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Intertwined Orders in a Quantum-Entangled Metal
Authors:
Junyoung Kwon,
Jaehwon Kim,
Gwansuk Oh,
Seyoung Jin,
Kwangrae Kim,
Hoon Kim,
Seunghyeok Ha,
Hyun-Woo J. Kim,
GiBaik Sim,
Bjorn Wehinger,
Gaston Garbarino,
Nour Maraytta,
Michael Merz,
Matthieu Le Tacon,
Christoph J. Sahle,
Alessandro Longo,
Jungho Kim,
Ara Go,
Gil Young Cho,
Beom Hyun Kim,
B. J. Kim
Abstract:
Entanglement underpins quantum information processing and computing, yet its experimental quantification in complex, many-body condensed matter systems remains a considerable challenge. Here, we reveal a highly entangled electronic phase proximate to a quantum metal-insulator transition, identified by resonant inelastic x-ray scattering interferometry. This approach reveals that entanglement acros…
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Entanglement underpins quantum information processing and computing, yet its experimental quantification in complex, many-body condensed matter systems remains a considerable challenge. Here, we reveal a highly entangled electronic phase proximate to a quantum metal-insulator transition, identified by resonant inelastic x-ray scattering interferometry. This approach reveals that entanglement across atomic sites generates characteristic interference patterns, which our model accurately reproduces, enabling extraction of a full entanglement spectrum and resolution of the underlying quantum states. Our analysis of the pyrochlore iridate Nd2Ir2O7 demonstrates that the system undergoes pronounced quantum fluctuations in its spin, orbital and charge degrees of freedom, even in the presence of a long-range 'all-in-all-out' antiferromagnetic order. Importantly, the observed entanglement signatures facilitate the coexistence of multiple exotic symmetry-breaking orders. Complementary investigations using Raman spectroscopy corroborate the presence of these hidden orders and their emergent excitations. In particular, we observe a two-magnon-bound state below the lowest single-magnon excitation energy, which, together with split phonon modes, provides strong evidence for cubic symmetry-breaking orders of magnetic origin juxtaposed with the all-in-all-out order. Our work thus establishes a direct link between quantum entanglement and emergent unconventional orders, opening new avenues for investigating quantum materials.
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Submitted 6 July, 2025;
originally announced July 2025.
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Magnetoelectric effect in van der Waals magnets
Authors:
Kai-Xuan Zhang,
Giung Park,
Youjin Lee,
Beom Hyun Kim,
Je-Geun Park
Abstract:
The magnetoelectric (ME) effect is a fundamental concept in modern condensed matter physics and represents the electrical control of magnetic polarisations or vice versa. Two-dimensional (2D) van-der-Waals (vdW) magnets have emerged as a new class of materials and exhibit novel ME effects with diverse manifestations. This review emphasizes some important recent discoveries unique to vdW magnets: m…
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The magnetoelectric (ME) effect is a fundamental concept in modern condensed matter physics and represents the electrical control of magnetic polarisations or vice versa. Two-dimensional (2D) van-der-Waals (vdW) magnets have emerged as a new class of materials and exhibit novel ME effects with diverse manifestations. This review emphasizes some important recent discoveries unique to vdW magnets: multiferroicity on two dimensions, spin-charge correlation, atomic ME effect and current-induced intrinsic spin-orbit torque, and electrical gating control and magnetic control of their electronic properties. We also highlight the promising route of utilizing quantum magnetic hetero- or homo-structures to engineer the ME effect and corresponding spintronic and optoelectronic device applications. Due to the intrinsic two-dimensionality, vdW magnets with those ME effects are expected to form a new, exciting research direction.
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Submitted 7 January, 2025; v1 submitted 3 January, 2025;
originally announced January 2025.
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X-ray magnetic circular dichroism and resonant inelastic X-ray scattering explained: role of many-body correlation and mixed-valence fluctuations
Authors:
Beom Hyun Kim,
Sang-Jun Lee,
H. Huang,
D. Lu,
S. S. Hong,
S. Lee,
P. Abbamonte,
Y. I. Joe,
P. Szypryt,
W. B. Doriese,
D. S. Swetz,
J. N. Ullom,
C. -C. Kao,
J. -S. Lee,
Bongjae Kim
Abstract:
X-ray magnetic circular dichroism (XMCD) and resonant inelastic X-ray scattering with magnetic circular dichroism (RIXS-MCD) provide unparalleled insights into the electronic and magnetic dynamics of complex materials. Yet, their spectra remain challenging to interpret due to intricate many-body interactions. Here, we introduce a theoretical framework based on the Anderson impurity model, fully in…
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X-ray magnetic circular dichroism (XMCD) and resonant inelastic X-ray scattering with magnetic circular dichroism (RIXS-MCD) provide unparalleled insights into the electronic and magnetic dynamics of complex materials. Yet, their spectra remain challenging to interpret due to intricate many-body interactions. Here, we introduce a theoretical framework based on the Anderson impurity model, fully incorporating charge transfer (CT) and core-valence exchange correlation (CVEC) effects. Using epitaxial ferromagnetic La0.7Sr0.3MnO3 film as a model system, we capture elusive spectral features, demonstrating the necessity of CT inclusion for resolving XMCD subpeaks and revealing the profound impact of CVEC on RIXS-MCD spectra. Our approach not only successfully mirrors experimental results but also opens new avenues for exploring spin, orbital, and charge excitations in 3d transition metals and other correlated materials.
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Submitted 10 December, 2024;
originally announced December 2024.
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Unstable Retention Behavior in MIFIS FEFET: Accurate Analysis of the Origin by Absolute Polarization Measurement
Authors:
Song-Hyeon Kuk,
Kyul Ko,
Bong Ho Kim,
Jae-Hoon Han,
Sang-Hyeon Kim
Abstract:
Ferroelectric field-effect-transistor (FEFET) has emerged as a scalable solution for 3D NAND and embedded flash (eFlash), with recent progress in achieving large memory window (MW) using metal-insulator-ferroelectric-insulator-semiconductor (MIFIS) gate stacks. Although the physical origin of the large MW in the MIFIS stack has already been discussed, its retention characteristics have not been ex…
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Ferroelectric field-effect-transistor (FEFET) has emerged as a scalable solution for 3D NAND and embedded flash (eFlash), with recent progress in achieving large memory window (MW) using metal-insulator-ferroelectric-insulator-semiconductor (MIFIS) gate stacks. Although the physical origin of the large MW in the MIFIS stack has already been discussed, its retention characteristics have not been explored yet. Here, we demonstrate MIFIS FEFET with a maximum MW of 9.7 V, and show that MIFIS FEFET has unstable retention characteristics, especially after erase. We discover the origin of the unstable retention characteristics and prove our hypothesis with absolute polarization measurement and different operation modes, showing that the unstable retention characteristics is a fundamental issue. Based on the understanding, we discuss a novel charge compensation model and promising engineering methodologies to achieve stable retention in MIFIS FEFET.
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Submitted 27 June, 2024;
originally announced June 2024.
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Highly Tunable Ru-dimer Molecular Orbital State in 6H-perovskite Ba$_3$MRu$_2$O$_9$
Authors:
Bo Yuan,
Beom Hyun Kim,
Qiang Chen,
Daniel Dobrowolski,
Monika Azmanska,
G. M. Luke,
Shiyu Fan,
Valentina Bisogni,
Jonathan Pelliciari,
J. P. Clancy
Abstract:
Molecular orbital (MO) systems with clusters of heavy transition metal (TM) ions are one of the most important classes of model materials for studying the interplay between local physics and effects of itinerancy. Despite a large number of candidates identified in the family of 4d TM materials, an understanding of their physics from competing \textit{microscopic} energy scales is still missing. We…
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Molecular orbital (MO) systems with clusters of heavy transition metal (TM) ions are one of the most important classes of model materials for studying the interplay between local physics and effects of itinerancy. Despite a large number of candidates identified in the family of 4d TM materials, an understanding of their physics from competing \textit{microscopic} energy scales is still missing. We bridge this gap by reporting the first resonant inelastic X-ray scattering (RIXS) measurement on a well-known series of Ru dimer systems with a 6H-perovskite structure, Ba$_3$MRu$_2$O$_9$ (M$^{3+}$=In$^{3+}$, Y$^{3+}$, La$^{3+}$). Our RIXS measurements reveal an extremely fragile MO state in these Ru dimer compounds, evidenced by an abrupt change in the RIXS spectrum accompanying a tiny change in the local structure tuned by the M-site ion. By modelling the RIXS spectra, we attribute the enhanced electronic instability in Ba$_3$MRu$_2$O$_9$ to the combined effect of a large hopping and a small spin-orbit coupling in the Ru dimers. The unique combination of energy scales uncovered in the present study make Ru MO systems ideal model systems for studying quantum phase transitions with molecular orbitals.
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Submitted 15 May, 2024;
originally announced May 2024.
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Eigenstate switching of topologically ordered states using non-Hermitian perturbations
Authors:
Cheol Hun Yeom,
Beom Hyun Kim,
Moon Jip Park
Abstract:
Topologically ordered phases have robust degenerate ground states against the local perturbations, providing a promising platform for fault-tolerant quantum computation. Despite of the non-local feature of the topological order, we find that local non-Hermitian perturbations can induce the transition between the topologically ordered ground states. In this work, we study the toric code in the pres…
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Topologically ordered phases have robust degenerate ground states against the local perturbations, providing a promising platform for fault-tolerant quantum computation. Despite of the non-local feature of the topological order, we find that local non-Hermitian perturbations can induce the transition between the topologically ordered ground states. In this work, we study the toric code in the presence of non-Hermitian perturbations. By controlling the non-Hermiticity, we show that non-orthogonal ground states can exhibit an eigenstate coalescence and have the spectral singularity, known as an exceptional point (EP). We explore the potential of the EPs in the control of topological order. Adiabatic encircling EPs allows for the controlled switching of eigenstates, enabling dynamic manipulation between the ground state degeneracy. Interestingly, we show a property of our scheme that arbitrary strengths of local perturbations can induce the EP and eigenstate switching. Finally, we also show the orientation-dependent behavior of non-adiabatic transitions (NAT) during the dynamic encirclement around an EP. Our work shows that control of the non-Hermiticity can serve as a promising strategy for fault-tolerant quantum information processing.
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Submitted 27 February, 2024;
originally announced February 2024.
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Non-local features of the spin-orbit exciton in Kitaev materials
Authors:
Blair W. Lebert,
Subin Kim,
Beom Hyun Kim,
Sae Hwan Chun,
Diego Casa,
Jaewon Choi,
Stefano Agrestini,
Kejin Zhou,
Mirian Garcia-Fernandez,
Young-June Kim
Abstract:
A comparative resonant inelastic x-ray scattering (RIXS) study of three well-known Kitaev materials is presented: $α$-Li$_2$IrO$_3$, Na$_2$IrO$_3$, and $α$-RuCl$_3$. Despite similar low-energy physics, these materials show distinct electronic properties, such as the large difference in the size of the charge gap. The RIXS spectra of the spin-orbit exciton for these materials show remarkably simila…
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A comparative resonant inelastic x-ray scattering (RIXS) study of three well-known Kitaev materials is presented: $α$-Li$_2$IrO$_3$, Na$_2$IrO$_3$, and $α$-RuCl$_3$. Despite similar low-energy physics, these materials show distinct electronic properties, such as the large difference in the size of the charge gap. The RIXS spectra of the spin-orbit exciton for these materials show remarkably similar three-peak features, including sharp low energy peak (peak A) as well as transitions between $j_{\text{eff}}=1/2$ and $j_{\text{eff}}=3/2$ states. Comparison of experimental spectra with cluster calculations reveals that the observed three-peak structure reflects the significant role that non-local physics plays in the electronic structure of these materials. In particular, the low-energy peak A arises from a holon-doublon pair rather than a conventional particle-hole exciton as proposed earlier. Our study suggests that while spin-orbit assisted Mott insulator is still the best description for these materials, electron itinerancy cannot be ignored when formulating low-energy Hamiltonian of these materials.
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Submitted 16 October, 2023;
originally announced October 2023.
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Collective non-Hermitian skin effect: Point-gap topology and the doublon-holon excitations in non-reciprocal many-body systems
Authors:
Beom Hyun Kim,
Jae-Ho Han,
Moon Jip Park
Abstract:
Open quantum systems provide a plethora of exotic topological phases of matter that has no Hermitian counterpart. Non-Hermitian skin effect, macroscopic collapse of bulk states to the boundary, has been extensively studied in various experimental platforms. However, it remains an open question whether such topological phases persist in the presence of many-body interactions. Notably, previous stud…
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Open quantum systems provide a plethora of exotic topological phases of matter that has no Hermitian counterpart. Non-Hermitian skin effect, macroscopic collapse of bulk states to the boundary, has been extensively studied in various experimental platforms. However, it remains an open question whether such topological phases persist in the presence of many-body interactions. Notably, previous studies have shown that the Pauli exclusion principle suppresses the skin effect. In this study, we present a compelling counterexample by demonstrating the presence of the skin effect in doublon-holon excitations. While the ground state of the spin-half Hatano-Nelson model shows no skin effect, the doublon-holon pairs, as its collective excitations, display the many-body skin effect even in strong coupling limit. We rigorously establish the robustness of this effect by revealing a bulk-boundary correspondence mediated by the point gap topology within the many-body energy spectrum. Our findings underscore the existence of non-Hermitian topological phases in collective excitations of many-body interacting systems.
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Submitted 14 September, 2023;
originally announced September 2023.
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Multiferroic-enabled magnetic exciton in 2D quantum entangled van der Waals antiferromagnet NiI2
Authors:
Suhan Son,
Youjin Lee,
Jae Ha Kim,
Beom Hyun Kim,
Chaebin Kim,
Woongki Na,
Hwiin Ju,
Sudong Park,
Abhishek Nag,
Ke-Jin Zhou,
Young-Woo Son,
Hyeongdo Kim,
Woo-Suk Noh,
Jae-Hoon Park,
Jong Seok Lee,
Hyeonsik Cheong,
Jae Hoon Kim,
Je-Geun Park
Abstract:
Matter-light interaction is at the center of diverse research fields from quantum optics to condensed matter physics, opening new fields like laser physics. A magnetic exciton is one such rare example found in magnetic insulators. However, it is relatively rare to observe that external variables control matter-light interaction. Here, we report that the broken inversion symmetry of multiferroicity…
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Matter-light interaction is at the center of diverse research fields from quantum optics to condensed matter physics, opening new fields like laser physics. A magnetic exciton is one such rare example found in magnetic insulators. However, it is relatively rare to observe that external variables control matter-light interaction. Here, we report that the broken inversion symmetry of multiferroicity can act as an external knob enabling the magnetic exciton in van der Waals antiferromagnet NiI2. We further discover that this magnetic exciton arises from a transition between Zhang-Rice-triplet and Zhang-Rice-singlet's fundamentally quantum entangled states. This quantum entanglement produces an ultra-sharp optical exciton peak at 1.384 eV with a 5 meV linewidth. Our work demonstrates that NiI2 is two-dimensional magnetically ordered with an intrinsically quantum entangled ground state.
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Submitted 22 December, 2021;
originally announced December 2021.
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The field-angle anisotropy of proximate Kitaev systems under an in-plane magnetic field
Authors:
Beom Hyun Kim
Abstract:
We have investigated the field-angle behaviors of magnetic excitations under an in-plane magnetic field for proximate Kitaev systems. By employing the exact diagonalization method in conjunction with the linear spin wave theory, we have demonstrated that the magnetic excitation gap in the polarized phase is determined by the magnon excitation at $M$ points and has a strong anisotropy with respect…
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We have investigated the field-angle behaviors of magnetic excitations under an in-plane magnetic field for proximate Kitaev systems. By employing the exact diagonalization method in conjunction with the linear spin wave theory, we have demonstrated that the magnetic excitation gap in the polarized phase is determined by the magnon excitation at $M$ points and has a strong anisotropy with respect to the field direction in the vicinity of the critical field limit. The specific heat from this magnon excitation bears qualitatively the same anisotropic behaviors as expected one for the non-Abelian spin liquid phase in the Kitaev model and experimentally observed one of the intermediate phases in $α$-RuCl$_3$.
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Submitted 14 October, 2021; v1 submitted 10 July, 2021;
originally announced July 2021.
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Exciton-driven antiferromagnetic metal in a correlated van der Waals insulator
Authors:
Carina A. Belvin,
Edoardo Baldini,
Ilkem Ozge Ozel,
Dan Mao,
Hoi Chun Po,
Clifford J. Allington,
Suhan Son,
Beom Hyun Kim,
Jonghyeon Kim,
Inho Hwang,
Jae Hoon Kim,
Je-Geun Park,
T. Senthil,
Nuh Gedik
Abstract:
Collective excitations of bound electron-hole pairs -- known as excitons -- are ubiquitous in condensed matter, emerging in systems as diverse as band semiconductors, molecular crystals, and proteins. Recently, their existence in strongly correlated electron materials has attracted increasing interest due to the excitons' unique coupling to spin and orbital degrees of freedom. The non-equilibrium…
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Collective excitations of bound electron-hole pairs -- known as excitons -- are ubiquitous in condensed matter, emerging in systems as diverse as band semiconductors, molecular crystals, and proteins. Recently, their existence in strongly correlated electron materials has attracted increasing interest due to the excitons' unique coupling to spin and orbital degrees of freedom. The non-equilibrium driving of such dressed quasiparticles offers a promising platform for realizing unconventional many-body phenomena and phases beyond thermodynamic equilibrium. Here, we achieve this in the van der Waals correlated insulator NiPS$_3$ by photoexciting its newly discovered spin-orbit-entangled excitons that arise from Zhang-Rice states. By monitoring the time evolution of the terahertz conductivity, we observe the coexistence of itinerant carriers produced by exciton dissociation and the long-wavelength antiferromagnetic magnon that coherently precesses in time. These results demonstrate the emergence of a transient metallic state that preserves long-range antiferromagnetism, a phase that cannot be reached by simply tuning the temperature. More broadly, our findings open an avenue toward the exciton-mediated optical manipulation of magnetism.
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Submitted 15 June, 2021;
originally announced June 2021.
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Modulating Curie Temperature and Magnetic Anisotropy in Nanoscale Layered Cr_{2}Te_{3} Films: Implications for Room-Temperature Spintronics
Authors:
In Hak Lee,
Byoung Ki Choi,
Hyuk Jin Kim,
Min Jay Kim,
Hu Young Jeong,
Jong Hoon Lee,
Seung-Young Park,
Younghun Jo,
Chanki Lee,
Jun Woo Choi,
Seong Won Cho,
Suyuon Lee,
Younghak Kim,
Beom Hyun Kim,
Kyeong Jun Lee,
Jin Eun Heo,
Seo Hyoung Chang,
Fengping Li,
Bheema Lingam Chittari,
Jeil Jung,
Young Jun Chang
Abstract:
Nanoscale layered ferromagnets have demonstrated fascinating two-dimensional magnetism down to atomic layers, providing a peculiar playground of spin orders for investigating fundamental physics and spintronic applications. However, strategy for growing films with designed magnetic properties is not well established yet. Herein, we present a versatile method to control the Curie temperature (T_{C}…
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Nanoscale layered ferromagnets have demonstrated fascinating two-dimensional magnetism down to atomic layers, providing a peculiar playground of spin orders for investigating fundamental physics and spintronic applications. However, strategy for growing films with designed magnetic properties is not well established yet. Herein, we present a versatile method to control the Curie temperature (T_{C}) and magnetic anisotropy during growth of ultrathin Cr_{2}Te_{3} films. We demonstrate increase of the TC from 165 K to 310 K in sync with magnetic anisotropy switching from an out-of-plane orientation to an in-plane one, respectively, via controlling the Te source flux during film growth, leading to different c-lattice parameters while preserving the stoichiometries and thicknesses of the films. We attributed this modulation of magnetic anisotropy to the switching of the orbital magnetic moment, using X-ray magnetic circular dichroism analysis. We also inferred that different c-lattice constants might be responsible for the magnetic anisotropy change, supported by theoretical calculations. These findings emphasize the potential of ultrathin Cr_{2}Te_{3} films as candidates for developing room-temperature spintronics applications and similar growth strategies could be applicable to fabricate other nanoscale layered magnetic compounds.
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Submitted 5 April, 2021;
originally announced April 2021.
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Interplay between multipolar spin interactions, Jahn-Teller effect and electronic correlation in a $J_{eff}=\frac{3}{2}$ insulator
Authors:
Dario Fiore Mosca,
Leonid V. Pourovskii,
Beom Hyun Kim,
Peitao Liu,
Samuele Sanna,
Federico Boscherini,
Sergii Khmelevskyi,
Cesare Franchini
Abstract:
In this work we study the complex entanglement between spin interactions, electron correlation and Janh-Teller structural instabilities in the 5d$^1$ $J_{eff}=\frac{3}{2}$ spin-orbit coupled double perovskite $\rm Ba_2NaOsO_6$ using first principles approaches. By combining non-collinear magnetic calculations with multipolar pseudospin Hamiltonian analysis and many-body techniques we elucidate the…
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In this work we study the complex entanglement between spin interactions, electron correlation and Janh-Teller structural instabilities in the 5d$^1$ $J_{eff}=\frac{3}{2}$ spin-orbit coupled double perovskite $\rm Ba_2NaOsO_6$ using first principles approaches. By combining non-collinear magnetic calculations with multipolar pseudospin Hamiltonian analysis and many-body techniques we elucidate the origin of the observed quadrupolar canted antifferomagnetic. We show that the non-collinear magnetic order originates from Jahn-Teller distortions due to the cooperation of Heisenberg exchange, quadrupolar spin-spin terms and both dipolar and multipolar Dzyaloshinskii-Moriya interactions. We find a strong competition between ferromagnetic and antiferromagnetic canted and collinear quadrupolar magnetic phases: the transition from one magnetic order to another can be controlled by the strength of the electronic correlation ($U$) and by the degree of Jahn-Teller distortions.
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Submitted 22 February, 2021;
originally announced February 2021.
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Proximate Kitaev system for an intermediate magnetic phase in in-plane magnetic fields
Authors:
Beom Hyun Kim,
Shigetoshi Sota,
Tomonori Shirakawa,
Seiji Yunoki,
Young-Woo Son
Abstract:
Motivated by the magnetic phase transition of a proximate Kitaev system $α$-RuCl$_3$ in the presence of a magnetic field, we study the simplest but essential quantum spin model with the ferromagnetic nearest neighboring (NN) Kitaev interaction and additional antiferromagnetic third NN Heisenberg interaction. Employing both exact diagonalization and density matrix renormalization group methods, we…
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Motivated by the magnetic phase transition of a proximate Kitaev system $α$-RuCl$_3$ in the presence of a magnetic field, we study the simplest but essential quantum spin model with the ferromagnetic nearest neighboring (NN) Kitaev interaction and additional antiferromagnetic third NN Heisenberg interaction. Employing both exact diagonalization and density matrix renormalization group methods, we demonstrate that the model shows the magnetic phase transition from the zigzag order phase to the spin polarized phase through an intermediate phase in both cases when an in-plane magnetic field is applied perpendicular to the NN bond direction and when an out-of-plane field is applied, in good agreement with experimental observations. Furthermore, we verify that additional symmetric off-diagonal $Γ$ interaction and ferromagnetic Heisenberg interaction between NN spins can both suppress the intermediate phase with the in-plane field. Our result gives important clues on determining relevant interactions in the field-induced magnetic phase transition of proximate Kiteav systems.
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Submitted 6 October, 2020; v1 submitted 6 June, 2020;
originally announced June 2020.
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Topological property of a $t_{2g}^5$ system with a honeycomb lattice structure
Authors:
Beom Hyun Kim,
Kazuhiro Seki,
Tomonori Shirakawa,
Seiji Yunoki
Abstract:
A $t_{2g}^5$ system with a honeycomb lattice structure such as Na$_2$IrO$_3$ was firstly proposed as a topological insulator even though Na$_2$IrO$_3$ and its isostructural materials in nature have been turned out to be a Mott insulator with magnetic order. Here we theoretically revisit the topological property based on a minimal tight-binding Hamiltonian for three $t_{2g}$ bands incorporating a s…
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A $t_{2g}^5$ system with a honeycomb lattice structure such as Na$_2$IrO$_3$ was firstly proposed as a topological insulator even though Na$_2$IrO$_3$ and its isostructural materials in nature have been turned out to be a Mott insulator with magnetic order. Here we theoretically revisit the topological property based on a minimal tight-binding Hamiltonian for three $t_{2g}$ bands incorporating a strong spin orbit coupling and two types of the first nearest neighbor (NN) hopping channel between transition metal ions, i.e., the hopping ($t_1$) mediated by edge-shared ligands and the direct hopping ($t_1'$) between $t_{2g}$ orbitals via $ddσ$ bonding. We demonstrate that the topological phase transition takes place by varying only these hopping parameters with the relative strength parametrized by $θ$, i.e., $t_1=t\cosθ$ and $t_1'=t\sinθ$. We also explore the effect of the second and third NN hopping channels, and the trigonal distortion on the topological phase for the whole range of $θ$. Furthermore, we examine the electronic and topological phases in the presence of on-site Coulomb repulsion $U$. Employing the cluster perturbation theory, we show that, with increasing $U$, a trivial or topological band insulator in the absence of $U$ can be transferred into a Mott insulator with nontrivial or trivial band topology. We also show that the main effect of the Hund's coupling can be understood simply as the renormalization of $U$. We briefly discuss the relevance of our results to the existing materials.
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Submitted 8 April, 2019; v1 submitted 16 January, 2019;
originally announced January 2019.
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Orbital-selective confinement effect of Ru $4d$ orbitals in SrRuO$_3$ ultrathin film
Authors:
Soonmin Kang,
Yi Tseng,
Beom Hyun Kim,
Seokhwan Yun,
Byungmin Sohn,
Bongju Kim,
Daniel McNally,
Eugenio Paris,
Choong H. Kim,
Changyoung Kim,
Tae Won Noh,
Sumio Ishihara,
Thorsten Schmitt,
Je-Geun Park
Abstract:
The electronic structure of SrRuO$_3$ thin film with thickness from 50 to 1 unit cell (u.c.) is investigated via the resonant inelastic x-ray scattering (RIXS) technique at the O K-edge to unravel the intriguing interplay of orbital and charge degrees of freedom. We found that orbital-selective quantum confinement effect (QCE) induces the splitting of Ru $4d$ orbitals. At the same time, we observe…
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The electronic structure of SrRuO$_3$ thin film with thickness from 50 to 1 unit cell (u.c.) is investigated via the resonant inelastic x-ray scattering (RIXS) technique at the O K-edge to unravel the intriguing interplay of orbital and charge degrees of freedom. We found that orbital-selective quantum confinement effect (QCE) induces the splitting of Ru $4d$ orbitals. At the same time, we observed a clear suppression of the electron-hole continuum across the metal-to-insulator transition (MIT) occurring at the 4 u.c. sample. From these two clear observations we conclude that QCE gives rise to a Mott insulating phase in ultrathin SrRuO$_3$ films. Our interpretation of the RIXS spectra is supported by the configuration interaction calculations of RuO$_6$ clusters.
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Submitted 24 December, 2018;
originally announced December 2018.
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Spin-orbital excitons and their potential condensation in pentavalent iridates
Authors:
Beom Hyun Kim,
Dmitry V. Efremov,
Jeroen van den Brink
Abstract:
We investigate magnetic excitations in iridium insulators with pentavalent Ir$^{5+}$ ($5d^4$) ions with strong spin-orbit coupling. We obtain a microscopic model based on the local Ir$^{5+}$ multiplets involving $J=0$ (singlet), $J=1$ (triplet), and $J=2$ (quintet) spin-orbital states. We get effective interactions between these multiplets on square and face-centered-cubic (fcc) structures of magn…
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We investigate magnetic excitations in iridium insulators with pentavalent Ir$^{5+}$ ($5d^4$) ions with strong spin-orbit coupling. We obtain a microscopic model based on the local Ir$^{5+}$ multiplets involving $J=0$ (singlet), $J=1$ (triplet), and $J=2$ (quintet) spin-orbital states. We get effective interactions between these multiplets on square and face-centered-cubic (fcc) structures of magnetic ions in the layered-perovskites and the double-perovkites, in particular Ba$_2$YIrO$_6$. Further, we derive an effective spin-orbital Hamiltonian in terms of bond bosons and explore possible instabilities towards magnetic and quadrupole orderings. Additionally, we study charge excitations with help of the variational cluster perturbation theory and calculate the electronic charge gap as a function of hopping and Coulomb interactions. Based on both electronic and magnetic phase diagrams, we verify the possibility of excitonic magnetism due to condensation of spin-orbital excitons in Ir$^{5+}$ iridates.
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Submitted 6 January, 2019; v1 submitted 30 October, 2018;
originally announced October 2018.
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Direct experimental observation of the molecular Jeff=3/2 ground state in the lacunar spinel GaTa4Se8
Authors:
Min Yong Jeong,
Seo Hyoung Chang,
Beom Hyun Kim,
Jae-Hoon Sim,
Ayman Said,
Diego Casa,
Thomas Gog,
Etienne Janod,
Laurent Cario,
Seiji Yunoki,
Myung Joon Han,
Jungho Kim
Abstract:
Strong spin-orbit coupling lifts the degeneracy of t2g orbitals in 5d transition-metal systems, leaving a Kramers doublet and quartet with effective angular momentum of Jeff = 1/2 and 3/2, respectively. These spin-orbit entangled states can host exotic quantum phases such as topological Mott state, unconventional superconductivity, and quantum spin liquid. The lacunar spinel GaTa4Se8 was theoretic…
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Strong spin-orbit coupling lifts the degeneracy of t2g orbitals in 5d transition-metal systems, leaving a Kramers doublet and quartet with effective angular momentum of Jeff = 1/2 and 3/2, respectively. These spin-orbit entangled states can host exotic quantum phases such as topological Mott state, unconventional superconductivity, and quantum spin liquid. The lacunar spinel GaTa4Se8 was theoretically predicted to form the molecular Jeff = 3/2 ground state. Experimental verification of its existence is an important first step to exploring the consequences of the Jeff = 3/2 state. Here, we report direct experimental evidence of the Jeff = 3/2 state in GaTa4Se8 by means of excitation spectra of resonant inelastic x-rays scattering at the Ta L3 and L2 edges. We found that the excitations involving the Jeff = 1/2 molecular orbital were suppressed only at the Ta L2 edge, manifesting the realization of the molecular Jeff = 3/2 ground state in GaTa4Se8.
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Submitted 20 October, 2017; v1 submitted 4 August, 2017;
originally announced August 2017.
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Optical Signatures of Spin-Orbit Exciton in Bandwidth Controlled Sr$_2$IrO$_4$ Epitaxial Films via High-Concentration Ca and Ba Doping
Authors:
M. Souri,
B. H. Kim,
J. H. Gruenewald,
J. G. Connell,
J. Thompson,
J. Nichols,
J. Terzic,
B. I. Min,
G. Cao,
J. W. Brill,
A. Seo
Abstract:
We have investigated the electronic and optical properties of (Sr$_{1-x}$Ca$_{x}$)$_2$IrO$_4$ (x= 0 - 0.375) and (Sr$_{1-y}$Ba$_y$)$_2$IrO$_4$ (y= 0 - 0.375) epitaxial thin-films, in which the bandwidth is systematically tuned via chemical substitutions of Sr ions by Ca and Ba. Transport measurements indicate that the thin-film series exhibits insulating behavior, similar to the J$_{eff}$= 1/2 spi…
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We have investigated the electronic and optical properties of (Sr$_{1-x}$Ca$_{x}$)$_2$IrO$_4$ (x= 0 - 0.375) and (Sr$_{1-y}$Ba$_y$)$_2$IrO$_4$ (y= 0 - 0.375) epitaxial thin-films, in which the bandwidth is systematically tuned via chemical substitutions of Sr ions by Ca and Ba. Transport measurements indicate that the thin-film series exhibits insulating behavior, similar to the J$_{eff}$= 1/2 spin-orbit Mott insulator Sr$_2$IrO$_4$. As the average A-site ionic radius increases from (Sr$_{1-x}$Ca$_{x}$)$_2$IrO$_4$ to (Sr$_{1-y}$Ba$_y$)$_2$IrO$_4$, optical conductivity spectra in the near-infrared region shift to lower energies, which cannot be explained by the simple picture of well-separated J$_{eff}$= 1/2 and J$_{eff}$= 3/2 bands. We suggest that the two-peak-like optical conductivity spectra of the layered iridates originates from the overlap between the optically-forbidden spin-orbit exciton and the inter-site optical transitions within the J$_{eff}$= 1/2 band. Our experimental results are consistent with this interpretation as implemented by a multi-orbital Hubbard model calculation: namely, incorporating a strong Fano-like coupling between the spin-orbit exciton and inter-site d-d transitions within the J$_{eff}$= 1/2 band.
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Submitted 12 June, 2017;
originally announced June 2017.
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Electronic Structure of the Kitaev Material $α$-$\textrm{RuCl}_3$ Probed by Photoemission and Inverse Photoemission Spectroscopies
Authors:
Soobin Sinn,
Choong Hyun Kim,
Beom Hyun Kim,
Kyung Dong Lee,
Choong Jae Won,
Ji Seop Oh,
Moonsup Han,
Young Jun Chang,
Namjung Hur,
Hitoshi Sato,
Byeong-Gyu Park,
Changyoung Kim,
Hyeong-Do Kim,
Tae Won Noh
Abstract:
Recently, $α$-$\textrm{RuCl}_3$ has attracted much attention as a possible material realization of the honeycomb Kitaev model, which may stabilize a quantum-spin-liquid state. Compared to extensive studies on its magnetic properties, there is still a lack of understanding on its electronic structure, which is strongly related with its Kitaev physics. Here, the electronic structure of $α$-…
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Recently, $α$-$\textrm{RuCl}_3$ has attracted much attention as a possible material realization of the honeycomb Kitaev model, which may stabilize a quantum-spin-liquid state. Compared to extensive studies on its magnetic properties, there is still a lack of understanding on its electronic structure, which is strongly related with its Kitaev physics. Here, the electronic structure of $α$-$\textrm{RuCl}_3$ is investigated by photoemission (PE) and inverse photoemission (IPE) spectroscopies. The band gap, directly measured from PE/IPE spectra, is found to be 1.9 eV, much larger than previous estimations. The LDA calculations show that the on-site Coulomb interaction $\textit{U}$ can open the band gap without spin-orbit coupling (SOC). However, the SOC should also be incorporated to reproduce the proper gap size, indicating that the interplay between $\textit{U}$ and SOC plays an essential role in the physics of $α$-$\textrm{RuCl}_3$. There exist some spectral features in PE/IPE spectra which cannot be explained by the LDA calculations. To explain such discrepancies, we perform the configuration-interaction calculations for a ${\textrm{RuCl}}_6^{3-}$ cluster. The experimental data and calculations demonstrate that the 4$\textit{d}$ compound $α$-$\textrm{RuCl}_3$ is a $J_{\textrm{eff}}$ = 1/2 Mott insulator rather than a quasimolecular-orbital insulator. Our study also provides important physical parameters, required in verifying the proposed Kitaev physics in $α$-$\textrm{RuCl}_3$.
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Submitted 22 August, 2016;
originally announced August 2016.
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From a quasimolecular band insulator to a relativistic Mott insulator in $t_{2g}^5$ systems with a honeycomb lattice structure
Authors:
Beom Hyun Kim,
Tomonori Shirakawa,
Seiji Yunoki
Abstract:
The $t_{2g}$ orbitals of an edge-shared transition-metal oxide with a honeycomb lattice structure form dispersionless electronic bands when only hopping mediated by the edge-sharing oxygens is accessible. This is due to the formation of isolated quasimolecular orbitals (QMOs) in each hexagon, introduced recently by Mazin et al. [Phys. Rev. Lett. 109, 197201 (2012)], which stabilizes a band insulat…
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The $t_{2g}$ orbitals of an edge-shared transition-metal oxide with a honeycomb lattice structure form dispersionless electronic bands when only hopping mediated by the edge-sharing oxygens is accessible. This is due to the formation of isolated quasimolecular orbitals (QMOs) in each hexagon, introduced recently by Mazin et al. [Phys. Rev. Lett. 109, 197201 (2012)], which stabilizes a band insulating phase for $t_{2g}^5$ systems. However, with help of the exact diagonalization method to treat the electron kinetics and correlations on an equal footing, we find that the QMOs are fragile against not only the spin-orbit coupling (SOC) but also the Coulomb repulsion. We show that the electronic phase of $t_{2g}^5$ systems can vary from a quasimolecular band insulator to a relativistic $J_{\rm eff}=1/2$ Mott insulator with increasing the SOC as well as the Coulomb repulsion. The different electronic phases manifest themselves in electronic excitations observed in optical conductivity and resonant inelastic x-ray scattering. Based on our calculations, we assert that the currently known Ru$^{3+}$- and Ir$^{4+}$-based honeycomb systems are far from the quasimolecular band insulator but rather the relativistic Mott insulator.
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Submitted 6 October, 2016; v1 submitted 22 June, 2016;
originally announced June 2016.
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Electrical Transport Property of ZnO Thin Films in High H2 Pressure up to 20 bar
Authors:
Hyunggon Chu,
Byung Hoon Kim,
Joonhee Kang
Abstract:
We have investigated the H2 pressure-dependent (from vacuum to 20 bar) current-voltage characteristics of ZnO thin films prepared by spin coating method. The gas pressure effect on conductance (G) was subtracted using He gas. The G increased as applying 2 bar of H2 pressure, and then it monotonously decreased with the further increment of H2 pressure. Using X-ray diffraction patterns and X-ray pho…
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We have investigated the H2 pressure-dependent (from vacuum to 20 bar) current-voltage characteristics of ZnO thin films prepared by spin coating method. The gas pressure effect on conductance (G) was subtracted using He gas. The G increased as applying 2 bar of H2 pressure, and then it monotonously decreased with the further increment of H2 pressure. Using X-ray diffraction patterns and X-ray photoelectron spectroscopy before and after H2 exposure, we found that the H2 spillover effect plays an important role in the variation of G of ZnO film.
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Submitted 23 May, 2016;
originally announced May 2016.
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Substrate-tuning of correlated spin-orbit oxides
Authors:
Bongjae Kim,
Beom Hyun Kim,
Kyoo Kim,
B. I. Min
Abstract:
We have systematically investigated substrate-strain effects on the electronic structures of two representative Sr-iridates, a correlated-insulator Sr$_2$IrO$_4$ and a metal SrIrO$_3$. Optical conductivities obtained by the \emph{ab initio} electronic structure calculations reveal that the tensile strain shifts the optical peak positions to higher energy side with altered intensities, suggesting t…
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We have systematically investigated substrate-strain effects on the electronic structures of two representative Sr-iridates, a correlated-insulator Sr$_2$IrO$_4$ and a metal SrIrO$_3$. Optical conductivities obtained by the \emph{ab initio} electronic structure calculations reveal that the tensile strain shifts the optical peak positions to higher energy side with altered intensities, suggesting the enhancement of the electronic correlation and spin-orbit coupling (SOC) strength in Sr-iridates. The response of the electronic structure upon tensile strain is found to be highly correlated with the direction of magnetic moment, the octahedral connectivity, and the SOC strength, which cooperatively determine the robustness of $J_{eff}$=1/2 ground states. Optical responses are analyzed also with microscopic model calculation and compared with corresponding experiments. In the case of SrIrO$_3$, the evolution of the electronic structure near the Fermi level shows high tunability of hole bands, as suggested by previous experiments.
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Submitted 18 December, 2015;
originally announced December 2015.
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The Insulating Nature of Na2IrO3: Mott-type or Slater-type?
Authors:
Minjae Kim,
Beom Hyun Kim,
B. I. Min
Abstract:
We have investigated temperature-dependent electronic structures of Na2IrO3 to unravel its insulating nature. Employing the combined scheme of the density-functional theory (DFT) and the dynamical mean-field theory (DMFT), we have shown that the insulating state persists even above the Neel temperature (T_{N}), which reveals that Na2IrO3 is classified into a Mott-type insulator. The measured photo…
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We have investigated temperature-dependent electronic structures of Na2IrO3 to unravel its insulating nature. Employing the combined scheme of the density-functional theory (DFT) and the dynamical mean-field theory (DMFT), we have shown that the insulating state persists even above the Neel temperature (T_{N}), which reveals that Na2IrO3 is classified into a Mott-type insulator. The measured photoemission spectrum in the paramagnetic (PM) state is well described by the electronic structure obtained from the DFT+DMFT for the insulating state above T_{N}. The analysis of optical conductivity, however, suggests that the non-local correlation effect is also important in Na2IrO3. Therefore, Na2IrO3 is not to be a standard Mott insulator in that the extended nature and the non-local correlation effect of Ir 5d electrons are important as well in describing its electronic and magnetic properties.
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Submitted 2 July, 2015;
originally announced July 2015.
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Resonant inelastic x-ray scattering on single-magnons at oxygen $K$-edges
Authors:
Beom Hyun Kim,
Jeroen van den Brink
Abstract:
The recent discovery that resonant inelastic x-ray scattering can probe single-magnon (SM) dispersions in transition metal (TM) oxides when the x-ray energy is tuned to the TM $L$-edge, has put this technique on a par with inelastic neutron scattering. It is generally presumed that selection rules forbid SM-scattering at oxygen (O) $K$-edges. However, based on a symmetry analysis and exact diagona…
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The recent discovery that resonant inelastic x-ray scattering can probe single-magnon (SM) dispersions in transition metal (TM) oxides when the x-ray energy is tuned to the TM $L$-edge, has put this technique on a par with inelastic neutron scattering. It is generally presumed that selection rules forbid SM-scattering at oxygen (O) $K$-edges. However, based on a symmetry analysis and exact diagonalization study, we show that SM-scattering at O K-edges becomes allowed when (i) spin-orbit coupling is present in the TM d-shell and (ii) inversion symmetry at the O-site is broken. For cuprates the resulting SM-amplitude is very weak but in iridates both prerequisites can amply be fulfilled.
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Submitted 8 April, 2014;
originally announced April 2014.
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Electronic excitations in the edge-shared relativistic Mott insulator: Na$_2$IrO$_3$
Authors:
Beom Hyun Kim,
G. Khaliullin,
B. I. Min
Abstract:
We have investigated the excitation spectra of $j_{eff}$=$\frac{1}{2}$ Mott insulator Na$_2$IrO$_3$. Taking into account a relativistic multiplet structure of Ir ions, we have calculated the optical conductivity $σ(ω)$ and resonant inelastic x-ray scattering (RIXS) spectra, which manifest different features from those of a canonical $j_{eff}$=$\frac{1}{2}$ system Sr$_2$IrO$_4$.Distinctly from the…
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We have investigated the excitation spectra of $j_{eff}$=$\frac{1}{2}$ Mott insulator Na$_2$IrO$_3$. Taking into account a relativistic multiplet structure of Ir ions, we have calculated the optical conductivity $σ(ω)$ and resonant inelastic x-ray scattering (RIXS) spectra, which manifest different features from those of a canonical $j_{eff}$=$\frac{1}{2}$ system Sr$_2$IrO$_4$.Distinctly from the two-peak structure in Sr$_2$IrO$_4$, $σ(ω)$ in Na$_2$IrO$_3$ has a broad single peak dominated by interband transitions from $j_{eff}$=$\frac{3}{2}$ to $\frac{1}{2}$. RIXS spectra exhibit the spin-orbit (SO) exciton that has a two-peak structure arising from the crystal-field effect, and the magnon peak at energies much lower than in Sr$_2$IrO$_4$. In addition, a small peak near the optical absorption edge is found in RIXS spectra, originating from the coupling between the electron-hole ($e$-$h$) excitation and the SO exciton. Our findings corroborate the validity of the relativistic electronic structure and importance of both itinerant and local features in Na$_2$IrO$_3$.
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Submitted 24 February, 2014; v1 submitted 2 July, 2013;
originally announced July 2013.
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Magnetic couplings, optical spectra, and spin-orbit exciton in 5d electron Mott insulator Sr2IrO4
Authors:
Beom Hyun Kim,
G. Khaliullin,
B. I. Min
Abstract:
Based on the microscopic model including strong spin-orbit coupling, on-site Coulomb and Hund's interactions, as well as crystal field effects, we have investigated magnetic and optical properties of Sr2IrO4. Taking into account all possible intermediate state multiplets generated by virtual hoppings of electrons, we calculated the isotropic Heisenberg, pseudodipolar, and Dzyaloshinsky-Moriya coup…
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Based on the microscopic model including strong spin-orbit coupling, on-site Coulomb and Hund's interactions, as well as crystal field effects, we have investigated magnetic and optical properties of Sr2IrO4. Taking into account all possible intermediate state multiplets generated by virtual hoppings of electrons, we calculated the isotropic Heisenberg, pseudodipolar, and Dzyaloshinsky-Moriya coupling constants, which describe the experiment quite well. We have also evaluated the optical conductivity σ(ω) by employing the exact diagonalization method on small clusters, and obtained two peaks at \sim 0.5 and \sim 1.0 eV in agreement with experiment. The two peak structure of σ(ω) arises from the unusual Fano-type overlap between electron-hole continuum of the Jeff = 1/2 band and the intrasite spin-orbit exciton observed recently in Sr2IrO4 by resonant x-ray scattering.
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Submitted 18 September, 2012; v1 submitted 15 May, 2012;
originally announced May 2012.
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Fermi Surface Reconstruction in CeTe2 Induced by Charge Density Wave: ARPES Study
Authors:
J. -S. Kang,
D. H. Kim,
H. J. Lee,
J. H. Hwang,
Han-Koo Lee,
H. -D. Kim,
B. H. Min,
K. E. Lee,
Y. S. Kwon,
J. W. Kim,
Kyoo Kim,
B. H. Kim,
B. I. Min
Abstract:
Electronic structures of a charge-density-wave CDW system CeTe_2-xSb_x (x=0, 0.05) have been investigated by employing angle-resolved photoemission spectroscopy (ARPES). The observed Fermi surface (FS) agrees very well with the calculated FS for the undistorted CeTe_2 both in shapes and sizes. The metallic states crossing the Fermi level(E_F) are observed in ARPES. The carriers near E_F have mainl…
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Electronic structures of a charge-density-wave CDW system CeTe_2-xSb_x (x=0, 0.05) have been investigated by employing angle-resolved photoemission spectroscopy (ARPES). The observed Fermi surface (FS) agrees very well with the calculated FS for the undistorted CeTe_2 both in shapes and sizes. The metallic states crossing the Fermi level(E_F) are observed in ARPES. The carriers near E_F have mainly the Te(1) 5p character, with the negligible contribution from Ce 4f states to the CDW formation. The supercell (shadow) bands and the corresponding very weak FS's are found to arise from band-folding due to the interaction with Ce-Te(2) layers. This work shows that the origin of the CDW formation in CeTe_2 is the FS nesting and that the CDW modulation vector is along Gamma-X (Q_CDW ~ X)
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Submitted 2 September, 2011;
originally announced September 2011.
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Antiferromagnetic and structural transitions in the superoxide KO2 from first principles: A 2p-electron system with spin-orbital-lattice coupling
Authors:
Minjae Kim,
Beom Hyun Kim,
Hong Chul Choi,
B. I. Min
Abstract:
KO2 exhibits concomitant antiferromagnetic (AFM) and structural transitions, both of which originate from the open-shell 2p electrons of O$_{2}^{-}$ molecules. The structural transition is accompanied by the coherent tilting of O$_{2}^{-}$ molecular axes. The interplay among the spin-orbital-lattice degrees of freedom in KO2 is investigated by employing the first-principles electronic structure…
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KO2 exhibits concomitant antiferromagnetic (AFM) and structural transitions, both of which originate from the open-shell 2p electrons of O$_{2}^{-}$ molecules. The structural transition is accompanied by the coherent tilting of O$_{2}^{-}$ molecular axes. The interplay among the spin-orbital-lattice degrees of freedom in KO2 is investigated by employing the first-principles electronic structure theory and the kinetic-exchange interaction scheme. We have shown that the insulating nature of the high symmetry phase of KO2 at high temperature (T) arises from the combined effect of the spin-orbit coupling and the strong Coulomb correlation of O 2p electrons. In contrast, for the low symmetry phase of KO2 at low T with the tilted O$_{2}^{-}$ molecular axes, the band gap and the orbital ordering are driven by the combined effects of the crystal-field and the strong Coulomb correlation. We have verified that the emergence of the O 2p ferro-orbital ordering is essential to achieve the observed AFM structure for KO2.
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Submitted 3 December, 2009; v1 submitted 30 November, 2009;
originally announced November 2009.
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Thermoelectric Power in the Double Exchange Model
Authors:
Beom Hyun Kim,
Unjong Yu,
Kyoo Kim,
B. I. Min
Abstract:
Employing the Monte-Carlo method and the exact diagonalization, we have investigated the temperature dependence of the thermoelectric power (TEP) for the double exchange model in the dilute carrier concentration limit. We have found that the TEP follows the Heikes formula in the high temperature regime, whereas, in the intermediate temperature regime, the TEP is suppressed by the exchange coupli…
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Employing the Monte-Carlo method and the exact diagonalization, we have investigated the temperature dependence of the thermoelectric power (TEP) for the double exchange model in the dilute carrier concentration limit. We have found that the TEP follows the Heikes formula in the high temperature regime, whereas, in the intermediate temperature regime, the TEP is suppressed by the exchange coupling between itinerant electrons and local spins. In the low temperature regime, the TEP exhibits an anomalous peak and dip feature near the magnetic transition temperature $T_C$ which can be understood based on the magnetic polaron state. We have also found that the TEP, in the presence of the magnetic field, shows the positive magnetothermoelectric power near $T_C$.
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Submitted 10 January, 2008; v1 submitted 19 December, 2007;
originally announced December 2007.