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Ultrafast spin-resolved spectroscopy reveals dominant exciton dynamics in conducting polymer polyaniline
Authors:
Soonyoung Cha,
Yoochan Hong,
Jaemoon Yang,
Inhee Maeng,
Seung Jae Oh,
Kiyoung Jeong,
Jin-Suck Suh,
Seungjoo Haam,
Yong-Min Huh,
Hyunyong Choi
Abstract:
The conducting polymer polyaniline (PANI) has a wide range of optoelectronic applications due to its unique electronic and optical characteristics. Although extensive works have been performed to understand the equilibrium properties, the nature of the charge type that governs its non-equilibrium optical response has been barely understood; a number of studies have debated the nature of photo-gene…
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The conducting polymer polyaniline (PANI) has a wide range of optoelectronic applications due to its unique electronic and optical characteristics. Although extensive works have been performed to understand the equilibrium properties, the nature of the charge type that governs its non-equilibrium optical response has been barely understood; a number of studies have debated the nature of photo-generated charge type in PANI, specifically whether it is polaron or exciton based. Here, we report experimental evidence that the charge relaxation dynamics of PANI are dominated by excitons. Utilizing ultrafast spin-resolved pump-probe spectroscopy, we observed that PANI charge dynamics are strongly spin-polarized, exhibiting a spin Pauli-blocking effect. Investigations including both spin-independent and spindependent dynamics reveal that there is no spin-flip process involved in charge relaxation. This provides compelling evidence of an exciton-dominated photo-response in PANI.
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Submitted 10 September, 2013;
originally announced September 2013.
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Photoemission Study of Rare-Earth Ditelluride Compounds (ReTe_2 : Re = La, Pr, Sm, and Gd)
Authors:
Jaegwan Chung,
Junghwan Park,
J. G. Park,
Byung-Hee Choi,
S. J. Oh,
E. J. Cho,
H. D. Kim,
Y. S. Kwon
Abstract:
We studied the electronic structure of rare-earth ditelluride (ReTe_2 : Re = La, Pr, Sm, and Gd) using photoemission spectroscopy. From the x-ray photoelectron spectroscopy (XPS) study of the 3d core levels of rare-earth elements, we found that all the rare earth elements are trivalent. We have also made theoretical calculations using the Gunnarsson and Schoenhammer approximation and multiplet c…
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We studied the electronic structure of rare-earth ditelluride (ReTe_2 : Re = La, Pr, Sm, and Gd) using photoemission spectroscopy. From the x-ray photoelectron spectroscopy (XPS) study of the 3d core levels of rare-earth elements, we found that all the rare earth elements are trivalent. We have also made theoretical calculations using the Gunnarsson and Schoenhammer approximation and multiplet calculations for the rare earth elements to find that the La and Gd~3d peaks are well explained using our calculations. There is no considerable change in the line-shape of the Te~3d peaks depending on different rare earth elements. On ther other hand, valence band spectra studied with the ultraviolet photoelectron spectroscopy (UPS) show a small change in the Te p band depending on rare-earth elements. According to the UPS data, LaTe_2 has very low carrier density at the Fermi level while SmTe_2 and PrTe_2 show strongly metallic band structure effects near the Fermi level.
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Submitted 27 October, 1999;
originally announced October 1999.
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Universal scaling of Hall resistivity in clean and moderately clean limits for Hg- and Tl-based superconductors
Authors:
W. N. Kang,
Wan-Seon Kim,
S. J. Oh,
Sung-Ik Lee,
D. H. Kim,
C. H. Choi,
H. -C. Ri,
C. W. Chu
Abstract:
The mixed-state Hall resistivity and the longitudinal resistivity in HgBa_{2}CaCu_{2}O_{6}, HgBa_{2}Ca_{2}Cu_{3}O_{8}, and Tl_{2}Ba_{2}CaCu_{2}O_{8} thin films have been investigated as functions of the magnetic field up to 18 T. We observe the universal scaling behavior between ρ_{xy} and ρ_{xx} in the regions of the clean and the moderately clean limit. The scaling exponent βis 1.9 in the clea…
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The mixed-state Hall resistivity and the longitudinal resistivity in HgBa_{2}CaCu_{2}O_{6}, HgBa_{2}Ca_{2}Cu_{3}O_{8}, and Tl_{2}Ba_{2}CaCu_{2}O_{8} thin films have been investigated as functions of the magnetic field up to 18 T. We observe the universal scaling behavior between ρ_{xy} and ρ_{xx} in the regions of the clean and the moderately clean limit. The scaling exponent βis 1.9 in the clean limit at high field and low temperature whereas βis 1.0 in the moderately clean limit at low field and high temperature, consistent with a theory based on the midgap states in the vortex cores. This finding implies that the Hall conductivity is also universal in Hg- and Tl-based superconductors.
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Submitted 14 May, 1999;
originally announced May 1999.
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Temperature-scaling behavior of the Hall conductivity for Hg-based superconducting thin films
Authors:
Wan-Seon Kim,
W. N. Kang,
S. J. Oh,
Mun-Seog Kim,
Yujoung Bai,
Sung-Ik Lee,
Chang Ho Choi,
H. -C. Ri
Abstract:
The Hall conductivities of HgBa_{2}CaCu_{2}O_{6+δ}and HgBa_{2}Ca_{2}Cu_{3}O_{8+δ} thin films are investigated for a magnetic field parallel to the c axis. The mixed-state Hall conductivity for these compounds is well described by σ_{xy}=C_{1}/H+C_{2}+C_{3}H. The prefactor C_1 shows a temperature dependence of the form C_1 = A(1-t)^n near T_c, where t=T/T_c is the reduced temperature. Contrary to…
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The Hall conductivities of HgBa_{2}CaCu_{2}O_{6+δ}and HgBa_{2}Ca_{2}Cu_{3}O_{8+δ} thin films are investigated for a magnetic field parallel to the c axis. The mixed-state Hall conductivity for these compounds is well described by σ_{xy}=C_{1}/H+C_{2}+C_{3}H. The prefactor C_1 shows a temperature dependence of the form C_1 = A(1-t)^n near T_c, where t=T/T_c is the reduced temperature. Contrary to the previous results, C_2 also follows a temperature-scaling behavior similar to that of the coefficient C_1. The observed value of n = 1.8 - 2.3 is comparable to the previously observed values for YBa_{2}Cu_{3}O_{7-δ} and La_{2-x}Sr_{x}CuO_{4}.
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Submitted 27 April, 1999;
originally announced April 1999.