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Collective Fluorescence of Graphene Quantum Dots on a surface
Authors:
Hugo Levy-Falk,
Suman Sarkar,
Thanh Trung Huynh,
Daniel Medina-Lopez,
Lauren Hurley,
Océane Capelle,
Muriel Bouttemy,
Gaëlle Trippé-Allard,
Stéphane Campidelli,
Loïc Rondin,
Elsa Cassette,
Emmanuelle Deleporte,
Jean-Sébastien Lauret
Abstract:
This study explores the organization of graphene quantum dots on the surface of monocrystalline halide perovskite. We show that graphene quantum dots tends to aggregate on the surface of perovskite unlike in solution or on other substrates, even at very low concentration of the initial solution that should yield single-molecule samples. Spectral analysis on small clusters shows a back-and-forth dy…
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This study explores the organization of graphene quantum dots on the surface of monocrystalline halide perovskite. We show that graphene quantum dots tends to aggregate on the surface of perovskite unlike in solution or on other substrates, even at very low concentration of the initial solution that should yield single-molecule samples. Spectral analysis on small clusters shows a back-and-forth dynamical transition between an uncoupled, monomer-like state, and an excimer state. Following this "dance" between states, a drastic one-way increase in fluorescence intensity combined with a shortening of the excited state lifetime has been observed on some clusters. This behavior is related to the emission of a collective state that may be a consequence of the dynamical organization of graphene quantum dots under illumination on the surface of the perovksite.
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Submitted 30 October, 2025; v1 submitted 30 July, 2025;
originally announced July 2025.
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Introducing new resonant soft x-ray scattering capability in SSRL
Authors:
Cheng-Tai Kuo,
Makoto Hashimoto,
Heemin Lee,
Tan Thanh Huynh,
Abraham Maciel,
Zina Zhang,
Dehong Zhang,
Benjamin Edwards,
Farzan Kazemifar,
Chi-Chang Kao,
Donghui Lu,
Jun-Sik Lee
Abstract:
Resonant soft X-ray scattering (RSXS) is a powerful technique for probing both spatial and electronic structures within solid-state systems. We present a newly developed RSXS capability at beamline 13-3 of the Stanford Synchrotron Radiation Lightsource (SSRL), designed to enhance materials science research. This advanced setup achieves a base sample temperature as low as 9.8 K combined with extens…
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Resonant soft X-ray scattering (RSXS) is a powerful technique for probing both spatial and electronic structures within solid-state systems. We present a newly developed RSXS capability at beamline 13-3 of the Stanford Synchrotron Radiation Lightsource (SSRL), designed to enhance materials science research. This advanced setup achieves a base sample temperature as low as 9.8 K combined with extensive angular motions (azimuthal φand flipping χ), enabling comprehensive exploration of reciprocal space. Two types of detectors, an Au/GaAsP Schottky photodiode and a CCD detector with over 95% quantum efficiency, are integrated to effectively capture scattered photons. Extensive testing has confirmed the enhanced functionality of this RSXS setup, including its temperature and angular performance. The versatility and effectiveness of the system have been demonstrated through studies of various materials, including superlattice heterostructures and high-temperature superconductors.
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Submitted 6 June, 2025; v1 submitted 9 January, 2025;
originally announced January 2025.
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Dynamics of magnetoelastic robots in water-saturated granular beds
Authors:
Animesh Biswas,
Trinh Huynh,
Balaram Desai,
Max Moss,
Arshad Kudrolli
Abstract:
We investigate the dynamics of a magnetoelastic robot with a dipolar magnetic head and a slender elastic body as it performs undulatory strokes and burrows through water-saturated granular beds. The robot is actuated by an oscillating magnetic field and moves forward when the stroke amplitude increases above a critical threshold. By visualizing the medium, we show that the undulating body fluidize…
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We investigate the dynamics of a magnetoelastic robot with a dipolar magnetic head and a slender elastic body as it performs undulatory strokes and burrows through water-saturated granular beds. The robot is actuated by an oscillating magnetic field and moves forward when the stroke amplitude increases above a critical threshold. By visualizing the medium, we show that the undulating body fluidizes the bed, resulting in the appearance of a dynamic burrow, which rapidly closes in behind the moving robot as the medium loses energy. We investigate the applicability of Lighthill's elongated body theory of fish locomotion, and estimate the contribution of thrust generated by the undulating body and the drag incorporating the granular volume fraction-dependent effective viscosity of the medium. The projected speeds are found to be consistent with the measured speeds over a range of frequencies and amplitudes above the onset of forward motion. However, systematic deviations are found to grow with increasing driving, pointing to a need for further sophisticated modelling of the medium-structure interactions.
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Submitted 28 September, 2023; v1 submitted 4 May, 2023;
originally announced May 2023.
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Density filamentation nonlinearly driven by the Weibel instability in relativistic beam plasmas
Authors:
Cong Tuan Huynh,
Chang-Mo Ryu,
Chulmin Kim
Abstract:
Density filamentation has been observed in many beam-plasma simulations and experiments. Because current filamentation is a pure transverse mode, charge density filamentation cannot be produced directly by the current filamentation process. To explain this phenomenon, several mechanisms are proposed such as the coupling of the Weibel instability to the two-stream instability, coupling to the Langm…
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Density filamentation has been observed in many beam-plasma simulations and experiments. Because current filamentation is a pure transverse mode, charge density filamentation cannot be produced directly by the current filamentation process. To explain this phenomenon, several mechanisms are proposed such as the coupling of the Weibel instability to the two-stream instability, coupling to the Langmuir wave, differences in thermal velocities between the beam and return currents, the magnetic pressure gradient force, etc. In this paper, it is shown that the gradient of the Lorentz factor can, in fact, represent the nonlinear behavior of a plasma fluid and further that the nonuniform Lorentz factor distribution can give rise to electrostatic fields and density filaments. Simulation results together with theoretical analyses are presented.
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Submitted 13 May, 2022; v1 submitted 8 May, 2022;
originally announced May 2022.
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Aerial mucosalivary droplet dispersal distributions with implications for disease mitigation
Authors:
Brian Chang,
Ram Sudhir Sharma,
Trinh Huynh,
Arshad Kudrolli
Abstract:
We investigate mucosalivary dispersal and deposition on horizontal surfaces corresponding to human exhalations with physical experiments under still-air conditions. Synthetic fluorescence tagged sprays with size and speed distributions comparable to human sneezes are observed with high-speed imaging. We show that while some larger droplets follow parabolic trajectories, smaller droplets stay aloft…
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We investigate mucosalivary dispersal and deposition on horizontal surfaces corresponding to human exhalations with physical experiments under still-air conditions. Synthetic fluorescence tagged sprays with size and speed distributions comparable to human sneezes are observed with high-speed imaging. We show that while some larger droplets follow parabolic trajectories, smaller droplets stay aloft for several seconds and settle slowly with speeds consistent with a buoyant cloud dynamics model. The net deposition distribution is observed to become correspondingly broader as the source height $H$ is increased, ranging from sitting at a table to standing upright. We find that the deposited mucosaliva decays exponentially in front of the source, after peaking at distance $x = 0.71$\,m when $H = 0.5$\,m, and $x = 0.56$\,m when $H=1.5$\,m, with standard deviations $\approx 0.5$\,m. Greater than 99\% of the mucosaliva is deposited within $x = 2$\,m, with faster landing times {\em further} from the source. We then demonstrate that a standard nose and mouth mask reduces the mucosaliva dispersed by a factor of at least a hundred compared to the peaks recorded when unmasked.
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Submitted 18 December, 2020;
originally announced December 2020.
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Orbital-hybridization-created optical excitations in Li2GeO3
Authors:
Vo Khuong Dien,
Hai Duong Pham,
Ngoc Thanh Thuy Tran,
Nguyen Thi Han,
Thi My Duyen Huynh,
Thi Dieu Hien Nguyen,
Ming Fa-Lin
Abstract:
Li2GeO3, a ternary electrolyte compound of Li+-based battery, presents the unusual essential properties. The main features are thoroughly explored from the first-principles calculations. The concise pictures, the critical orbital hybridizations in Li-O and Ge-O bonds, are clearly examined through the optimal Moire superlattice, the atom-dominated electronic energy spectrum, the spatial charge dens…
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Li2GeO3, a ternary electrolyte compound of Li+-based battery, presents the unusual essential properties. The main features are thoroughly explored from the first-principles calculations. The concise pictures, the critical orbital hybridizations in Li-O and Ge-O bonds, are clearly examined through the optimal Moire superlattice, the atom-dominated electronic energy spectrum, the spatial charge densities, the atom- and orbital-decomposed van Hove singularities, and the strong optical responses. The unusual optical transitions cover the red-shift optical gap, 16 frequency-dependent absorption structures and the most prominent plasmon mode in terms of the dielectric functions, energy loss functions, reflectance spectra, and absorption coefficients. Optical excitations, depending on the directions of electric polarization, are strongly affected by the excitonic effects. The close combinations of electronic and optical properties can identify a significant orbital hybridization for each available excitation channel. The developed theoretical framework will be very useful in fully understanding the diverse phenomena of cathode/electrolyte/anode materials in ion-based batteries.
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Submitted 7 October, 2020; v1 submitted 4 September, 2020;
originally announced September 2020.
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Geometric and Electronic Properties of Li$_2$GeO$_3$
Authors:
Vo Khuong Dien,
Nguyen Thi Han,
Thi Dieu Hien Nguyen,
Thi My Duyen Huynh,
Hai Duong Pham,
Ming-Fa Lin
Abstract:
The 3D ternary Li$_2$GeO$_3$ compound, which could serve as the electrolyte material in Li+-based batteries, exhibits an unusual lattice symmetry (orthorhombic crystal), band structure, charge density distribution and density of states. The essential properties are fully explored through the first-principles method. In the delicate calculations and analyses, the main features of atom-dominated ele…
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The 3D ternary Li$_2$GeO$_3$ compound, which could serve as the electrolyte material in Li+-based batteries, exhibits an unusual lattice symmetry (orthorhombic crystal), band structure, charge density distribution and density of states. The essential properties are fully explored through the first-principles method. In the delicate calculations and analyses, the main features of atom-dominated electronic energy spectrum, space-charge distribution, and atom-/orbital-projected density of states are suffi$cient to identify the critical multi-orbital hybridizations of the chemical bonds: 2s-(2p$_x, 2p$_y$, 2p$_z$) and (4s, 4p$_x$, 4p$_y$, 4p$_z$)-(2s, 2p$_x$, 2p$_y$, 2p$_z$), respectively, for Li-O and Ge-O. This system possesses a large indirect gap of Eg = 3.77 eV. There exist a lot of significant covalent bonds, with an obvious non-uniformity and anisotropy. In addition, spin-dependent magnetic configurations are completely absent. The theoretical framework could be developed to investigate the important features of anode and cathode materials related to lithium oxide compounds.
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Submitted 4 September, 2020;
originally announced September 2020.
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Kinetics of charge carrier recombination in beta-Ga2O3 crystals
Authors:
T. T. Huynh,
L. L. C. Lem,
A. Kuramata,
M. R. Phillips,
C. Ton-That
Abstract:
Cathodoluminescence spectra were measured to determine the characteristics of luminescence bands and carrier dynamics in beta-Ga2O3 bulk single crystals. The CL emission was found to be dominated by a broad UV emission peaked at 3.40 eV, which exhibits strong quenching with increasing temperature; however, its spectral shape and energy position remain virtually unchanged. We observed a super-linea…
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Cathodoluminescence spectra were measured to determine the characteristics of luminescence bands and carrier dynamics in beta-Ga2O3 bulk single crystals. The CL emission was found to be dominated by a broad UV emission peaked at 3.40 eV, which exhibits strong quenching with increasing temperature; however, its spectral shape and energy position remain virtually unchanged. We observed a super-linear increase of CL intensity with excitation density; this kinetics of carrier recombination can be explained in terms of carrier trapping and charge transfer at Fe impurity centres. The temperature-dependent properties of this UV band are consistent with weakly bound electrons in self-trapped excitons with an activation energy of 48 +/- 10 meV. In addition to the self-trapped exciton emission, a blue luminescence (BL) band is shown to be related to a donor-like defect, which increases significantly in concentration after hydrogen plasma annealing. The point defect responsible for the BL, likely an oxygen vacancy, is strongly coupled to the lattice exhibiting a Huang-Rhys factor of ~ 7.3.
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Submitted 27 May, 2020;
originally announced May 2020.
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Red Luminescence in H-doped beta-Ga2O3
Authors:
Thanh Tung Huynh,
Ekaterine Chikoidze,
Curtis P. Irvine,
Muhammad Zakria,
Yves Dumont,
Ferechteh H. Teherani,
Eric V. Sandana,
Philippe Bove,
David J. Rogers,
Matthew R. Phillips,
Cuong Ton-That
Abstract:
The effects of hydrogen incorporation into beta-Ga2O3 thin films have been investigated by chemical, electrical and optical characterization techniques. Hydrogen incorporation was achieved by remote plasma doping without any structural alterations of the film; however, X-ray photoemission reveals major changes in the oxygen chemical environment. Depth-resolved cathodoluminescence (CL) reveals that…
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The effects of hydrogen incorporation into beta-Ga2O3 thin films have been investigated by chemical, electrical and optical characterization techniques. Hydrogen incorporation was achieved by remote plasma doping without any structural alterations of the film; however, X-ray photoemission reveals major changes in the oxygen chemical environment. Depth-resolved cathodoluminescence (CL) reveals that the near-surface region of the H-doped Ga2O3 film exhibits a distinct red luminescence (RL) band at 1.9 eV. The emergence of the H-related RL band is accompanied by an enhancement in the electrical conductivity of the film by an order of magnitude. Temperature-resolved CL points to the formation of abundant H-related donors with a binding energy of 28 +/- 4 meV. The RL emission is attributed to shallow donor-deep acceptor pair recombination, where the acceptor is a VGa-H complex and the shallow donor is interstitial H. The binding energy of the VGa-H complex, based on our experimental considerations, is consistent with the computational results by Varley et al [J. Phys.: Condens. Matter, 23, 334212, 2011].
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Submitted 15 July, 2020; v1 submitted 27 May, 2020;
originally announced May 2020.
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Deep Learning for The Inverse Design of Mid-infrared Graphene Plasmons
Authors:
Anh D. Phan,
Cuong V. Nguyen,
Pham T. Linh,
Tran V. Huynh,
Vu D. Lam,
Anh-Tuan Le
Abstract:
We theoretically investigate the plasmonic properties of mid-infrared graphene-based metamaterials and apply deep learning of a neural network for the inverse design. These artificial structures have square periodic arrays of graphene plasmonic resonators deposited on dielectric thin films. Optical spectra vary significantly with changes in structural parameters. Our numerical results are in accor…
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We theoretically investigate the plasmonic properties of mid-infrared graphene-based metamaterials and apply deep learning of a neural network for the inverse design. These artificial structures have square periodic arrays of graphene plasmonic resonators deposited on dielectric thin films. Optical spectra vary significantly with changes in structural parameters. Our numerical results are in accordance with previous experiments. Then, the theoretical approach is employed to generate data for training and testing deep neural networks. By merging the pre-trained neural network with the inverse network, we implement calculations for inverse design of the graphene-based metameterials. We also discuss the limitation of the data-driven approach.
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Submitted 19 February, 2020; v1 submitted 28 November, 2019;
originally announced November 2019.
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Hydrostatic pressure effects on the electrical transport properties of Pr0.5Sr0.5MnO3
Authors:
F. J. Rueckert,
M. Steiger,
B. K. Davis,
T. Huynh,
J. J. Neumeier,
M. S. Torikachvili
Abstract:
We studied single-crystalline Pr0.5Sr0.5MnO3 by means of measurements of magnetic susceptibility and specific heat at ambient pressure (P), and electrical resistivity (r) in hydrostatic pressures up to 2 GPa. This material displays ferromagnetic (FM) order, with Curie temperature TC ~ 255 K. A crystallographic transformation from I4/mcm to Fmmm is accompanied by the onset of antiferromagnetism (…
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We studied single-crystalline Pr0.5Sr0.5MnO3 by means of measurements of magnetic susceptibility and specific heat at ambient pressure (P), and electrical resistivity (r) in hydrostatic pressures up to 2 GPa. This material displays ferromagnetic (FM) order, with Curie temperature TC ~ 255 K. A crystallographic transformation from I4/mcm to Fmmm is accompanied by the onset of antiferromagnetism (AFM), with Neel temperature TN ~ 161 K. The effect of pressure is to lower TC, and raise TN at the approximate rates of -3.2 K/GPa, and 14.2 K/GPa, respectively. Although the value of TN increases with P, due to the enhancement of the superexchange interactions, the AFM-Fmmm state is progressively suppressed, as pressure stabilizes the FM-I4/mcm phase to lower temperatures. The r vs T data suggest that the AFM phase should be completely suppressed near 2.4 GPa.
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Submitted 29 September, 2007;
originally announced October 2007.