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Processing and mechanical properties of novel biodegradable poly-lactic acid/Zn 3D printed scaffolds for application in tissue regeneration
Authors:
C. Pascual-González,
J. de la Vega,
C. Thompson,
J. P. Fernández-Blázquez,
D. Herráez-Molinero,
N. Biurrun,
I. Lizarralde,
J. Sánchez del Río,
C. González,
J. LLorca
Abstract:
The feasibility to manufacture scaffolds of poly-lactic acid reinforced with Zn particles by fused filament fabrication is demonstrated for the first time. Filaments of 2.85 mm in diameter of PLA reinforced with different weight fractions of $μ$m-sized Zn - 1 wt. \% Mg alloy particles (in the range 3.5 to 17.5 wt. \%) were manufactured by a double extrusion in method in which standard extrusion is…
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The feasibility to manufacture scaffolds of poly-lactic acid reinforced with Zn particles by fused filament fabrication is demonstrated for the first time. Filaments of 2.85 mm in diameter of PLA reinforced with different weight fractions of $μ$m-sized Zn - 1 wt. \% Mg alloy particles (in the range 3.5 to 17.5 wt. \%) were manufactured by a double extrusion in method in which standard extrusion is followed by a precision extrusion in a filament-maker machine. Filaments with constant diameter, negligible porosity and a homogeneous reinforcement distribution were obtained for Zn weight fractions of up to 10.5\%. It was found that the presence of Zn particles led to limited changes in the physico-chemical properties of the PLA that did not affect the window temperature for 3D printing nor the melt flow index. Thus, porous scaffolds could be manufactured by fused filament fabrication at 190\textdegree C with poly-lactic acid/Zn composites containing 3.5 and 7 wt. \% of Zn and at 170\textdegree C when the Zn content was 10.5 wt. \% with excellent dimensional accuracy and mechanical properties.
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Submitted 4 August, 2023;
originally announced August 2023.
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Crystalline C60 fulleride with metal inside
Authors:
Ayano Nakagawa,
Makiko Nishino,
Hiroyuki Niwa,
Katsuma Ishino,
Zhiyong Wang,
Haruka Omachi,
Ko Furukawa,
Takahisa Yamaguchi,
Tatsuhisa Kato,
Shunji Bandow,
Jeremy Rio,
Chris Ewels,
Shinobu Aoyagi,
Hisanori Shinohara
Abstract:
Endohedral metallofullerenes have been extensively studied, since the first experimental observation of La@C60 in a laser-vaporized supersonic beam in 1985. However, all of these studies have been carried out on metallofullerenes larger than C60 such as (metal)@C82, and there are no reported purified C60-based metallofullerenes except for [Li@C60]+(SbCl6)- salt. Pure (metal)@C60 has not been obtai…
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Endohedral metallofullerenes have been extensively studied, since the first experimental observation of La@C60 in a laser-vaporized supersonic beam in 1985. However, all of these studies have been carried out on metallofullerenes larger than C60 such as (metal)@C82, and there are no reported purified C60-based metallofullerenes except for [Li@C60]+(SbCl6)- salt. Pure (metal)@C60 has not been obtained because of their extremely high chemical reactivity. We report here the first isolation, structural determination and electromagnetic properties of crystalline C60-based metallofullerenes, Gd@C60(CF3)5 and La@C60(CF3)5. Synchrotron X-ray single-crystal diffraction reveals that La and Gd atoms are indeed encapsulated in the Ih-C60 fullerene. The HOMO-LUMO gaps of Gd@C60 and La@C60 are significantly widened by an order of magnitude with addition of CF3- groups. Magnetic measurements show the presense of a weak antiferromagnetic coupling in Gd@C60(CF3)3 crystals at low temperatures. Gd@C60 and La@C60 might exhibit superconductivity as the electronic structures resemble those of superconducting alkali-doped C60 fullerides.
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Submitted 30 January, 2018;
originally announced January 2018.
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Transient situations in traffic flow: Modelling the Mexico City Cuernavaca Highway
Authors:
J. A. del Rio,
M. E. Larraga
Abstract:
In this paper a recent variable anticipation cellular automata model for single-lane traffic flow is extended to analyze the situation of free and congested flow in the Highway from Mexico City to Cuernavaca. This highway presents free flow in standard days; but in the returning day of long weekends or holidays it exhibits congested flow and in rush hours jamming appears. We illustrate how our C…
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In this paper a recent variable anticipation cellular automata model for single-lane traffic flow is extended to analyze the situation of free and congested flow in the Highway from Mexico City to Cuernavaca. This highway presents free flow in standard days; but in the returning day of long weekends or holidays it exhibits congested flow and in rush hours jamming appears. We illustrate how our CA model for traffic flow can deal appropriately with transient situations and can be used to search new alternatives that allow to improve the traffic flow in Mexican highways.
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Submitted 24 January, 2005;
originally announced January 2005.
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Tailoring the photonic bandgap of porous silicon dielectric mirror
Authors:
V. Agarwal,
J. A. del Rio
Abstract:
A systematic method to fabricate porous silicon one dimensional photonic crystals has been engineered to have a photonic bandwidth up to 2000nm. The observation of the tailorability of the photonic bandgap (PBG) underscores the requirement of the large refractive index contrast for making broad PBG structures. In this letter, we present the fabrication and characteristics of such structures that…
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A systematic method to fabricate porous silicon one dimensional photonic crystals has been engineered to have a photonic bandwidth up to 2000nm. The observation of the tailorability of the photonic bandgap (PBG) underscores the requirement of the large refractive index contrast for making broad PBG structures. In this letter, we present the fabrication and characteristics of such structures that may be promising structures for a large variety of applications.
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Submitted 18 July, 2003;
originally announced July 2003.
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Platoon formation in a traffic model with variable anticipation
Authors:
M. E. Larraga,
J. A. del Rio,
A. Schadschneider
Abstract:
A cellular automaton model of traffic flow taking into account velocity anticipation is introduced. The strength of anticipation can be varied which allows to describe different driving schemes. We find phase separation into a free-flow regime and a so-called $v$-platoon in an intermediate density regime. In a $v$-platoon all cars move with velocity $v$ and have vanishing headway. The velocity…
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A cellular automaton model of traffic flow taking into account velocity anticipation is introduced. The strength of anticipation can be varied which allows to describe different driving schemes. We find phase separation into a free-flow regime and a so-called $v$-platoon in an intermediate density regime. In a $v$-platoon all cars move with velocity $v$ and have vanishing headway. The velocity $v$ of a platoon only depends on the strength of anticipation. At high densities, a congested state characterized by the coexistence of a 0-platoon with several $v$-platoons is reached. The results are not only relevant for automated highway systems, but also help to elucidate the effects of anticipation that play an essential role in realistic traffic models. From a physics point of view the model is interesting because it exhibits phase separation with a condensed phase in which particles move coherently with finite velocity coexisting with either a non-condensed (free-flow) phase or another condensed phase that is non-moving.
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Submitted 20 June, 2003;
originally announced June 2003.
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Harmonically Trapped Quantum Gases
Authors:
M. Grether,
M. Fortes,
M. de Llano,
J. L. del Río,
F. J. Sevilla,
M. A. Solís,
Ariel A. Valladares
Abstract:
We solve the problem of a Bose or Fermi gas in $d$-dimensions trapped by $% δ\leq d$ mutually perpendicular harmonic oscillator potentials. From the grand potential we derive their thermodynamic functions (internal energy, specific heat, etc.) as well as a generalized density of states. The Bose gas exhibits Bose-Einstein condensation at a nonzero critical temperature $T_{c}$ if and only if…
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We solve the problem of a Bose or Fermi gas in $d$-dimensions trapped by $% δ\leq d$ mutually perpendicular harmonic oscillator potentials. From the grand potential we derive their thermodynamic functions (internal energy, specific heat, etc.) as well as a generalized density of states. The Bose gas exhibits Bose-Einstein condensation at a nonzero critical temperature $T_{c}$ if and only if $d+δ>2$, and a jump in the specific heat at $T_{c}$ if and only if $d+δ>4$. Specific heats for both gas types precisely coincide as functions of temperature when $d+δ=2$. The trapped system behaves like an ideal free quantum gas in $d+δ$ dimensions. For $δ=0$ we recover all known thermodynamic properties of ideal quantum gases in $d$ dimensions, while in 3D for $δ=$ 1, 2 and 3 one simulates behavior reminiscent of quantum {\it wells, wires}and{\it dots}, respectively.
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Submitted 22 May, 2002;
originally announced May 2002.
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Light-scattering spectrum of a viscoelastic fluid subjected to an external temperature gradient
Authors:
M. Lopez de Haro,
J. A. del Rio,
F. Vazquez
Abstract:
The light-scattering spectrum for a Maxwell fluid in a steady state due to the presence of an external temperature gradient is computed. In such a fluid heat conduction is assumed to be governed by the classical Fourier law. The calculation is carried out through the use of fluctuating hydrodynamics. The effect of the non-Newtonian character of the fluid in the resulting spectrum is discussed.
The light-scattering spectrum for a Maxwell fluid in a steady state due to the presence of an external temperature gradient is computed. In such a fluid heat conduction is assumed to be governed by the classical Fourier law. The calculation is carried out through the use of fluctuating hydrodynamics. The effect of the non-Newtonian character of the fluid in the resulting spectrum is discussed.
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Submitted 12 December, 2001;
originally announced December 2001.
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Two effective temperatures in traffic flow models: analogies with granular flow
Authors:
M. E. Larraga,
J. A. del Rio,
Anita Mehta
Abstract:
We present a model of traffic flow, with rules that describe the behaviour of automated vehicles in an open system. We show first of all that the fundamental diagram of this system collapses to a point, where states of free and jammed traffic can coexist in phase space. This leads us to consider separately the roles of average velocities and densities as better descriptors of the actual state of…
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We present a model of traffic flow, with rules that describe the behaviour of automated vehicles in an open system. We show first of all that the fundamental diagram of this system collapses to a point, where states of free and jammed traffic can coexist in phase space. This leads us to consider separately the roles of average velocities and densities as better descriptors of the actual state of the traffic. Next, we observe that the transition between free and jammed traffic as a function of the braking parameter R is different for high and low initial densities, in the steady state; it turns out to be 'smeared out' for low densities, a behaviour which is already portended by the transient behaviour of the system. Our results indicate strongly that, at least for such models, two effective temperatures (one related to R, and the other to the density) are needed to describe the global behaviour of this system in statistical mechanical terms. Analogies with granular flow are discussed in this context.
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Submitted 6 December, 2001;
originally announced December 2001.
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Cellular Automata for One-Lane Traffic Flow Modelling: Safety and Automation
Authors:
M. E. Larraga,
J. A. del Rio
Abstract:
In recent years the modelling of traffic flow using methods from statistical physics, especially cellular automata models have allowed simulations of large traffic networks faster than real time. In this paper, we study a probabilistic cellular automaton model for microsimulations of traffic flow of automated vehicles in highways. This model describes single-lane traffic flow on a ring. We study…
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In recent years the modelling of traffic flow using methods from statistical physics, especially cellular automata models have allowed simulations of large traffic networks faster than real time. In this paper, we study a probabilistic cellular automaton model for microsimulations of traffic flow of automated vehicles in highways. This model describes single-lane traffic flow on a ring. We study the equilibrium properties by including a parameter of safe distance in the model and calculate the so-called fundamental diagrams (flow vs. density graph) considering parallel dynamics. This is done numerically by computer simulations of the model and by means of an analysis of speed variance.
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Submitted 5 December, 2001;
originally announced December 2001.