because of its relativistic Dirac excitation with large fine structure constant. However, essential role of the Klein tunneling… ▽ More In relativistic physics, both atomic collapse in heavy nucleus and Hawking radiation in black hole are predicted to occur through Klein tunneling process that couples particles and antiparticles. Recently, atomic collapse states (ACSs) were explicitly realized in graphene because of its relativistic Dirac excitation with large fine structure constant. However, essential role of the Klein tunneling on the ACSs remains elusive in experiment. Here we systematically study the quasibound states in elliptical graphene quantum dots (GQDs). Bonding and antibonding molecular collapse states formed by two coupled ACSs are observed in the elliptical GQDs. Our experiments, supported by theoretical calculations, indicate that the antibonding state of the ACSs will change into a Klein-tunneling-induced quasibound state, revealing deep connection between the ACSs and the Klein tunneling. △ Less

Submitted 14 June, 2022; originally announced June 2022.

Comments: 3 figures in main text

Journal ref: Phys. Rev. Lett. 130, 076202 (2023)

Visualization of Chiral Electronic Structure and Anomalous Optical Response in a Material with Chiral Charge Density Waves

Authors: H. F. Yang, K. Y. He, J. Koo, S. W. Shen, S. H. Zhang, G. Liu, Y. Z. Liu, C. Chen, A. J. Liang, K. Huang, M. X. Wang, J. J. Gao, X. Luo, L. X. Yang, J. P. Liu, Y. P. Sun, S. C. Yan, B. H. Yan, Y. L. Chen, X. Xi, Z. K. Liu

Abstract: Chiral materials have attracted significant research interests as they exhibit intriguing physical properties, such as chiral optical response, spin-momentum locking and chiral induced spin selectivity. Recently, layered transition metal dichalcogenide 1T-TaS2 has been found to host a chiral charge density wave (CDW) order. Nevertheless, the physical consequences of the chiral order, for example,… ▽ More Chiral materials have attracted significant research interests as they exhibit intriguing physical properties, such as chiral optical response, spin-momentum locking and chiral induced spin selectivity. Recently, layered transition metal dichalcogenide 1T-TaS2 has been found to host a chiral charge density wave (CDW) order. Nevertheless, the physical consequences of the chiral order, for example, in electronic structures and the optical properties, are yet to be explored. Here, we report the spectroscopic visualization of an emergent chiral electronic band structure in the CDW phase, characterized by windmill-shape Fermi surfaces. We uncover a remarkable chirality-dependent circularly polarized Raman response due to the salient chiral symmetry of CDW, although the ordinary circular dichroism vanishes. Chiral Fermi surfaces and anomalous Raman responses coincide with the CDW transition, proving their lattice origin. Our work paves a path to manipulate the chiral electronic and optical properties in two-dimensional materials and explore applications in polarization optics and spintronics. △ Less

Submitted 19 May, 2022; originally announced May 2022.

Ferromagnetic MnBi4Te7 obtained with low concentration Sb doping: A promising platform for exploring topological quantum states

Authors: Y. D. Guan, C. H. Yan, S. H. Lee, X. Gui, W. Ning, J. L. Ning, Y. L. Zhu, M. Kothakonda, C. Q. Xu, X. L. Ke, J. W. Sun, W. W. Xie, S. L. Yang, Z. Q. Mao

Abstract: The tuning of magnetic phase, chemical potential, and structure is crucial to observe diverse exotic topological quantum states in $MnBi_2Te_4(Bi_2Te_3)_m$ (m = 0, 1, 2, & 3). Here we show a ferromagnetic (FM) phase with a chiral crystal structure in $Mn(Bi_{1-x}Sb_x)_4Te_7$, obtained via tuning the growth conditions and Sb concentration. Unlike previously reported $Mn(Bi_{1-x}Sb_x)_4Te_7$, which… ▽ More The tuning of magnetic phase, chemical potential, and structure is crucial to observe diverse exotic topological quantum states in $MnBi_2Te_4(Bi_2Te_3)_m$ (m = 0, 1, 2, & 3). Here we show a ferromagnetic (FM) phase with a chiral crystal structure in $Mn(Bi_{1-x}Sb_x)_4Te_7$, obtained via tuning the growth conditions and Sb concentration. Unlike previously reported $Mn(Bi_{1-x}Sb_x)_4Te_7$, which exhibits FM transitions only at high Sb doping levels, our samples show FM transitions ($T_C$ = 13.5 K) at 15%-27% doping levels. Furthermore, our single crystal x-ray diffraction structure refinements find Sb doping leads to a chiral structure with the space group of P3, contrasted with the centrosymmetric P-3m1 crystal structure of the parent compound $MnBi_4Te_7$. Through ARPES measurements, we also demonstrated that the non-trivial band topology is preserved in the Sb-doped FM samples. Given that the non-trivial band topology of this system remains robust for low Sb doping levels, our success in making FM $Mn(Bi_{1-x}Sb_x)_4Te_7$ with $x$ = 0.15, 0.175, 0.2 & 0.27 paves the way for realizing the predicted topological quantum states such as axion insulator and Weyl semimetals. Additionally, we also observed magnetic glassy behavior in both antiferromagnetic $MnBi_4Te_7$ and FM $Mn(Bi_{1-x}Sb_x)_4Te_7$ samples, which we believe originates from cluster spin glass phases coexisting with long-range AFM/FM orders. We have also discussed how the antisite Mn ions impact the interlayer magnetic coupling and how FM interlayer coupling is stabilized in this system. △ Less

Submitted 4 May, 2022; originally announced May 2022.

Comments: 37 Pages, 7 Figures and 2 Tables. Supplementary Materials is included

Journal ref: Phys. Rev. Materials 6, 054203 (2022)

Layer-by-layer growth of bilayer graphene single-crystals enabled by self-transmitting catalytic activity

Authors: Zhihong Zhang, Linwei Zhou, Zhaoxi Chen, Antonín Jaroš, Miroslav Kolíbal, Petr Bábor, Quanzhen Zhang, Changlin Yan, Ruixi Qiao, Qing Zhang, Teng Zhang, Wei Wei, Yi Cui, Jingsi Qiao, Liwei Liu, Lihong Bao, Haitao Yang, Zhihai Cheng, Yeliang Wang, Enge Wang, Zhi Liu, Marc Willinger, Hong-Jun Gao, Kaihui Liu, Zhu-Jun Wang , et al. (1 additional authors not shown)

Abstract: Direct growth of large-area vertically stacked two-dimensional (2D) van der Waal (vdW) materials is a prerequisite for their high-end applications in integrated electronics, optoelectronics and photovoltaics. Currently, centimetre- to even metre-scale monolayers of single-crystal graphene (MLG) and hexagonal boron nitride (h-BN) have been achieved by epitaxial growth on various single-crystalline… ▽ More Direct growth of large-area vertically stacked two-dimensional (2D) van der Waal (vdW) materials is a prerequisite for their high-end applications in integrated electronics, optoelectronics and photovoltaics. Currently, centimetre- to even metre-scale monolayers of single-crystal graphene (MLG) and hexagonal boron nitride (h-BN) have been achieved by epitaxial growth on various single-crystalline substrates. However, in principle, this success in monolayer epitaxy seems extremely difficult to be replicated to bi- or few-layer growth, as the full coverage of the first layer was believed to terminate the reactivity of those adopting catalytic metal surfaces. Here, we report an exceptional layer-by-layer chemical vapour deposition (CVD) growth of large size bi-layer graphene single-crystals, enabled by self-transmitting catalytic activity from platinum (Pt) surfaces to the outermost graphene layers. In-situ growth and real-time surveillance experiments, under well-controlled environments, unambiguously verify that the growth does follow the layer-by-layer mode on open surfaces of MLG/Pt(111). First-principles calculations indicate that the transmittal of catalytic activity is allowed by an appreciable electronic hybridisation between graphene overlayers and Pt surfaces, enabling catalytic dissociation of hydrocarbons and subsequently direct graphitisation of their radicals on the outermost sp2 carbon surface. This self-transmitting catalytic activity is also proven to be robust for tube-furnace CVD in fabricating single-crystalline graphene bi-, tri- and tetra-layers, as well as h-BN few-layers. Our findings offer an exceptional strategy for potential controllable, layer-by-layer and wafer-scale growth of vertically stacked few-layered 2D single crystals. △ Less

Submitted 3 May, 2022; originally announced May 2022.

Comments: 5 figures and 9 extended figures

Evolution of phase transition in the finite-fugacity extended dimer model

Authors: Yao Hongxu, Li Jiaze, Hou Jintao, Lou Jie, Chen Yan

Abstract: We investigate the evolution of phase transition of the classical fully compact dimer model on the bipartite square lattice with second nearest bonds at finite temperatures. We use the numeric Monte Carlo method with the directed-loop algorithm to simulate the model. Our results show that the order of the phase transition depends on the fugacity of the second nearest bonds. We find that the phase… ▽ More We investigate the evolution of phase transition of the classical fully compact dimer model on the bipartite square lattice with second nearest bonds at finite temperatures. We use the numeric Monte Carlo method with the directed-loop algorithm to simulate the model. Our results show that the order of the phase transition depends on the fugacity of the second nearest bonds. We find that the phase transition reduces from the Kosterlitz-Thouless transition to unconventional high-order phase transitions which feature the coexistence of properties Kosterliz-Thouless transition and the first-order phases transition simultaneously. As the fugacity increases further, phase transition evolves to the first-order phase transition. In addition, our results of dimer-dimer correlation functions and their corresponding structure factor functions computed by us show the evolution of decay correlation for different fugacity. △ Less

Submitted 24 April, 2022; originally announced April 2022.

Crosscap Contribution to Late-Time Two-Point Correlators

Authors: Cynthia Yan

Abstract: We show that in Jackiw-Teitelboim (JT) gravity, late-time two-point functions can get a leading non-decaying contribution from a spacetime with the topology of a Mobius strip (a disk with one crosscap). There is an interesting interplay between this contribution and the standard "plateau". The two can add together or cancel, depending on topological weighting factors. We match this behavior to Ran… ▽ More We show that in Jackiw-Teitelboim (JT) gravity, late-time two-point functions can get a leading non-decaying contribution from a spacetime with the topology of a Mobius strip (a disk with one crosscap). There is an interesting interplay between this contribution and the standard "plateau". The two can add together or cancel, depending on topological weighting factors. We match this behavior to Random Matrix Theory (RMT) and the N mod 8 periodicity of Sachdev-Kitaev-Ye (SYK) results. △ Less

Submitted 27 March, 2022; originally announced March 2022.

Comments: 39 pages + appendices

Realizing One-dimensional Metallic States in Graphene via Periodically Coupled Zeroth Pseudo-Landau Levels

Authors: Yi-Wen Liu, Zhen Zhan, Zewen Wu, Chao Yan, Shengjun Yuan, Lin He

Abstract: Strain-induced pseudo-magnetic fields can mimic real magnetic fields to generate a zero-magnetic-field analogue of the Landau levels (LLs), i.e., the pseudo-LLs, in graphene. The distinct nature of the pseudo-LLs enables one to realize novel electronic states beyond that can be feasible with real LLs. Here, we report the realization of one-dimensional (1D) metallic states, which can be described w… ▽ More Strain-induced pseudo-magnetic fields can mimic real magnetic fields to generate a zero-magnetic-field analogue of the Landau levels (LLs), i.e., the pseudo-LLs, in graphene. The distinct nature of the pseudo-LLs enables one to realize novel electronic states beyond that can be feasible with real LLs. Here, we report the realization of one-dimensional (1D) metallic states, which can be described well by the Su-Schrieffer-Heeger model, in graphene via periodically coupled zeroth pseudo-LLs. In our experiment, nanoscale strained structures embedded with pseudo-LLs are generated periodically along 1D channel of suspended graphene monolayer. Our experiments demonstrate that the zeroth pseudo-LLs of these strained structures are coupled to form metallic states, exhibiting a serpentine pattern that snakes back and forth along the 1D suspended graphene monolayer. These results are verified theoretically by large-scale tight-binding calculations of the strained samples. Our result provides a new pathway to realize novel quantum states and engineer the electronic properties of graphene by using the localized pseudo-LLs as building blocks. △ Less

Submitted 21 December, 2021; originally announced December 2021.

Direct Imaging Strain-field Vortex Networks in Twisted Bilayer Graphene Magnified by Moiré Superlattices

Authors: Ya-Ning Ren, Yi-Wen Liu, Chao Yan, Lin He

Abstract: In two-dimensional (2D) twisted bilayers, the van der Waals (vdW) interlayer interaction introduces atomic-scale reconstruction at interface by locally rotating lattice to form strain-field vortex networks in their moiré superlattice. However, direct imaging the tiny local lattice rotation of the strain-field vortex requires extremely high spatial resolution and is an outstanding challenge in expe… ▽ More In two-dimensional (2D) twisted bilayers, the van der Waals (vdW) interlayer interaction introduces atomic-scale reconstruction at interface by locally rotating lattice to form strain-field vortex networks in their moiré superlattice. However, direct imaging the tiny local lattice rotation of the strain-field vortex requires extremely high spatial resolution and is an outstanding challenge in experiment. Here, a topmost small-period graphene moiré pattern is introduced to magnify sub-Angstrom distortions of the lattice and tiny local lattice rotation in underlying twisted bilayer graphene (TBG). The local periods and low-energy van Hove singularities of the topmost graphene moiré patterns are spatially modified by the atomic-scale reconstruction of the underlying TBG, thus enabling real-space imaging of the strain-field vortex networks. Our results indicate that structure-reconstructed vdW systems can provide a unique substrate to spatially engineer supported two-dimensional materials both in structures and electronic properties. △ Less

Submitted 21 December, 2021; originally announced December 2021.

Signatures of Lifshitz transition in the optical conductivity of two-dimensional tilted Dirac materials

Authors: Chao-Yang Tan, Jian-Tong Hou, Chang-Xu Yan, Hong Guo, Hao-Ran Chang

Abstract: Lifshitz transition is a kind of topological phase transition in which the Fermi surface is reconstructed. It can occur in the two-dimensional (2D) tilted Dirac materials when the energy bands change between the type-I phase ($0<t<1$) and the type-II phase ($t>1$) through the type-III phase ($t=1$), where different tilts are parametrized by the values of $t$. In order to characterize the Lifshitz… ▽ More Lifshitz transition is a kind of topological phase transition in which the Fermi surface is reconstructed. It can occur in the two-dimensional (2D) tilted Dirac materials when the energy bands change between the type-I phase ($0<t<1$) and the type-II phase ($t>1$) through the type-III phase ($t=1$), where different tilts are parametrized by the values of $t$. In order to characterize the Lifshitz transition therein, we theoretically investigate the longitudinal optical conductivities (LOCs) in type-I, type-II, and type-III Dirac materials within linear response theory. In the undoped case, the LOCs are constants either independent of the tilt parameter in both type-I and type-III phases or determined by the tilt parameter in the type-II phase. In the doped case, the LOCs are anisotropic and possess two critical frequencies determined by $ω=ω_1(t)$ and $ω=ω_2(t)$, which are also confirmed by the joint density of state. The tilt parameter and chemical potential can be extracted from optical experiments by measuring the positions of these two critical boundaries and their separation $Δω(t)=ω_2(t)-ω_1(t)$. With increasing the tilting, the separation becomes larger in the type-I phase whereas smaller in the type-II phase. The LOCs in the regime of large photon energy are exactly the same as that in the undoped case. The type of 2D tilted Dirac bands can be determined by the asymptotic background values, critical boundaries and their separation in the LOCs. These can therefore be taken as signatures of Lifshitz transition therein. The results of this work are expected to be qualitatively valid for a large number of 2D tilted Dirac materials, such as 8-\emph{Pmmn} borophene monolayer, $α$-SnS$_2$, TaCoTe$_2$, TaIrTe$_4$, and $1T^\prime$ transition metal dichalcogenides, due to the underlying intrinsic similarities of 2D tilted Dirac bands. △ Less

Submitted 7 October, 2022; v1 submitted 17 December, 2021; originally announced December 2021.

Comments: 26 pages, 5 figures, 4 appendices

Journal ref: Phys. Rev. B 106, 165404 (2022)

An Integrated Quantum Material Testbed with Multi-Resolution Photoemission Spectroscopy

Authors: Chenhui Yan, Emanuel Green, Riku Fukumori, Nikola Protic, Seng Huat Lee, Sebastian Fernandez-Mulligan, Rahim Raja, Robin Erdakos, Zhiqiang Mao, Shuolong Yang

Abstract: We present the development of a multi-resolution photoemission spectroscopy (MRPES) setup which probes quantum materials in energy, momentum, space, and time. This versatile setup integrates three light sources in one photoemission setup, and can conveniently switch between traditional angle-resolved photoemission spectroscopy (ARPES), time-resolved ARPES (trARPES), and micron-scale spatially reso… ▽ More We present the development of a multi-resolution photoemission spectroscopy (MRPES) setup which probes quantum materials in energy, momentum, space, and time. This versatile setup integrates three light sources in one photoemission setup, and can conveniently switch between traditional angle-resolved photoemission spectroscopy (ARPES), time-resolved ARPES (trARPES), and micron-scale spatially resolved ARPES ($μ$ARPES). It provides a first-time all-in-one solution to achieve an energy resolution $< 4$ meV, a time resolution $< 35$ fs, and a spatial resolution $\sim 10$ $μ$m in photoemission spectroscopy. Remarkably, we obtain the shortest time resolution among the trARPES setups using solid-state nonlinear crystals for frequency upconversion. Furthermore, this MRPES setup is integrated with a shadow-mask assisted molecular beam epitaxy system, which transforms the traditional photoemission spectroscopy into a quantum device characterization instrument. We demonstrate the functionalities of this novel quantum material testbed using FeSe/SrTiO$_3$ thin films and MnBi$_4$Te$_7$ magnetic topological insulators. △ Less

Submitted 10 November, 2021; v1 submitted 27 September, 2021; originally announced September 2021.

Journal ref: Rev. Sci. Instrum. 92, 113907 (2021)