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Nanoscale friction of manganite superlattice films controlled by layer thickness and fluorine content
Authors:
Niklas A. Weber,
Miru Lee,
Florian Schönewald,
Leonard Schüler,
Vasily Moshnyaga,
Matthias Krüger,
Cynthia A. Volkert
Abstract:
We investigate nanoscale friction in [LaMnO3]m/[SrMnO3]n superlattice films using lateral force microscopy, focusing on the effects of fluorine doping and top-layer thickness. For all samples, friction forces scale linearly with the sum of the applied normal and adhesion forces. While friction forces vary spatially due to local adhesion fluctuations, the friction coefficient remains position indep…
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We investigate nanoscale friction in [LaMnO3]m/[SrMnO3]n superlattice films using lateral force microscopy, focusing on the effects of fluorine doping and top-layer thickness. For all samples, friction forces scale linearly with the sum of the applied normal and adhesion forces. While friction forces vary spatially due to local adhesion fluctuations, the friction coefficient remains position independent for each specimen. It is, however, systematically influenced by fluorine concentration and top-layer thickness. Our data indicates that frictional energy dissipation extends up to 5 nm beneath the surface, demonstrating a clear dependence on subsurface structure. We attribute this to viscoelastic dissipation within the stress field and evanescent waves generated by the sliding tip, which can quantitatively account for the observed friction coefficients. These results show that, once adhesion is properly accounted for, the friction coefficient is a reproducible material property that can be tuned via controlled modifications to surface and subsurface layers.
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Submitted 14 August, 2025; v1 submitted 12 July, 2025;
originally announced July 2025.
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Neutron imaging of high-temperature Na-Zn Cells: implications for cell design and fabrication
Authors:
William Nash,
Martins Sarma,
Tobias Lappan,
Pavel Trtik,
Catherine K. W. Solem,
Zhaohui Wang,
Alberto Beltrán,
Norbert Weber,
Tom Weier
Abstract:
Electrochemical cells employing Sodium (Na) and Zinc (Zn) electrodes and a chloride salt electrolyte have been imaged by neutron radiography during cycling. The use of such abundant raw materials confers a very low energy-normalised cost to the Na-Zn system, but its operation requires them to be entirely molten, and therefore to be operated at 600 °C. To suppress the self-discharge that results fr…
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Electrochemical cells employing Sodium (Na) and Zinc (Zn) electrodes and a chloride salt electrolyte have been imaged by neutron radiography during cycling. The use of such abundant raw materials confers a very low energy-normalised cost to the Na-Zn system, but its operation requires them to be entirely molten, and therefore to be operated at 600 °C. To suppress the self-discharge that results from this all-molten configuration, porous ceramic diaphragms are used to partition the electrolyte and thereby impede the movement of the Zn2+ ions responsible towards the Na electrode. Neutron images reveal large gas bubbles trapped beneath these diaphragms, formed during the cell fabrication process due to the large volume change that accompanies melting/solidifying of the electrolyte. Cycling data confirm that these bubbles interfere with cell operation by substantially increasing ohmic resistance. They indicate the need for either a new diaphragm design, or a cell fabrication process that prevents their formation in the first instance.
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Submitted 24 July, 2024;
originally announced July 2024.
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Yamdb: easily accessible thermophysical properties of liquid metals and molten salts
Authors:
Tom Weier,
William Nash,
Paolo Personnettaz,
Norbert Weber
Abstract:
Yamdb (Yet another materials data base) addresses the need to provide thermophysical properties of liquid metals and molten salts in an easily accessible manner. Mathematical relations describing material properties - usually determined by experiment - are taken from the literature. Equations and their coefficients are stored separately. The former can be implemented in any programming language (P…
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Yamdb (Yet another materials data base) addresses the need to provide thermophysical properties of liquid metals and molten salts in an easily accessible manner. Mathematical relations describing material properties - usually determined by experiment - are taken from the literature. Equations and their coefficients are stored separately. The former can be implemented in any programming language (Python and Go in this case) and the latter are kept in YAML files together with additional information (source, temperature range, composition, accuracy if available, etc).
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Submitted 28 January, 2024;
originally announced February 2024.
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A continuous multiphase model for liquid metal batteries
Authors:
Omar E. Godinez-Brizuela,
Carolina Duczek,
Norbert Weber,
Kristian E. Einarsrud
Abstract:
Liquid metal batteries (LMBs) are a promising alternative for large-scale stationary energy storage for renewable applications. Using high-abundance electrode materials such as Sodium and Zinc is highly desirable due to their low cost and excellent cell potential. LMBs undergo multiple complex mass transport dynamics and as a result, their operation limits and other critical parameters are not ful…
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Liquid metal batteries (LMBs) are a promising alternative for large-scale stationary energy storage for renewable applications. Using high-abundance electrode materials such as Sodium and Zinc is highly desirable due to their low cost and excellent cell potential. LMBs undergo multiple complex mass transport dynamics and as a result, their operation limits and other critical parameters are not fully understood yet. In this work, a multiphase numerical model was developed to resolve electrode and electrolyte components in 1D and simulate the discharge process of a Na-Zn battery including the interfacial displacement of the molten metal electrodes. The variation in electrolyte composition was predicted throughout the process, including the species distribution and its effect on the cell conductivity and capacity. Volume change and species redistribution were found to be important in predicting the maximum theoretical capacity of the cell when neglecting convective phenomena.
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Submitted 8 June, 2023;
originally announced June 2023.
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Ferroelastic twin angles at the surface of CaTiO$_\mathrm{3}$ quantified by PhotoEmission Electron Microscopy
Authors:
G. Magagnin,
C. Lubin,
M. Escher,
N. Weber,
L. Tortech,
N. Barrett
Abstract:
We use photoemission electron microscopy to measure the ferroelastic twin wall angles at the surface of CaTiO$_\mathrm{3}$(001) and deduce the strain ordering. We analyze the angular dependence of the photoelectron emission from different domain surfaces, each with their own characteristic tilt angle in the factory roof-like topography. By considering the surface topography as a field perturbation…
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We use photoemission electron microscopy to measure the ferroelastic twin wall angles at the surface of CaTiO$_\mathrm{3}$(001) and deduce the strain ordering. We analyze the angular dependence of the photoelectron emission from different domain surfaces, each with their own characteristic tilt angle in the factory roof-like topography. By considering the surface topography as a field perturbation, the offset in the photoemission threshold can be directly related to the tilt angles. With knowledge of the symmetry allowed twin walls we quantify twin topography between 179.1° to 180.8°.
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Submitted 17 April, 2023;
originally announced April 2023.
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Nanoscale friction controlled by top layer thickness in [LaMnO$_{3}$]$_{m}$/[SrMnO$_{3}$]$_{n}$ superlattices
Authors:
Niklas A. Weber,
Miru Lee,
Florian Schönewald,
Leonard Schüler,
Vasily Moshnyaga,
Matthias Krüger,
Cynthia A. Volkert
Abstract:
We conducted lateral force microscopy measurements on seven [LaMnO$_{3}$]$_{m}$/[SrMnO$_{3}$]$_{n}$ superlattices with varied layer thicknesses. We observe that the friction forces and the friction coefficients initially increase with increasing LaMnO3 top layer thickness, followed by saturation when the top layer thickness exceeds a few nanometers. These observations clearly demonstrate that slid…
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We conducted lateral force microscopy measurements on seven [LaMnO$_{3}$]$_{m}$/[SrMnO$_{3}$]$_{n}$ superlattices with varied layer thicknesses. We observe that the friction forces and the friction coefficients initially increase with increasing LaMnO3 top layer thickness, followed by saturation when the top layer thickness exceeds a few nanometers. These observations clearly demonstrate that sliding friction is affected by sub-surface material properties to a depth of several nanometers and is not just determined by dynamics in the contact interface. We argue that the sub-surface dissipated energy is governed by damping in the elastically strained volume below the AFM tip, an effect which we estimate via thermoelasticity. The absence of a correlation between friction and the thermal resistivity of our superlattices shows furthermore that high-frequency phonons and heat conduction do not play a role in determining friction. Our observations thus demonstrate that friction can be tailored by sub-surface material properties.
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Submitted 18 October, 2022;
originally announced October 2022.
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Friction on layered media: How deep do phonons reach?
Authors:
Miru Lee,
Niklas Weber,
Cynthia A. Volkert,
Matthias Krüger
Abstract:
We theoretically study the frictional damping of a small probe object on a coated planar surface, analyzing the resulting phonon modes via a theory of viscoelasticity. Three different types of excitations are found to contribute to friction in distinct ways: traveling (3D) spherical waves, traveling (2D) surface waves, and evanescent waves. While traveling waves transport energy away from the prob…
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We theoretically study the frictional damping of a small probe object on a coated planar surface, analyzing the resulting phonon modes via a theory of viscoelasticity. Three different types of excitations are found to contribute to friction in distinct ways: traveling (3D) spherical waves, traveling (2D) surface waves, and evanescent waves. While traveling waves transport energy away from the probe, determined by long range elastic properties (wavelength), evanescent waves transform energy into heat in a near-field range, characterized by the size of the probe. Thus, fundamentally different behaviors are predicted, depending on coating thickness and material properties.
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Submitted 23 May, 2023; v1 submitted 2 May, 2022;
originally announced May 2022.
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Cell voltage model for Li-Bi liquid metal batteries
Authors:
Norbert Weber,
Carolina Duczek,
Gerrit M. Horstmann,
Steffen Landgraf,
Michael Nimtz,
Paolo Personnettaz,
Tom Weier,
Donald R. Sadoway
Abstract:
Lithium-bismuth bimetallic cells are amongst the best explored liquid metal batteries. A simple and fast quasi-one-dimensional cell voltage model for such devices is presented. The equilibrium cell potential is obtained from a complex two-dimensional fit of data drawn from multiple studies of equilibrium cell potential and rendered congruent with the phase diagram. Likewise, several analytical and…
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Lithium-bismuth bimetallic cells are amongst the best explored liquid metal batteries. A simple and fast quasi-one-dimensional cell voltage model for such devices is presented. The equilibrium cell potential is obtained from a complex two-dimensional fit of data drawn from multiple studies of equilibrium cell potential and rendered congruent with the phase diagram. Likewise, several analytical and fit functions for the ohmic potential drop across the electrolyte are provided for different battery geometries. Mass transport overpotentials originating from the alloying of Li into Bi are modelled by solving a diffusion equation, either analytically or numerically, and accounting for the volume change of the positive electrode. The applicability and limitations of the model are finally illustrated in three distinct experimental settings.
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Submitted 13 January, 2022;
originally announced January 2022.
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Deep learning based quantum vortex detection in atomic Bose-Einstein condensates
Authors:
Friederike Metz,
Juan Polo,
Natalya Weber,
Thomas Busch
Abstract:
Quantum vortices naturally emerge in rotating Bose-Einstein condensates (BECs) and, similarly to their classical counterparts, allow the study of a range of interesting out-of-equilibrium phenomena like turbulence and chaos. However, the study of such phenomena requires to determine the precise location of each vortex within a BEC, which becomes challenging when either only the condensate density…
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Quantum vortices naturally emerge in rotating Bose-Einstein condensates (BECs) and, similarly to their classical counterparts, allow the study of a range of interesting out-of-equilibrium phenomena like turbulence and chaos. However, the study of such phenomena requires to determine the precise location of each vortex within a BEC, which becomes challenging when either only the condensate density is available or sources of noise are present, as is typically the case in experimental settings. Here, we introduce a machine learning based vortex detector motivated by state-of-the-art object detection methods that can accurately locate vortices in simulated BEC density images. Our model allows for robust and real-time detection in noisy and non-equilibrium configurations. Furthermore, the network can distinguish between vortices and anti-vortices if the condensate phase profile is also available. We anticipate that our vortex detector will be advantageous both for experimental and theoretical studies of the static and dynamical properties of vortex configurations in BECs.
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Submitted 13 April, 2021; v1 submitted 23 December, 2020;
originally announced December 2020.
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Polaronic Contributions to Friction in a Manganite Thin Film
Authors:
Niklas A. Weber,
Hendrik Schmidt,
Tim Sievert,
Christian Jooss,
Friedrich Güthoff,
Vasily Moshneaga,
Konrad Samwer,
Matthias Krüger,
Cynthia A. Volkert
Abstract:
Despite the huge importance of friction in regulating movement in all natural and technological processes, the mechanisms underlying dissipation at a sliding contact are still a matter of debate. Attempts to explain the dependence of measured frictional losses at nanoscale contacts on the electronic degrees of freedom of the surrounding materials have so far been controversial. Here, it is propose…
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Despite the huge importance of friction in regulating movement in all natural and technological processes, the mechanisms underlying dissipation at a sliding contact are still a matter of debate. Attempts to explain the dependence of measured frictional losses at nanoscale contacts on the electronic degrees of freedom of the surrounding materials have so far been controversial. Here, it is proposed that friction can be explained by considering damping of stick-slip pulses in a sliding contact. Based on friction force microscopy studies of La$_{(1-x)}$Sr$_x$MnO$_3$ films at the ferromagnetic-metallic to paramagnetic-polaronic conductor phase transition, it is confirmed that the sliding contact generates thermally-activated slip pulses in the nanoscale contact, and argued that these are damped by direct coupling into phonon bath. Electron-phonon coupling leads to the formation of Jahn-Teller polarons and a clear increase in friction in the high temperature phase. There is no evidence for direct electronic drag on the atomic force microscope tip nor any indication of contributions from electrostatic forces. This intuitive scenario, that friction is governed by the damping of surface vibrational excitations, provides a basis for reconciling controversies in literature studies as well as suggesting possible tactics for controlling friction.
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Submitted 25 September, 2020;
originally announced September 2020.
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Switching friction at a manganite surface using electric fields
Authors:
H. Schmidt,
J. -O. Krisponeit,
N. Weber,
K. Samwer,
C. A. Volkert
Abstract:
We report active control of the friction force at the contact between a nanoscale asperity and a La$_{0.55}$Ca$_{0.45}$MnO$_3$ (LCMO) thin film using electric fields. We use friction force microscopy under ultrahigh vacuum conditions to measure the friction force as we change the film resistive state by electric field-induced resistive switching. Friction forces are high in the insulating state an…
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We report active control of the friction force at the contact between a nanoscale asperity and a La$_{0.55}$Ca$_{0.45}$MnO$_3$ (LCMO) thin film using electric fields. We use friction force microscopy under ultrahigh vacuum conditions to measure the friction force as we change the film resistive state by electric field-induced resistive switching. Friction forces are high in the insulating state and clearly change to lower values when the probed local region is switched to the conducting state. Upon switching back to an insulating state, the friction forces increase again. Thus, we demonstrate active control of friction without having to change the contact temperature or pressure. By comparing with measurements of friction at the metal-to-insulator transition and with the effect of applied voltage on adhesion, we rule out electronic excitations, electrostatic forces and changes in contact area as the reasons for the effect of resistive switching on friction. Instead, we argue that friction is limited by phonon relaxation times which are strongly coupled to the electronic degrees of freedom through distortions of the MnO6 octahedra. The concept of controlling friction forces by electric fields should be applicable to any materials where the field produces strong changes in phonon lifetimes.
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Submitted 16 May, 2020;
originally announced May 2020.
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Binary Mixtures of Particles with Different Diffusivities Demix
Authors:
Simon N. Weber,
Christoph A. Weber,
Erwin Frey
Abstract:
The influence of size differences, shape, mass and persistent motion on phase separation in binary mixtures has been intensively studied. Here we focus on the exclusive role of diffusivity differences in binary mixtures of equal-sized particles. We find an effective attraction between the less diffusive particles, which are essentially caged in the surrounding species with the higher diffusion con…
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The influence of size differences, shape, mass and persistent motion on phase separation in binary mixtures has been intensively studied. Here we focus on the exclusive role of diffusivity differences in binary mixtures of equal-sized particles. We find an effective attraction between the less diffusive particles, which are essentially caged in the surrounding species with the higher diffusion constant. This effect leads to phase separation for systems above a critical size: A single close-packed cluster made up of the less diffusive species emerges. Experiments for testing of our predictions are outlined.
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Submitted 14 February, 2016; v1 submitted 4 May, 2015;
originally announced May 2015.
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Functional single-layer graphene sheets from aromatic monolayers
Authors:
Dan G. Matei,
Nils-Eike Weber,
Simon Kurasch,
Stefan Wundrack,
Miroslaw Woszczyna,
Miriam Grothe,
Thomas Weimann,
Franz Ahlers,
Rainer Stosch,
Ute Kaiser,
Andrey Turchanin
Abstract:
We demonstrate how self-assembled monolayers of aromatic molecules on copper substrates can be converted into high-quality single-layer graphene using low-energy electron irradiation and subsequent annealing. We characterize this two-dimensional solid state transformation on the atomic scale and study the physical and chemical properties of the formed graphene sheets by complementary microscopic a…
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We demonstrate how self-assembled monolayers of aromatic molecules on copper substrates can be converted into high-quality single-layer graphene using low-energy electron irradiation and subsequent annealing. We characterize this two-dimensional solid state transformation on the atomic scale and study the physical and chemical properties of the formed graphene sheets by complementary microscopic and spectroscopic techniques and by electrical transport measurements. As substrates we successfully use Cu(111) single crystals and the technologically relevant polycrystalline copper foils.
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Submitted 8 June, 2014;
originally announced June 2014.
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Energy-filtered transmission electron microscopy of biological samples on highly transparent carbon nanomembranes
Authors:
Daniel Rhinow,
Matthias Büenfeld,
Nils-Eike Weber,
André Beyer,
Armin Gölzhäuser,
Werner Kühlbrandt,
Norbert Hampp,
Andrey Turchanin
Abstract:
Ultrathin carbon nanomembranes (CNM) comprising crosslinked biphenyl precursors have been tested as support films for energy-filtered transmission electron microscopy (EFTEM) of biological specimens. Due to their high transparency CNM are ideal substrates for electron energy loss spectroscopy (EELS) and electron spectroscopic imaging (ESI) of stained and unstained biological samples. Virtually bac…
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Ultrathin carbon nanomembranes (CNM) comprising crosslinked biphenyl precursors have been tested as support films for energy-filtered transmission electron microscopy (EFTEM) of biological specimens. Due to their high transparency CNM are ideal substrates for electron energy loss spectroscopy (EELS) and electron spectroscopic imaging (ESI) of stained and unstained biological samples. Virtually background-free elemental maps of tobacco mosaic virus (TMV) and ferritin have been obtained from samples supported by ~ 1 nm thin CNM. Furthermore, we have tested conductive carbon nanomembranes (cCNM) comprising nanocrystalline graphene, obtained by thermal treatment of CNM, as supports for cryoEM of ice-embedded biological samples. We imaged ice-embedded TMV on cCNM and compared the results with images of ice-embedded TMV on conventional carbon film (CC), thus analyzing the gain in contrast for TMV on cCNM in a quantitative manner. In addition we have developed a method for the preparation of vitrified specimens, suspended over the holes of a conventional holey carbon film, while backed by ultrathin cCNM.
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Submitted 6 October, 2011;
originally announced October 2011.
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Single-walled carbon nanotubes and nanocrystalline graphene reduce beam-induced movements in high-resolution electron cryo-microscopy of ice-embedded biological samples
Authors:
Daniel Rhinow,
Nils-Eike Weber,
Andrey Turchanin,
Armin Gölzhäuser,
Werner Kühlbrandt
Abstract:
For single particle electron cryo-microscopy (cryoEM), contrast loss due to beam-induced charging and specimen movement is a serious problem, as the thin films of vitreous ice spanning the holes of a holey carbon film are particularly susceptible to beam-induced movement. We demonstrate that the problem is at least partially solved by carbon nanotechnology. Doping ice-embedded samples with single-…
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For single particle electron cryo-microscopy (cryoEM), contrast loss due to beam-induced charging and specimen movement is a serious problem, as the thin films of vitreous ice spanning the holes of a holey carbon film are particularly susceptible to beam-induced movement. We demonstrate that the problem is at least partially solved by carbon nanotechnology. Doping ice-embedded samples with single-walled carbon nanotubes (SWNT) in aqueous suspension or adding nanocrystalline graphene supports, obtained by thermal conversion of cross-linked self-assembled biphenyl precursors, significantly reduces contrast loss in high-resolution cryoEM due to the excellent electrical and mechanical properties of SWNTs and graphene.
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Submitted 6 October, 2011;
originally announced October 2011.