Showing 1–20 of 20 results for author: Guin, S

Anomalous Hall Effect in Silicon-Compatible Altermagnetic alpha-MnTe Thin Films

Authors: Rajib Sarkar, Subhransu Kumar Negi, Arindom Das, Arijit Mandal, Pankaj Bhardwaj, Sohini Guin, Aryaman Das, Naresh Shyaga, Laxmipriya Nanda, B. R. K. Nanda, Dhavala Suri

Abstract: Integrating spin-dependent functionality with mainstream semiconductor technology is a central goal of modern spintronics, yet most candidate materials remain incompatible with silicon-based platforms. Here, we report the direct epitaxial integration of alpha-MnTe thin films on Si(111) via molecular beam epitaxy and demonstrate a robust anomalous Hall effect (AHE) in this silicon-compatible alterm… ▽ More Integrating spin-dependent functionality with mainstream semiconductor technology is a central goal of modern spintronics, yet most candidate materials remain incompatible with silicon-based platforms. Here, we report the direct epitaxial integration of alpha-MnTe thin films on Si(111) via molecular beam epitaxy and demonstrate a robust anomalous Hall effect (AHE) in this silicon-compatible altermagnetic system. Despite the absence of net magnetization, the films exhibit a pronounced hysteretic Hall response, providing clear evidence of finite Berry curvature generated by symmetry breaking in the thin-film geometry. High resolution structural and spectroscopic characterization confirms phase-pure, epitaxial growth with hexagonal NiAs-type symmetry, while magnetotransport measurements reveal correlated hysteresis in both transverse and longitudinal channels with systematic temperature evolution. First-principles calculations reveal substantial uncompensated Berry curvature arising from the spin-split band structure consistent with altermagnetic symmetry and the origin of the observed Hall response. These results establish MnTe/Si(111) as a silicon-compatible altermagnetic platform and chart a concrete pathway for embedding Berry-phase-driven functionalities into scalable semiconductor device architectures. △ Less

Submitted 25 May, 2026; originally announced May 2026.

Vortex Transport in Ni/Bi Bilayer Superconductor with Strong Spin-Orbit and Exchange Interaction

Authors: Laxmipriya Nanda, Sohini Guin, Yasen Hou, Rajib Sarkar, Naresh Shyaga, Souvik Banerjee, A. Sundaresan, N. S. Vidhyadhiraja, Jagadeesh S. Moodera, Dhavala Suri

Abstract: Nickel/bismuth (Ni/Bi) bilayers are a promising platform for exploring unconventional superconductivity. Ferromagnetic Ni is coupled to Bi, a strong spin orbit metal that only becomes superconducting below approx 10 mK, forming a bilayer exhibits superconductivity at a much higher temperatures, a Tc of 3 to 4 K. Such a bilayer thus makes an ideal system to probe Cooper pairing in strong spin orbit… ▽ More Nickel/bismuth (Ni/Bi) bilayers are a promising platform for exploring unconventional superconductivity. Ferromagnetic Ni is coupled to Bi, a strong spin orbit metal that only becomes superconducting below approx 10 mK, forming a bilayer exhibits superconductivity at a much higher temperatures, a Tc of 3 to 4 K. Such a bilayer thus makes an ideal system to probe Cooper pairing in strong spin orbit coupled magnetic environments. Magneto transport studies near Tc reveal the behavior of vortex dynamics and exchange proximity effects. It is seen that isolated vortices of the bilayers respond sensitively to out of plane fields, producing antisymmetric transverse resistance peaks attributable to competing Magnus and viscous forces. Control experiments using a ferromagnetic insulator confirm that superconductivity extends throughout the bilayer, not just confined at the interface. Overall, the results provide a unified picture of transport dominated by vortex dynamics and show that a conventional s wave order parameter accounts for the observations, with any likely unconventional contributions being only subtle. △ Less

Submitted 4 May, 2026; originally announced May 2026.

Time Reversal Symmetry Broken Electronic Phases in Thin Films of Bi$_2$Sr$_2$CaCu$_2$O$_{8+δ}$

Authors: Sohini Guin, Naresh Shyaga, Jagadish Rajendran, Aryaman Das, Subhransu Kumar Negi, Saisab Bhowmik, Pankaj Bhardwaj, U. Chandni, Dhavala Suri

Abstract: High-temperature superconductors (high-Tc SCs) host a rich landscape of electronic phases encompassing the pseudogap, strange metal, superconducting, antiferromagnetic insulating, and Fermi-liquid regimes. The superconducting phase is notable for non-dissipative electronic functionality at relatively high temperatures. These phases are commonly probed in thermodynamic phase space by varying temper… ▽ More High-temperature superconductors (high-Tc SCs) host a rich landscape of electronic phases encompassing the pseudogap, strange metal, superconducting, antiferromagnetic insulating, and Fermi-liquid regimes. The superconducting phase is notable for non-dissipative electronic functionality at relatively high temperatures. These phases are commonly probed in thermodynamic phase space by varying temperature or current through the sample. They can also be probed by breaking time-reversal symmetry (TRS) with an external magnetic field, which yields transition signatures distinct from those arising solely from temperature or current tuning. Here we show that electron transport in Bi$_2$Sr$_2$CaCu$_2$O$_{8+δ}$ is primarily governed by two-dimensional superconductivity consistent with a Berezinskii-Kosterlitz-Thouless (BKT) topological phase transition, as supported by current-voltage characteristics measured under temperature variation; these measurements preserve TRS. In contrast, when an external magnetic field is applied, the superconducting state is consistently preceded by weak antilocalization (WAL), where bound vortex-antivortex pairs dissociate into a normal metallic state through an intermediate localized phase. We further establish that highly disordered films exhibit transport dominated by three-dimensional weak localization, with superconductivity entirely suppressed. △ Less

Submitted 12 August, 2026; v1 submitted 2 November, 2025; originally announced November 2025.

Comments: Central conclusions/inferences of the paper have changed significantly

Effect of Cr Segregation on Grain Growth in Nanocrystalline α-Fe Alloy: A Multiscale Modelling Approach

Authors: Sandip Guin, Albert Linda, Yu-Chieh Lo, Somanth Bhowmick, Rajdip Mukherjee

Abstract: We present a multiscale modelling framework that integrates density functional theory (DFT) with a phase-field model (PFM) to explore the intricate dynamics of grain growth in nanocrystalline α-Fe single-phase alloy in the presence of chromium (Cr) segregation. We begin our study by validating our simulation results for equilibrium segregation in stationary GB with Mclean isotherm. Polycrystal sim… ▽ More We present a multiscale modelling framework that integrates density functional theory (DFT) with a phase-field model (PFM) to explore the intricate dynamics of grain growth in nanocrystalline α-Fe single-phase alloy in the presence of chromium (Cr) segregation. We begin our study by validating our simulation results for equilibrium segregation in stationary GB with Mclean isotherm. Polycrystal simulations featuring nanocrystalline grains at different temperatures reveal that the grain growth kinetics depends on the ratio of Cr diffusivity to intrinsic GB mobility. In the absence of segregation, the relationship between the square of average grain size (d 2 ) and time (t) demonstrates a linear correlation. We observe that the d 2 vs. t plot exhibits a consistent linear trend up to a threshold grain size, independent of Cr segregation at GB. However, when Cr is segregated at GB, a deviation from this linear trend with a decreasing slope is evident within the temperature range of 700K to 900K beyond the threshold size. This threshold grain size decreases with increasing temperature. Notably, at 1000K, the deviation from the linear trend is observed from the initial stages of grain growth with segregation, albeit with a linear trend exhibiting a smaller slope. We also present an analytical formulation based on Cahn solute drag theory to predict grain growth behaviour in the presence of solute segregation and our simulation results well aligned this analytical formulation. △ Less

Submitted 12 June, 2024; originally announced June 2024.

Interplay between thermal and compositional gradients decides the microstructure during thermomigration: a phase-field study

Authors: Sandip Guin, Soumya Bandyopadhyay, Saswata Bhattacharyya, Rajdip Mukherjee

Abstract: The presence of thermal gradients in alloys often leads to non-uniformity in concentration profiles, which can induce the thermomigration of microstructural features such as precipitates. To investigate such microstructural changes, we present a phase-field model that incorporates coupling between concentration and thermal gradients. First, we simulated the evolution of non-uniform concentration p… ▽ More The presence of thermal gradients in alloys often leads to non-uniformity in concentration profiles, which can induce the thermomigration of microstructural features such as precipitates. To investigate such microstructural changes, we present a phase-field model that incorporates coupling between concentration and thermal gradients. First, we simulated the evolution of non-uniform concentration profiles in the single-phase regions of Fe-C and Fe-N alloy systems due to imposed thermal gradients. To validate our model with the classical experiments performed by Darken and Oriani, we studied the evolution of spatially varying concentration profiles where thermal gradients encompass single-phase and two-phase regions. We developed a parameterized thermodynamic description of the two-phase region of a binary alloy to systematically study the effect of interactions between chemically-driven and thermal gradient-driven diffusion of solute on the evolution of precipitates. Our simulations show how thermal gradient, precipitate size, and interparticle distance influence the migration and associated morphological changes of precipitates. The composition profiles and migration rates obtained from single-particle simulations show an exact match with our analytical model. We use twoparticle simulations to show conditions under which thermomigration induces the growth of the smaller particle and shrinkage of the larger one in contrast to the isothermal Ostwald ripening behavior. Our multiparticle simulations show similar behavior during coarsening. Moreover, in the presence of a thermal gradient, there is a shift in the center of mass of the precipitates towards the high-temperature region. Thus, our study offers new insights into the phenomena of microstructure evolution in the presence of thermal gradient. △ Less

Submitted 2 June, 2024; originally announced June 2024.

Discovery of a Topological Charge Density Wave

Authors: Maksim Litskevich, Md Shafayat Hossain, Songbo Zhang, Zi-Jia Cheng, Satya N. Guin, Nitesh Kumar, Chandra Shekhar, Zhiwei Wang, Yongkai Li, Guoqing Chang, Jia-Xin Yin, Qi Zhang, Guangming Cheng, Yu-Xiao Jiang, Tyler A. Cochran, Nana Shumiya, Xian P. Yang, Daniel Multer, Xiaoxiong Liu, Nan Yao, Yugui Yao, Claudia Felser, Titus Neupert, M. Zahid Hasan

Abstract: Charge density waves (CDWs) appear in numerous condensed matter platforms, ranging from high-Tc superconductors to quantum Hall systems. Despite such ubiquity, there has been a lack of direct experimental study on boundary states that can uniquely stem from the charge order. Here, using scanning tunneling microscopy, we directly visualize the bulk and boundary phenomenology of CDW in a topological… ▽ More Charge density waves (CDWs) appear in numerous condensed matter platforms, ranging from high-Tc superconductors to quantum Hall systems. Despite such ubiquity, there has been a lack of direct experimental study on boundary states that can uniquely stem from the charge order. Here, using scanning tunneling microscopy, we directly visualize the bulk and boundary phenomenology of CDW in a topological material, Ta2Se8I. Below the transition temperature (TCDW = 260 K), tunneling spectra on an atomically resolved lattice reveal a large insulating gap in the bulk and on the surface, exceeding 500 meV, surpassing predictions from standard weakly-coupled mean-field theory. Spectroscopic imaging confirms the presence of CDW, with LDOS maxima at the conduction band corresponding to the LDOS minima at the valence band, thus revealing a π phase difference in the respective CDW order. Concomitantly, at a monolayer step edge, we detect an in-gap boundary mode with modulations along the edge that match the CDW wavevector along the edge. Intriguingly, the phase of the edge state modulation shifts by π within the charge order gap, connecting the fully gapped bulk (and surface) conduction and valence bands via a smooth energy-phase relation. This bears similarity to the topological spectral flow of edge modes, where the boundary modes bridge the gapped bulk modes in energy and momentum magnitude but in Ta2Se8I, the connectivity distinctly occurs in energy and momentum phase. Notably, our temperature-dependent measurements indicate a vanishing of the insulating gap and the in-gap edge state above TCDW, suggesting their direct relation to CDW. The theoretical analysis also indicates that the observed boundary mode is topological and linked to CDW. △ Less

Submitted 25 January, 2024; originally announced January 2024.

Comments: Nature Physics (2024); in press

Journal ref: Nature Physics 20, 1253 (2024)

Solute Segregation in a Moving Grain Boundary: A Novel Phase-Field Approach

Authors: Sandip Guin, Miral Verma, Soumya Bandyopadhyay, Yu-Chieh Lo, Rajdip Mukherjee

Abstract: We present a novel phase-field approach for investigating solute segregation in a moving grain boundary. In our model, the correct choice of various parameters can control the solute-grain boundary interaction potential, resulting in various segregation profiles that agree with Cahn solute drag theory. Furthermore, we explore how different segregation profiles evolve at varying GB velocities owing… ▽ More We present a novel phase-field approach for investigating solute segregation in a moving grain boundary. In our model, the correct choice of various parameters can control the solute-grain boundary interaction potential, resulting in various segregation profiles that agree with Cahn solute drag theory. Furthermore, we explore how different segregation profiles evolve at varying GB velocities owing to the inequality of the atomic flux of solute between the front and back faces of the moving grain boundary. We highlight velocity variations among segregation profiles in low and high-velocity regimes. This model reveals how grain boundary segregation affects grain growth, providing insights for future alloy design △ Less

Submitted 16 August, 2023; originally announced August 2023.

Berry curvature induced anomalous Hall conductivity in magnetic topological oxide double perovskite Sr2FeMoO6

Authors: Tirthankar Chakraborty, Kartik Samanta, Satya N. Guin, Jonathan Noky, Iñigo Robredo, Suchitra Prasad, Juergen Kuebler, Chandra Shekhar, Maia G. Vergniory, Claudia Felser

Abstract: Oxide materials exhibit several novel structural, magnetic, and electronic properties. Their stability under ambient conditions, easy synthesis, and high transition temperatures provide such systems with an ideal ground for realizing topological properties and real-life technological applications. However, experimental evidence of topological states in oxide materials is rare. In this study, we ha… ▽ More Oxide materials exhibit several novel structural, magnetic, and electronic properties. Their stability under ambient conditions, easy synthesis, and high transition temperatures provide such systems with an ideal ground for realizing topological properties and real-life technological applications. However, experimental evidence of topological states in oxide materials is rare. In this study, we have synthesized single crystals of oxide double perovskite Sr2FeMoO6 and revealed its topological nature by investigating its structural, magnetic, and electronic properties. We observed that the system crystallized in the cubic space group Fm-3m, which is a half-metallic ferromagnet. Transport measurements show an anomalous Hall effect, and it is evident that the Hall contribution originates from the Berry curvature. Assuming a shift of the Fermi energy towards the conduction band, the contribution of the anomalous Hall effect is enhanced owing to the presence of a gaped nodal line. This study can be used to explore and realize the topological properties of bulk oxide systems. △ Less

Submitted 25 August, 2022; originally announced August 2022.

Comments: Topological quantum material, Oxide topological material

Doping as a tuning mechanism for magneto-thermoelectric effects to improve zT in polycrystalline NbP

Authors: Eleanor F. Scott, Katherine A. Schlaak, Poulomi Chakraborty, Chenguang Fu, Satya N. Guin, Safa Khodabakhsh, Ashley E. Paz y Puente, Claudia Felser, Brian Skinner, Sarah J. Watzman

Abstract: Weyl semimetals combine topological and semimetallic effects, making them candidates for interesting and effective thermoelectric transport properties. Here, we present experimental results on polycrystalline NbP, demonstrating the simultaneous existence of a large Nernst effect and a large magneto-Seebeck effect, which is typically not observed in a single material at the same temperature. We com… ▽ More Weyl semimetals combine topological and semimetallic effects, making them candidates for interesting and effective thermoelectric transport properties. Here, we present experimental results on polycrystalline NbP, demonstrating the simultaneous existence of a large Nernst effect and a large magneto-Seebeck effect, which is typically not observed in a single material at the same temperature. We compare transport results from two polycrystalline samples of NbP with previously published work, observing a shift in the temperature at which the maximum Nernst and magneto-Seebeck thermopowers occur, while still maintaining thermopowers of similar magnitude. Theoretical modeling shows how doping strongly alters both the Seebeck and Nernst magneto-thermopowers by shifting the temperature-dependent chemical potential, and the corresponding calculations provide a consistent interpretation of our results. Thus, we offer doping as a tuning mechanism for shifting magneto-thermoelectric effects to temperatures appropriate for device applications, improving zT at desirable operating temperature. Furthermore, the simultaneous presence of both a large Nernst and magneto-Seebeck thermopower is uncommon and offers unique device advantages if the thermopowers are used additively. Here, we also propose a unique thermoelectric device which would collectively harness the large Nernst and magneto-Seebeck thermopowers to greatly enhance the output and zT of conventional thermoelectric devices. △ Less

Submitted 23 November, 2022; v1 submitted 28 June, 2022; originally announced June 2022.

Comments: 32 pages, 21 figures

Giant anomalous Hall conductivity in the itinerant ferromagnet LaCrSb3 and the effect of f-electrons

Authors: Nitesh Kumar, Neetu Lamba, Jacob Gayles, Congcong Le, Praveen Vir, Satya N. Guin, Yan Sun, Claudia Felser, Chandra Shekhar

Abstract: Itinerant ferromagnets constitute an important class of materials wherein spin-polarization can affect the electric transport properties in nontrivial ways. One such phenomenon is anomalous Hall effect which depends on the details of the band structure such as the amount of band crossings in the valence band of the ferromagnet. Here, we have found extraordinary anomalous Hall effect in an itineran… ▽ More Itinerant ferromagnets constitute an important class of materials wherein spin-polarization can affect the electric transport properties in nontrivial ways. One such phenomenon is anomalous Hall effect which depends on the details of the band structure such as the amount of band crossings in the valence band of the ferromagnet. Here, we have found extraordinary anomalous Hall effect in an itinerant ferromagnetic metal LaCrSb3. The rather two-dimensional nature of the magnetic subunit imparts large anisotropic anomalous Hall conductivity of 1250 S/cm at 2K. Our investigations suggest that a strong Berry curvature by abundant momentum-space crossings and narrow energy-gap openings are the primary sources of the anomalous Hall conductivity. An important observation is the existence of quasi-dispersionless bands in LaCrSb3 which is now known to increase the anomalous Hall conductivity. After introducing f-electrons, anomalous Hall conductivity experiences more than two-fold increase and reaches 2900 S/cm in NdCrSb3. △ Less

Submitted 3 May, 2021; originally announced May 2021.

Comments: 9 pages, 4 figures, and supplementary

Journal ref: Adv. Quantum Technol. 2021, 2100023

Topological quantum materials from the viewpoint of chemistry

Authors: Nitesh Kumar, Satya N. Guin, Kaustuv Manna, Chandra Shekhar, Claudia Felser

Abstract: Topology, a mathematical concept, has recently become a popular and truly transdisciplinary topic encompassing condensed matter physics, solid state chemistry, and materials science. Since there is a direct connection between real space, namely atoms, valence electrons, bonds and orbitals, and reciprocal space, namely bands and Fermi surfaces, via symmetry and topology, classifying topological mat… ▽ More Topology, a mathematical concept, has recently become a popular and truly transdisciplinary topic encompassing condensed matter physics, solid state chemistry, and materials science. Since there is a direct connection between real space, namely atoms, valence electrons, bonds and orbitals, and reciprocal space, namely bands and Fermi surfaces, via symmetry and topology, classifying topological materials within a single-particle picture is possible. Currently, most materials are classified as trivial insulators, semimetals and metals, or as topological insulators, Dirac and Weyl nodal-line semimetals, and topological metals. The key ingredients for topology are: certain symmetries, the inert pair effect of the outer electrons leading to inversion of the conduction and valence bands, and spin-orbit coupling. This review presents the topological concepts related to solids from the viewpoint of a solid-state chemist, summarizes techniques for growing single crystals, and describes basic physical property measurement techniques to characterize topological materials beyond their structure and provide examples of such materials. Finally, a brief outlook on the impact of topology in other areas of chemistry is provided at the end of the article. △ Less

Submitted 22 March, 2021; originally announced March 2021.

Comments: Review Article, 28 Figures

Journal ref: Chemical Reviews 121, 2780-2815 (2021)

Large Nernst Power Factor over a Broad Temperature Range in Polycrystalline Weyl Semimetal NbP

Authors: Chenguang Fu, Satya N. Guin, Sarah J. Watzman, Guowei Li, Enke Liu, Nitesh Kumar, Vicky Süß, Walter Schnelle, Gudrun Auffermann, Chandra Shekhar, Yan Sun, Johannes Gooth, Claudia Felser

Abstract: The discovery of topological materials has provided new opportunities to exploit advanced materials for heat-to-electricity energy conversion as they share many common characteristics with thermoelectric materials. In this work, we report the magneto-thermoelectric properties and Nernst effect of the topological Weyl semimetal NbP. We find that polycrystalline, bulk NbP shows a significantly large… ▽ More The discovery of topological materials has provided new opportunities to exploit advanced materials for heat-to-electricity energy conversion as they share many common characteristics with thermoelectric materials. In this work, we report the magneto-thermoelectric properties and Nernst effect of the topological Weyl semimetal NbP. We find that polycrystalline, bulk NbP shows a significantly larger Nernst thermopower than its conventional thermopower under magnetic field. As a result, a maximum Nernst power factor of ~ 35*10-4 Wm-1K-2 is achieved at 9 T and 136 K, which is 4 times higher than its conventional power factor and is also comparable to that of state-of-the-art thermoelectrics. Moreover, the Nernst power factor maintains relatively large value over a broad temperature range. These results highlight that the enhancement of thermoelectric performance can be achieved in topological semimetals based on the Nernst effect and transverse transport. △ Less

Submitted 26 March, 2020; originally announced March 2020.

Journal ref: Energy Environ. Sci. 11 (2018) 2813-2820

Zero-field Nernst effect in a ferromagnetic kagome-lattice Weyl-semimetal Co3Sn2S2

Authors: Satya N. Guin, Praveen Vir, Yang Zhang, Nitesh Kumar, Sarah J. Watzman, Chenguang Fu, Enke Liu, Kaustuv Manna, Walter Schnelle, Johannes Gooth, Chandra Shekhar, Yan Sun, Claudia Felser

Abstract: The discovery of magnetic topological semimetals recently attracted significant attention in the field of topology and thermoelectrics. In a thermoelectric device based on the Nernst geometry, an external magnet is required as an integral part. We report a zero-field Nernst effect in a newly discovered hard-ferromagnetic kagome-lattice Weyl-semimetal Co3Sn2S2. A maximum Nernst thermopower of 3 mic… ▽ More The discovery of magnetic topological semimetals recently attracted significant attention in the field of topology and thermoelectrics. In a thermoelectric device based on the Nernst geometry, an external magnet is required as an integral part. We report a zero-field Nernst effect in a newly discovered hard-ferromagnetic kagome-lattice Weyl-semimetal Co3Sn2S2. A maximum Nernst thermopower of 3 microvolt/K at 80 K in zero field is achieved in this magnetic Weyl-semimetal. Our results demonstrate the possibility of application of topological hard magnetic semimetals for low-power thermoelectric devices based on the Nernst effect and are thus valuable for the comprehensive understanding of transport properties in this class of materials. △ Less

Submitted 25 March, 2020; originally announced March 2020.

Journal ref: Advanced Materials 2019, 31, 1806622

Observation of giant spin-split Fermi-arc with maximal Chern number in the chiral topological semimetal PtGa

Authors: Mengyu Yao, Kaustuv Manna, Qun Yang, Alexander Fedorov, Vladimir Voroshnin, B. Valentin Schwarze, Jacob Hornung, S. Chattopadhyay, Zhe Sun, Satya N Guin, Jochen Wosnitza, Horst Borrmann, Chandra Shekhar, Nitesh Kumar, Jörg Fink, Yan Sun, Claudia Felser

Abstract: Non-symmorphic chiral topological crystals host exotic multifold fermions, and their associated Fermi arcs helically wrap around and expand throughout the Brillouin zone between the high-symmetry center and surface-corner momenta. However, Fermi-arc splitting and realization of the theoretically proposed maximal Chern number rely heavily on the spin-orbit coupling (SOC) strength. In the present wo… ▽ More Non-symmorphic chiral topological crystals host exotic multifold fermions, and their associated Fermi arcs helically wrap around and expand throughout the Brillouin zone between the high-symmetry center and surface-corner momenta. However, Fermi-arc splitting and realization of the theoretically proposed maximal Chern number rely heavily on the spin-orbit coupling (SOC) strength. In the present work, we investigate the topological states of a new chiral crystal, PtGa, which has the strongest SOC among all chiral crystals reported to date. With a comprehensive investigation using high-resolution angle-resolved photoemission spectroscopy, quantum-oscillation measurements, and state-of-the-art ab initio calculations, we report a giant SOC-induced splitting of both Fermi arcs and bulk states. Consequently, this study experimentally confirms the realization of a maximal Chern number equal to |4| for the first time in multifold fermionic systems, thereby providing a platform to observe large-quantized photogalvanic currents in optical experiments. △ Less

Submitted 17 March, 2020; originally announced March 2020.

Comments: Accepted in Nature Communications

Journal ref: Nature Communications, volume 11, Article number: 2033 (2020)

Intrinsic anomalous Hall effect in Ni-substituted magnetic Weyl semimetal Co3Sn2S2

Authors: Gohil S. Thakur, Praveen Vir, Satya N. Guin, Chandra Shekhar, Richard Weihrich, Yan Sun, Nitesh Kumar, Claudia Felser

Abstract: Topological materials have recently attracted considerable attention among materials scientists as their properties are predicted to be protected against perturbations such as lattice distortion and chemical substitution. However, any experimental proof of such robustness is still lacking. In this study, we experimentally demonstrate that the topological properties of the ferromagnetic kagome comp… ▽ More Topological materials have recently attracted considerable attention among materials scientists as their properties are predicted to be protected against perturbations such as lattice distortion and chemical substitution. However, any experimental proof of such robustness is still lacking. In this study, we experimentally demonstrate that the topological properties of the ferromagnetic kagome compound Co3Sn2S2 are preserved upon Ni substitution. We systematically vary the Ni content in Co3Sn2S2 single crystals and study their magnetic and anomalous transport properties. For the intermediate Ni substitution, we observe a remarkable increase in the coercive field while still maintaining significant anomalous Hall conductivity. The large anomalous Hall conductivity of these compounds is intrinsic, consistent with first-principle calculations, which proves its topological origin. Our results can guide further studies on the chemical tuning of topological materials for better understanding. △ Less

Submitted 12 February, 2020; originally announced February 2020.

Comments: 8 Figures

Journal ref: Chemistry of Materials (2020)

Anisotropic electrical and thermal magnetotransport in the magnetic semimetal GdPtBi

Authors: Clemens Schindler, Stanislaw Galeski, Walter Schnelle, Rafał Wawrzyńczak, Wajdi Abdel-Haq, Satya N. Guin, Johannes Kroder, Nitesh Kumar, Chenguang Fu, Horst Borrmann, Chandra Shekhar, Claudia Felser, Tobias Meng, Adolfo G. Grushin, Yang Zhang, Yan Sun, Johannes Gooth

Abstract: The half-Heusler rare-earth intermetallic GdPtBi has recently gained attention due to peculiar magnetotransport phenomena that have been associated with the possible existence of Weyl fermions, thought to arise from the crossings of spin-split conduction and valence bands. On the other hand, similar magnetotransport phenomena observed in other rare-earth intermetallics have often been attributed t… ▽ More The half-Heusler rare-earth intermetallic GdPtBi has recently gained attention due to peculiar magnetotransport phenomena that have been associated with the possible existence of Weyl fermions, thought to arise from the crossings of spin-split conduction and valence bands. On the other hand, similar magnetotransport phenomena observed in other rare-earth intermetallics have often been attributed to the interaction of itinerant carriers with localized magnetic moments stemming from the $4f$-shell of the rare-earth element. In order to address the origin of the magnetotransport phenomena in GdPtBi, we performed a comprehensive study of the magnetization, electrical and thermal magnetoresistivity on two single-crystalline GdPtBi samples. In addition, we performed an analysis of the Fermi surface via Shubnikov-de Haas oscillations in one of the samples and compared the results to \emph{ab initio} band structure calculations. Our findings indicate that the electrical and thermal magnetotransport in GdPtBi cannot be solely explained by Weyl physics and is strongly influenced by the interaction of both itinerant charge carriers and phonons with localized magnetic Gd-ions and possibly also paramagnetic impurities. △ Less

Submitted 23 March, 2020; v1 submitted 4 October, 2018; originally announced October 2018.

Comments: 11 figures

Journal ref: Phys. Rev. B 101, 125119 (2020)

Anomalous Nernst effect beyond the magnetization scaling relation in the ferromagnetic Heusler compound Co$_2$MnGa

Authors: Satya N. Guin, Kaustuv Manna, Jonathan Noky, Sarah J. Watzman, Chenguang Fu, Nitesh Kumar, Walter Schnelle, Chandra Shekhar, Yan Sun, Johannes Gooth, Claudia Felser

Abstract: Applying a temperature gradient in a magnetic material generates a voltage that is perpendicular to both the heat flow and the magnetization. This is the anomalous Nernst effect (ANE) which was thought to be proportional to the value of the magnetization for a long time. However, more generally, the ANE has been predicted to originate from a net Berry curvature of all bands near the Fermi level. S… ▽ More Applying a temperature gradient in a magnetic material generates a voltage that is perpendicular to both the heat flow and the magnetization. This is the anomalous Nernst effect (ANE) which was thought to be proportional to the value of the magnetization for a long time. However, more generally, the ANE has been predicted to originate from a net Berry curvature of all bands near the Fermi level. Subsequently, a large anomalous Nernst thermopower has recently been observed in topological materials with no net magnetization but large net Berry curvature around E$_F$. These experiments clearly fall outside the scope of the conventional magnetization-model of the ANE, but a significant question remains: Can the value of the ANE in topological ferromagnets exceed the highest values observed in conventional ferromagnets? Here, we report a remarkably high anomalous Nernst thermopower value of ~6.0 μV/K at 1 T in the ferromagnetic topological Heusler compound Co$_2$MnGa at room temperature, which is around 7-times larger than any anomalous Nernst thermopower value ever reported for a conventional ferromagnet. Combined electrical, thermoelectric and first-principles calculations reveal that this high value of the ANE arises from a large net Berry curvature near the Fermi level associated with nodal lines and Weyl points. △ Less

Submitted 18 June, 2018; originally announced June 2018.

Journal ref: NPG Asia Materials 2019

Planar Hall effect in the Weyl semimetal GdPtBi

Authors: Nitesh Kumar, Satya N. Guin, Claudia Felser, Chandra Shekhar

Abstract: Observation of Weyl and Dirac Fermions in condensed matter systems is one of the most important discoveries. Among the very few available tools to characterize Weyl semimetals through electrical transport, negative magnetoresistance is most commonly used. Considering shortcomings of this method, new tools to characterize chiral anomaly in Weyl semimetals are desirable. We employ planar Hall effect… ▽ More Observation of Weyl and Dirac Fermions in condensed matter systems is one of the most important discoveries. Among the very few available tools to characterize Weyl semimetals through electrical transport, negative magnetoresistance is most commonly used. Considering shortcomings of this method, new tools to characterize chiral anomaly in Weyl semimetals are desirable. We employ planar Hall effect as an effective technique in half Heusler Weyl semimetal GdPtBi to study chiral anomaly. This compound exhibits a large value of 1.5 mohm cm planar Hall resistivity at 2 K and in 9 T. Our analysis reveals that the observed amplitude is dominated by Berry curvature and chiral anomaly contributions. Through the angle dependent transport studies we establish that GdPtBi with relatively small orbital magnetoresistance is an ideal candidate to observe large planar Hall effect . △ Less

Submitted 26 July, 2018; v1 submitted 11 November, 2017; originally announced November 2017.

Comments: Updated texts

Journal ref: Phys. Rev. B 98, 041103 (2018)

Extremely high conductivity observed in the triple point topological metal MoP

Authors: Nitesh Kumar, Yan Sun, Michael Nicklas, Sarah J. Watzman, Olga Young, Inge Leermakers, Jacob Hornung, Johannes Klotz, Johannes Gooth, Kaustuv Manna, Vicky Süß, Satya N. Guin, Tobias Förster, Marcus Schmidt, Lukas Muechler, Binghai Yan, Peter Werner, Walter Schnelle, Uli Zeitler, Jochen Wosnitza, Stuart S. P. Parkin, Claudia Felser, Chandra Shekhar

Abstract: Weyl and Dirac fermions have created much attention in condensed matter physics and materials science. Recently, several additional distinct types of fermions have been predicted. Here, we report ultra-high electrical conductivity in MoP at low temperature, which has recently been established as a triple point Fermion material. Here we show that the electrical resistivity is 6 n-ohm cm at 2 K with… ▽ More Weyl and Dirac fermions have created much attention in condensed matter physics and materials science. Recently, several additional distinct types of fermions have been predicted. Here, we report ultra-high electrical conductivity in MoP at low temperature, which has recently been established as a triple point Fermion material. Here we show that the electrical resistivity is 6 n-ohm cm at 2 K with a large mean free path of 11 microns. de Haas-van Alphen oscillations reveal spin splitting of the Fermi surfaces. In contrast to noble metals with similar conductivity and number of carriers, the magnetoresistance in MoP does not saturate up to 9 T at 2 K. Interestingly, the momentum relaxing time of the electrons is found to be more than 15 times larger than the quantum coherence time. This difference between the scattering scales shows that momentum conserving scattering dominates in MoP at low temperatures. △ Less

Submitted 11 June, 2019; v1 submitted 10 March, 2017; originally announced March 2017.

Comments: Updated texts and supplementary

Journal ref: Nature Communications 10, 2475(2019)

Direct evidence of strong local ferroelectric ordering in a thermoelectric semiconductor

Authors: Leena Aggarwal, Jagmeet S. Sekhon, Satya N. Guin, Ashima Arora, Devendra S. Negi, Ranjan Datta, Kanishka Biswas, Goutam Sheet

Abstract: It is thought that the proposed new family of multi-functional materials namely the ferroelectric thermoelectrics may exhibit enhanced functionalities due to the coupling of the thermoelectric parameters with ferroelectric polarization in solids. Therefore, the ferroelectric thermoelectrics are expected to be of immense technological and fundamental significance. As a first step towards this direc… ▽ More It is thought that the proposed new family of multi-functional materials namely the ferroelectric thermoelectrics may exhibit enhanced functionalities due to the coupling of the thermoelectric parameters with ferroelectric polarization in solids. Therefore, the ferroelectric thermoelectrics are expected to be of immense technological and fundamental significance. As a first step towards this direction, it is most important to identify the existing high performance thermoelectric materials exhibiting ferroelectricity. Herein, through the direct measurement of local polarization switching we show that the recently discovered thermoelectric semiconductor $AgSbSe_{2}$ has local ferroelectric ordering. Using piezo-response force microscopy, we demonstrate the existence of nanometer scale ferroelectric domains that can be switched by external electric field. These observations are intriguing as $AgSbSe_{2}$ crystalizes in cubic rock salt structure with centro-symmetric space group (Fm-3m) and therefore no ferroelectricity is expected. However, from high resolution transmission electron microscopy (HRTEM) measurement we found the evidence of local superstructure formation which, we believe, leads to local distortion of the centro-symmetric arrangement in $AgSbSe_{2}$ and gives rise to the observed ferroelectricity. Stereochemically active $5s^{2}$ lone pair of Sb can also give rise to local structural distortion, which creates ferroelectricity in $AgSbSe_{2}$. △ Less

Submitted 12 May, 2014; originally announced May 2014.