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Stress-triggered atomic explosion of trapped hydrogen initiates crack nucleation
Authors:
Liang Gao,
Thomas Schwarz-Selinger,
Martin Balden,
Cong Li,
Peter Manz,
Wolfgang Jacob,
Rudolf Neu,
Christian Linsmeier,
GuangHong Lu
Abstract:
Hydrogen embrittlement (HE) has persisted for more than a century as one of the most intractable problems in materials science. The prevailing view1 that diffusive H governs embrittlement has fostered the widespread assumption that H trapping at crystal defects mitigates HE. Here we overturn this conventional paradigm. Using plasma/ion irradiation of tungsten, we decouple -- for the first time --…
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Hydrogen embrittlement (HE) has persisted for more than a century as one of the most intractable problems in materials science. The prevailing view1 that diffusive H governs embrittlement has fostered the widespread assumption that H trapping at crystal defects mitigates HE. Here we overturn this conventional paradigm. Using plasma/ion irradiation of tungsten, we decouple -- for the first time -- H-induced crack nucleation from subsequent cavity propagation, and reveal nucleation as a two-stage mechanochemical fracture instability enabled by trapped H in the absence of diffusive H. In the first stage, H accumulation to a critical occupancy at dislocation cores acts as a chemical fuse, collapsing the local cohesive strength to a threshold at which infinitesimal external loads can trigger atomic decohesion. This bond rupture instantaneously enables the second stage: confined recombination of atomic hydrogen into molecular form. The abrupt release of chemical energy within an atomically restricted volume generates a transient inflation pressure that drives a dynamic, brittle jump to an internal macroscopic cavity. By separating mechanical decohesion triggering from energetic crack driving, our results provide a deterministic framework for the onset of H-induced crack nucleation under low-stress conditions. Furthermore, we place experimentally the classical H-enhanced decohesion model on an atomistic foundation and elevate it from phenomenology to prediction. Finally, by shifting the focus from experimentally elusive diffusive H to directly measurable trapped H, this work reframes HE as a deterministic, quantifiable instability, establishing a new paradigm for understanding and mitigating H-induced failure in high-strength metals.
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Submitted 17 June, 2026; v1 submitted 2 June, 2026;
originally announced June 2026.
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Long Term H-Release from Amorphous Carbon Evidenced by in Situ Raman Microscopy under Isothermal Heating
Authors:
Cedric Pardanaud,
C. Martin,
G. Giacometti,
P. Roubin,
B. Pégourié,
C. Hopf,
T. Schwarz-Selinger,
W. Jacob,
J. G. Buijnsters
Abstract:
We study the kinetics of the H release from plasma-deposited hydrogenated amorphous carbon films under isothermal heating at 450, 500 and 600 {\degree}C for long times up to several days using in situ Raman microscopy. Four Raman parameters are analyzed. They allow the identification of different processes such as the carbon network reorganization and the H release from sp3 or sp2 carbon atoms and…
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We study the kinetics of the H release from plasma-deposited hydrogenated amorphous carbon films under isothermal heating at 450, 500 and 600 {\degree}C for long times up to several days using in situ Raman microscopy. Four Raman parameters are analyzed. They allow the identification of different processes such as the carbon network reorganization and the H release from sp3 or sp2 carbon atoms and the corresponding timescales. Carbon reorganization with aromatization and loss of sp3 hybridization occurs first in 100 minutes at 500 {\degree}C. The final organization is similar at all investigated temperatures. Full H release from sp3 carbon occurs on a longer timescale of about 10 hours while H release from sp2 carbon atoms is only partial, even after several days. All these processes occur more rapidly with higher initial H content, in agreement with what is known about the stability of these types of films. A quantitative analysis of these kinetics studies gives valuable information about the microscopic processes at the origin of the H release through the determination of activation energies.
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Submitted 21 August, 2013;
originally announced August 2013.
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Raman spectroscopy investigation of the H content of heated hard amorphous carbon layers
Authors:
Cedric Pardanaud,
C. Martin,
P. Roubin,
G. Giacometti,
C. Hopf,
T. Schwarz-Selinger,
W. Jacob
Abstract:
We revisit here how Raman spectroscopy can be used to estimate the H content in hard hydrogenated amorphous carbon layers. The H content was varied from 2 at.% to 30 at.%, using heat treatments of a a-C:H, from room temperature to 1300 K and was determined independently using ion beam analysis. We examine the correlation of various Raman parameters and the consistency of their thermal evolution wi…
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We revisit here how Raman spectroscopy can be used to estimate the H content in hard hydrogenated amorphous carbon layers. The H content was varied from 2 at.% to 30 at.%, using heat treatments of a a-C:H, from room temperature to 1300 K and was determined independently using ion beam analysis. We examine the correlation of various Raman parameters and the consistency of their thermal evolution with thermo-desorption results. We identify a weak band at 860 cm-1 attributed to H bonded to C(sp2). We show that the HD/HG parameter (Height ratio between the D and G bands) is quasi-linear in the full range of H content and can thus be used to estimate the H content. Conversely, we show that the m/HG parameter (ratio between the photoluminescence background, m, and the height of the G band), often used to estimate the H content, should be used with care, first because it is sensitive to various photoluminescence quenching processes and second because it is not sensitive to H bonded to C(sp2).
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Submitted 21 August, 2013;
originally announced August 2013.
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Raman micro-spectroscopy as a tool to measure the absorption coefficient and the erosion rate of hydrogenated amorphous carbon films heat-treated under hydrogen bombardment
Authors:
Cedric Pardanaud,
E. Aréou,
C. Martin,
R. Ruffe,
T. Angot,
P. Roubin,
C. Hopf,
T. Schwarz-Selinger,
W. Jacob
Abstract:
We present a fast and simple way to determine the erosion rate and absorption coefficient of hydrogenated amorphous carbon films exposed to a hydrogen atomic source based on ex-situ Raman micro-spectroscopy. Results are compared to ellipsometry measurement. The method is applied to films eroded at different temperatures. A maximum of the erosion rate is found at ~ 450 {\degree}C in agreement with…
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We present a fast and simple way to determine the erosion rate and absorption coefficient of hydrogenated amorphous carbon films exposed to a hydrogen atomic source based on ex-situ Raman micro-spectroscopy. Results are compared to ellipsometry measurement. The method is applied to films eroded at different temperatures. A maximum of the erosion rate is found at ~ 450 {\degree}C in agreement with previous results. This technique is suitable for future quantitative studies on the erosion of thin carbonaceous films, especially of interest for plasma wall interactions occurring in thermonuclear fusion devices.
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Submitted 21 August, 2013;
originally announced August 2013.
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Raman study of CFC tiles extracted from the toroidal pump limiter of Tore Supra
Authors:
Cedric Pardanaud,
G. Giacometti,
C. Martin,
R. Ruffe,
T. Angot,
E. Aréou,
B. Pégourié,
E. Tsitrone,
T. Dittmar,
C. Hopf,
W. Jacob,
T. Schwarz-Selinger,
P. Roubin
Abstract:
The structure of six tiles extracted from the erosion and deposition zones (thin and thick deposition) of the Tore Supra toroidal pump limiter (TPL) have been analysed in the framework of the DITS campaign using micro-Raman spectroscopy. This post-mortem analysis gives information on both carbon structure and D content. We have found that the carbon structure is most often similar to that of plasm…
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The structure of six tiles extracted from the erosion and deposition zones (thin and thick deposition) of the Tore Supra toroidal pump limiter (TPL) have been analysed in the framework of the DITS campaign using micro-Raman spectroscopy. This post-mortem analysis gives information on both carbon structure and D content. We have found that the carbon structure is most often similar to that of plasma-deposited hard amorphous carbon layers. The role of the surface temperature during the discharge in the D content is investigated: in all locations where the temperature does not reach more than 500{\degree}C the D content seems to be roughly uniform with D/D+C \approx 20%.
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Submitted 21 August, 2013;
originally announced August 2013.