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Quantum Hall effect in vacancy-engineered $β$-Ag$_2$Te
Authors:
Mizuki Ohno,
Veronica Show,
Reiley Dorrian,
Joseph Falson
Abstract:
Accessing surface quantum transport in topological insulators is hampered by residual bulk conduction arising from lattice defects. Here, we demonstrate a novel synthesis pathway for realizing high mobility $β$-Ag$_2$Te thin films where surface transport is dominant. An \textit{in-situ} vacancy engineering step as part of the molecular beam epitaxy growth process acts to modify the stoichiometry a…
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Accessing surface quantum transport in topological insulators is hampered by residual bulk conduction arising from lattice defects. Here, we demonstrate a novel synthesis pathway for realizing high mobility $β$-Ag$_2$Te thin films where surface transport is dominant. An \textit{in-situ} vacancy engineering step as part of the molecular beam epitaxy growth process acts to modify the stoichiometry and suppress donor-type defects, enabling continuous tuning of the sheet carrier density over more than an order of magnitude through the charge-neutrality point without an external gate electrode. In the lower-carrier-density films, a fully developed $ν=1$ quantum Hall state is observed, and Landau-level energies extracted across samples collapse onto the $E_N=v_\mathrm{F}\sqrt{2e\hbar NB}$ relation, providing evidence for the massless Dirac dispersion of the top and bottom surface states. These results establish stoichiometry-driven vacancy engineering as a versatile lithography- and gate-free approach to accessing quantum Hall transport in epitaxial topological-insulator thin films.
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Submitted 3 June, 2026;
originally announced June 2026.
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Pair-Breaking and Dimensionality in Spin-Orbit Coupled Superconductors
Authors:
Reiley Dorrian,
Mizuki Ohno,
Elena Williams,
Adrian Llanos,
Joseph Falson
Abstract:
The response of ultra-thin superconducting materials under parallel magnetic fields is often leveraged to obtain insight into the nature of the condensate, including features attributable to unconventional forms of pairing. Despite there being multiple competing mechanisms responsible for suppressing superconductivity, it is common for these analyses to overlook certain depairing channels. Here we…
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The response of ultra-thin superconducting materials under parallel magnetic fields is often leveraged to obtain insight into the nature of the condensate, including features attributable to unconventional forms of pairing. Despite there being multiple competing mechanisms responsible for suppressing superconductivity, it is common for these analyses to overlook certain depairing channels. Here we report an analysis of thickness dependent superconductivity in thin films of \ce{LaBi2} using the multi-mechanism Kharitonov-Feigel'man framework . By resolving field-enhanced superconductivity in the thin-limit, we obtain an estimate the role of spin exchange scattering, in addition to paramagnetic and orbital effects. Our analyses offer insight into how fundamental quantities such as the critical temperature as well as Pauli limit are defined, recasting the landscape for how scattering times in two-dimensional superconductors can be interpreted.
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Submitted 7 May, 2026;
originally announced May 2026.
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Anisotropic multiband magnetotransport in LaAg$_2$Ge$_2$ thin films
Authors:
Mizuki Ohno,
Reiley Dorrian,
Veronica Show,
Joseph Falson
Abstract:
ThCr$_2$Si$_2$-type intermetallics are layered conductors in which crystallographic anisotropy and multiband electronic states often give rise to characteristic magnetotransport phenomena. Here, we report the molecular-beam epitaxy growth of LaAg$_2$Ge$_2$ thin films on MgO(001) and their magnetotransport properties. The Hall effect and magnetoresistance are captured by an effective two-carrier de…
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ThCr$_2$Si$_2$-type intermetallics are layered conductors in which crystallographic anisotropy and multiband electronic states often give rise to characteristic magnetotransport phenomena. Here, we report the molecular-beam epitaxy growth of LaAg$_2$Ge$_2$ thin films on MgO(001) and their magnetotransport properties. The Hall effect and magnetoresistance are captured by an effective two-carrier description with a high-mobility electron band, yielding a positive magnetoresistance of 22.5% at 9 T. Angle-dependent magnetoresistance exhibits a dominant twofold anisotropy and additional reproducible dip/peak features at characteristic tilt angles that are nearly independent of field and temperature. These results extend our understanding of the anisotropic electronic transport in thin-film germanides within the ThCr$_2$Si$_2$ family.
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Submitted 22 April, 2026;
originally announced April 2026.
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Relativistic Effects in LaBi$_2$ Thin Films
Authors:
Reiley Dorrian,
Sungmin Song,
Jinwoong Kim,
Mizuki Ohno,
Seung-Hoon Jhi,
Nicholas Kioussis,
Joseph Falson
Abstract:
Chemical substitution in crystalline quantum materials is a powerful way to explore the consequences of strong spin-orbit coupling on their structural and electronic properties. In this work, we present an investigation of thin films of the La$\textit{Pn}_2$ ($\textit{Pn}$~=~Sb, Bi) class of layered square-net intermetallics. We report the growth of LaBi$_2$ with a pristine layer-by-layer growth m…
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Chemical substitution in crystalline quantum materials is a powerful way to explore the consequences of strong spin-orbit coupling on their structural and electronic properties. In this work, we present an investigation of thin films of the La$\textit{Pn}_2$ ($\textit{Pn}$~=~Sb, Bi) class of layered square-net intermetallics. We report the growth of LaBi$_2$ with a pristine layer-by-layer growth mode, classifying it as a good metal displaying superconductivity at $\sim$0.55~K. Compared to LaSb$_2$, we attribute the enhanced metallic behavior and improved growth dynamics of LaBi$_2$ to significant relativistic corrections to its electronic band structure and the resulting impact on both surface energy and intrinsic phonon scattering.
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Submitted 10 February, 2026;
originally announced February 2026.
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Omics-scale polymer computational database transferable to real-world artificial intelligence applications
Authors:
Ryo Yoshida,
Yoshihiro Hayashi,
Hidemine Furuya,
Ryohei Hosoya,
Kazuyoshi Kaneko,
Hiroki Sugisawa,
Yu Kaneko,
Aiko Takahashi,
Yoh Noguchi,
Shun Nanjo,
Keiko Shinoda,
Tomu Hamakawa,
Mitsuru Ohno,
Takuya Kitamura,
Misaki Yonekawa,
Stephen Wu,
Masato Ohnishi,
Chang Liu,
Teruki Tsurimoto,
Arifin,
Araki Wakiuchi,
Kohei Noda,
Junko Morikawa,
Teruaki Hayakawa,
Junichiro Shiomi
, et al. (81 additional authors not shown)
Abstract:
Developing large-scale foundational datasets is a critical milestone in advancing artificial intelligence (AI)-driven scientific innovation. However, unlike AI-mature fields such as natural language processing, materials science, particularly polymer research, has significantly lagged in developing extensive open datasets. This lag is primarily due to the high costs of polymer synthesis and proper…
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Developing large-scale foundational datasets is a critical milestone in advancing artificial intelligence (AI)-driven scientific innovation. However, unlike AI-mature fields such as natural language processing, materials science, particularly polymer research, has significantly lagged in developing extensive open datasets. This lag is primarily due to the high costs of polymer synthesis and property measurements, along with the vastness and complexity of the chemical space. This study presents PolyOmics, an omics-scale computational database generated through fully automated molecular dynamics simulation pipelines that provide diverse physical properties for over $10^5$ polymeric materials. The PolyOmics database is collaboratively developed by approximately 260 researchers from 48 institutions to bridge the gap between academia and industry. Machine learning models pretrained on PolyOmics can be efficiently fine-tuned for a wide range of real-world downstream tasks, even when only limited experimental data are available. Notably, the generalisation capability of these simulation-to-real transfer models improve significantly as the size of the PolyOmics database increases, exhibiting power-law scaling. The emergence of scaling laws supports the "more is better" principle, highlighting the significance of ultralarge-scale computational materials data for improving real-world prediction performance. This unprecedented omics-scale database reveals vast unexplored regions of polymer materials, providing a foundation for AI-driven polymer science.
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Submitted 7 November, 2025;
originally announced November 2025.
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Stacking-Selective Epitaxy of Rare-Earth Diantimonides
Authors:
Reiley Dorrian,
Jinwoong Kim,
Adrian Llanos,
Veronica Show,
Mizuki Ohno,
Nicholas Kioussis,
Joseph Falson
Abstract:
Deterministic control of the layering configuration of two-dimensional quantum materials plays a central role in studying their emergent electronic properties. Here we demonstrate in-situ control over competing stacking configurations in thin film crystals of the rare-earth diantimonides by synthesizing in proximity to competing structural orders. A crossover between the epitaxially stabilized mon…
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Deterministic control of the layering configuration of two-dimensional quantum materials plays a central role in studying their emergent electronic properties. Here we demonstrate in-situ control over competing stacking configurations in thin film crystals of the rare-earth diantimonides by synthesizing in proximity to competing structural orders. A crossover between the epitaxially stabilized monoclinic structure and the orthorhombic structure commonly observed in bulk crystals is navigated through three axes; the relative cation/anion ratio, growth temperature, and choice of lanthanide ion, culminating with a comparative magnetotransport study of single-yet-distinct phase CeSb2 films. These results set the stage for an expanded search for hidden stacking configurations in layered compounds which have evaded detection.
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Submitted 13 May, 2025;
originally announced May 2025.
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Berry curvature derived negative magnetoconductivity observed in type-II magnetic Weyl semimetal films
Authors:
Ayano Nakamura,
Shinichi Nishihaya,
Hiroaki Ishizuka,
Markus Kriener,
Mizuki Ohno,
Yuto Watanabe,
Masashi Kawasaki,
Masaki Uchida
Abstract:
Here we study nonmonotonic features which appear both in magnetoresistivity and anomalous Hall resistivity during the simple magnetization process, by systematically measuring type-II magnetic Weyl semimetal EuCd$_2$Sb$_2$ films over a wide carrier density range. We find that a positive magnetoresistivity hump can be explained as manifestation of a field-linear term in the generalized magnetocondu…
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Here we study nonmonotonic features which appear both in magnetoresistivity and anomalous Hall resistivity during the simple magnetization process, by systematically measuring type-II magnetic Weyl semimetal EuCd$_2$Sb$_2$ films over a wide carrier density range. We find that a positive magnetoresistivity hump can be explained as manifestation of a field-linear term in the generalized magnetoconductivity formula including the Berry curvature. As also confirmed by model calculation, the term can be negative and pronounced near the Weyl point energy in the case that the Weyl cones are heavily tilted. Our findings demonstrate extensive effects of the Berry curvature on various magnetotransport in magnetic Weyl semimetals beyond the anomalous Hall effect.
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Submitted 14 March, 2024;
originally announced March 2024.
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Intrinsic insulating transport characteristics in low-carrier density EuCd2As2 films
Authors:
Shinichi Nishihaya,
Ayano Nakamura,
Mizuki Ohno,
Markus Kriener,
Yuto Watanabe,
Masashi Kawasaki,
Masaki Uchida
Abstract:
Searching for an ideal magnetic Weyl semimetal hosting only a single pair of Weyl points has been a focal point for systematic clarification of its unique magnetotransport derived from the interplay between topology and magnetization. Among the candidates, triangular-lattice antiferromagnet EuCd$_2$As$_2$ has been attracting special attention due to the prediction of the ideal Weyl semimetal phase…
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Searching for an ideal magnetic Weyl semimetal hosting only a single pair of Weyl points has been a focal point for systematic clarification of its unique magnetotransport derived from the interplay between topology and magnetization. Among the candidates, triangular-lattice antiferromagnet EuCd$_2$As$_2$ has been attracting special attention due to the prediction of the ideal Weyl semimetal phase in the ferromagnetic state, however, transport properties of low-carrier density samples have remained elusive. Here we report molecular beam epitaxy growth of EuCd$_2$As$_2$ films, achieving low-hole density in the range of $10^{15}$-$10^{16}$ cm$^{-3}$ at low temperature. Transport measurements of such low-carrier density films reveal an insulating behavior with an activation gap of about 200 meV, which persists even in the field-induced ferromagnetic state. Our work provides an important experimental clue that EuCd$_2$As$_2$ is intrinsically insulating, contrary to the previous prediction.
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Submitted 3 January, 2024;
originally announced January 2024.
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Impact of iso-structural template layer on stabilizing pyrochlore Bi$_2$Rh$_2$O$_7$
Authors:
M. Ohno,
T. C. Fujita,
M. Kawasaki
Abstract:
We present an epitaxial stabilization of pyrochlore Bi$_2$Rh$_2$O$_7$ on Y-stabilized ZrO$_2$ (YSZ) (111) substrate by inserting a pyrochlore Eu$_2$Ti$_2$O$_7$ template layer, otherwise Bi-based layered structures being formed directly on YSZ (111) substrate. This result reveals that "iso-structural crystal phase" plays an important role in the interfacial phase control. The Bi$_2$Rh$_2$O$_7$ film…
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We present an epitaxial stabilization of pyrochlore Bi$_2$Rh$_2$O$_7$ on Y-stabilized ZrO$_2$ (YSZ) (111) substrate by inserting a pyrochlore Eu$_2$Ti$_2$O$_7$ template layer, otherwise Bi-based layered structures being formed directly on YSZ (111) substrate. This result reveals that "iso-structural crystal phase" plays an important role in the interfacial phase control. The Bi$_2$Rh$_2$O$_7$ film exhibits $p$-type electrical conduction with the lowest longitudinal resistivity ($ρ_\mathrm{xx}$) among the reported Rh pyrochlore oxides. Such parameters as $ρ_\mathrm{xx}$, carrier density, and mobility show almost no temperature dependence in the measured range of 2$-$300 K, indicating Bi$_2$Rh$_2$O$_7$ as one of the rare examples of conducting pyrochlore oxides.
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Submitted 29 March, 2023;
originally announced March 2023.
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Novel supercell compounds of layered Bi-Rh-O with $p$-type metallic conduction materialized as a thin film form
Authors:
M. Ohno,
T. C. Fujita,
Y. Masutake,
H. Kumigashira,
M. Kawasaki
Abstract:
Layered oxides have been intensively studied due to their high degree of freedom in designing various electromagnetic properties and functionalities. While Bi-based layered supercell (LSC) compounds [Bi$_n$O$_{n+δ}$]-[$M$O$_2$] ($M$ = Mn, Mn/Al, Mn/Fe, or Mn/Ni; $n=2, 3$) are a group of prospective candidates, all of the reported compounds are insulators. Here, we report on the synthesis of two no…
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Layered oxides have been intensively studied due to their high degree of freedom in designing various electromagnetic properties and functionalities. While Bi-based layered supercell (LSC) compounds [Bi$_n$O$_{n+δ}$]-[$M$O$_2$] ($M$ = Mn, Mn/Al, Mn/Fe, or Mn/Ni; $n=2, 3$) are a group of prospective candidates, all of the reported compounds are insulators. Here, we report on the synthesis of two novel metallic LSC compounds [Bi$_{n}$O$_{n+δ}$]-[RhO$_2$] ($n=2, 3$) by pulsed laser deposition and subsequent annealing. With tuning the thickness of the sublattice from Bi$_2$O$_{2+δ}$ to Bi$_3$O$_{3+δ}$, a dimensionality-dependent electrical transport is revealed from a conventional metallic transport in $n=2$ to a localized transport in $n=3$. Our successful growth will be an important step for further exploring novel layered oxide compounds.
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Submitted 27 February, 2023;
originally announced February 2023.
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Data-Driven Design of a New Organic Semiconductor via an Electronic Structure Chart
Authors:
Daniel M. Packwood,
Yu Kaneko,
Daiji Ikeda,
Mitsuru Ohno
Abstract:
Data-driven methodologies for designing new materials are developing apace, yet advances for organic crystals have been infrequent. For organic crystals, the need to predict solid-state electronic properties from molecular structure alone is an exceedingly difficult task for typical, regression-based design strategies. In this paper, we present a new strategy for designing organic crystals which c…
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Data-driven methodologies for designing new materials are developing apace, yet advances for organic crystals have been infrequent. For organic crystals, the need to predict solid-state electronic properties from molecular structure alone is an exceedingly difficult task for typical, regression-based design strategies. In this paper, we present a new strategy for designing organic crystals which circumvents the need to regress solid-state physical properties directly. At the core of this strategy is an electronic structure chart, a two-dimensional projection of an organic crystal database in which each material is positioned according to its solid-state electronic properties. We illustrate this strategy by identifying a new molecule which is predicted to show a targeted band gap and better-than-average band curvatures in the crystalline state. This strategy is the first data-driven method which can design new molecules on the basis of genuine solid-state electronic properties, and has potential to accelerate breakthroughs in the field of organic electronics and beyond.
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Submitted 20 April, 2022;
originally announced April 2022.
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Maximizing intrinsic anomalous Hall effect by controlling the Fermi level in simple Weyl semimetal films
Authors:
Mizuki Ohno,
Susumu Minami,
Yusuke Nakazawa,
Shin Sato,
Markus Kriener,
Ryotaro Arita,
Masashi Kawasaki,
Masaki Uchida
Abstract:
Large intrinsic anomalous Hall effect (AHE) originating in the Berry curvature has attracted growing attention for potential applications. Recently proposed magnetic Weyl semimetal EuCd$_2$Sb$_{\mathrm{2}}$ provides an excellent platform for controlling the intrinsic AHE because it only hosts a Weyl-points related band structure near the Fermi energy. Here we report the fabrication of EuCd$_2$Sb…
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Large intrinsic anomalous Hall effect (AHE) originating in the Berry curvature has attracted growing attention for potential applications. Recently proposed magnetic Weyl semimetal EuCd$_2$Sb$_{\mathrm{2}}$ provides an excellent platform for controlling the intrinsic AHE because it only hosts a Weyl-points related band structure near the Fermi energy. Here we report the fabrication of EuCd$_2$Sb$_{\mathrm{2}}$ single-crystalline films and control of their anomalous Hall effect by film technique. As also analyzed by first-principles calculations of energy-dependent intrinsic anomalous Hall conductivity, the obtained anomalous Hall effect shows a sharp peak as a function of carrier density, demonstrating clear energy dependence of the intrinsic AHE.
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Submitted 14 April, 2022;
originally announced April 2022.
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Thermal Conductivity due to Spins in the Two-Dimensional Spin System Ba$_2$Cu$_3$O$_4$Cl$_2$
Authors:
Masumi Ohno,
Takayuki Kawamata,
Megumi Akoshima,
Yoji Koike
Abstract:
We have measured the temperature dependences of the thermal conductivity of Ba$_2$Cu$_{3-x}M_x$O$_4$Cl$_2$ ($M$ = Pd, Ni, Co; $x$ = 0, 0.03) single crystals including two-dimensional (2D) Cu$_3$O$_4$ planes consisting of a strong 2D spin network of CuA$^{2+}$ spins and a weak 2D spin network of CuB$^{2+}$ spins. It has been found that the thermal conductivity due to spins, $κ_{\mathrm{spin}}$, exi…
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We have measured the temperature dependences of the thermal conductivity of Ba$_2$Cu$_{3-x}M_x$O$_4$Cl$_2$ ($M$ = Pd, Ni, Co; $x$ = 0, 0.03) single crystals including two-dimensional (2D) Cu$_3$O$_4$ planes consisting of a strong 2D spin network of CuA$^{2+}$ spins and a weak 2D spin network of CuB$^{2+}$ spins. It has been found that the thermal conductivity due to spins, $κ_{\mathrm{spin}}$, exists in the thermal conductivity parallel to the Cu$_3$O$_4$ plane owing to the strong 2D spin network of CuA$^{2+}$ spins and exhibits a broad peak around room temperature. The maximum value of $κ_{\mathrm{spin}}$ is ~7 W/Km and comparable with that in Nd$_2$CuO$_4$ with almost the same 2D spin network of Cu$^{2+}$ spins. The $κ_{\mathrm{spin}}$ has been found to be suppressed by 1% impurities on account the decrease in the mean free path of magnetic excitations, suggesting that $κ_{\mathrm{spin}}$ is expected to be enhanced in 2D quantum spin systems such as Ba$_2$Cu$_3$O$_4$Cl$_2$ by reducing the amount of impurities in a single crystal. Moreover, it has concluded that the frustration between CuA$^{2+}$ and CuB$^{2+}$ spins little affects the existence of $κ_{\mathrm{spin}}$.
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Submitted 15 December, 2021;
originally announced December 2021.
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Molecular beam deposition of a new layered pnictide with distorted Sb square nets
Authors:
M. Ohno,
M. Uchida,
Y. Nakazawa,
S. Sato,
M. Kriener,
A. Miyake,
M. Tokunaga,
Y. Taguchi,
M. Kawasaki
Abstract:
While the family of layered pnictides $ABX_2$ ($A$ : rare or alkaline earth metals, $B$ : transition metals, $X$ : Sb/Bi) can host Dirac dispersions based on Sb/Bi square nets, nearly half of them has not been synthesized yet for possible combinations of the $A$ and $B$ cations. Here we report the fabrication of EuCdSb$_{\mathrm{2}}$ with the largest $B$-site ionic radius, which is stabilized for…
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While the family of layered pnictides $ABX_2$ ($A$ : rare or alkaline earth metals, $B$ : transition metals, $X$ : Sb/Bi) can host Dirac dispersions based on Sb/Bi square nets, nearly half of them has not been synthesized yet for possible combinations of the $A$ and $B$ cations. Here we report the fabrication of EuCdSb$_{\mathrm{2}}$ with the largest $B$-site ionic radius, which is stabilized for the first time in thin film form by molecular beam deposition. EuCdSb$_{\mathrm{2}}$ crystallizes in an orthorhombic $Pnma$ structure and exhibits antiferromagnetic ordering of the Eu magnetic moments at $T_\mathrm{N}=15$K. Our successful growth will be an important step for further exploring novel Dirac materials using film techniques.
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Submitted 3 June, 2021;
originally announced June 2021.
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Quantum transport observed in films of magnetic topological semimetal EuSb$_2$
Authors:
Mizuki Ohno,
Masaki Uchida,
Ryosuke Kurihara,
Susumu Minami,
Yusuke Nakazawa,
Shin Sato,
Markus Kriener,
Motoaki Hirayama,
Atsushi Miyake,
Yasujiro Taguchi,
Ryotaro Arita,
Masashi Tokunaga,
Masashi Kawasaki
Abstract:
We report fabrication of EuSb$_2$ single-crystalline films and investigation of their quantum transport. First-principles calculations demonstrate that EuSb$_2$ is a magnetic topological nodal-line semimetal protected by nonsymmorphic symmetry. Observed Shubnikov-de Haas oscillations with multiple frequency components exhibit small effective masses and two-dimensional field-angle dependence even i…
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We report fabrication of EuSb$_2$ single-crystalline films and investigation of their quantum transport. First-principles calculations demonstrate that EuSb$_2$ is a magnetic topological nodal-line semimetal protected by nonsymmorphic symmetry. Observed Shubnikov-de Haas oscillations with multiple frequency components exhibit small effective masses and two-dimensional field-angle dependence even in a 250 nm thick film, further suggesting possible contributions of surface states. This finding of the high-mobility magnetic topological semimetal will trigger further investigation of exotic quantum transport phenomena by controlling magnetic order in topological semimetal films.
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Submitted 26 April, 2021; v1 submitted 5 April, 2021;
originally announced April 2021.
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Enhancement of spin-orbit coupling in Dirac semimetal Cd$_{3}$As$_{2}$ films by Sb-doping
Authors:
Yusuke Nakazawa,
Masaki Uchida,
Shinichi Nishihaya,
Mizuki Ohno,
Shin Sato,
Masashi Kawasaki
Abstract:
We present a study on magnetotransport in films of the topological Dirac semimetal Cd$_{3}$As$_{2}$ doped with Sb grown by molecular beam epitaxy. In our weak antilocalization analysis, we find a significant enhancement of the spin-orbit scattering rate, indicating that Sb doping leads to a strong increase of the pristine band-inversion energy. We discuss possible origins of this large enhancement…
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We present a study on magnetotransport in films of the topological Dirac semimetal Cd$_{3}$As$_{2}$ doped with Sb grown by molecular beam epitaxy. In our weak antilocalization analysis, we find a significant enhancement of the spin-orbit scattering rate, indicating that Sb doping leads to a strong increase of the pristine band-inversion energy. We discuss possible origins of this large enhancement by comparing Sb-doped Cd$_{3}$As$_{2}$ with other compound semiconductors. Sb-doped Cd$_{3}$As$_{2}$ will be a suitable system for further investigations and functionalization of topological Dirac semimetals.
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Submitted 10 January, 2021;
originally announced January 2021.
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Thermal Conductivity and Spin State of the Spin Diamond-Chain System Azurite Cu3(CO3)2(OH)2
Authors:
Yuta Hagiya,
Takayuki Kawamata,
Koki Naruse,
Masumi Ohno,
Yoshiharu Matsuoka,
Hiroki Sudo,
Hideki Nagasawa,
Hikomitu Kikuchi,
Takahiko Sasaki,
Yoji Koike
Abstract:
In order to investigate the spin state of azurite, Cu3(CO3)2(OH)2, we have measured the thermal conductivity along the c-axis, $κ$c, perpendicular to the spin diamond-chains. It has been found that the temperature dependence of $κ$c shows a broad peak at ~ 100 K, which is explained as being due to the strong phonon-scattering by the strong spin-fluctuation owing to the spin frustration at low temp…
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In order to investigate the spin state of azurite, Cu3(CO3)2(OH)2, we have measured the thermal conductivity along the c-axis, $κ$c, perpendicular to the spin diamond-chains. It has been found that the temperature dependence of $κ$c shows a broad peak at ~ 100 K, which is explained as being due to the strong phonon-scattering by the strong spin-fluctuation owing to the spin frustration at low temperatures below ~ 100 K. Furthermore, it has been found that the temperature dependence of $κ$c shows another peak at low temperatures below 20 K and that $κ$c is suppressed by the application of magnetic field along the c-axis at low temperatures below ~ 35 K. In high magnetic fields above ~ 8 T at low temperatures below ~ 6 K, it has been found that $κ$c increases with increasing field. The present results have indicated that both spin-singlet dimers with a spin gap of ~ 35 K and antiferromagnetically correlated spin-chains with the antiferromagnetic exchange interaction of ~ 5.4 K are formed at low temperatures, which is consistent with the recent conclusion by Jeschke et al. [Phys. Rev. Lett. 106, 217201 (2011)] that the ground state of spins in azurite in zero field is a spin-fluid one. In addition, a new quantum critical line in magnetic fields at temperatures above 3 K has been proposed to exist.
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Submitted 29 December, 2015;
originally announced December 2015.
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Thermal Conductivity of the S = 1/2 Quasi-One-Dimensional Ferromagnetic Spin System CsCuCl3
Authors:
T. Kawamata,
H. Sudo,
Y. Matsuoka,
K. Naruse,
M. Ohno,
T. Sasaki,
Y. Koike
Abstract:
We have measured the thermal conductivity along the c-axis, \k{appa}||c, parallel to ferromagnetic spin-chains of single crystals of the S = 1/2 quasi-one-dimensional spin system CsCuCl3 in magnetic fields up to 14 T, in order to investigate the thermal conductivity due to spins, \k{appa}spin, and the change of thermal conductivity corresponding to the change of the spin state. In the temperature…
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We have measured the thermal conductivity along the c-axis, \k{appa}||c, parallel to ferromagnetic spin-chains of single crystals of the S = 1/2 quasi-one-dimensional spin system CsCuCl3 in magnetic fields up to 14 T, in order to investigate the thermal conductivity due to spins, \k{appa}spin, and the change of thermal conductivity corresponding to the change of the spin state. In the temperature dependence of \k{appa}||c, no contribution of \k{appa}spin has been observed, while a dip has been observed at the antiferromagnetic phase transition temperature, TN. Furthermore, it has been found that \k{appa}||c at a low temperature of 5.1 K below TN changes with increasing field perpendicular to the c-axis in good correspondence to the field-induced change of the spin state.
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Submitted 29 October, 2015;
originally announced October 2015.
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Thermal Conductivity in the Triangular-Lattice Antiferromagnet Ba3CoSb2O9
Authors:
K. Naruse,
T. Kawamata,
M. Ohno,
Y. Matsuoka,
H. Sudo,
H. Nagasawa,
Y. Hagiya,
T. Sasaki,
Y. Koike
Abstract:
We have measured the thermal conductivity in the ab-plane, $κ$ab, and along the c-axis, $κ$c, of single crystals of the S = 1/2 triangular-lattice antiferromagnet Ba3CoSb2O9 in zero field and magnetic fields. In zero field, it has been found that both $κ$ab and $κ$c show a similar broad peak around 40 K, suggesting that the thermal conductivity due to phonons is dominant in this compound and that…
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We have measured the thermal conductivity in the ab-plane, $κ$ab, and along the c-axis, $κ$c, of single crystals of the S = 1/2 triangular-lattice antiferromagnet Ba3CoSb2O9 in zero field and magnetic fields. In zero field, it has been found that both $κ$ab and $κ$c show a similar broad peak around 40 K, suggesting that the thermal conductivity due to phonons is dominant in this compound and that the mean free path of phonons is suppressed so much by strong magnetic-fluctuations due to the magnetic frustration. It has also been found that both $κ$ab and $κ$c show a kink at the antiferromagnetic transition temperature TN. In magnetic fields parallel to the ab-plane up to 14 T, magnetic-field dependences of both $κ$ab and $κ$c at temperatures below and above TN have been found to be understood taking into account the phonon-magnon scattering in the so-called 120$°$ structure phase and the up-up-down (UUD) phase, while the minima of $κ$ab and $κ$c observed in the middle of the UUD phase have not been understood. This suggests the occurrence of some change of the magnetic state in the middle of the UUD phase.
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Submitted 29 October, 2015;
originally announced October 2015.
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Thermal Conductivity in the Frustrated Two-Leg Spin-Ladder System BiCu2PO6
Authors:
H. Nagasawa,
T. Kawamata,
K. Naruse,
M. Ohno,
Y. Matsuoka,
H. Sudo,
Y. Hagiya,
M. Fujita,
T. Sasaki,
Y. Koike
Abstract:
We have measured temperature and magnetic-field dependences of the thermal conductivity of single crystals of the frustrated two-leg spin-ladder system BiCu2PO6 in magnetic fields up to 14 T. It has been found that the temperature dependence of the thermal conductivity along every principal crystallographic axis shows two peaks in zero field but that the magnitude of the thermal conductivity along…
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We have measured temperature and magnetic-field dependences of the thermal conductivity of single crystals of the frustrated two-leg spin-ladder system BiCu2PO6 in magnetic fields up to 14 T. It has been found that the temperature dependence of the thermal conductivity along every principal crystallographic axis shows two peaks in zero field but that the magnitude of the thermal conductivity along the b-axis parallel to spin ladders, $κ$b, is significantly larger than those of the thermal conductivity along the a-axis, $κ$a, and along the c-axis, $κ$c, at high temperatures above 7 K. These results suggest that the thermal conductivity due to spins probably exists only in $κ$b. Furthermore, it has been found that both magnetic-field dependences of $κ$a and $κ$b at 3 K show kinks at ~ 7 T and ~ 10 T, where the spin state may change.
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Submitted 29 October, 2015;
originally announced October 2015.
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Magnetic State of the Geometrically Frustrated Quasi-One-Dimensional Spin System Cu$_3$Mo$_2$O$_9$ Studied by Thermal Conductivity
Authors:
Koki Naruse,
Takayuki Kawamata,
Masumi Ohno,
Yoshiharu Matsuoka,
Masashi Hase,
Haruhiko Kuroe,
Tomoyuki Sekine,
Kunihiko Oka,
Toshimitsu Ito,
Hiroshi Eisaki,
Takahiko Sasaki,
Yoji Koike
Abstract:
We have measured the thermal conductivity of the geometrically frustrated quasi-onedimensional spin system Cu$_3$Mo$_2$O$_9$ in magnetic fields. A contribution of the thermal conductivity due to spins has been observed in the thermal conductivity along the spin chains. The thermal conductivity due to phonons, $κ_{\rm phonon}$, has been found to decrease by the application of a magnetic field, whic…
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We have measured the thermal conductivity of the geometrically frustrated quasi-onedimensional spin system Cu$_3$Mo$_2$O$_9$ in magnetic fields. A contribution of the thermal conductivity due to spins has been observed in the thermal conductivity along the spin chains. The thermal conductivity due to phonons, $κ_{\rm phonon}$, has been found to decrease by the application of a magnetic field, which has been explained as being due to the reduction in the spin gap originating from the spin-singlet dimers. Moreover, it has been found that $κ_{\rm phonon}$ increases with increasing field in high fields above ~7 T at low temperatures. This suggests the existence of a novel field-induced spin state and is discussed in terms of the possible spin-chirality ordering in a frustrated Mott insulator.
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Submitted 29 October, 2015;
originally announced October 2015.
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Observation of the Thermal Conductivity due to Spins in the One-Dimensional Antiferromagnetic Ising-Like Spin System ACoX3 (A = Rb, Cs; X = Cl, Br)
Authors:
Yoshiharu Matsuoka,
Takayuki Kawamata,
Koki Naruse,
Masumi Ohno,
Yoichi Nishiwaki,
Tetsuya Kato,
Takahiko Sasaki,
Yoji Koike
Abstract:
Thermal conductivity measurements have been carried out for single crystals of the onedimensional (1D) antiferromagnetic (AF) Ising-like spin system ACoX3 (A = Rb, Cs; X = Cl, Br). A shoulder originating from the thermal conductivity due to spin excitations, \k{appa}?spin, has been observed around 60 K in the temperature dependence of the thermal conductivity along the c-axis parallel to spin chai…
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Thermal conductivity measurements have been carried out for single crystals of the onedimensional (1D) antiferromagnetic (AF) Ising-like spin system ACoX3 (A = Rb, Cs; X = Cl, Br). A shoulder originating from the thermal conductivity due to spin excitations, \k{appa}?spin, has been observed around 60 K in the temperature dependence of the thermal conductivity along the c-axis parallel to spin chains for every ACoX3. To our knowledge, this is the first observation of ?\k{appa}spin in 1D AF Ising-like spin systems. It has been found that the magnitude of ?\k{appa}spin in ACoX3 is a little smaller than those in 1D AF Heisenberg spin systems. The reason is discussed in terms of the Heisenberg-like character in ACoX3.
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Submitted 13 May, 2014;
originally announced May 2014.
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Thermal conductivity and annealing effects in the iron-based superconductor FeSe$_{0.3}$Te$_{0.7}$
Authors:
Masumi Ohno,
Takayuki Kawamata,
Takashi Noji,
Koki Naruse,
Yoshiharu Matsuoka,
Tadashi Adachi,
Terukazu Nishizaki,
Takahiko Sasaki,
Yoji Koike
Abstract:
Thermal conductivity measurements in magnetic fields have been carried out for FeSe$_{0.3}$Te$_{0.7}$ single crystals as-grown and annealed at 400 {\degree}C for 100 h in vacuum ($\sim$ 10$^{-4}$ Pa). It has been found that the thermal conductivity in the {\it ab}-plane, {\kab}, of the annealed crystal shows an enhancement at low temperatures just below the superconducting transition temperature,…
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Thermal conductivity measurements in magnetic fields have been carried out for FeSe$_{0.3}$Te$_{0.7}$ single crystals as-grown and annealed at 400 {\degree}C for 100 h in vacuum ($\sim$ 10$^{-4}$ Pa). It has been found that the thermal conductivity in the {\it ab}-plane, {\kab}, of the annealed crystal shows an enhancement at low temperatures just below the superconducting transition temperature, {\tc}, owing to the thermal conductivity due to quasiparticles, while {\kab} of the as-grown crystal does not. This suggests that FeSe$_{1-x}$Te$_{x}$ is a strongly correlated electron system. It has also been found that both the degree of the enhancement of {\kab} just below {\tc} and the behavior of the suppression of {\kab} by the application of magnetic field for the annealed crystal depend on the thickness of the crystal. These results indicate that bulk superconductivity is absent in the as-grown crystal, appears only in the surface area in the annealed-thick crystal and appears in the almost whole region in the annealed-thin crystal. It has been concluded that the excess Fe included in the as-grown crystal is removed from the surface through the vacuum-annealing.
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Submitted 11 June, 2013;
originally announced June 2013.
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Datta-Das type spin-field effect transistor in non-ballistic regime
Authors:
Munekazu Ohno,
Kanji Yoh
Abstract:
It is revealed that in spin helix state of (001) quantum well system, strong suppression of D'yakonov-Perel' spin relaxation process occurs by an interplay between Rashba and Dresselhaus couplings over a wide range of Rashba coupling strength. Contrary to common belief in early works, this leads to the finding that Datta-Das type spin-field effect transistor is actually applicable to more realis…
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It is revealed that in spin helix state of (001) quantum well system, strong suppression of D'yakonov-Perel' spin relaxation process occurs by an interplay between Rashba and Dresselhaus couplings over a wide range of Rashba coupling strength. Contrary to common belief in early works, this leads to the finding that Datta-Das type spin-field effect transistor is actually applicable to more realistic non-ballistic transport regime in two dimensional electron gas system.
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Submitted 25 June, 2007;
originally announced June 2007.
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Effect of Nonmagnetic Impurity in Nearly Antiferromagnetic Fermi Liquid: Magnetic Correlations and Transport Phenomena
Authors:
Hiroshi Kontani,
Masanori Ohno
Abstract:
In nearly antiferromagnetic (AF) metals such as high-Tc superconductors (HTSC's), a single nonmagnetic impurity frequently causes nontrivial widespread change of the electronic states. To elucidate this long-standing issue, we study a Hubbard model with a strong onsite impurity potential based on an improved fluctuation-exchange (FLEX) approximation, which we call the GV^I-FLEX method. This mode…
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In nearly antiferromagnetic (AF) metals such as high-Tc superconductors (HTSC's), a single nonmagnetic impurity frequently causes nontrivial widespread change of the electronic states. To elucidate this long-standing issue, we study a Hubbard model with a strong onsite impurity potential based on an improved fluctuation-exchange (FLEX) approximation, which we call the GV^I-FLEX method. This model corresponds to the HTSC with dilute nonmagnetic impurity concentration. We find that (i) both local and staggered susceptibilities are strongly enhanced around the impurity. By this reason, (ii) the quasiparticle lifetime as well as the local density of states (DOS) are strongly suppressed in a wide area around the impurity (like a Swiss cheese hole), which causes the ``huge residual resistivity'' beyond the s-wave unitary scattering limit. We stress that the excess quasiparticle damping rate caused by impurities has strong momentum-dependence due to non-s-wave scatterings induced by many-body effects, so the structure of the ``hot spot/cold spot'' in the host system persists against impurity doping. This result could be examined by the ARPES measurements. In addition, (iii) only a few percent of impurities can causes a ``Kondo-like'' upturn of resistivity ($dρ/dT<0$) at low temperatures when the system is very close to the AF quantum critical point (QCP). The results (i)-(iii) obtained in the present study, which cannot be derived by the simple FLEX approximation, naturally explains the main impurity effects in HTSC's. We also discuss the impurity effect in heavy fermion systems and organic superconductors.
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Submitted 24 July, 2006;
originally announced July 2006.
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Nonlocal Effect of Local Nonmagnetic Impurity in High-Tc Superconductors: Induced Local Moment and Huge Residual Resistivity
Authors:
Hiroshi Kontani,
Masanori Ohno
Abstract:
We study a Hubbard model with a strong onsite impurity potential based on an improved fluctuation-exchange (FLEX) approximation, which we call the GVI-FLEX method. We find that (i) both local and staggered susceptibilities are strongly enhanced around the impurity. By this reason, (ii) the quasiparticle lifetime as well as the local density of states (DOS) are strongly suppressed in a wide area…
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We study a Hubbard model with a strong onsite impurity potential based on an improved fluctuation-exchange (FLEX) approximation, which we call the GVI-FLEX method. We find that (i) both local and staggered susceptibilities are strongly enhanced around the impurity. By this reason, (ii) the quasiparticle lifetime as well as the local density of states (DOS) are strongly suppressed in a wide area around the impurity (like a Swiss cheese hole), which causes the ``huge residual resistivity'' beyond the s-wave unitary scattering value. These results by the GVI method naturally explains the various impurity effects in HTSC's in a unified way, which had been a long-standing theoretical problem.
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Submitted 1 July, 2006;
originally announced July 2006.
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Intermediate states of superconducting thermometers for x-ray microcalorimeters
Authors:
H. Pressler,
M. Koike,
M. Ohkubo,
D. Fukuda,
Y. Noguchi,
M. Ohno,
H. Takahashi,
M. Nakazawa
Abstract:
Intermediate states near normal-superconducting transition at ~100mK, important for a sensitive thermometer in x-ray calorimetry, have been studied by an imaging technique based on Low Temperature Scanning Synchrotron Microscopy (LTSSM). In conjunction with iridium superconducting transition-edge sensors operating in electrothermal feedback mode, the LTSSM visualizations reveal that a normal-sup…
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Intermediate states near normal-superconducting transition at ~100mK, important for a sensitive thermometer in x-ray calorimetry, have been studied by an imaging technique based on Low Temperature Scanning Synchrotron Microscopy (LTSSM). In conjunction with iridium superconducting transition-edge sensors operating in electrothermal feedback mode, the LTSSM visualizations reveal that a normal-superconducting phase separation takes place in the actual intermediate states.
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Submitted 2 May, 2002;
originally announced May 2002.