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Angular Dependence of X-ray Absorption Spectrum for Field-aligned Fe-based Superconductors
Authors:
B. C. Chang,
Y. B. You,
T. J. Shiu,
M. F. Tai,
H. C. Ku,
Y. Y. Hsu,
L. Y. Jang,
J. F. Lee,
Z. Wei,
K. Q. Ruan,
X. G. Li
Abstract:
Anisotropic Fe K-edge and As K-edge X-ray absorption near edge spectrum (XANES) measurements on superconducting (T_c = 52 K) (Sm_{0.95}La_{0.05})FeAs(O_{0.85}F_{0.15}) field-aligned microcrystalline powder are presented. The angular dependence of Fe pre-edge peak (dipole transition of Fe-1s electrons to Fe-3d/As-4p hybrid bands) relative to the tetragonal ab-plane of aligned powder indicates lar…
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Anisotropic Fe K-edge and As K-edge X-ray absorption near edge spectrum (XANES) measurements on superconducting (T_c = 52 K) (Sm_{0.95}La_{0.05})FeAs(O_{0.85}F_{0.15}) field-aligned microcrystalline powder are presented. The angular dependence of Fe pre-edge peak (dipole transition of Fe-1s electrons to Fe-3d/As-4p hybrid bands) relative to the tetragonal ab-plane of aligned powder indicates larger density of state (DOS) along the c-axis, and is consistent with the LDA band structure calculation. The anisotropic Fe K-edge spectra exhibit a chemical shift to lower energy compared to FeO which are closely related to the itinerant character of Fe^{2+}-3d^6 orbitals. The anisotropic As K-edge spectra are more or less the mirror images of Fe K-edge due to the symmetrical Fe-As hybridiztion in the FeAs layer. Angular dependence of As main peak (dipole transition of As-1s electrons to higher energy hybrid bands) was observed suggesting character of As-4d e_g orbitals.
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Submitted 22 September, 2009;
originally announced September 2009.
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Anisotropic magnetic and superconducting properties of aligned weak-ferromagnetic superconductor RuSr$_2$RCu$_2$O$_8$ (R = rare earths)
Authors:
B. C. Chang,
C. H. Hsu,
M. F. Tai,
H. C. Ku,
Y. Y. Hsu
Abstract:
The powder alignment method is used to investigate the anisotropic physical properties of the weak-ferromagnetic superconductor system RuSr2RCu2O8 (R = Pr, Nd, Sm, Eu, Gd, Gd0.5Dy0.5). The RuSr2GdCu2O8 cuprate is a weak-ferromagnetic superconductor with a magnetic ordering of Ru moments at TN(Ru) = 131 K, a superconducting transition in the CuO2 layers at Tc = 56 K, and a low temperature Gd anti…
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The powder alignment method is used to investigate the anisotropic physical properties of the weak-ferromagnetic superconductor system RuSr2RCu2O8 (R = Pr, Nd, Sm, Eu, Gd, Gd0.5Dy0.5). The RuSr2GdCu2O8 cuprate is a weak-ferromagnetic superconductor with a magnetic ordering of Ru moments at TN(Ru) = 131 K, a superconducting transition in the CuO2 layers at Tc = 56 K, and a low temperature Gd antiferromagnetic ordering at TN(Gd) = 2.5 K. Due to weak magnetic anisotropy of this tetragonal system, highly c-axis aligned microcrystalline powder (diameter ~ 1-10 $μ$m) in epoxy can be obtained only for R = Eu and Gd through the field-rotation powder alignment method where c-axis is perpendicular to the aligned magnetic field Ba = 0.9 T and parallel to the rotation axis. For smaller rare earth compound R = Gd0.5Dy0.5, powder alignment can be achieved using the simple field powder alignment method where c-axis is partially aligned along the aligned magnetic field. The anisotropic temperature dependence of magnetic susceptibility for the c-axis aligned powders exhibit weak anisotropy with $χ_{c} > χ_{ab}$ at room temperature due to anisotropic rare earth, Eu and Gd, contribution and crossover to $χ_{c} < χ_{ab}$ below 190 K where strong Ru anisotropic short-range exchange interaction overtakes the rare earth contribution. Anisotropic diamagnetic superconducting intragrain shielding signal of aligned microcrystalline RuSr2GdCu2O8 powder-in-epoxy below vortex lattice melting temperature at 39 K in 1-G field is much weaker than the intergrain polycrystalline bulk sample signal due to the small grain size (d ~ 1-10 $μ$m), long penetration depth ($λ_{ab}$ ~ 0.55 $μ$m, $λ_{c}$ ~ 0.66 $μ$m) and the two-dimensional (2D) character of CuO2 layers.
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Submitted 20 November, 2008;
originally announced November 2008.
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Anisotropic superconducting properties of aligned Sm$_{0.95}$La$_{0.05}$FeAsO$_{0.85}$F$_{0.15}$ microcrystalline powder
Authors:
B. C. Chang,
C. H. Hsu,
Y. Y. Hsu,
Z. Wei,
K. Q. Ruan,
X. G. Li,
H. C. Ku
Abstract:
The Sm$_{0.95}$La$_{0.05}$FeAsO$_{0.85}$F$_{0.15}$ compound is a quasi-2D layered superconductor with a superconducting transition temperature T$_c$ = 52 K. Due to the Fe spin-orbital related anisotropic exchange coupling (antiferromagnetic or ferromagnetic fluctuation), the tetragonal microcrystalline powder can be aligned at room temperature using the field-rotation method where the tetragonal…
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The Sm$_{0.95}$La$_{0.05}$FeAsO$_{0.85}$F$_{0.15}$ compound is a quasi-2D layered superconductor with a superconducting transition temperature T$_c$ = 52 K. Due to the Fe spin-orbital related anisotropic exchange coupling (antiferromagnetic or ferromagnetic fluctuation), the tetragonal microcrystalline powder can be aligned at room temperature using the field-rotation method where the tetragonal $\it{ab}$-plane is parallel to the aligned magnetic field B$_{a}$ and $\it{c}$-axis along the rotation axis. Anisotropic superconducting properties with anisotropic diamagnetic ratio $χ_{c}/χ_{ab}\sim$ 2.4 + 0.6 was observed from low field susceptibility $χ$(T) and magnetization M(B$_{a}$). The anisotropic low-field phase diagram with the variation of lower critical field gives a zero-temperature penetration depth $λ_{c}$(0) = 280 nm and $λ_{ab}$(0) = 120 nm. The magnetic fluctuation used for powder alignment at 300 K may be related with the pairing mechanism of superconductivity at lower temperature.
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Submitted 17 July, 2008;
originally announced July 2008.
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Anomalous physical properties of underdoped weak-ferromagnetic superconductor RuSr$_2$EuCu$_{2}$O$_{8}$
Authors:
B. C. Chang,
C. Y. Yang,
H. C. Ku,
J. C. Ho,
C. B. Tsai,
Y. Y. Chen,
D. C. Ling
Abstract:
Similar to the optimal-doped, weak-ferromagnetic (WFM induced by canted antiferromagnetism, T$_{Curie}$ = 131 K) and superconducting (T$_{c}$ = 56 K) RuSr$_{2}$GdCu$_{2}$O$_{8}$, the underdoped RuSr$_{2}$EuCu$_{2}$O$_{8}$ (T$_{Curie}$ = 133 K, T$_{c}$ = 36 K) also exhibited a spontaneous vortex state (SVS) between 16 K and 36 K. The low field ($\pm$20 G) superconducting hysteresis loop indicates…
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Similar to the optimal-doped, weak-ferromagnetic (WFM induced by canted antiferromagnetism, T$_{Curie}$ = 131 K) and superconducting (T$_{c}$ = 56 K) RuSr$_{2}$GdCu$_{2}$O$_{8}$, the underdoped RuSr$_{2}$EuCu$_{2}$O$_{8}$ (T$_{Curie}$ = 133 K, T$_{c}$ = 36 K) also exhibited a spontaneous vortex state (SVS) between 16 K and 36 K. The low field ($\pm$20 G) superconducting hysteresis loop indicates a weak and narrow Meissner state region of average lower critical field B$_{c1}^{ave}$(T) = B$_{c1}^{ave}$(0)[1 - (T/T$_{SVS}$)$^{2}$], with B$_{c1}^{ave}$(0) = 7 G and T$_{SVS}$ = 16 K. The vortex melting transition (T$_{melting}$ = 21 K) below T$_{c}$ obtained from the broad resistivity drop and the onset of diamagnetic signal indicates a vortex liquid region due to the coexistence and interplay between superconductivity and WFM order. No visible jump in specific heat was observed near T$_{c}$ for Eu- and Gd-compound. This is not surprising, since the electronic specific heat is easily overshadowed by the large phonon and weak-ferromagnetic contributions. Furthermore, a broad resistivity transition due to low vortex melting temperature would also lead to a correspondingly reduced height of any specific heat jump. Finally, with the baseline from the nonmagnetic Eu-compound, specific heat data analysis confirms the magnetic entropy associated with antiferromagnetic ordering of Gd$^{3+}$ (J = S = 7/2) at 2.5 K to be close to $\it{N_{A}k}$ ln8 as expected.
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Submitted 2 February, 2007;
originally announced February 2007.
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Critical fields and spontaneous vortex state in the weak-ferromagnetic superconductor RuSr2GdCu2O8
Authors:
C. Y. Yang,
B. C. Chang,
H. C. Ku,
Y. Y. Hsu
Abstract:
A spontaneous vortex state (SVS) between 30 K and 56 K was observed for the weak-ferromagnetic superconductor RuSr2GdCu2O8 with ferromagnetic Curie temperature TC = 131 K and superconducting transition temperature Tc = 56 K. The low field (20 G) Superconducting hysteresis loop indicates a narrow Meissner state region within average lower critical field Bc1(T)= Bc1(0)[1 - (T/T0)2], with average B…
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A spontaneous vortex state (SVS) between 30 K and 56 K was observed for the weak-ferromagnetic superconductor RuSr2GdCu2O8 with ferromagnetic Curie temperature TC = 131 K and superconducting transition temperature Tc = 56 K. The low field (20 G) Superconducting hysteresis loop indicates a narrow Meissner state region within average lower critical field Bc1(T)= Bc1(0)[1 - (T/T0)2], with average Bave c1 (0) = 12 G and T0 = 30 K. Full Meissner shielding signal in very low applied field indicates an ab-plane Bab c1(0) ~ 4 G with an estimated anisotropic parameter g ~ 7 for this layered system. The existence of a spontaneous vortex state between 30 K and 56 K is the result of weak-ferromagnetic order with a net spontaneous magnetic moment of ~ 0.1 muB/Ru, which generates a weak magnetic dipole field around 10 G in the CuO2 bi-layers. The upper critical field Bc2 varies linearly as (1 - T/Tc) up to 7-T field. The vortex melting line Bm varies as (1 - T/Tm)3.5 with melting transition temperature Tm = 39 K and a very broad vortex liquid region due to the coexistence and the interplay between superconductivity and weak-ferromagnetic order.
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Submitted 1 July, 2005;
originally announced July 2005.
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The role of the cooperative Jahn-Teller effect in the charge ordered La1-xCaxMnO3 (0.5<=x<=0.87) manganites
Authors:
R. K. Zheng,
G. Li,
A. N. Tang,
Y. Yang,
W. Wang,
X. G. Li,
Z. D. Wang,
H. C. Ku
Abstract:
Based on the magnetoresistance, magnetization, ultrasound, and crystallographic data, we studied the role of the cooperative Jahn-Teller effect in the charge ordered (CO) state for La1-xCaxMnO3. We found that, with increasing the fraction of Q3 mode of Jahn-Teller distortion and decreasing that of Q2 mode in the CO state, the magnetic structure evolves from CE-type to C-type and the orbital orde…
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Based on the magnetoresistance, magnetization, ultrasound, and crystallographic data, we studied the role of the cooperative Jahn-Teller effect in the charge ordered (CO) state for La1-xCaxMnO3. We found that, with increasing the fraction of Q3 mode of Jahn-Teller distortion and decreasing that of Q2 mode in the CO state, the magnetic structure evolves from CE-type to C-type and the orbital ordering changes from 3d(x2-r2)/3d(y2-r2)-type to 3d(x2-z2)-type, with the strength of ferromagnetism and the phase separation tendency being suppressed. At the same time, the stability of the CO state and the cooperative Jahn-Teller lattice distortion increase. These effects imply that the cooperative Jahn-Teller effect with different vibration modes is the key ingredient in understanding the essential physics of the CO state.
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Submitted 8 November, 2003;
originally announced November 2003.