Showing 1–50 of 130 results for author: Jang, H

Sublattice-resolved coherent phonon dynamics in charge density waves

Authors: Kyoung Hun Oh, Honglie Ning, Zongqi Shen, Yifan Su, Jack Maier, Gyeongbo Kang, Hyeongi Choi, Dong Wu, Qiaomei Liu, Hyun-Woo J. Kim, Seunghyeok Ha, Jaehwon Kim, Byungjune Lee, B. J. Kim, N. L. Wang, Yao Wang, Hoyoung Jang, Nuh Gedik

Abstract: Phonons govern fundamental material properties and play a central role in various electronic phase transitions. Coherent driving of specific phonon modes enables on-demand phase control, motivating sublattice-resolved identification of real-space phonon motions. Yet experimentally resolving these motions remains challenging, limiting precise phonon-based control. Here, we introduce a dynamical pro… ▽ More Phonons govern fundamental material properties and play a central role in various electronic phase transitions. Coherent driving of specific phonon modes enables on-demand phase control, motivating sublattice-resolved identification of real-space phonon motions. Yet experimentally resolving these motions remains challenging, limiting precise phonon-based control. Here, we introduce a dynamical protocol to track element-resolved phonon dynamics in the charge density wave material EuTe4, in which the dominant Te-sublattice charge order is accompanied by a previously unreported Eu-sublattice component. We leverage the elemental selectivity of time-resolved resonant X-ray scattering to reveal three coherent phonon modes with distinct sublattice character, thereby disentangling Eu- and Te-dominated lattice dynamics, in good agreement with theoretical calculations of the phonon eigenvectors. This time-domain approach, which surpasses the energy-resolution limits of conventional frequency-domain inelastic scattering, provides a broadly applicable framework for decomposing coherent phonons in multi-element materials, which is crucial for the targeted control of phases of matter. △ Less

Submitted 6 August, 2026; originally announced August 2026.

Comments: 7 pages, 4 figures

Quasiparticle phono-conversion: filming carriers coalescing into excitons

Authors: Enrico Perfetto, Takumi Fukuda, Xing Zhu, Jacques Hawecker, Harley Suchiang, Joanna Nadolna, Nanami Tomoda, Suji Park, Houk Jang, Kenji Watanabe, Takashi Taniguchi, Michael K. L. Man, Julien Madéo, Keshav M. Dani, Gianluca Stefanucci

Abstract: Condensed matter physics is replete with phenomena involving high-energy free particles coalescing into low-energy bound few-particle states. While the cooling of the individual particles is well understood, the crucial step by which cold free carriers form a bound state remains elusive, involving complex energy and momentum relaxation pathways. Here, by combining ultrafast time- and momentum-reso… ▽ More Condensed matter physics is replete with phenomena involving high-energy free particles coalescing into low-energy bound few-particle states. While the cooling of the individual particles is well understood, the crucial step by which cold free carriers form a bound state remains elusive, involving complex energy and momentum relaxation pathways. Here, by combining ultrafast time- and momentum-resolved photoemission spectroscopy on a monolayer WSe$_2$ with the first-principles excitonic-Bloch equations, we resolve the conversion of initially free electrons and holes at the bandedges into bound excitons. With unprecedented energy resolution, we observe the transient \textit{coexistence} of free-carrier and excitonic bands, accompanied by a transfer of spectral weight between the two. We establish the phononic origin of exciton formation and ascribe this coexistence to a sequential relaxation cascade toward the lowest-energy excitonic states, wherein intermediate states remain weakly populated. The efficiency of this process is controlled by valley multiplicity, large-momentum phonon emission and spin-flip processes. By elucidating how bound states emerge from their elementary constituents, our results point to strategies for engineering exciton formation, with direct implications for optical materials and devices that operate with excitons or free carriers. △ Less

Submitted 30 July, 2026; originally announced July 2026.

Proximity-induced charge transfer, strain and magnetic exchange in graphene/CrSBr heterostructure

Authors: Asish K. Kundu, Anil Rajapitamahuni, Niraj Aryal, Turgut Yilmaz, Margalit L. Feuer, Suji Park, Houk Jang, Abhay Pasupathy, Xavier Roy, Jerzy T. Sadowski, Elio Vescovo

Abstract: Stacking van der Waals materials provides a powerful route to engineer emergent electronic and magnetic behaviors through proximity-driven interactions. The graphene/CrSBr heterostructure has emerged as a compelling platform in this frontier, exhibiting exotic macroscopic responses-- including uniaxial surface-plasmon-polariton propagation and an unconventional quantum Hall effect-- indicative of… ▽ More Stacking van der Waals materials provides a powerful route to engineer emergent electronic and magnetic behaviors through proximity-driven interactions. The graphene/CrSBr heterostructure has emerged as a compelling platform in this frontier, exhibiting exotic macroscopic responses-- including uniaxial surface-plasmon-polariton propagation and an unconventional quantum Hall effect-- indicative of strong interfacial electronic and magnetic coupling. However, a microscopic electronic landscape governing these phenomena has remained elusive. Here, we provide a comprehensive spectroscopic characterization of the graphene/CrSBr interface using a combination of angle-resolved photoemission spectroscopy (ARPES), low-energy electron microscopy (LEEM), and density functional theory. We resolve a massive redistribution of interfacial charge that concurrently hole dopes graphene and populates the quasi-one-dimensional spin-polarized conduction band of CrSBr, resulting insulator-to-metal transition in the interfacial CrSBr layer. Furthermore, electronic structure of CrSBr exhibits strong momentum-dependent renormalization distinct from conventional charge doping, and theoretical modeling supported by Raman spectroscopy points to additional interfacial compressive strain. In addition, ARPES reveals a splitting-like feature in the graphene Dirac cone consistent with spin degeneracy lifting, providing possible evidence of magnetic proximity coupling. These findings provide crucial microscopic insight into the system's optical and transport responses and establish graphene/CrSBr as a versatile platform for charge-transfer control, strain-driven band engineering, magnetic-proximity coupling, and directionally confined excitations for next-generation spintronic and nanophotonic devices. △ Less

Submitted 22 July, 2026; originally announced July 2026.

Comments: 26 pages, 4 figures

Electrolyte Bonding Engineering for Highly Uniform GeTe-based CBRAM and Parallel Hebbian Learning in Selector-free Hopfield Networks

Authors: Jiin Bang, Jingyeong Hwang, Unhyeon Kang, Seungmin Oh, Kyungmin Lee, Jaehyun Park, Younghyun Lee, Hyun Jae Jang, Seongsik Park, YeonJoo Jeong, Inho Kim, Jong Keuk Park, Suyoun Lee

Abstract: Hopfield networks offer a hardware-friendly framework for energy-efficient associative memory, yet their practical realization in memristor crossbar arrays is critically hindered by device-to-device (D2D) variability, which prevents reliable parallel programming. Here, we address this bottleneck through systematic composition engineering of the Ge-Te solid electrolyte in conductive bridge random a… ▽ More Hopfield networks offer a hardware-friendly framework for energy-efficient associative memory, yet their practical realization in memristor crossbar arrays is critically hindered by device-to-device (D2D) variability, which prevents reliable parallel programming. Here, we address this bottleneck through systematic composition engineering of the Ge-Te solid electrolyte in conductive bridge random access memory (CBRAM) devices. By varying the Ge:Te ratio, we identify Ge3.5Te1 as an optimal electrolyte composition that suppresses stochastic resistance variation by approximately three orders of magnitude compared to GeSe-based devices. Raman spectroscopy reveals that this dramatic improvement originates from a bonding network dominated by asymmetric-stretching GeTe4 tetrahedral units, which form interconnected free-volume channels that confine and stabilize Cu+ ion migration pathways. Leveraging this enhanced uniformity, we fabricate a selector-less 16x16 Cu/Ge3.5Te1 CBRAM crossbar array and demonstrate a 4x4 Hopfield associative network capable of learning and recalling binary pattern pairs via fully parallel programming using a half-selection scheme. Successful pattern recall is achieved for up to two stored associations despite the absence of selector elements, establishing a proof-of-concept for selector-free hardware implementations of associative memory. These results highlight the critical role of electrolyte bonding structure in determining memristor uniformity and provide a materials-driven pathway toward scalable, parallel neuromorphic computing systems. △ Less

Submitted 4 June, 2026; originally announced June 2026.

Equilibrium Stabilization of a Hidden Phase Like Metallic State in 1T-TaS2

Authors: Turgut Yilmaz, Anil Rajapitamahuni, Suji Park, Houk Jang, Asish K. Kundu, Elio Vescovo

Abstract: Electronic phases that lie outside the equilibrium ground state offer a route to explore competing configurations in correlated materials. In 1T-TaS2, ultrafast excitation accesses a metallic hidden phase that is distinct from the commensurate insulating ground state. Here we use angle-resolved photoemission spectroscopy to show that an equivalent electronic configuration is stabilized in exfoliat… ▽ More Electronic phases that lie outside the equilibrium ground state offer a route to explore competing configurations in correlated materials. In 1T-TaS2, ultrafast excitation accesses a metallic hidden phase that is distinct from the commensurate insulating ground state. Here we use angle-resolved photoemission spectroscopy to show that an equivalent electronic configuration is stabilized in exfoliated intermediate-thickness 1T-TaS2 flakes, where it persists up to room temperature before evolving through a different sequence of electronic transitions. This equilibrium hidden-phase-like state hosts a metallic band with finite Fermi-level spectral weight while retaining the characteristic hybridization gaps associated with the star-of-David band folding. These results establish a platform for controlling competing electronic states in layered materials, with implications for both quantum science and phase change technologies. △ Less

Submitted 24 July, 2026; v1 submitted 21 May, 2026; originally announced May 2026.

A Hardware-aware Hopfield Network with a Nonlinear Memristor Array for Robust Associative Memory with Superlinear Capacity

Authors: Younghyun Lee, Hakseung Rhee, Unhyeon Kang, Seungmin Oh, Kyungmin Lee, Hyun Jae Jang, Seongsik Park, YeonJoo Jeong, Inho Kim, Jong Keuk Park, Kyung Min Kim, Suyoun Lee

Abstract: Associative memory retrieves complete patterns from partial or corrupted inputs and constitutes a primitive form of generative inference. Classical Hopfield networks (CHN) provide a canonical framework for associative memory but suffer from limited memory capacity. Recently, modern Hopfield networks (MHN) were introduced to achieve higher capacity by using explicit pattern-wise storage and neurons… ▽ More Associative memory retrieves complete patterns from partial or corrupted inputs and constitutes a primitive form of generative inference. Classical Hopfield networks (CHN) provide a canonical framework for associative memory but suffer from limited memory capacity. Recently, modern Hopfield networks (MHN) were introduced to achieve higher capacity by using explicit pattern-wise storage and neurons with the softmax activation function, which makes the MHN vulnerable to noise and the hardware implementation complicated due to its network size varying with the number of stored patterns. Here, we introduce a hardware-aware Hopfield network (HHN), in which the intrinsic nonlinear current-voltage characteristics of a charge-trap memristor are leveraged to engineer the energy landscape of the HN, increasing the memory capacity. Using a 25 x 25 nonlinear memristor array, we demonstrate reliable reconstruction of corrupted patterns with memory capacity far exceeding the classical limit (K ~ 0.14N, where N is the number of neurons). The HHN preserves Hopfield-type energy-minimization dynamics and remains robust to synaptic conductance noise. Large-scale simulations on high-dimensional image data reveal an empirical memory capacity scaling of K ~ 0.3 x N^1.2 under a fixed synaptic budget. These results establish HHN as a scalable hardware-native architecture for low-power associative memory and generative inference. △ Less

Submitted 8 May, 2026; originally announced May 2026.

Feedback percolation on complex networks

Authors: Hoseung Jang, Ginestra Bianconi, Byungjoon Min

Abstract: Traditional percolation theory assumes static microscopic rules, limiting its ability to describe real-world complex systems where macroscopic order actively regulates local interactions. Here, we introduce feedback percolation, an unified framework that dynamically couples the microscopic activation probability to the macroscopic size of the giant component. We show that this simple feedback mech… ▽ More Traditional percolation theory assumes static microscopic rules, limiting its ability to describe real-world complex systems where macroscopic order actively regulates local interactions. Here, we introduce feedback percolation, an unified framework that dynamically couples the microscopic activation probability to the macroscopic size of the giant component. We show that this simple feedback mechanism produces a rich variety of behaviors both analytically and numerically. Depending on the feedback functions, the system exhibits explosive discontinuous jumps, hybrid transitions, limit-cycle oscillations, and routes to chaos, absent in classical percolation. Our findings establish that macroscopic feedback provides a unifying physical mechanism for phenomena ranging from self-regulating oscillations to systemic infrastructure collapse. △ Less

Submitted 23 March, 2026; originally announced March 2026.

Comments: 9 pages, 5 figures

Competing Hydrogenation Pathways to Metastable CaH$_6$ Revealed by Machine-Learning-Potential Molecular Dynamics

Authors: Ryuhei Sato, Peter I. C. Cooke, Maélie Caussé, Hung Ba Tran, Seong Hoon Jang, Di Zhang, Hao Li, Shin-ichi Orimo, Yasushi Shibuta, Chris J. Pickard

Abstract: The synthesis of the high-$T_c$ superhydride CaH$_6$ has stimulated significant interest in understanding synthesis pathways for metastable hydrides. However, the microscopic mechanisms governing such hydrogenation reactions remain poorly understood. Here, we show that machine-learning potential molecular dynamics (MLP-MD) simulations can reproduce and distinguish competing reaction pathways leadi… ▽ More The synthesis of the high-$T_c$ superhydride CaH$_6$ has stimulated significant interest in understanding synthesis pathways for metastable hydrides. However, the microscopic mechanisms governing such hydrogenation reactions remain poorly understood. Here, we show that machine-learning potential molecular dynamics (MLP-MD) simulations can reproduce and distinguish competing reaction pathways leading to metastable and stable hydrides. By simulating hydrogenation reactions at CaH$_2$/H$_2$ and CaH$_4$/H$_2$ interfaces, we identify two distinct pathways that produce clathrate-type CaH$_6$ and A15-type CaH$_{5.75}$, respectively. CaH$_{5.75}$ lies on the convex hull but requires extensive Ca sublattice rearrangement and therefore forms only at elevated temperatures. In contrast, CaH$_6$ becomes kinetically accessible when CaH$_2$ is used as the precursor. The crystallographic compatibility between the Ca sublattice of CaH$_2$ and the bcc framework of CaH$_6$ enables a martensitic-like topotactic transformation that bypasses the reconstructive pathway leading to CaH$_{5.75}$. These results reveal how precursor structure and thermodynamic stability compete to determine superhydride formation pathways and demonstrate that machine-learning molecular dynamics can directly capture the kinetic selection of metastable phases in reactive materials systems. △ Less

Submitted 9 March, 2026; originally announced March 2026.

Comments: 5 figures with supporting information

A Maxwell Fish-Eye Lens in a Bose-Einstein Condensate

Authors: Jelte Duchêne, Elinor Kath, Floriane Arrouas, Hanyi Jang, Helmut Strobel, Markus K. Oberthaler, Jay Mehta, Liam M. Farrell, Wyatt Kirkby, Duncan H. J. O'Dell

Abstract: We experimentally realize an analogue of the optical Maxwell fish-eye lens (MFEL) using phononic excitations in a Bose-Einstein condensate (BEC). A MFEL is characterized by a radially symmetric, spatially varying refractive index with the remarkable property that rays emitted from any point within the lens are perfectly focused at their antipodal points. While the implementation of such gradient-i… ▽ More We experimentally realize an analogue of the optical Maxwell fish-eye lens (MFEL) using phononic excitations in a Bose-Einstein condensate (BEC). A MFEL is characterized by a radially symmetric, spatially varying refractive index with the remarkable property that rays emitted from any point within the lens are perfectly focused at their antipodal points. While the implementation of such gradient-index lenses is challenging in conventional optical systems, BECs offer a highly tunable platform in which the spatially varying speed of sound of collective excitations -- phonons, the acoustic analogues of photons -- can be engineered and their dynamics observed in real time. Time-resolved measurements of phonon wavefronts reveal focusing behavior that shows good agreement with analytical theory and numerical simulations. This work provides both a geometric and physical framework for engineering effective refractive indices using ultracold atoms, and simulating wave propagation on effective spherical geometries. △ Less

Submitted 6 July, 2026; v1 submitted 26 February, 2026; originally announced February 2026.

Comments: 14 pages, 3 figures

Journal ref: New J. Phys. 28 064510 (2026)

Suppressed coarsening after an interaction quench in the Holstein chain

Authors: Ho Jang, Gia-Wei Chern

Abstract: We investigate the nonequilibrium dynamics induced by an interaction quench in the semiclassical Holstein model within the Ehrenfest nonadiabatic framework, which describes an isolated hybrid quantum-classical system with strictly conserved total energy. Focusing on the half-filled case, where the equilibrium ground state exhibits commensurate charge-density-wave (CDW) order for any nonzero coupli… ▽ More We investigate the nonequilibrium dynamics induced by an interaction quench in the semiclassical Holstein model within the Ehrenfest nonadiabatic framework, which describes an isolated hybrid quantum-classical system with strictly conserved total energy. Focusing on the half-filled case, where the equilibrium ground state exhibits commensurate charge-density-wave (CDW) order for any nonzero coupling, we identify three distinct post-quench dynamical regimes as a function of the final electron-phonon coupling: a nonequilibrium metallic state without CDW order, an intermediate regime characterized by slow scale-invariant ordering dynamics, and a frozen CDW state with arrested coarsening and immobile kinks. We analyze the intermediate regime in detail and uncover an unconventional algebraic decay of the kink density, $n \sim t^{-1/3}$, distinct from both ballistic annihilation and diffusive coarsening in classical dissipative systems. We show that this anomalous exponent arises from the hybrid nature of the dynamics: while the lattice evolves deterministically, the electronic degrees of freedom act as an effective internal bath that induces diffusive kink motion without energy dissipation. An effective reaction-diffusion description, incorporating both annihilation and elastic scattering of kinks, quantitatively accounts for the observed scaling behavior. Our results reveal a distinct coarsening mechanism in isolated hybrid systems, demonstrating how internal quantum dynamics can qualitatively reshape defect kinetics far from equilibrium. △ Less

Submitted 5 February, 2026; originally announced February 2026.

Comments: 14 pages, 6 figures

Transformer Learning of Chaotic Collective Dynamics in Many-Body Systems

Authors: Ho Jang, Gia-Wei Chern

Abstract: Learning reduced descriptions of chaotic many-body dynamics is fundamentally challenging: although microscopic equations are Markovian, collective observables exhibit strong memory and exponential sensitivity to initial conditions and prediction errors. We show that a self-attention-based transformer framework provides an effective approach for modeling such chaotic collective dynamics directly fr… ▽ More Learning reduced descriptions of chaotic many-body dynamics is fundamentally challenging: although microscopic equations are Markovian, collective observables exhibit strong memory and exponential sensitivity to initial conditions and prediction errors. We show that a self-attention-based transformer framework provides an effective approach for modeling such chaotic collective dynamics directly from time-series data. By selectively reweighting long-range temporal correlations, the transformer learns a non-Markovian reduced description that overcomes intrinsic limitations of conventional recurrent architectures. As a concrete demonstration, we study the one-dimensional semiclassical Holstein model, where interaction quenches induce strongly nonlinear and chaotic dynamics of the charge-density-wave order parameter. While pointwise predictions inevitably diverge at long times, the transformer faithfully reproduces the statistical "climate" of the chaos, including temporal correlations and characteristic decay scales. Our results establish self-attention as a powerful mechanism for learning effective reduced dynamics in chaotic many-body systems. △ Less

Submitted 26 January, 2026; originally announced January 2026.

Comments: 10 pages, 5 figures

Pseudospin Formulation of Quench Dynamics in the Semiclassical Holstein Model

Authors: Lingyu Yang, Ho Jang, Sankha Subhra Bakshi, Yang Yang, Gia-Wei Chern

Abstract: We present a pseudospin formulation for the post-quench dynamics of charge-density-wave (CDW) order in the half-filled spinless Holstein model on a square lattice, assuming spatially homogeneous evolution. This Anderson pseudospin description captures the coherent nonequilibrium dynamics of the coupled electron-lattice system. Numerical simulations reveal three distinct dynamical regimes of the CD… ▽ More We present a pseudospin formulation for the post-quench dynamics of charge-density-wave (CDW) order in the half-filled spinless Holstein model on a square lattice, assuming spatially homogeneous evolution. This Anderson pseudospin description captures the coherent nonequilibrium dynamics of the coupled electron-lattice system. Numerical simulations reveal three distinct dynamical regimes of the CDW order parameter following a quench-locked oscillations, Landau-damped dynamics, and overdamped relaxation-closely paralleling quench dynamics in BCS superconductors and other electronically driven symmetry-breaking phases. Crucially, however, the presence of dynamical lattice degrees of freedom leads to qualitatively different long-time behavior. In particular, while the oscillation amplitude is reduced in the damped regimes, CDW oscillations do not fully decay but instead persist indefinitely due to feedback from the lattice field. We further show that these persistent oscillations are characterized by a nonequilibrium electronic distribution, which provides an intuitive understanding of both their amplitude and the renormalization of the oscillation frequency relative to the bare Holstein phonon frequency. Our results highlight the essential role of lattice dynamics in nonequilibrium ordered phases and establish a clear distinction between electron-lattice-driven CDW dynamics and their purely electronic counterparts. △ Less

Submitted 4 January, 2026; originally announced January 2026.

Comments: 13 pages, 6 figures

Ovonic switches enable energy-efficient dendrite-like computing

Authors: Unhyeon Kang, Jaesang Lee, Seungmin Oh, Hanchan Song, Jongkil Park, Jaewook Kim, Seongsik Park, Hyun Jae Jang, Sangbum Kim, Su-in Yi, Suhas Kumar, Suyoun Lee

Abstract: Over the last decade, dendrites within individual biological neurons, which were previously thought to generally perform information pooling and networking, have now been shown to express complex temporal dynamics, Boolean-like logic, arithmetic, signal discrimination, and edge detection for image and sound recognition. Mimicking this rich functional density could offer a powerful primitive for ne… ▽ More Over the last decade, dendrites within individual biological neurons, which were previously thought to generally perform information pooling and networking, have now been shown to express complex temporal dynamics, Boolean-like logic, arithmetic, signal discrimination, and edge detection for image and sound recognition. Mimicking this rich functional density could offer a powerful primitive for neuromorphic computing, which has sought to replace the aging digital computing paradigms using biological inspirations. Here, using electrically driven Ovonic threshold switching in Sb-Te-doped GeSe, we demonstrate a single two-terminal component capable of self-sustained dynamics and universal Boolean logic, in addition to XOR operations (which is traditionally thought to require a network of active components). We then employ logic-driven dynamics in a single component to detect and estimate the gradients of edges in images, a task that otherwise requires elaborate circuits. A network of Ovonic switches exhibits properties of a half adder and a full adder, in addition to discriminative logic accommodating inhibitory and excitatory signals. We show that this computational primitive is not only seemingly simpler, but also offers many orders of magnitude improved energy efficiency compared to prevailing digital solutions. As such, this work paves the path for potentially emulating dendrites for efficient post-digital neuromorphic computing. △ Less

Submitted 24 December, 2025; originally announced December 2025.

Comments: 17 pages, 5 figures, 1 table. Published in Nano Letters (2025). This document is the unedited Author's version of a Submitted Work that was subsequently accepted for publication in Nano Letters, copyright (c) American Chemical Society after peer review. To access the final edited and published work see https://pubs.acs.org/doi/full/10.1021/acs.nanolett.5c04348

Wigner polarons reveal Wigner crystal dynamics in a monolayer semiconductor

Authors: Lifu Zhang, Liuxin Gu, Haydn S. Adlong, Arthur Christianen, Eugen Dizer, Ruihao Ni, Rundong Ma, Suji Park, Houk Jang, Takashi Taniguchi, Kenji Watanabe, Ilya Esterlis, Richard Schmidt, Atac Imamoglu, You Zhou

Abstract: Wigner crystals, lattices made purely of electrons, are a quintessential paradigm of studying correlation-driven quantum phase transitions. Despite decades of research, the internal dynamics of Wigner crystals has remained extremely challenging to access, with most experiments probing only static order or collective motion. Here, we establish monolayer WSe2 as a new materials platform to host zero… ▽ More Wigner crystals, lattices made purely of electrons, are a quintessential paradigm of studying correlation-driven quantum phase transitions. Despite decades of research, the internal dynamics of Wigner crystals has remained extremely challenging to access, with most experiments probing only static order or collective motion. Here, we establish monolayer WSe2 as a new materials platform to host zero-field Wigner crystals and then demonstrate that exciton spectroscopy provides a direct means to probe both static and dynamic properties of these electron lattices. We uncover striking optical resonances that we identify as Wigner polarons, quasiparticles formed when the electron lattice is locally distorted by exciton-Wigner crystal coupling. We further achieve all-optical control of spins in the Wigner crystal, directly probing valley-dependent Wigner polaron scattering well above the magnetic ordering temperature and in the absence of any external magnetic field. Finally, we demonstrate optical melting of the Wigner crystal and observe intriguingly different responses of the umklapp (static) and Wigner polaron (dynamic) resonances to optical excitation. Our results open up exciting new avenues for elucidating electron dynamics and achieving ultrafast optical control of interaction-driven quantum phase transitions in strongly correlated electron systems. △ Less

Submitted 5 August, 2026; v1 submitted 18 December, 2025; originally announced December 2025.

Comments: Main Text and Supplementary Information

Anomalous coarsening and nonlinear diffusion of kinks in an one-dimensional quasi-classical Holstein model

Authors: Ho Jang, Yang Yang, Gia-Wei Chern

Abstract: We study the phase-ordering dynamics of a quasi-classical Holstein model. At half-filling, the zero-temperature ground state is a commensurate charge-density-wave (CDW) with alternating occupied and empty sites. This quasi-classical formulation enables us to isolate the role of electrons in coarsening dynamics. Following a thermal quench, CDW domains grow through the diffusion and annihilation of… ▽ More We study the phase-ordering dynamics of a quasi-classical Holstein model. At half-filling, the zero-temperature ground state is a commensurate charge-density-wave (CDW) with alternating occupied and empty sites. This quasi-classical formulation enables us to isolate the role of electrons in coarsening dynamics. Following a thermal quench, CDW domains grow through the diffusion and annihilation of kinks -- topological defects separating the two symmetry-related CDW orders. While standard diffusive dynamics predicts domain sizes scaling as the square root of time, our large-scale simulations reveal a slower power-law growth with a temperature-dependent exponent. We trace this anomalous behavior to a cooperative kink hopping arising from Fermi-Dirac statistics of electrons and quasi-conservation of electron numbers. The correlated-hopping of kinks in turn gives rise to an effective diffusion coefficient that depends on the kink density. These results uncover a new mechanism for slow coarsening and carry implications for phase-ordering in the full Holstein model and related electron-phonon systems. △ Less

Submitted 8 December, 2025; originally announced December 2025.

Comments: 13 pages, 9 figures

Learning Degenerate Manifolds of Frustrated Magnets with Boltzmann Machines

Authors: Ho Jang, Jackson C. Glass, Gia-Wei Chern

Abstract: We show that Restricted Boltzmann Machines (RBMs) provide a flexible generative framework for modeling spin configurations in disordered yet strongly correlated phases of frustrated magnets. As a benchmark, we first demonstrate that an RBM can learn the zero-temperature ground-state manifold of the one-dimensional ANNNI model at its multiphase point, accurately reproducing its characteristic oscil… ▽ More We show that Restricted Boltzmann Machines (RBMs) provide a flexible generative framework for modeling spin configurations in disordered yet strongly correlated phases of frustrated magnets. As a benchmark, we first demonstrate that an RBM can learn the zero-temperature ground-state manifold of the one-dimensional ANNNI model at its multiphase point, accurately reproducing its characteristic oscillatory and exponentially decaying correlations. We then apply RBMs to kagome spin ice and show that they successfully learn the local ice rules and short-range correlations of the extensively degenerate ice-I manifold. Correlation functions computed from RBM-generated configurations closely match those from direct Monte Carlo simulations. For the partially ordered ice-II phase -- featuring long-range charge order and broken time-reversal symmetry -- accurate modeling requires RBMs with uniform-sign bias fields, mirroring the underlying symmetry breaking. These results highlight the utility of RBMs as generative models for learning constrained and highly frustrated magnetic states. △ Less

Submitted 18 February, 2026; v1 submitted 24 November, 2025; originally announced November 2025.

Comments: 13 pages, 10 figures

From Quantum Annealing to Alloy Discovery: Towards Accelerated Design of High-Entropy Alloys

Authors: Diego Ibarra-Hoyos, Peter Connors, Ho Jang, Nathan Grain, Israel Klich, Gia-Wei Chern, Peter K. Liaw, John R. Scully, Joseph Poon

Abstract: Data scarcity remains a central challenge in materials discovery, where finding meaningful descriptors and tuning models for generalization is critical but inherently a discrete optimization problem prone to multiple local minima confounding the true optimal state. Classical methods often get trapped in these minima, while quantum annealing can escape them via quantum fluctuations, including tunne… ▽ More Data scarcity remains a central challenge in materials discovery, where finding meaningful descriptors and tuning models for generalization is critical but inherently a discrete optimization problem prone to multiple local minima confounding the true optimal state. Classical methods often get trapped in these minima, while quantum annealing can escape them via quantum fluctuations, including tunneling, that overcome narrow energy barriers. We present a quantum-assisted machine-learning (QaML) framework that employs quantum annealing to address these combinatorial optimization challenges through feature selection, support-vector training formulated in QUBO form for classification and regression, and a new QUBO-based neural-network pruning formulation. Recursive batching enables quantum annealing to handle large feature spaces beyond current qubit limits, while quantum-pruned networks exhibit superior generalization over classical methods, suggesting that quantum annealing preferentially samples flatter, more stable regions of the loss landscape. Applied to high-entropy alloys (HEAs), a data-limited but compositionally complex testbed, the framework integrates models for fracture-strain classification and yield-strength regression under physics-based constraints. The framework identified and experimentally validated Al8Cr38Fe50Mn2Ti2 (at.%), a single-phase BCC alloy exhibiting a 0.2 % yield strength of 568 MPa, greater than 40 % compressive strain without fracture, and a critical current density in reducing acid nearly an order of magnitude lower than 304 stainless steel. These results establish QA as a practical route to overcome classical optimization limits and accelerate materials discovery. △ Less

Submitted 7 November, 2025; originally announced November 2025.

Role of Phase Fluctuation in Dynamic Competition Between Charge Order and Superconductivity in Cuprates

Authors: Mingu Kang, Pavel E. Dolgirev, Chao C. Zhang, Hoyoung Jang, Byungjune Lee, Minseok Kim, Sang-Youn Park, Ronny Sutarto, Eugene Demler, Jae-Hoon Park, John Y. T. Wei, Riccardo Comin

Abstract: Phase fluctuations are a key factor distinguishing nonthermal (ultrafast) and thermal phase transitions. Charge order in cuprates is characterized by short-range coherence while competing with superconductivity, and as such, it provides a representative case to study the role of phase fluctuation in coupled order parameter dynamics. In this work, we investigated the intertwined evolution of charge… ▽ More Phase fluctuations are a key factor distinguishing nonthermal (ultrafast) and thermal phase transitions. Charge order in cuprates is characterized by short-range coherence while competing with superconductivity, and as such, it provides a representative case to study the role of phase fluctuation in coupled order parameter dynamics. In this work, we investigated the intertwined evolution of charge order and superconductivity in cuprate/manganite heterostructures using time-resolved resonant X-ray scattering. The resulting dynamics are analyzed within a space- and time-dependent nonperturbative model capturing both amplitude and phase dynamics. At low fluence, photo-induced suppression of superconductivity results in a nonthermal enhancement of charge order, underscoring the dynamic competition between charge order and superconductivity. With increasing fluence, the slowing down of melting and recovery dynamics is observed, indicating a critical role of phase fluctuations. At high fluence, both charge order and superconductivity remain suppressed for an extended time window due to decoupling between amplitude and phase dynamics and the delayed recovery of phase coherence. Our work underscores the importance of phase fluctuation for understanding the dynamic competition between order parameters in cuprates. △ Less

Submitted 30 October, 2025; originally announced October 2025.

Comments: 19 pages, 7 figures

Kinetics of Peierls dimerization transition: Machine learning force-field approach

Authors: Ho Jang, Yang Yang, Gia-Wei Chern

Abstract: We present a machine learning (ML) force-field framework for simulating the non-equilibrium dynamics of charge-density-wave (CDW) order driven by the Peierls instability. Since the Peierls distortion arises from the coupling between lattice displacements and itinerant electrons, evaluating the adiabatic forces during time evolution is computationally intensive, particularly for large systems. To o… ▽ More We present a machine learning (ML) force-field framework for simulating the non-equilibrium dynamics of charge-density-wave (CDW) order driven by the Peierls instability. Since the Peierls distortion arises from the coupling between lattice displacements and itinerant electrons, evaluating the adiabatic forces during time evolution is computationally intensive, particularly for large systems. To overcome this bottleneck, we develop a generalized Behler-Parrinello neural-network architecture -- originally formulated for ab initio molecular dynamics -- to accurately and efficiently predict forces from local structural environments. Using the locality of electronic responses, the resulting ML force field achieves linear scaling efficiency while maintaining quantitative accuracy. Large-scale dynamical simulations using this framework uncover a two-stage coarsening behavior of CDW domains: an early-time regime characterized by a power-law growth $L \sim t^α$ with an effective exponent $α\approx 0.7$, followed by a crossover to the Allen-Cahn scaling $L \sim \sqrt{t}$ at late times. The enhanced early-time coarsening is attributed to anisotropic domain-wall motion arising from electron-mediated directional interactions. This work demonstrates the promise of ML-based force fields for multiscale dynamical modeling of condensed-matter lattice models. △ Less

Submitted 23 October, 2025; originally announced October 2025.

Comments: 20 pages, 9 figures

Chemical States and Local Structure in Cu-Deficient CuInSe2 Thin Films: Insights into Engineering and Bandgap Narrowing

Authors: Ahmed Yousef Mohamed, Byoung Gun Han, Hyeonseo Jang, Jun Oh Jeon, Yejin Kim, Haeseong Jang, Min Gyu Kim, Kug-Seung Lee, Deok-Yong Cho

Abstract: The Cu-deficient CuxInSe2 (x larger than 0.3) phase can be stabilized as a thin film. A uniform Cu-deficient composition with a chalcopyrite structure was obtained by the precision engineering of a two-step synthesis process involving electron-beam evaporation and Se vapor deposition. Detailed structural and chemical analyses were performed employing various X-ray and microscopic techniques to dem… ▽ More The Cu-deficient CuxInSe2 (x larger than 0.3) phase can be stabilized as a thin film. A uniform Cu-deficient composition with a chalcopyrite structure was obtained by the precision engineering of a two-step synthesis process involving electron-beam evaporation and Se vapor deposition. Detailed structural and chemical analyses were performed employing various X-ray and microscopic techniques to demonstrate that the chemical states and local structure in the Cu-Se-In tetrahedral networks change with the loss of Cu, the In-Se bond becomes shorter, and the In ions become excessively oxidized without phase separation. Moreover, the results indicate that the bandgap narrowing is primarily attributed to the reconstruction of In3+d 5s orbital states. The bandgap narrows from 1.51 eV to 1.4 eV, which is optimal for the photon absorber. Therefore, cation-deficient selenide is promising for stable nontoxic photovoltaics with tunable bandgaps. △ Less

Submitted 21 October, 2025; originally announced October 2025.

Journal ref: J. Mater. Chem. C, 11, 12016 (2023)

Bidirectional ultrafast control of charge density waves via phase competition

Authors: Honglie Ning, Kyoung Hun Oh, Yifan Su, Zhengyan Darius Shi, Dong Wu, Qiaomei Liu, B. Q. Lv, Alfred Zong, Gyeongbo Kang, Hyeongi Choi, Hyun-Woo J. Kim, Seunghyeok Ha, Jaehwon Kim, Suchismita Sarker, Jacob P. C. Ruff, B. J. Kim, N. L. Wang, Todadri Senthil, Hoyoung Jang, Nuh Gedik

Abstract: The intricate competition between coexisting charge density waves (CDWs) can lead to rich phenomena, offering unique opportunities for phase manipulation through electromagnetic stimuli. Leveraging time-resolved X-ray diffraction, we demonstrate ultrafast control of a CDW in EuTe$_4$ upon optical excitation. At low excitation intensities, the amplitude of one of the coexisting CDW orders increases… ▽ More The intricate competition between coexisting charge density waves (CDWs) can lead to rich phenomena, offering unique opportunities for phase manipulation through electromagnetic stimuli. Leveraging time-resolved X-ray diffraction, we demonstrate ultrafast control of a CDW in EuTe$_4$ upon optical excitation. At low excitation intensities, the amplitude of one of the coexisting CDW orders increases at the expense of the competing CDW, whereas at high intensities, it exhibits a nonmonotonic temporal evolution characterized by both enhancement and reduction. This transient bidirectional controllability, tunable by adjusting photo-excitation intensity, arises from the interplay between optical quenching and phase-competition-induced enhancement. Our findings, supported by phenomenological time-dependent Ginzburg-Landau theory simulations, not only clarify the relationship between the two CDWs in EuTe$_4$, but also highlight the versatility of optical control over order parameters enabled by phase competition. △ Less

Submitted 30 September, 2025; originally announced October 2025.

Comments: 8 pages, 4 figures

Journal ref: Phys. Rev. Lett. 135, 246504 (2025)

Strain-Gradient-Driven Decoupling of Thermal Suppression from Anisotropy in \b{eta}-Ga2O3

Authors: Guangwu Zhang, Xing Xiang, Ziyan Qian, Yixin Xu, Shengying Yue, Hyejin Jang, Lin Yang, Yanguang Zhou, Xinyu Wang, Qiye Zheng

Abstract: Strain gradients, ubiquitous in flexible devices and epitaxial nanostructures, are a major blind spot for thermal transport in \b{eta}-Ga2O3. We establish that strain gradient unlocks a thermal conductivity (k) suppression mechanism fundamentally more potent than uniform strain: moderate uniaxial gradients (0.6%/nm) suppress k by 32-37% (27-30%) in thin films (nanowires), intensifying to 43.3% wit… ▽ More Strain gradients, ubiquitous in flexible devices and epitaxial nanostructures, are a major blind spot for thermal transport in \b{eta}-Ga2O3. We establish that strain gradient unlocks a thermal conductivity (k) suppression mechanism fundamentally more potent than uniform strain: moderate uniaxial gradients (0.6%/nm) suppress k by 32-37% (27-30%) in thin films (nanowires), intensifying to 43.3% with biaxial gradients. This reduction far exceeds that from equivalent uniform strain and surpasses benchmark materials like silicon and BAs. Critically, a surprising decoupling emerges: while 3% uniform strain alters thermal anisotropy by ~25%, strain gradient strongly suppresses k with preserving this ratio. Mechanistically, strain gradients-induced symmetry breaking and enhanced mode coupling anisotropically activate forbidden scattering channels, making gradient-driven scattering dominant over intrinsic phonon scattering below 6.25 THz. These findings redefine non-uniform strain from a parasitic flaw into a powerful design tool for engineering thermal isolation and heat flux in next-generation flexible and high-power \b{eta}-Ga2O3 electronics. △ Less

Submitted 30 September, 2025; originally announced September 2025.

Dynamics of a jointly commensurate moiré charge density wave

Authors: Kyoung Hun Oh, Yifan Su, Honglie Ning, B. Q. Lv, Alfred Zong, Dong Wu, Qiaomei Liu, Gyeongbo Kang, Hyeongi Choi, Hyun-Woo J. Kim, Seunghyeok Ha, Jaehwon Kim, Suchismita Sarker, Jacob P. C. Ruff, Xiaozhe Shen, Duan Luo, Stephen Weathersby, Patrick Kramer, Xinxin Cheng, Dongsung Choi, Doron Azoury, Masataka Mogi, B. J. Kim, N. L. Wang, Hoyoung Jang , et al. (1 additional authors not shown)

Abstract: The advent of two-dimensional moiré systems has revolutionized the exploration of phenomena arising from strong correlations and nontrivial band topology. Recently, a moiré superstructure formed by two coexisting charge density waves (CDWs) with slightly mismatched wavevectors has been realized. These incommensurate CDWs can collectively exhibit commensurability, resulting in the jointly commensur… ▽ More The advent of two-dimensional moiré systems has revolutionized the exploration of phenomena arising from strong correlations and nontrivial band topology. Recently, a moiré superstructure formed by two coexisting charge density waves (CDWs) with slightly mismatched wavevectors has been realized. These incommensurate CDWs can collectively exhibit commensurability, resulting in the jointly commensurate CDW (JC-CDW) and establishing a new paradigm for controlling moiré potential and periodicity. Achieving such functionality, however, hinges on a key open question: how do the amplitude, phase coherence, and periodicity of this order respond to external perturbations? Here, we address this question using a suite of time- and momentum-resolved diffraction and spectroscopic techniques to probe light-induced CDW dynamics in EuTe$_4$. Our time-resolved diffraction measurements distinguish the instantaneous quenching of the JC-CDW amplitude, as verified by time-resolved photoemission spectroscopy, from the much slower evolution of phase fluctuations. Furthermore, while the JC-CDW wavevector remains locked along the CDW direction upon photoexcitation, indicating a preserved moiré periodicity, the correlation length of JC-CDW shows an exclusive reduction perpendicular to its wavevector, unveiling the formation of previously unexplored shear-type defects. Together, this multimodal methodology reconstructs the spatiotemporal evolution of the JC-CDW upon excitation. These findings not only highlight the remarkable robustness of JC-CDWs out of equilibrium, but also provide insight into optical manipulation and engineering of moiré quantum materials through defect control. △ Less

Submitted 2 July, 2026; v1 submitted 19 September, 2025; originally announced September 2025.

Comments: 24 pages, 4 figures

Direct Observation of d-Wave Superconducting Gap Symmetry in Pressurized La3Ni2O7-delta Single Crystals

Authors: Zi-Yu Cao, Di Peng, Seokmin Choi, Fujun Lan, Lan Yu, Enkang Zhang, Zhenfang Xing, Yuxin Liu, Feiyang Zhang, Tao Luo, Lixing Chen, Vuong Thi Anh Hong, Seung-Yeop Paek, Harim Jang, Jinghong Xie, Huayu Liu, Hongbo Lou, Zhidan Zeng, Yang Ding, Jun Zhao, Cailong Liu, Tuson Park, Qiaoshi Zeng, Ho-kwang Mao

Abstract: The recent discovery of superconductivity in pressure-stabilized bulk La3Ni2O7-delta, with a critical temperature (Tc) exceeding 77 K, has opened a new frontier in high-temperature superconductivity research beyond cuprates. Yet, the superconducting gap amplitude and symmetry, the key parameters to characterize a superconductor, remain elusive due to the overwhelming challenges of gap studies unde… ▽ More The recent discovery of superconductivity in pressure-stabilized bulk La3Ni2O7-delta, with a critical temperature (Tc) exceeding 77 K, has opened a new frontier in high-temperature superconductivity research beyond cuprates. Yet, the superconducting gap amplitude and symmetry, the key parameters to characterize a superconductor, remain elusive due to the overwhelming challenges of gap studies under high pressure. Here, we introduce in situ directional point-contact spectroscopy conducted under truly hydrostatic pressure, enabling the direct mapping of the superconducting gap in pressurized La3Ni2O7-delta single crystals. Depending on the junction orientation, differential conductance (dI/dV) spectra exhibit distinct V-shaped quasiparticle features and a sharp zero-bias peak, indicating a predominant d-wave-like pairing symmetry. Measurement of the c-axis gap amplitude Delta yields a gap-to-Tc ratio of 2Delta/kBTc = 4.2(5), positioning La3Ni2O7-delta firmly among unconventional, nodal high-Tc superconductors. These findings set stringent constraints on theoretical models for nickelate superconductors and establish a robust spectroscopic approach for understanding superconductors under extreme pressures. △ Less

Submitted 15 September, 2025; originally announced September 2025.

Comments: 20 pages, 4 figures, 4 supplementary figures

"DIVE" into Hydrogen Storage Materials Discovery with AI Agents

Authors: Di Zhang, Xue Jia, Tran Ba Hung, Seong Hoon Jang, Linda Zhang, Ryuhei Sato, Yusuke Hashimoto, Toyoto Sato, Kiyoe Konno, Shin-ichi Orimo, Hao Li

Abstract: Data-driven artificial intelligence (AI) approaches are fundamentally transforming the discovery of new materials. Despite the unprecedented availability of materials data in the scientific literature, much of this information remains trapped in unstructured figures and tables, hindering the construction of large language model (LLM)-based AI agent for automated materials design. Here, we present… ▽ More Data-driven artificial intelligence (AI) approaches are fundamentally transforming the discovery of new materials. Despite the unprecedented availability of materials data in the scientific literature, much of this information remains trapped in unstructured figures and tables, hindering the construction of large language model (LLM)-based AI agent for automated materials design. Here, we present the Descriptive Interpretation of Visual Expression (DIVE) multi-agent workflow, which systematically reads and organizes experimental data from graphical elements in scientific literatures. We focus on solid-state hydrogen storage materials-a class of materials central to future clean-energy technologies and demonstrate that DIVE markedly improves the accuracy and coverage of data extraction compared to the direct extraction by multimodal models, with gains of 10-15% over commercial models and over 30% relative to open-source models. Building on a curated database of over 30,000 entries from 4,000 publications, we establish a rapid inverse design workflow capable of identifying previously unreported hydrogen storage compositions in two minutes. The proposed AI workflow and agent design are broadly transferable across diverse materials, providing a paradigm for AI-driven materials discovery. △ Less

Submitted 24 September, 2025; v1 submitted 18 August, 2025; originally announced August 2025.

Comments: 23 pages, 5 figures. The supplementary video is available at the GitHub link provided in the manuscript

Journal ref: Chemical Science 2026

Robustness of Majorana modes to potential disorder in Fe chains on a superconducting Rashba alloy

Authors: Harim Jang, Daniel Crawford, Khai Ton That, Lucas Schneider, Jens Wiebe, Makoto Shimizu, Harald O. Jeschke, Stephan Rachel, Roland Wiesendanger

Abstract: Majorana modes offer great potential for fault-tolerant quantum computation due to their topological protection. However, for superconductor-semiconductor nanowire hybrids, intrinsic disorder makes the unambiguous detection of Majorana modes difficult. Here, we construct 1D spin chains from individual Fe atoms on the Rashba surface alloy BiAg2/Ag(111) with proximity-induced superconductivity from… ▽ More Majorana modes offer great potential for fault-tolerant quantum computation due to their topological protection. However, for superconductor-semiconductor nanowire hybrids, intrinsic disorder makes the unambiguous detection of Majorana modes difficult. Here, we construct 1D spin chains from individual Fe atoms on the Rashba surface alloy BiAg2/Ag(111) with proximity-induced superconductivity from a Nb(110) substrate. While the Fe chains exhibit perfect crystalline order, we observe nano-scale potential disorder of the BiAg2/Ag(111)/Nb(110) heterostructure by scanning tunneling microscopy. However, this does not prevent the emergence of zero-energy modes at both ends of the Fe chains, in agreement with tight-binding calculations showing that they are only found in the topologically non-trivial regime of the phase diagram. These Majorana modes are indeed robust against potential disorder. △ Less

Submitted 20 June, 2025; originally announced June 2025.

Comments: 25 pages, 4 figures

Time-domain decoding of unconventional charge order mechanisms in nonmagnetic and magnetic kagome metals

Authors: Seongyong Lee, Byungjune Lee, Hoyoung Jang, Xueliang Wu, Jimin Kim, Gyeongbo Kang, Choongjae Won, Hyeongi Choi, Sang-Youn Park, Kyle M. Shen, Federico Cilento, Aifeng Wang, Jae-Hoon Park, Mingu Kang

Abstract: In kagome lattice materials, quantum interplay between charge, spin, orbital, and lattice degrees of freedom gives rise to a remarkably rich set of emergent phenomena, ranging from unconventional charge order and superconductivity to topological magnetism. While the exact nature of these exotic orders is often challenging to comprehend in static experiments, time-resolved techniques can offer crit… ▽ More In kagome lattice materials, quantum interplay between charge, spin, orbital, and lattice degrees of freedom gives rise to a remarkably rich set of emergent phenomena, ranging from unconventional charge order and superconductivity to topological magnetism. While the exact nature of these exotic orders is often challenging to comprehend in static experiments, time-resolved techniques can offer critical insights by disentangling coupled degrees of freedom on the time-axis. In this work, we demonstrate that the nature of charge orders in two representative kagome metals - nonmagnetic ScV6Sn6 and magnetic FeGe - which has been highly controversial in static studies, can be directly deciphered in the time-domain through their fundamentally distinct order parameter dynamics measured via time-resolved X-ray scattering at an X-ray free electron laser. In nonmagnetic ScV6Sn6, the dynamics are characterized by ultrafast melting and coherent amplitudon oscillations, typical of a phonon-coupled charge order. In stark contrast, magnetic FeGe exhibits resilient metastable charge order dynamics, hitherto unobserved in any other charge-ordered system - this unique time-domain behavior directly signifies an unconventional magnetism-interlocked charge order state realized in this kagome magnet. Our results not only provide a model case where unconventional nature of electronic order, hidden in equilibrium, is directly unraveled in the time-domain, but also pave the way for future out-of-equilibrium engineering of novel quantum orders in kagome lattice platforms. △ Less

Submitted 17 June, 2025; originally announced June 2025.

Comments: 4 figures

Ultrafast Orbital-Selective Photodoping Melts Charge Order in Overdoped Bi-based Cuprates

Authors: Xinyi Jiang, Qizhi Li, Qingzheng Qiu, Li Yue, Junhan Huang, Yiwen Chen, Byungjune Lee, Hyeongi Choi, Xingjiang Zhou, Tao Dong, Nanlin Wang, Hoyoung Jang, Yingying Peng

Abstract: High-temperature superconductivity in cuprates remains one of the enduring puzzles of condensed matter physics, with charge order (CO) playing a central yet elusive role, particularly in the overdoped regime. Here, we employ time-resolved X-ray absorption spectroscopy and resonant X-ray scattering at a free-electron laser to probe the transient electronic density of states and ultrafast CO dynamic… ▽ More High-temperature superconductivity in cuprates remains one of the enduring puzzles of condensed matter physics, with charge order (CO) playing a central yet elusive role, particularly in the overdoped regime. Here, we employ time-resolved X-ray absorption spectroscopy and resonant X-ray scattering at a free-electron laser to probe the transient electronic density of states and ultrafast CO dynamics in overdoped (Bi,Pb)$_{2.12}$Sr$_{1.88}$CuO$_{6+δ}$. We reveal a striking pump laser wavelength dependence - the 800 nm light fails to suppress CO, whereas the 400 nm light effectively melts it. This behavior originates from the fact that 400 nm photons can promote electrons from the Zhang-Rice singlet band to the upper Hubbard band or apical oxygen states, while 800 nm photons lack the energy to excite electrons across the charge-transfer gap. The CO recovery time ($\sim$3 ps) matches that of the underdoped cuprates, indicating universal electronic instability in the phase diagram. Additionally, melting overdoped CO requires an order-of-magnitude higher fluence highlighting the role of lattice interactions. Our findings demonstrate orbital-selective photodoping and provide a route to ultrafast control of emergent quantum phases in correlated materials. △ Less

Submitted 5 June, 2025; originally announced June 2025.

Comments: 13 pages, 11 figures, comments are welcome

Symmetry-protected electronic metastability in an optically driven cuprate ladder

Authors: Hari Padma, Filippo Glerean, Sophia F. R. TenHuisen, Zecheng Shen, Haoxin Wang, Luogen Xu, Joshua D. Elliott, Christopher C. Homes, Elizabeth Skoropata, Hiroki Ueda, Biaolong Liu, Eugenio Paris, Arnau Romaguera, Byungjune Lee, Wei He, Yu Wang, Seng Huat Lee, Hyeongi Choi, Sang-Youn Park, Zhiqiang Mao, Matteo Calandra, Hoyoung Jang, Elia Razzoli, Mark P. M. Dean, Yao Wang , et al. (1 additional authors not shown)

Abstract: Optically excited quantum materials exhibit nonequilibrium states with remarkable emergent properties, but these phenomena are usually transient, decaying on picosecond timescales and limiting practical applications. Advancing the design and control of nonequilibrium phases requires the development of targeted strategies to achieve long-lived, metastable phases. Here, we report the discovery of sy… ▽ More Optically excited quantum materials exhibit nonequilibrium states with remarkable emergent properties, but these phenomena are usually transient, decaying on picosecond timescales and limiting practical applications. Advancing the design and control of nonequilibrium phases requires the development of targeted strategies to achieve long-lived, metastable phases. Here, we report the discovery of symmetry-protected electronic metastability in the model cuprate ladder Sr$_{14}$Cu$_{24}$O$_{41}$. Using femtosecond resonant x-ray scattering and spectroscopy, we show that this metastability is driven by a transfer of holes from chain-like charge reservoirs into the ladders. This ultrafast charge redistribution arises from the optical dressing and activation of a hopping pathway that is forbidden by symmetry at equilibrium. Relaxation back to the ground state is hence suppressed after the pump coherence dissipates. Our findings highlight how dressing materials with electromagnetic fields can dynamically activate terms in the electronic Hamiltonian, and provide a rational design strategy for nonequilibrium phases of matter. △ Less

Submitted 3 June, 2025; originally announced June 2025.

Comments: Submitted version. Main text: 27 pages, 6 figures. SI: 36 pages, 19 figures

Journal ref: Nature Materials 24, 1584-1591 (2025)

Exciton Bohr radius of lead halide perovskites for photovoltaic and light-emitting applications

Authors: Hyun Myung Jang, Kyung Yeon Jang, Song Hee Lee, Jinwoo Park, Tae-Woo Lee

Abstract: Exciton Bohr radius (a_B) and exciton binding energy (E_b) of metal halide perovskites are two prime quantities in their applications to both light-emitting diode displays and photovoltaic devices. We develop a reliable theoretical method of simultaneously finding a_B and ε_r^c (dielectric constant) based on the net exciton energy above the bulk band gap. It is estimated that a_B under the dielect… ▽ More Exciton Bohr radius (a_B) and exciton binding energy (E_b) of metal halide perovskites are two prime quantities in their applications to both light-emitting diode displays and photovoltaic devices. We develop a reliable theoretical method of simultaneously finding a_B and ε_r^c (dielectric constant) based on the net exciton energy above the bulk band gap. It is estimated that a_B under the dielectric confinement is substantially smaller than a_B in the absence of dielectric confinement: 4.36 nm vs. 5.61 nm in the case of CH3NH3PbBr3. We attribute the enhanced a_B to variations of ε_r^c and the electron-hole correlation energy. We also develop a simple method of finding E_b based on the same net exciton energy. Using this, we attribute the well-known difference in E_b between organic bromide perovskites and iodide counterparts to ε_r^c and explain that iodide perovskites are more suited than bromide counterparts in photovoltaic applications, which require smaller E_b for efficient charge-carriers transport. △ Less

Submitted 21 May, 2025; originally announced May 2025.

Comments: 38 pages including Supplementary Materials, 5 figures, 2 tables, 23 equations (Main Manuscript), 41 references

Probing Quantum Anomalous Hall States in Twisted Bilayer WSe2 via Attractive Polaron Spectroscopy

Authors: Beini Gao, Mahdi Ghafariasl, Mahmoud Jalali Mehrabad, Tsung-Sheng Huang, Lifu Zhang, Deric Session, Pranshoo Upadhyay, Rundong Ma, Ghadah Alshalan, Daniel Gustavo Suárez Forero, Supratik Sarkar, Suji Park, Houk Jang, Kenji Watanabe, Takashi Taniguchi, Ming Xie, You Zhou, Mohammad Hafezi

Abstract: Moiré superlattices in semiconductors exhibit a rich variety of interaction-induced topological states, including quantum anomalous Hall (QAH) effects. A recent study hinted that twisted WSe2 homobilayer (tWSe2) could host a QAH state but lacked direct evidence of ferromagnetism, a key hallmark of this phase. Here, we report the first direct evidence of QAH states in tWSe2 with spontaneous ferroma… ▽ More Moiré superlattices in semiconductors exhibit a rich variety of interaction-induced topological states, including quantum anomalous Hall (QAH) effects. A recent study hinted that twisted WSe2 homobilayer (tWSe2) could host a QAH state but lacked direct evidence of ferromagnetism, a key hallmark of this phase. Here, we report the first direct evidence of QAH states in tWSe2 with spontaneous ferromagnetism. Specifically, we employ polarization-resolved attractive polaron spectroscopy on a dual-gated, 2 degree tWSe2 and observe direct signatures of spontaneous time-reversal symmetry breaking at hole filling ν= 1. Together with a Chern number measurement via Streda formula analysis, we identify this magnetized state as a topological state, characterized by C = 1. Furthermore, we demonstrate that these topological and magnetic properties are tunable via a finite displacement field, between a QAH ferromagnetic state and an antiferromagnetic state. Our findings position tWSe2 as a highly versatile, stable, and optically addressable platform for investigating topological order and strong correlations in two-dimensional landscapes. △ Less

Submitted 10 March, 2026; v1 submitted 15 April, 2025; originally announced April 2025.

Journal ref: Phys. Rev. X 16, 021037 (2026)

Roadmap for Photonics with 2D Materials

Authors: F. Javier García de Abajo, D. N. Basov, Frank H. L. Koppens, Lorenzo Orsini, Matteo Ceccanti, Sebastián Castilla, Lorenzo Cavicchi, Marco Polini, P. A. D. Gonçalves, A. T. Costa, N. M. R. Peres, N. Asger Mortensen, Sathwik Bharadwaj, Zubin Jacob, P. J. Schuck, A. N. Pasupathy, Milan Delor, M. K. Liu, Aitor Mugarza, Pablo Merino, Marc G. Cuxart, Emigdio Chávez-Angel, Martin Svec, Luiz H. G. Tizei, Florian Dirnberger , et al. (123 additional authors not shown)

Abstract: Triggered by the development of exfoliation and the identification of a wide range of extraordinary physical properties in self-standing films consisting of one or few atomic layers, two-dimensional (2D) materials such as graphene, transition metal dichalcogenides (TMDs), and other van der Waals (vdW) crystals currently constitute a wide research field protruding in multiple directions in combinat… ▽ More Triggered by the development of exfoliation and the identification of a wide range of extraordinary physical properties in self-standing films consisting of one or few atomic layers, two-dimensional (2D) materials such as graphene, transition metal dichalcogenides (TMDs), and other van der Waals (vdW) crystals currently constitute a wide research field protruding in multiple directions in combination with layer stacking and twisting, nanofabrication, surface-science methods, and integration into nanostructured environments. Photonics encompasses a multidisciplinary collection of those directions, where 2D materials contribute with polaritons of unique characteristics such as strong spatial confinement, large optical-field enhancement, long lifetimes, high sensitivity to external stimuli (e.g., electric and magnetic fields, heating, and strain), a broad spectral range from the far infrared to the ultraviolet, and hybridization with spin and momentum textures of electronic band structures. The explosion of photonics with 2D materials as a vibrant research area is producing breakthroughs, including the discovery and design of new materials and metasurfaces with unprecedented properties as well as applications in integrated photonics, light emission, optical sensing, and exciting prospects for applications in quantum information, and nanoscale thermal transport. This Roadmap summarizes the state of the art in the field, identifies challenges and opportunities, and discusses future goals and how to meet them through a wide collection of topical sections prepared by leading practitioners. △ Less

Submitted 14 April, 2025; v1 submitted 6 April, 2025; originally announced April 2025.

Comments: 199 pages, 42 figures, 1154 references

Journal ref: ACS Photonics 12, 3961 (2025)

In situ and real-time ultrafast spectroscopy of photoinduced reactions in perovskite nanomaterials

Authors: Gi Rim Han, Mai Ngoc An, Hyunmin Jang, Noh Soo Han, JunWoo Kim, Kwang Seob Jeong, Tai Hyun Yoon, Minhaeng Cho

Abstract: Employing two synchronized mode-locked femtosecond lasers and interferometric detection of the pump-probe spectra -- referred to as asynchronous and interferometric transient absorption (AI-TA) -- we have developed a method for broad dynamic range and rapid data acquisition. Using AI-TA, we examined photochemical changes during femtosecond pump-probe experiments on all-inorganic cesium lead halide… ▽ More Employing two synchronized mode-locked femtosecond lasers and interferometric detection of the pump-probe spectra -- referred to as asynchronous and interferometric transient absorption (AI-TA) -- we have developed a method for broad dynamic range and rapid data acquisition. Using AI-TA, we examined photochemical changes during femtosecond pump-probe experiments on all-inorganic cesium lead halide nanomaterials, including perovskite nanocrystals (PeNCs) and nanoplatelets (PeNPLs). The laser pulse train facilitates photoreactions while allowing real-time observation of charge carrier dynamics. In PeNCs undergoing halide anion photo-substitution, transient absorption spectra showed increasing bandgap energy and faster relaxation dynamics as the Cl/Br ratio increased. For colloidal PeNPLs, continuous observation revealed both spectral and kinetic changes during the light-induced coalescence of nanoplatelets, by analyzing temporal segments. This integrated technique not only deepens understanding of exciton dynamics and environmental influences in perovskite nanomaterials but also establishes AI-TA as a transformative tool for real-time observation of photochemical dynamics. △ Less

Submitted 3 April, 2025; originally announced April 2025.

Lithium-ion dynamics in synthetic quartz studied via the NMR of implanted $^{8}$Li$^{+}$

Authors: W. Andrew MacFarlane, Ryan M. L. McFadden, Signy Spencer, Aris Chatzichristos, John O. Ticknor, David L. Cortie, Martin H. Dehn, Sarah R. Dunsiger, Derek Fujimoto, Z. H. Jang, Victoria L. Karner, Robert F. Kiefl, Gerald D. Morris, Monika Stachura

Abstract: We report $β$-detected nuclear magnetic resonance ($β$-NMR) measurements of implanted $^{8}$Li$^{+}$ in a synthetic single crystal of $α$-SiO$_2$ (quartz). At 6.55 Tesla, the spectrum is comprised of a large amplitude broad resonance and a quadrupolar multiplet that is only revealed by an RF comb excitation. The quadrupole splitting is surprisingly small, increases with temperature, and provides i… ▽ More We report $β$-detected nuclear magnetic resonance ($β$-NMR) measurements of implanted $^{8}$Li$^{+}$ in a synthetic single crystal of $α$-SiO$_2$ (quartz). At 6.55 Tesla, the spectrum is comprised of a large amplitude broad resonance and a quadrupolar multiplet that is only revealed by an RF comb excitation. The quadrupole splitting is surprisingly small, increases with temperature, and provides information on the implantation site. Supercell density functional theory calculations show that the small EFG is consistent with an in-channel interstitial site (Wyckoff 3$a$). The spin-lattice relaxation is unexpectedly fast and strongly temperature dependent with a diffusive peak above 200 K and a second more prominent relaxation peak at lower temperature. Analysis of the diffusive relaxation yields an activation barrier 178(43) meV for the isolated Li$^{+}$, in the range of other measurements and calculations. To account for many of the other features of the data, it is suggested that some of the implanted ions trap an electron forming the neutral Li$^{0}$, which is stable over a narrow range of temperatures. △ Less

Submitted 24 March, 2025; originally announced March 2025.

Comments: 16 pages, 18 figures, 2 tables

Journal ref: Phys. Rev. B 112, 014103 (2025)

Quantum confining excitons with electrostatic moiré superlattice

Authors: Liuxin Gu, Lifu Zhang, Sam Felsenfeld, Rundong Ma, Suji Park, Houk Jang, Takashi Taniguchi, Kenji Watanabe, You Zhou

Abstract: Quantum confining excitons has been a persistent challenge in the pursuit of strong exciton interactions and quantum light generation. Unlike electrons, which can be readily controlled via electric fields, imposing strong nanoscale potentials on excitons to enable quantum confinement has proven challenging. In this study, we utilize piezoresponse force microscopy to image the domain structures of… ▽ More Quantum confining excitons has been a persistent challenge in the pursuit of strong exciton interactions and quantum light generation. Unlike electrons, which can be readily controlled via electric fields, imposing strong nanoscale potentials on excitons to enable quantum confinement has proven challenging. In this study, we utilize piezoresponse force microscopy to image the domain structures of twisted hexagonal boron nitride (hBN), revealing evidence of strong in-plane electric fields at the domain boundaries. By placing a monolayer MoSe2 only one to two nanometers away from the twisted hBN interface, we observe energy splitting of neutral excitons and Fermi polarons by several millielectronvolts at the moiré domain boundaries. By directly correlating local structural and optical properties, we attribute such observations to excitons confined in a nanoscale one-dimensional electrostatic potential created by the strong in-plane electric fields at the moiré domain boundaries. Intriguingly, this 1D quantum confinement results in pronounced polarization anisotropy in the excitons' reflection and emission, persistent to temperatures as high as ~80 Kelvins. These findings open new avenues for exploring and controlling strongly interacting excitons for classical and quantum optoelectronics. △ Less

Submitted 20 January, 2025; originally announced January 2025.

Comments: 23 pages, 11 figures

Beyond-Hubbard pairing in a cuprate ladder

Authors: Hari Padma, Jinu Thomas, Sophia TenHuisen, Wei He, Ziqiang Guan, Jiemin Li, Byungjune Lee, Yu Wang, Seng Huat Lee, Zhiqiang Mao, Hoyoung Jang, Valentina Bisogni, Jonathan Pelliciari, Mark P. M. Dean, Steven Johnston, Matteo Mitrano

Abstract: The Hubbard model is believed to capture the essential physics of cuprate superconductors. However, recent theoretical studies suggest that it fails to reproduce a robust and homogeneous superconducting ground state. Here, using resonant inelastic x-ray scattering and density matrix renormalization group calculations, we show that magnetic excitations in the prototypical cuprate ladder Sr$_{14}$Cu… ▽ More The Hubbard model is believed to capture the essential physics of cuprate superconductors. However, recent theoretical studies suggest that it fails to reproduce a robust and homogeneous superconducting ground state. Here, using resonant inelastic x-ray scattering and density matrix renormalization group calculations, we show that magnetic excitations in the prototypical cuprate ladder Sr$_{14}$Cu$_{24}$O$_{41}$ are inconsistent with those of a simple Hubbard model. The magnetic response of hole carriers, contributing to an emergent branch of spin excitations, is strongly suppressed. This effect is the consequence of d-wave-like pairing, enhanced by nearly an order of magnitude through a large nearest-neighbor attractive interaction. The similarity between cuprate ladders and the two-dimensional compounds suggests that such an enhanced hole pairing may be a universal feature of superconducting cuprates. △ Less

Submitted 17 January, 2025; originally announced January 2025.

Comments: Main + SM: 21 pages, 13 figures

Journal ref: Physical Review X 15, 021049 (2025)

Wafer-scale Semiconductor Grafting: Enabling High-Performance, Lattice-Mismatched Heterojunctions

Authors: Jie Zhou, Qiming Zhang, Jiarui Gong, Yi Lu, Yang Liu, Haris Abbasi, Haining Qiu, Jisoo Kim, Wei Lin, Donghyeok Kim, Yiran Li, Tien Khee Ng, Hokyung Jang, Dong Liu, Haiyan Wang, Boon S. Ooi, Zhenqiang Ma

Abstract: Semiconductor heterojunctions are foundational to many advanced electronic and optoelectronic devices. However, achieving high-quality, lattice-mismatched interfaces remains challenging, limiting both scalability and device performance. Semiconductor grafting offers a promising solution by directly forming electrically active, lattice-mismatched heterojunctions between dissimilar materials. Howeve… ▽ More Semiconductor heterojunctions are foundational to many advanced electronic and optoelectronic devices. However, achieving high-quality, lattice-mismatched interfaces remains challenging, limiting both scalability and device performance. Semiconductor grafting offers a promising solution by directly forming electrically active, lattice-mismatched heterojunctions between dissimilar materials. However, its scalability and uniformity at the wafer level have yet to be demonstrated. This work demonstrates the achievement of highly uniform, reproducible results across silicon, sapphire, and gallium nitride (GaN) substrates using wafer-scale semiconductor grafting. To illustrate this scalability, we conducted an in-depth study of a grafted Si/GaN heterojunction, examining band alignment through X-ray photoelectron spectroscopy and confirming crystallinity and interfacial integrity with scanning transmission electron microscopy. The resulting p-n diodes exhibit significantly enhanced electrical performance and wafer-scale uniformity compared to conventional approaches. This work establishes wafer-scale semiconductor grafting as a versatile and scalable technology, bridging the gap between laboratory-scale research and industrial manufacturing for heterogeneous semiconductor integration, and paving the way for novel, high-performance electronic and optoelectronic devices. △ Less

Submitted 12 November, 2024; originally announced November 2024.

Comments: 23 pages, 6 figures

True decoherence-free-subspace derived from a semiconductor double quantum dot Heisenberg spin-trimer

Authors: Wonjin Jang, Jehyun Kim, Jaemin Park, Min-Kyun Cho, Hyeongyu Jang, Sangwoo Sim, Hwanchul Jung, Vladimir Umansky, Dohun Kim

Abstract: Spins in solid systems can inherently serve as qubits for quantum simulation or quantum information processing. Spin qubits are usually prone to environmental magnetic field fluctuations; however, a spin qubit encoded in a decoherence-free-subspace (DFS) can be protected from certain degrees of environmental noise depending on the specific structure of the DFS. Here, we derive the "true" DFS from… ▽ More Spins in solid systems can inherently serve as qubits for quantum simulation or quantum information processing. Spin qubits are usually prone to environmental magnetic field fluctuations; however, a spin qubit encoded in a decoherence-free-subspace (DFS) can be protected from certain degrees of environmental noise depending on the specific structure of the DFS. Here, we derive the "true" DFS from an antiferromagnetic Heisenberg spin-1/2 trimer, which protects the qubit states against both short- and long-wavelength magnetic field fluctuations. We define the spin trimer with three electrons confined in a gate-defined GaAs double quantum dot (DQD) where we exploit Wigner-molecularization in one of the quantum dots. We first utilize the trimer for dynamic nuclear polarization (DNP), which generates a sizable magnetic field difference, $ΔB_\mathrm{z}$, within the DQD. We show that large $ΔB_\mathrm{z}$ significantly alters the eigenspectrum of the trimer and results in the "true" DFS in the DQD. Real-time Bayesian estimation of the DFS energy gap explicitly demonstrates protection of the DFS against short-wavelength magnetic field fluctuations in addition to long-wavelength ones. Our findings pave the way toward compact DFS structures for exchange-coupled quantum dot spin chains, the internal structure of which can be coherently controlled completely decoupled from environmental magnetic fields. △ Less

Submitted 29 September, 2024; originally announced September 2024.

Journal ref: npj Quantum Information 12, 1 (2026)

Thermoelectric signature of quantum criticality in the heavy-fermion superconductor CeRhIn$_5$

Authors: Zi-Yu Cao, Honghong Wang, Chan-Koo Park, Tae Beom Park, Harim Jang, Soonbeom Seo, Sung-Il Kim, Tuson Park

Abstract: The evolution of the Fermi surface across the quantum critical point (QCP), which is relevant for characterizing the quantum criticality and understanding its relation with unconventional superconductivity, is an intriguing subject in the study of strongly correlated electron systems. In this study, we report the thermopower measurements to investigate a change in Fermi surface across the QCP in p… ▽ More The evolution of the Fermi surface across the quantum critical point (QCP), which is relevant for characterizing the quantum criticality and understanding its relation with unconventional superconductivity, is an intriguing subject in the study of strongly correlated electron systems. In this study, we report the thermopower measurements to investigate a change in Fermi surface across the QCP in pure and 4.4% Sn-doped CeRhIn$_5$. Results show that their thermopower behavior differs significantly in the vicinity of their respective pressure-induced QCP. In pure CeRhIn$_5$, a drastic collapse of the thermopower takes place at the Kondo breakdown QCP, where the Fermi surface reconstructs concurrently with the development of the magnetic order. By contrast, the thermopower exhibits a broadly symmetric behavior around the QCP in 4.4% Sn-doped CeRhIn$_5$, which is a characteristic of the spin-density-wave QCP. These observations are consistent with the theoretical expectations and suggest the effectiveness of thermopower measurement in discriminating the nature of quantum criticality in heavy-fermion systems. △ Less

Submitted 24 August, 2024; originally announced August 2024.

Comments: 12 pages, 4 figures

Monte Carlo study of frustrated Ising model with nearest- and next-nearest-neighbor interactions in generalized triangular lattices

Authors: Hoseung Jang, Unjong Yu

Abstract: We investigate the frustrated $J_1$-$J_2$ Ising model with nearest-neighbor interaction $J_1$ and next-nearest-neighbor interaction $J_2$ in two kinds of generalized triangular lattices (GTLs) employing the Wang--Landau Monte Carlo method and finite-size scaling analysis. In the first GTL (GTL1), featuring anisotropic properties, we identify three kinds of super-antiferromagnetic ground states wit… ▽ More We investigate the frustrated $J_1$-$J_2$ Ising model with nearest-neighbor interaction $J_1$ and next-nearest-neighbor interaction $J_2$ in two kinds of generalized triangular lattices (GTLs) employing the Wang--Landau Monte Carlo method and finite-size scaling analysis. In the first GTL (GTL1), featuring anisotropic properties, we identify three kinds of super-antiferromagnetic ground states with stripe structures. Meanwhile, in the second GTL (GTL2), which is non-regular in next-nearest-neighbor interaction, the ferrimagnetic 3$\times$3 and two kinds of partial spin liquid ground states are observed. We confirm that residual entropy is proportional to the number of spins in the partial spin liquid ground states. Additionally, we construct finite-temperature phase diagrams for ferromagnetic nearest-neighbor and antiferromagnetic next-nearest-neighbor interactions. In GTL1, the transition into the ferromagnetic phase is continuous, contrasting with the first-order transition into the stripe phase. In GTL2, the critical temperature into the ferromagnetic ground state decreases as antiferromagnetic next-nearest-neighbor interaction intensifies until it meets the 3$\times$3 phase boundary. For intermediate values of the next-nearest-neighbor interaction, two successive transitions emerge: one from the paramagnetic phase to the ferromagnetic phase, followed by the other transition from the ferromagnetic phase to the 3$\times$3 phase. △ Less

Submitted 26 June, 2024; v1 submitted 22 June, 2024; originally announced June 2024.

Comments: 16 pages, 12 figures

Frustrated phonon with charge density wave in vanadium Kagome metal

Authors: Seung-Phil Heo, Choongjae Won, Heemin Lee, Hanbyul Kim, Eunyoung Park, Sung Yun Lee, Junha Hwang, Hyeongi Choi, Sang-Youn Park, Byungjune Lee, Woo-Suk Noh, Hoyoung Jang, Jae-Hoon Park, Dongbin Shin, Changyong Song

Abstract: The formation of a star of David CDW superstructure, resulting from the coordinated displacements of vanadium ions on a corner sharing triangular lattice, has garnered significant attention to comprehend the influence of electron phonon interaction within geometrically intricate lattice of Kagome metals, specifically AV3Sb5 (where A represents K, Rb, or Cs). However, understanding of the underlyin… ▽ More The formation of a star of David CDW superstructure, resulting from the coordinated displacements of vanadium ions on a corner sharing triangular lattice, has garnered significant attention to comprehend the influence of electron phonon interaction within geometrically intricate lattice of Kagome metals, specifically AV3Sb5 (where A represents K, Rb, or Cs). However, understanding of the underlying mechanism behind CDW formation, coupled with symmetry protected lattice vibrations, remains elusive. Here, from femtosecond time resolved X ray scattering experiments, we reveal that the phonon mode, associated with Cs ions out-of-plane motion, becomes frustrated in the CDW phase. Furthermore, we observed the photoinduced emergence of a metastable CDW phase, facilitated by alleviating the frustration. By not only elucidating the longstanding puzzle surrounding the intervention of phonons but introducing the phononic frustration, this research offers fresh insights into the competition between phonons and periodic lattice distortions, a phenomenon widespread in other correlated quantum materials including layered high TC superconductors. △ Less

Submitted 5 March, 2025; v1 submitted 10 June, 2024; originally announced June 2024.

Comments: Manuscript: 23 pages, 4 figures, SI: 17 pages, 11 figures

Journal ref: Nat. Commun. 16, 4861 (2025)

Sub-wavelength optical lattice in 2D materials

Authors: Supratik Sarkar, Mahmoud Jalali Mehrabad, Daniel G. Suárez-Forero, Liuxin Gu, Christopher J. Flower, Lida Xu, Kenji Watanabe, Takashi Taniguchi, Suji Park, Houk Jang, You Zhou, Mohammad Hafezi

Abstract: Recently, light-matter interaction has been vastly expanded as a control tool for inducing and enhancing many emergent non-equilibrium phenomena. However, conventional schemes for exploring such light-induced phenomena rely on uniform and diffraction-limited free-space optics, which limits the spatial resolution and the efficiency of light-matter interaction. Here, we overcome these challenges usi… ▽ More Recently, light-matter interaction has been vastly expanded as a control tool for inducing and enhancing many emergent non-equilibrium phenomena. However, conventional schemes for exploring such light-induced phenomena rely on uniform and diffraction-limited free-space optics, which limits the spatial resolution and the efficiency of light-matter interaction. Here, we overcome these challenges using metasurface plasmon polaritons (MPPs) to form a sub-wavelength optical lattice. Specifically, we report a ``non-local" pump-probe scheme where MPPs are excited to induce a spatially modulated AC Stark shift for excitons in a monolayer of MoSe$_2$, several microns away from the illumination spot. Remarkably, we identify nearly two orders of magnitude reduction for the required modulation power compared to the free-space optical illumination counterpart. Moreover, we demonstrate a broadening of the excitons' linewidth as a robust signature of MPP-induced periodic sub-diffraction modulation. Our results will allow exploring power-efficient light-induced lattice phenomena below the diffraction limit in active chip-compatible MPP architectures. △ Less

Submitted 12 March, 2025; v1 submitted 1 June, 2024; originally announced June 2024.

Using magnetic dynamics to measure the spin gap in a candidate Kitaev material

Authors: Xinyi Jiang, Qingzheng Qiu, Cheng Peng, Hoyoung Jang, Wenjie Chen, Xianghong Jin, Li Yue, Byungjune Lee, Sang-Youn Park, Minseok Kim, Hyeong-Do Kim, Xinqiang Cai, Qizhi Li, Tao Dong, Nanlin Wang, Joshua J. Turner, Yuan Li, Yao Wang, Yingying Peng

Abstract: Materials potentially hosting Kitaev spin-liquid states are considered crucial for realizing topological quantum computing. However, the intricate nature of spin interactions within these materials complicates the precise measurement of low-energy spin excitations indicative of fractionalized excitations. Using Na$_{2}$Co$_2$TeO$_{6}$ as an example, we study these low-energy spin excitations using… ▽ More Materials potentially hosting Kitaev spin-liquid states are considered crucial for realizing topological quantum computing. However, the intricate nature of spin interactions within these materials complicates the precise measurement of low-energy spin excitations indicative of fractionalized excitations. Using Na$_{2}$Co$_2$TeO$_{6}$ as an example, we study these low-energy spin excitations using the time-resolved resonant elastic x-ray scattering (tr-REXS). Our observations unveil remarkably slow spin dynamics at the magnetic peak, whose recovery timescale is several nanoseconds. This timescale aligns with the extrapolated spin gap of $\sim$ 1 $μ$eV, obtained by density matrix renormalization group (DMRG) simulations in the thermodynamic limit. The consistency demonstrates the efficacy of tr-REXS in discerning low-energy spin gaps inaccessible to conventional spectroscopic techniques. △ Less

Submitted 6 May, 2024; originally announced May 2024.

Comments: 9 pages, 6 figures

Journal ref: npj Quantum Materials 10, 15 (2025)

Probing superconducting gap in CeH$_9$ under pressure

Authors: Zi-Yu Cao, Seokmin Choi, Liu-Cheng Chen, Philip Dalladay-Simpson, Harim Jang, Federico Aiace Gorelli, Jia-Feng Yan, Soon-Gil Jung, Ge Huang, Lan Yu, Yongjae Lee, Jaeyong Kim, Tuson Park, Xiao-Jia Chen

Abstract: The recent discovery of superconductivity in hydrogen-rich compounds has garnered significant experimental and theoretical interest because of the record-setting critical temperatures. As the direct observation of the superconducting (SC) gap in these superhydrides is rare, the underlying mechanism behind its occurrence has yet to be settled down. Here, we report a successful synthesis of the… ▽ More The recent discovery of superconductivity in hydrogen-rich compounds has garnered significant experimental and theoretical interest because of the record-setting critical temperatures. As the direct observation of the superconducting (SC) gap in these superhydrides is rare, the underlying mechanism behind its occurrence has yet to be settled down. Here, we report a successful synthesis of the $\textit{P6$_3$}$/$\textit{mmc}$ phase of CeH$_9$ that exhibits the SC transition with SC critical temperature of about 100 K at a pressure of about 100 GPa. The observation of the zero electrical resistance and the critical current demonstrates that the SC phase is realized in Ce-based superhydride. Quasiparticle scattering spectroscopy (QSS) reveals the Andreev reflection at zero bias voltage, a hallmark of superconductivity, in the differential conductance. The obtained SC gap-to-$\textit{T}$$_c$ ratio of 4.36 and temperature dependence of SC gap are consistent with the prediction from the Bardeen-Cooper-Schrieffer theory with a moderate coupling strength. The successful realization of QSS under Megabar conditions is expected to provide a desired route to the study of the mechanism of superconductivity as well as the establishment of the SC phase in superhydride high-$\textit{T}$$_c$ systems. △ Less

Submitted 23 January, 2024; originally announced January 2024.

Comments: 20 pages, 4 figures

Electrical control and transport of tightly bound interlayer excitons in a MoSe2/hBN/MoSe2 heterostructure

Authors: Lifu Zhang, Ruihao Ni, Liuxin Gu, Ming Xie, Suji Park, Houk Jang, Takashi Taniguchi, Kenji Watanabe, You Zhou

Abstract: Controlling interlayer excitons in van der Waals heterostructures holds promise for exploring Bose-Einstein condensates and developing novel optoelectronic applications, such as excitonic integrated circuits. Despite intensive studies, several key fundamental properties of interlayer excitons, such as their binding energies and interactions with charges, remain not well understood. Here we report… ▽ More Controlling interlayer excitons in van der Waals heterostructures holds promise for exploring Bose-Einstein condensates and developing novel optoelectronic applications, such as excitonic integrated circuits. Despite intensive studies, several key fundamental properties of interlayer excitons, such as their binding energies and interactions with charges, remain not well understood. Here we report the formation of momentum-direct interlayer excitons in a high-quality MoSe2/hBN/MoSe2 heterostructure under an electric field, characterized by bright photoluminescence (PL) emission with high quantum yield and a narrow linewidth of less than 4 meV. These interlayer excitons show electrically tunable emission energy spanning ~180 meV through the Stark effect, and exhibit a sizable binding energy of ~81 meV in the intrinsic regime, along with trion binding energies of a few millielectronvolts. Remarkably, we demonstrate the long-range transport of interlayer excitons with a characteristic diffusion length exceeding ten micrometers, which can be attributed, in part, to their dipolar repulsive interactions. Spatially and polarization-resolved spectroscopic studies reveal rich exciton physics in the system, such as valley polarization, local trapping, and the possible existence of dark interlayer excitons. The formation and transport of tightly bound interlayer excitons with narrow linewidth, coupled with the ability to electrically manipulate their properties, open exciting new avenues for exploring quantum many-body physics, including excitonic condensate and superfluidity, and for developing novel optoelectronic devices, such as exciton and photon routers. △ Less

Submitted 5 April, 2024; v1 submitted 4 December, 2023; originally announced December 2023.

Comments: 4 figures

Triple-sinusoid hedgehog lattice in a centrosymmetric Kondo metal

Authors: Soohyeon Shin, Jin-Hong Park, Romain Sibille, Harim Jang, Tae Beom Park, Suyoung Kim, Tian Shang, Marisa Medarde, Eric D. Bauer, Oksana Zaharko, Michel Kenzelmann, Tuson Park

Abstract: Superposed symmetry-equivalent magnetic ordering wave vectors can lead to topologically non-trivial spin textures, such as magnetic skyrmions and hedgehogs, and give rise to novel quantum phenomena due to fictitious magnetic fields associated with a non-zero Berry curvature of these spin textures. To date, all known spin textures are constructed through the superposition of multiple spiral orders,… ▽ More Superposed symmetry-equivalent magnetic ordering wave vectors can lead to topologically non-trivial spin textures, such as magnetic skyrmions and hedgehogs, and give rise to novel quantum phenomena due to fictitious magnetic fields associated with a non-zero Berry curvature of these spin textures. To date, all known spin textures are constructed through the superposition of multiple spiral orders, where spins vary in directions with constant amplitude. Recent theoretical studies have suggested that multiple sinusoidal orders, where collinear spins vary in amplitude, can construct distinct topological spin textures regarding chirality properties. However, such textures have yet to be experimentally realised. In this work, we report the observation of a zero-field magnetic hedgehog lattice from a superposition of triple sinusoidal wave vectors in the magnetically frustrated Kondo lattice CePtAl4Ge2. Notably, we also observe the emergence of anomalous electrical and thermodynamic behaviours near the field-induced transition from the zero-field topological hedgehog lattice to a non-topological sinusoidal state. These observations highlight the role of Kondo coupling in stabilising the zero-field hedgehog state in the Kondo lattice and warrant an expedited search for other topological magnetic structures coupled with Kondo coupling. △ Less

Submitted 22 November, 2023; originally announced November 2023.

Evidence for charge delocalization crossover in the quantum critical superconductor CeRhIn$_5$

Authors: Honghong Wang, Tae Beom Park, Jihyun Kim, Harim Jang, Eric D. Bauer, Joe D. Thompson, Tuson Park

Abstract: The nature of charge degrees-of-freedom distinguishes scenarios for interpreting the character of a second order magnetic transition at zero temperature, that is, a magnetic quantum critical point (QCP). Heavy-fermion systems are prototypes of this paradigm, and in those, the relevant question is where, relative to a magnetic QCP, does the Kondo effect delocalize their $f$-electron degrees-of-free… ▽ More The nature of charge degrees-of-freedom distinguishes scenarios for interpreting the character of a second order magnetic transition at zero temperature, that is, a magnetic quantum critical point (QCP). Heavy-fermion systems are prototypes of this paradigm, and in those, the relevant question is where, relative to a magnetic QCP, does the Kondo effect delocalize their $f$-electron degrees-of-freedom. Herein, we use pressure-dependent Hall measurements to identify a finite-temperature scale $E_\text{loc}$ that signals a crossover from $f$-localized to $f$-delocalized character. As a function of pressure, $E_\text{loc}(P)$ extrapolates smoothly to zero temperature at the antiferromagnetic QCP of CeRhIn$_5$ where its Fermi surface reconstructs, hallmarks of Kondo-breakdown criticality that generates critical magnetic and charge fluctuations. In 4.4% Sn-doped CeRhIn$_5$, however, $E_\text{loc}(P)$ extrapolates into its magnetically ordered phase and is decoupled from the pressure-induced magnetic QCP, which implies a spin-density-wave (SDW) type of criticality that produces only critical fluctuations of the SDW order parameter. Our results demonstrate the importance of experimentally determining $E_\text{loc}$ to characterize quantum criticality and the associated consequences for understanding the pairing mechanism of superconductivity that reaches a maximum $T_\text{c}$ in both materials at their respective magnetic QCP. △ Less

Submitted 15 November, 2023; originally announced November 2023.

Comments: 19 pages, 5 figures, published in Nature Communications

Journal ref: Nat Commun 14, 7341 (2023)

Coherence of a field-gradient-driven singlet-triplet qubit coupled to many-electron spin states in 28Si/SiGe

Authors: Younguk Song, Jonginn Yun, Jehyun Kim, Wonjin Jang, Hyeongyu Jang, Jaemin Park, Min-Kyun Cho, Hanseo Sohn, Noritaka Usami, Satoru Miyamoto, Kohei M. Itoh, Dohun Kim

Abstract: Engineered spin-electric coupling enables spin qubits in semiconductor nanostructures to be manipulated efficiently and addressed individually. While synthetic spin-orbit coupling using a micromagnet is widely used for driving qubits based on single spins in silicon, corresponding demonstration for encoded spin qubits is so far limited to natural silicon. Here, we demonstrate fast singlet-triplet… ▽ More Engineered spin-electric coupling enables spin qubits in semiconductor nanostructures to be manipulated efficiently and addressed individually. While synthetic spin-orbit coupling using a micromagnet is widely used for driving qubits based on single spins in silicon, corresponding demonstration for encoded spin qubits is so far limited to natural silicon. Here, we demonstrate fast singlet-triplet qubit oscillation (~100 MHz) in a gate-defined double quantum dot in $^{28}$Si/SiGe with an on-chip micromagnet with which we show the oscillation quality factor of an encoded spin qubit exceeding 580. The coherence time $\textit{T}_{2}$* is analyzed as a function of potential detuning and an external magnetic field. In weak magnetic fields, the coherence is limited by fast noise compared to the data acquisition time, which limits $\textit{T}_{2}$* < 1 $μ$s in the ergodic limit. We present evidence of sizable and coherent coupling of the qubit with the spin states of a nearby quantum dot, demonstrating that appropriate spin-electric coupling may enable a charge-based two-qubit gate in a (1,1) charge configuration. △ Less

Submitted 25 October, 2023; v1 submitted 19 October, 2023; originally announced October 2023.

Journal ref: npj Quantum Inf. 10, 77 (2024)

Chiral Flat-Band Optical Cavity with Atomically Thin Mirrors

Authors: Daniel G. Suárez-Forero, Ruihao Ni, Supratik Sarkar, Mahmoud Jalali Mehrabad, Erik Mechtel, Valery Simonyan, Andrey Grankin, Kenji Watanabe, Takashi Taniguchi, Suji Park, Houk Jang, Mohammad Hafezi, You Zhou

Abstract: A fundamental requirement for photonic technologies is the ability to control the confinement and propagation of light. Widely utilized platforms include two-dimensional (2D) optical microcavities in which electromagnetic waves are confined between either metallic or distributed Bragg reflectors. Recently, transition metal dichalcogenides hosting tightly bound excitons with high optical quality ha… ▽ More A fundamental requirement for photonic technologies is the ability to control the confinement and propagation of light. Widely utilized platforms include two-dimensional (2D) optical microcavities in which electromagnetic waves are confined between either metallic or distributed Bragg reflectors. Recently, transition metal dichalcogenides hosting tightly bound excitons with high optical quality have emerged as promising atomically thin mirrors. In this work, we propose and experimentally demonstrate a sub-wavelength 2D nano-cavity using two atomically thin mirrors with degenerate resonances. Angle-resolved measurements show a flat band, which sets this system apart from conventional photonic cavities. Remarkably, we demonstrate how the excitonic nature of the mirrors enables the formation of chiral and tunable optical modes upon the application of an external magnetic field. Moreover, we show the electrical tunability of the confined mode. Our work demonstrates a mechanism for confining light with high-quality excitonic materials, opening perspectives for spin-photon interfaces, and chiral cavity electrodynamics. △ Less

Submitted 10 November, 2024; v1 submitted 8 August, 2023; originally announced August 2023.

Comments: Main text: 10 pages, 4 figures. Supplementary Material: 7 pages, 11 figures

Journal ref: Science Advances 10, eadr5904 (2024)

Giant optical nonlinearity of Fermi polarons in atomically thin semiconductors

Authors: Liuxin Gu, Lifu Zhang, Ruihao Ni, Ming Xie, Dominik S. Wild, Suji Park, Houk Jang, Takashi Taniguchi, Kenji Watanabe, Mohammad Hafezi, You Zhou

Abstract: Realizing strong nonlinear optical responses is a long-standing goal of both fundamental and technological importance. Recently significant efforts have focused on exploring excitons in solids as a pathway to achieving nonlinearities even down to few-photon levels. However, a crucial tradeoff arises as strong light-matter interactions require large oscillator strength and short radiative lifetime… ▽ More Realizing strong nonlinear optical responses is a long-standing goal of both fundamental and technological importance. Recently significant efforts have focused on exploring excitons in solids as a pathway to achieving nonlinearities even down to few-photon levels. However, a crucial tradeoff arises as strong light-matter interactions require large oscillator strength and short radiative lifetime of the excitons, which limits their interaction strength and nonlinearity. Here we experimentally demonstrate strong nonlinear optical responses by exploiting the coupling between excitons and carriers in an atomically thin semiconductor of trilayer tungsten diselenide. By controlling the electric field and electrostatic doping of the trilayer, we observe the hybridization between intralayer and interlayer excitons along with the formation of Fermi polarons due to the interactions between excitons and free carriers. We find substantial optical nonlinearity can be achieved under both continuous wave and pulsed laser excitation, where the resonance of the hole-doped Fermi polaron blueshifts by as much as ~10 meV. Intriguingly, we observe a remarkable asymmetry in the optical nonlinearity between electron and hole doping, which is tunable by the applied electric field. We attribute these features to the strong interactions between excitons and free charges with optically induced valley polarization. Our results establish that atomically thin heterostructures are a highly versatile platform for engineering nonlinear optical response with applications to classical and quantum optoelectronics, and open avenues for exploring many-body physics in hybrid Fermionic-Bosonic systems. △ Less

Submitted 19 June, 2023; originally announced June 2023.

Comments: 4 figures with SI