Showing 1–50 of 335 results for author: Budker, D

Wavelength-Resolved Photoinduced Spin Polarization in a Broad Optical Range for a Porphyrin-Quinone System

Authors: Liubov Chuchkova, Oleg Tretiak, Kirill F. Sheberstov, Danila A. Barskiy, Raphael Kircher, Dmitry Budker

Abstract: Photochemically induced dynamic nuclear polarization (photo-CIDNP) in liquid-state donor-acceptor systems is typically studied at a limited number of excitation wavelengths, leaving its spectral dependence incompletely characterized. Understanding the wavelength dependence of photo-CIDNP is important both for elucidating the underlying spin-chemical mechanisms and for optimizing hyperpolarization… ▽ More Photochemically induced dynamic nuclear polarization (photo-CIDNP) in liquid-state donor-acceptor systems is typically studied at a limited number of excitation wavelengths, leaving its spectral dependence incompletely characterized. Understanding the wavelength dependence of photo-CIDNP is important both for elucidating the underlying spin-chemical mechanisms and for optimizing hyperpolarization strategies in chemically and biologically relevant molecular systems. Here, we investigate wavelength-resolved photo-CIDNP in a tetraphenylporphyrin-1,4-benzoquinone donor-acceptor system over the 350-800 nm spectral range. Photon-flux-normalized CIDNP amplitudes were measured using both a tunable laser system and a broadband xenon lamp equipped with interchangeable 10 nm interference filters. The CIDNP response exhibits a non-monotonic dependence on excitation wavelength. Pronounced hyperpolarization is observed near 350 nm and in the 500-550 nm region, whereas excitation within the strongly absorbing 400-450 nm range results in a substantially reduced CIDNP response. Comparison with the UV-Vis absorption spectrum demonstrates that photo-CIDNP efficiency is not governed solely by optical absorption and reflects wavelength-dependent photophysical processes. After normalization to the excitation photon flux, lamp- and laser-based measurements yield consistent CIDNP results, validating broadband filtered excitation as a reliable and experimentally accessible approach for wavelength-resolved photo-CIDNP studies. These results establish excitation wavelength as an independent control parameter for liquid-state photo-CIDNP and provide a framework for systematic investigations of wavelength-dependent spin hyperpolarization. △ Less

Submitted 30 July, 2026; originally announced July 2026.

Comments: 10 pages, 5 figures

High-Frequency Gravitational Wave Constraints from Precision Spectroscopy

Authors: Dmitry Budker, Valerie Domcke, Joachim Kopp, Oleg Tretiak

Abstract: Gravitational waves affect the propagation of electromagnetic waves in laser cavities, modulating the frequency of emitted photons. We use this effect to search for high-frequency gravitational waves between 100 kHz and 100 MHz using optical precision spectroscopy. Our limits constrain much of this frequency range for the first time. We discuss future improvements of the technique, which we expect… ▽ More Gravitational waves affect the propagation of electromagnetic waves in laser cavities, modulating the frequency of emitted photons. We use this effect to search for high-frequency gravitational waves between 100 kHz and 100 MHz using optical precision spectroscopy. Our limits constrain much of this frequency range for the first time. We discuss future improvements of the technique, which we expect to enhance the sensitivity by eight orders of magnitude, and to extend the frequency coverage up to at least 1 GHz. △ Less

Submitted 14 July, 2026; originally announced July 2026.

Comments: 10 pages, 3 figures; codes available at https://github.com/koppj/hf-gw-spectroscopy-public

Report number: CERN-TH-2026-168, MITP-26-033

Generation of continuous-wave laser light at 148.4 nm using cavity-enhanced second harmonic generation in $BaMgF_4$

Authors: Keerthan Subramanian, Hiroki Tanaka, Simon J. Herr, Nutan Kumari Sah, Gaurav Jha, Florian Zacherl, Srinivasa Arasada Pradeep, Valerii Andriushkov, Ke Zhang, Darius Fenner, Yumiao Wang, Milena Hugenschmidt, Frank Kühnemann, Gaetano G. M. Bonetti, Shoichi Ui, Matthias Bickermann, Chenxi Ma, Xian Zheng, Michael Zopf, Bettina Lommel, Jan C. Müller, Stephan Hannig, Dmitry Budker, Ferdinand Schmidt-Kaler, Lars von der Wense

Abstract: We experimentally investigate the potential of $BaMgF_4$ crystals to create a continuous-wave (CW) solid state laser at the vacuum ultraviolet (VUV) wavelength of 148.4 nm via cavity-enhanced second harmonic generation. This investigation is motivated by the development of a nuclear optical clock based on a transition between the ground and isomeric state in the $^{229}Th$ nucleus. For this purpos… ▽ More We experimentally investigate the potential of $BaMgF_4$ crystals to create a continuous-wave (CW) solid state laser at the vacuum ultraviolet (VUV) wavelength of 148.4 nm via cavity-enhanced second harmonic generation. This investigation is motivated by the development of a nuclear optical clock based on a transition between the ground and isomeric state in the $^{229}Th$ nucleus. For this purpose, a $BaMgF_4$ crystal was grown, optically polished and periodically poled. The crystal was inserted into a power-enhancement cavity, resonant at the fundamental wavelength of 296.8 nm and the generated laser light at 148.4 nm was characterized. Within this proof-of-concept investigation, a VUV output power of typically ($16\pm1$) pW is obtained. This marks the first time that this type of crystal is used to generate VUV laser light. The experimental findings are compared to theoretical expectations and provide a clear path for future improvements. △ Less

Submitted 23 June, 2026; originally announced June 2026.

Comments: 9 pages, 5 figures

A tunable feedback-controlled magnetic trap for a magnet in free fall

Authors: Changhao Xu, Alexander Heidt, Mohammadreza Nematollahi, Christoph Lotz, Ernst Maria Rasel, Yan Liu, Wei Ji, Dmitry Budker

Abstract: Ferromagnets in free space are predicted to exhibit pure Larmor precession at near-zero magnetic fields and provide exceptional sensitivity for magnetometry and gyroscopy. Notably, pure Larmor precession has not been observed in a macroscopic ferromagnetic particle, despite its fundamental importance and potential for probing relativistic effects and dark-matter interactions. Realizing such dynami… ▽ More Ferromagnets in free space are predicted to exhibit pure Larmor precession at near-zero magnetic fields and provide exceptional sensitivity for magnetometry and gyroscopy. Notably, pure Larmor precession has not been observed in a macroscopic ferromagnetic particle, despite its fundamental importance and potential for probing relativistic effects and dark-matter interactions. Realizing such dynamics requires true free fall to eliminate clamping losses and trap-induced systematics. A central challenge is designing a tunable trap that is weak enough to permit near-free evolution yet robust enough to withstand the disturbances of launch and release. Here, we propose and demonstrate a novel master proportional-integral-differential magnetic trap (MPIDMT) combining a PID-controlled coil system with a master control coil system. Implemented in the third-generation drop tower - Einstein-Elevator, during the microgravity phase the system stably levitates a ferromagnetic particle against shock accelerations up to 1.5 g and resolves its motion in both a low-field (0.4 g) configuration and in pure free fall. These results represent a key step toward free-fall ferromagnetic magnetometry, the long-sought direct observation of macroscopic Larmor precession, and future space-based experiments. △ Less

Submitted 31 May, 2026; originally announced June 2026.

Shielded inner-shell transitions in atomic samarium for tests of fundamental physics

Authors: R. Aramyan, D. Budker, V. A. Dzuba, V. V. Flambaum, S. G. Porsev, M. S. Safronova, O. Tretiak, K. Zhang

Abstract: Forbidden atomic transitions provide some of the most stringent low-energy tests of physics beyond the Standard Model, with sensitivity set by the interplay between the sought-for signals and systematics suppressed by symmetry. Here we identify the previously unobserved $4f^{6}6s^{2}\,{}^{5}$D$_{0}$ level of neutral samarium at $14\,564.90(2)\,\mathrm{cm}^{-1}$, opening the ${}^{7}$F… ▽ More Forbidden atomic transitions provide some of the most stringent low-energy tests of physics beyond the Standard Model, with sensitivity set by the interplay between the sought-for signals and systematics suppressed by symmetry. Here we identify the previously unobserved $4f^{6}6s^{2}\,{}^{5}$D$_{0}$ level of neutral samarium at $14\,564.90(2)\,\mathrm{cm}^{-1}$, opening the ${}^{7}$F$_{0}\rightarrow{}^{5}$D$_{0}$ inner-shell transition for precision spectroscopy. Candidate lines extracted from dual-comb absorption spectra were assigned using double-resonance population-depletion and sequential-excitation measurements. The observed pressure broadening, $0.12(2)\,\mathrm{MHz/torr}$, and pressure shift, $0.145(4)\,\mathrm{MHz/torr}$, indicate an inner-shell $4f$-transition shielded from external perturbations. Many-body calculations predict a $\sim\!120\,\mathrm{ms}$ metastable lifetime (quality factor $\mathcal{Q}\sim 3\times 10^{14}$), large sensitivity coefficients for variation of the fine-structure constant, and a nuclear-spin-dependent parity-violation amplitude comparable to that of cesium. Crucially, the $J=0\rightarrow J=0$ selection rule suppresses by symmetry both the nuclear-spin-independent parity-violation channel and the M1 and E2 backgrounds that complicated previous heavy-atom experiments, yielding a uniquely clean window onto the nuclear anapole moment. The two stable spin-$7/2$ isotopes of samarium provide a remarkable opportunity to largely cancel atomic-structure uncertainties by measuring the ratio of parity-violation effects in the two isotopes. These results establish neutral samarium as a platform for inner-shell precision spectroscopy and tests of physics beyond the Standard Model. △ Less

Submitted 28 May, 2026; v1 submitted 21 May, 2026; originally announced May 2026.

Optically detected nuclear magnetic resonance of carbon-13 in bulk diamond

Authors: Maxwell D. Aiello, Janis Smits, Yaser Silani, Andris Berzins, David Lidsky, Bryan A. Richards, Amilcar Jeronimo Perez, Chandrasekhar Ramanathan, Sebastián C. Carrasco, Jabir Chathanathil, Michael Goerz, Vladimir Malinovsky, Dmitry Budker, Sean Lourette, Andrey Jarmola, Victor M. Acosta

Abstract: Precision measurements based on optically detected nuclear magnetic resonance offer exquisite sensitivity to absolute shifts in spin transition frequencies, with potential applications in fundamental physics experiments and inertial sensing. We investigate 13C nuclear spins in diamond as a candidate system for solid-state implementations, which hold the promise for high-fidelity readout of large n… ▽ More Precision measurements based on optically detected nuclear magnetic resonance offer exquisite sensitivity to absolute shifts in spin transition frequencies, with potential applications in fundamental physics experiments and inertial sensing. We investigate 13C nuclear spins in diamond as a candidate system for solid-state implementations, which hold the promise for high-fidelity readout of large numbers of coherent nuclear spins in millitesla or lower magnetic fields. We demonstrate a technique that allows for both optical polarization and readout of large ensembles of ~10^{16} polarized nuclear spins. Our method takes advantage of state-selective Landau-Zener transitions under microwave frequency sweeping, which bidirectionally transfer spin polarization between Nitrogen-Vacancy (NV) electron spins and remote 13C nuclear spins. Using natural isotopic abundance diamonds with nitrogen densities of ~0.5-10 ppm, we perform optically-detected 13C Ramsey spectroscopy and realize a nuclear-spin-dependent fluorescence contrast exceeding 0.5% peak-to-peak. We observe nuclear spin dephasing times T2*~2 ms that only modestly improve with homonuclear dipolar decoupling, indicating that they are limited by the longitudinal spin relaxation of nearby NV electron spins. We study the magnetic field dependence of the optical readout and find comparable contrast and dephasing times for magnetic fields in the range 8-20 mT. Our method can be interpreted as a type of repetitive readout, where each NV center optically reads out the spin state of ~100 nuclei before nuclear spins depolarize. △ Less

Submitted 29 May, 2026; v1 submitted 30 April, 2026; originally announced May 2026.

Comments: 25 pages, 17 figures, 7 tables, 70 refs. v2 fixed two typos

Control of relaxation properties of a macroscopic nuclear spin ensemble

Authors: János Ádám, Andrew J. Winter, Deniz Aybas, Dmitry Budker, Derek F. Jackson Kimball, Arne Wickenbrock, Alexander O. Sushkov

Abstract: Macroscopic spin ensembles in solids are powerful platforms for quantum sensing and precision metrology. A key challenge is controlling the nuclear spin population relaxation time $T_1$, which can become prohibitively long at cryogenic temperatures due to phonon freeze-out. We demonstrate optical control of the $T_1$ relaxation time of the $^{207}$Pb nuclear spin ensemble in lead-containing ferroe… ▽ More Macroscopic spin ensembles in solids are powerful platforms for quantum sensing and precision metrology. A key challenge is controlling the nuclear spin population relaxation time $T_1$, which can become prohibitively long at cryogenic temperatures due to phonon freeze-out. We demonstrate optical control of the $T_1$ relaxation time of the $^{207}$Pb nuclear spin ensemble in lead-containing ferroelectric crystals PbTiO$_3$ (PT) and (PbMg$_{1/3}$Nb$_{2/3}$O$_3$)$_{2/3}$-(PbTiO$_3$)$_{1/3}$ (PMN-PT). Using X-band electron paramagnetic resonance (EPR) spectroscopy at 10 K, we characterize light-induced paramagnetic centers created by 405 nm laser illumination. In PT, we observe paramagnetic Pb$^{3+}$ centers and their hyperfine interaction with nearby nuclear spins. In PMN-PT, we identify two populations: isotropic Pb$^{3+}$ centers and anisotropic Ti$^{3+}$ centers occupying $d$-orbitals, with spin number densities of $(2.5 \pm 1.0) \times 10^{17}$ cm$^{-3}$ and $(4.1 \pm 1.7) \times 10^{17}$ cm$^{-3}$, respectively. Power-dependent EPR measurements enable extraction of spin relaxation times. We investigate the ionization and recombination dynamics of these transient paramagnetic centers. Using saturation-recovery nuclear magnetic resonance, we demonstrate that laser illumination reduces the $^{207}$Pb nuclear $T_1$ by approximately a factor of two, from $(17 \pm 2)$ s to $(7 \pm 1)$ s at 4.6 MHz, and from $(1550 \pm 40)$ s to $(850 \pm 70)$ s at 40 MHz. We develop a model relating the nuclear relaxation rate to the density of photoinduced paramagnetic centers. This optical control of nuclear spin relaxation provides a pathway toward accelerated thermal polarization and dynamic nuclear polarization in solid-state NMR-based precision measurements, including searches for axion-like dark matter. △ Less

Submitted 28 April, 2026; originally announced April 2026.

Floquet engineering of spin-spin interactions in a hybrid atomic system

Authors: Daniel Gavilan-Martin, Grzegorz Łukasiewicz, Vincent Schäfer, Mikhail Padniuk, Adam Stefański, Adam Węglik, Emmanuel Klinger, Szymon Pustelny, Derek F. Jackson Kimball, Dmitry Budker, Arne Wickenbrock

Abstract: We demonstrate dynamical control of the effective spin-spin interaction, dominated by Fermi-contact interaction, in a hybrid spin system via parametric modulation. We show that, in an alkali-noble-gas comagnetometer, periodic modulation of the direction of the electron spin polarization with respect to the nuclear polarization leads to a Floquet-induced renormalization of the spin-exchange couplin… ▽ More We demonstrate dynamical control of the effective spin-spin interaction, dominated by Fermi-contact interaction, in a hybrid spin system via parametric modulation. We show that, in an alkali-noble-gas comagnetometer, periodic modulation of the direction of the electron spin polarization with respect to the nuclear polarization leads to a Floquet-induced renormalization of the spin-exchange coupling, governed by a zeroth-order Bessel function. This effect enables continuous tuning and suppression of the effective interaction strength without altering the intrinsic properties of the system. We develop a theoretical model that supports the experimental measurements. The results establish a general mechanism for controlling interaction strengths in hybrid atomic systems and provide new opportunities for precision measurements and quantum memories. △ Less

Submitted 20 April, 2026; originally announced April 2026.

Global detector network to search for high-frequency gravitational waves (GravNet): conceptual design

Authors: Dorian Amaral, Diego Blas, Yuliia Borysenkova, Dmitry Budker, Alessandro D'Elia, Giorgio Dho, Alejandro Díaz-Morcillo, Daniele Di Gioacchino, Sebastian Ellis, Claudio Gatti, Benito Gimeno, Jordan Gué, Stefan Horodenski, Saarik Kalia, Younggeun Kim, Tom Krokotsch, Tomas Kvietkauskas, Adrián Lambíes-Asensio, Carlo Ligi, Giovanni Maccarrone, Giovanni Mazzitelli, Juan Monzó-Cabrera, José R. Navarro-Madrid, José Reina-Valero, Alessio Rettaroli , et al. (8 additional authors not shown)

Abstract: We propose GravNet (Global detector network to search for high-frequency gravitational waves), a novel experimental scheme enabling the search for gravitational waves in the MHz to GHz frequency range. Such high-frequency gravitational waves could arise from a variety of phenomena connected to some of the most pressing and fundamental questions in modern cosmology. The GravNet concept is based on… ▽ More We propose GravNet (Global detector network to search for high-frequency gravitational waves), a novel experimental scheme enabling the search for gravitational waves in the MHz to GHz frequency range. Such high-frequency gravitational waves could arise from a variety of phenomena connected to some of the most pressing and fundamental questions in modern cosmology. The GravNet concept is based on synchronous measurements of signals from multiple experimental measurement devices operating at geographically separated locations. While gravitational-wave-induced signatures may be present in the signal of a single detector, distinguishing them from instrumental or environmental noise is highly challenging. By analyzing correlations between signals from several distant detectors, the detection significance is substantially enhanced, while simultaneously enabling studies of the nature and origin of the gravitational-wave signal. In this work, we discuss the GravNet concept specifically in the context of cavities operated in strong magnetic fields, as these currently represent the most technically mature and experimentally advanced realization of the scheme. As part of this proposal, a first demonstration experiment using a non-superconducting cavity has been performed, providing the basis for the data-analysis strategies discussed in this work. Finally, we outline the prospects and future development of GravNet as a global network for high-frequency gravitational-wave searches. △ Less

Submitted 25 March, 2026; originally announced March 2026.

Comments: 25 pages, 10 figures

Chemically-polarized material for nuclear and particle physics

Authors: Benjamin G. Collins, Daniel P. Watts, Mikhail Bashkanov, Stephen Kay, Simon B. Duckett, Andreas Thomas, Dmitry Budker, Danila Barskiy, Raphael Kircher

Abstract: Spin-polarized solid targets have underpinned many recent key advances in nuclear and particle physics, yet traditional methods to produce them face significant limitations due to the high cost and demanding cryogenic and magnetic field requirements. These factors constrain experimental geometries and present challenges in intense radiation environments where depolarization and materials damage ca… ▽ More Spin-polarized solid targets have underpinned many recent key advances in nuclear and particle physics, yet traditional methods to produce them face significant limitations due to the high cost and demanding cryogenic and magnetic field requirements. These factors constrain experimental geometries and present challenges in intense radiation environments where depolarization and materials damage can occur. We present the first results assessing the capabilities of the chemical hyperpolarization (ChHP) method Signal Amplification By Reversible Exchange (SABRE) to act as the polarization method to produce targets or active detector media. We show by using in-beam measurements that there is no depolarizing effect observed with the SABRE-polarized material in the A2 photon beam at the Mainzer Mikrotron (MAMI), as well as showing the resilience of such media to radioactive doses of up to \SI{3}{\kilo\gray}. We also illustrate the capabilities for using SABRE-polarized material as a scintillation or Cherenkov detector. △ Less

Submitted 6 March, 2026; originally announced March 2026.

Black hole scalar sirens in the Milky Way

Authors: Daniel Gavilan-Martin, Olivier Simon, Dhashin Krishna, Derek F. Jackson Kimball, Dmitry Budker, Arne Wickenbrock

Abstract: Hypothetical light scalar particles trigger the superradiant instability around spinning black holes (BHs), causing clouds of scalars to grow around the BH. In the presence of sufficiently strong particle self-interactions (characterized by the decay constant $f$), scalars are ejected from BH orbits, resulting in coherent, non-relativistic emissions that continuously carry away the BH's angular mo… ▽ More Hypothetical light scalar particles trigger the superradiant instability around spinning black holes (BHs), causing clouds of scalars to grow around the BH. In the presence of sufficiently strong particle self-interactions (characterized by the decay constant $f$), scalars are ejected from BH orbits, resulting in coherent, non-relativistic emissions that continuously carry away the BH's angular momentum. Parameters exist for which cloud growth is much faster, and scalar depletion is much slower, than the age of the Galaxy. This defines a distinct class of astrophysical sources of scalars, which we call BH scalar sirens -- BHs that persistently emit scalars effectively forever. We compute the scalar background from the expected population of $N_\text{BH}\sim 10^{8}$ isolated stellar-mass BHs in the Milky Way, which are sirens for scalars in the mass range $10^{-13}$--$10^{-11}\,$eV and $f\lesssim 10^{14}$--$10^{9}\,$GeV. This provides a detection target independent of early-universe scalar production or cosmological initial conditions. The generated observable signals are up to two orders-of-magnitude larger than those expected from a misaligned cosmic scalar in this mass range. The energy spectrum of emitted scalars is distinctly broader and at higher velocities (up to $\sim 10^{-1}c$) than that of virialized dark matter, and encodes the mass and spin distributions of the BH population. While stellar-mass Milky Way BHs are our primary target, our framework extends to supermassive, intermediate-mass and light BHs. Given the difficulty of directly observing populations of isolated BHs, scalar emissions offer a novel probe of these otherwise invisible objects, highlighting the potential for joint discovery between scalars and BHs, and broadly motivating searches for scalars over many orders-of-magnitude in mass. △ Less

Submitted 10 March, 2026; v1 submitted 26 February, 2026; originally announced February 2026.

Comments: v2: Updated citations. Expanded section IIIA4

Testing Exotic Electron-Electron Interactions with the Helium Ionization-Energy Anomaly

Authors: Lei Cong, Filip Ficek, Rinat Abdullin, Mikhail G. Kozlov, Dmitry Budker

Abstract: Precision atomic spectroscopy provides a sensitive probe of physics beyond the Standard Model. A recently reported $9σ$ theory-experiment discrepancy in the ionization energy of metastable helium has motivated the hypothesis of a new boson mediating exotic electron-electron interactions. Using a model-independent sign-consistency analysis of the induced energy shifts, we show that the sign require… ▽ More Precision atomic spectroscopy provides a sensitive probe of physics beyond the Standard Model. A recently reported $9σ$ theory-experiment discrepancy in the ionization energy of metastable helium has motivated the hypothesis of a new boson mediating exotic electron-electron interactions. Using a model-independent sign-consistency analysis of the induced energy shifts, we show that the sign requirement alone excludes vector-vector and pseudoscalar-pseudoscalar interactions as possible explanations of the anomaly. Incorporating existing constraints together with improved limits obtained here further excludes axial-vector scenarios. Within the single-boson framework considered in this work, only a narrowly constrained scalar-mediated interaction remains viable. The remaining parameter space could be probed, for example, by modest improvements in the determination of the electron gyromagnetic ratio. △ Less

Submitted 10 February, 2026; originally announced February 2026.

Comments: 5 pages, 3 figures

Human Cardiac Measurements with Diamond Magnetometers

Authors: Muhib Omar, Magnus Benke, Shaowen Zhang, Jixing Zhang, Michael Kuebler, Pouya Sharbati, Ara Rahimpour, Arno Gueck, Maryna Kapitonova, Devyani Kadam, Carlos Rene Izquierdo Geiser, Jens Haller, Arno Trautmann, Katharina Jag-Lauber, Robert Roelver, Thanh-Duc Nguyen, Leonardo Gizzi, Michelle Schweizer, Mena Abdelsayed, Ingo Wickenbrock, Andrew M. Edmonds, Matthew Markham, Peter A. Koss, Oliver Schnell, Ulrich G. Hofmann , et al. (5 additional authors not shown)

Abstract: We demonstrate direct, non-invasive and non-contact detection of human cardiac magnetic signals using quantum sensors based on nitrogen-vacancy (NV) centers in diamond. Three configurations were employed recording magnetocardiography (MCG) signals in various shielded and unshielded environments. The signals were averaged over a few hundreds up to several thousands of heart beats to detect the MCG… ▽ More We demonstrate direct, non-invasive and non-contact detection of human cardiac magnetic signals using quantum sensors based on nitrogen-vacancy (NV) centers in diamond. Three configurations were employed recording magnetocardiography (MCG) signals in various shielded and unshielded environments. The signals were averaged over a few hundreds up to several thousands of heart beats to detect the MCG traces. The compact room-temperature NV sensors exhibit sensitivities of 6-26 pT/Hz^(1/2) with active sensing volumes below 0.5 mm^3, defining the performance level of the demonstrated MCG measurements. While the present signals are obtained by averaging, this performance already indicates a clear path toward single-shot MCG sensing. To move beyond shielded environments toward practical clinical use, strong noise suppression is required. To this end, we implement NV-based gradiometry and achieve efficient common-mode noise rejection, enabled by the intrinsically small sensing volume of NV sensors. Together, these multi-platform results obtained across diverse magnetic environments provide a solid foundation for translating quantum sensors into human medical diagnostics such as MCG and magnetoencephalography (MEG). △ Less

Submitted 26 January, 2026; originally announced January 2026.

Towards a temperature-insensitive composite diamond clock

Authors: Sean Lourette, Andrey Jarmola, Jabir Chathanathil, Victor M. Acosta, A. Glen Birdwell, Peter Blümler, Dmitry Budker, Sebastián C. Carrasco, Tony G. Ivanov, Shimon Kolkowitz, Vladimir S. Malinovsky

Abstract: Frequency references based on solid state spins promise simplicity, compactness, robustness, multifunctionality, ease of integration, and high densities of emitters. Nitrogen-vacancy (NV) centers in diamond are a natural candidate, but the electronic zero-field splitting exhibits a large fractional temperature dependence, which has precluded its use as a stable clock transition. Here we show that… ▽ More Frequency references based on solid state spins promise simplicity, compactness, robustness, multifunctionality, ease of integration, and high densities of emitters. Nitrogen-vacancy (NV) centers in diamond are a natural candidate, but the electronic zero-field splitting exhibits a large fractional temperature dependence, which has precluded its use as a stable clock transition. Here we show that this limitation can be overcome by forming a composite frequency reference that combines measurements of the electronic splitting D with the nuclear quadrupole splitting of the $^{14}$N nuclear spin intrinsic to the NV center. We further benchmark this composite approach against alternative strategies for mitigating temperature sensitivity. By implementing a specially designed pulse sequence with an eight-phase control scheme that suppresses pulse imperfections, we interleave measurements of D and Q in a high-density NV ensemble and demonstrate a temperature-compensated composite frequency reference. The stability of this composite diamond clock is characterized over a 10-day period at room temperature through a comparison to a Rb vapor-cell clock, yielding a fractional instability below $5 \times 10^{-9}$ for an averaging time of $τ= 200$ s and below $1 \times 10^{-8}$ at $τ= 2 \times 10^5$ s, corresponding to measured improvements by a factor of 4 and 200, respectively, over a clock based purely on the single frequency D for the same periods. By characterizing the residual sensitivity to magnetic fields, optical power, and radio-frequency drive amplitudes, we find that temperature is no longer the dominant source of instability. These results establish complementary electron- and nuclear-spin transitions in diamond as a viable route to thermally robust frequency metrology, providing a pathway toward compact, multifunctional solid-state clocks and quantum sensors. △ Less

Submitted 31 December, 2025; originally announced January 2026.

Comments: 14 pages, 6 figures

Search for a solar-bound axion halo using the Global Network of Optical Magnetometers for Exotic physics searches

Authors: Tatum Z. Wilson, Derek F. Jackson Kimball, Samer Afach, Jiexiao Bi, B. C. Buchler, Dmitry Budker, Kaleb Cervantes, Joshua Eby, Nataniel L. Figueroa, Ron Folman, Jiawei Gao, Daniel Gavilán-Martín, Menachem Givon, Zoran D. Grujić, Hong Guo, Paul Hamilton, M. P. Hedges, Zhejun Huang, Dongok Kim, Younggeun Kim, Sami S. Khamis, Emmanuel Klinger, Abaz Kryemadhi, Nina Kukowski, Jianjun Li , et al. (28 additional authors not shown)

Abstract: We report on a search for a gravitationally bound solar axion halo using data from the Global Network of Optical Magnetometers for Exotic physics searches (GNOME), a worldwide array of magnetically shielded atomic magnetometers with sensitivity to exotic spin couplings. Motivated by recent theoretical work suggesting that self-interacting ultralight axions can be captured by the Sun's gravitationa… ▽ More We report on a search for a gravitationally bound solar axion halo using data from the Global Network of Optical Magnetometers for Exotic physics searches (GNOME), a worldwide array of magnetically shielded atomic magnetometers with sensitivity to exotic spin couplings. Motivated by recent theoretical work suggesting that self-interacting ultralight axions can be captured by the Sun's gravitational field and thermalize into the ground state, we develop a signal model for the pseudo-magnetic fields generated by axion-proton gradient couplings in such a halo. The analysis focuses on the fifth GNOME Science Run (69 days, 12 stations), employing a cross-correlation pipeline with time-shifted daily modulation templates to search for the global, direction-dependent, monochromatic signal expected from a solar axion halo. No statistically significant candidate signals are observed. We set 95% confidence-level upper limits on the amplitude of the axion-induced pseudo-magnetic field over the frequency range $\approx 0.05-20$ Hz, translating to constraints on the linear and quadratic axion-proton couplings for halo densities predicted by gravitational capture models and for the maximum overdensities allowed by planetary ephemerides. In the quadratic coupling case, our limits surpass existing astrophysical bounds by over two orders of magnitude across much of the accessible parameter space. △ Less

Submitted 1 July, 2026; v1 submitted 10 December, 2025; originally announced December 2025.

Comments: 22 pages, 18 figures

Journal ref: Phys. Rev. D 113, 115027 (2026)

Zero- to low-field J-spectroscopy with a diamond magnetometer

Authors: Muhib Omar, Jingyan Xu, Raphael Kircher, Pouya Sharbati, Shaowen Zhang, Georgios Chatzidrosos, James Eills, Roman Picazo-Frutos, Dmitry Budker, Danila A. Barskiy, Arne Wickenbrock

Abstract: We report measurements of zero- to ultra-low-field nuclear magnetic resonance (ZULF NMR) signals at frequencies of a few hertz with a diamond-based magnetic sensor. The sensing diamond is a truncated pyramid with 0.18 mm height and a 0.5 mm x 0.5mm base. The minimum stand-off distance is < 1 mm, and the sensor sensitivity is 13 pT/(Hz)^(1/2) at frequencies f above 5 Hz with 1/f-like behavior at lo… ▽ More We report measurements of zero- to ultra-low-field nuclear magnetic resonance (ZULF NMR) signals at frequencies of a few hertz with a diamond-based magnetic sensor. The sensing diamond is a truncated pyramid with 0.18 mm height and a 0.5 mm x 0.5mm base. The minimum stand-off distance is < 1 mm, and the sensor sensitivity is 13 pT/(Hz)^(1/2) at frequencies f above 5 Hz with 1/f-like behavior at lower frequencies. NMR signals were generated via signal amplification by reversible exchange (SABRE) parahydrogen-based hyperpolarization resulting in zero-field signals at 1.7 Hz and 3.4 Hz corresponding to the expected hetero-nuclear J-coupling pattern of acetonitrile. This work demonstrates a magnet-free platform for detecting chemically specific NMR signals at ultra-low frequencies paving the way for portable noninvasive diagnostics in microscopic sample volumes for biomedicine, industrial sensing through metal enclosures, and field-deployable quantum analytical devices. △ Less

Submitted 26 January, 2026; v1 submitted 5 December, 2025; originally announced December 2025.

Second-order correlations in directed emissions in sodium atoms

Authors: Ara Tonoyan, Sushree Subhadarshinee Sahoo, Anahit Gogyan, Oleg Tretiak, Razmik Aramyan, Alexander Akulshin, Dmitry Budker

Abstract: We report on measurements of second-order intensity correlations $g^{(2)}(τ)$ of infrared emission under bichromatic excitation at 589.2\,nm and 569.0\,nm of sodium atoms contained in a buffer-gas-free and uncoated 10-cm-long vapor cell. Directional emissions at $2.34\,μ$m in the forward direction and $2.21\,μ$m in both forward and backward directions under different experimental parameters are co… ▽ More We report on measurements of second-order intensity correlations $g^{(2)}(τ)$ of infrared emission under bichromatic excitation at 589.2\,nm and 569.0\,nm of sodium atoms contained in a buffer-gas-free and uncoated 10-cm-long vapor cell. Directional emissions at $2.34\,μ$m in the forward direction and $2.21\,μ$m in both forward and backward directions under different experimental parameters are considered for this study. The measured values of $g^{(2)}(0)$ in all cases are found to exceed unity, while remaining significantly below the thermal light limit of 2. Cross-correlation measurements reveal that forward- and backward-propagating $2.21\,μ$m radiations are correlated. Oscillatory features in $g^{(2)}(τ)$ are observed over a broad range of excitation powers, and the dependence of the oscillation frequency on laser power can be attributed to AC Stark shifts, with contributions from hyperfine atomic structure in selected atomic velocity groups even in the presence of Doppler broadening. Our study establishes that the observed mid-infrared emission arises from a phase-matched, continuous-wave cooperative process that combines features of lasing and collective amplified spontaneous emission. The results highlight the buildup of long-range dipole coherence and velocity-selective coupling of atomic groups, which together govern the observed photon correlations and forward-backward emission symmetry. The demonstrated backward emission is of particular interest for applications in laser guidestar generation and mesospheric remote sensing, where understanding the statistical properties of the emitted light is essential for optimizing sodium-based light sources. △ Less

Submitted 15 November, 2025; originally announced November 2025.

Comments: 8 pages, 5 figures

Nuclear spin relaxation in zero- to ultralow-field magnetic resonance spectroscopy

Authors: Florin Teleanu, Anne M. Fabricant, Chengtong Zhang, Gary P. Centers, Dmitry Budker, Danila A. Barskiy, Alexej Jerschow

Abstract: Nuclear-magnetic-resonance experiments can interrogate a broad spectrum of molecular-tumbling regimes and can accurately measure interatomic distances in solution with sub-nanometer resolution. In the zero- to ultralow-field (ZULF) regime, population and coherence decay reveal nontrivial behavior due to strong coupling between nuclear spins. We note, in particular, the surprising effects that diff… ▽ More Nuclear-magnetic-resonance experiments can interrogate a broad spectrum of molecular-tumbling regimes and can accurately measure interatomic distances in solution with sub-nanometer resolution. In the zero- to ultralow-field (ZULF) regime, population and coherence decay reveal nontrivial behavior due to strong coupling between nuclear spins. We note, in particular, the surprising effects that different resonances show different relaxation rates, depending on (i) the (pre)polarizing magnet field and the shuttling trajectory to the detection region at nano- and microtesla fields, (ii) the strength of the measurement field, (iii) the detection method (single-channel or quadrature), and even (iv) the nutation angle induced by the excitation pulse. We describe herein experimental data of relaxation rates measured for a 13C-labeled formic acid sample, with an atomic-magnetometer-based ZULF setup, and develop a theoretical framework to explain the detected effects and extract molecular properties. The observed effects could be used for spectral assignment, for the establishment of specific motional regimes, for image contrast, and for the characterization of relaxation processes at nano- to microtesla magnetic fields. △ Less

Submitted 11 November, 2025; originally announced November 2025.

Comments: 22 pages, 10 figures, 3 simulation notebooks, all experimental data

Study of the elusive $5s-4f$ level crossing in highly charged osmium with optical transitions suitable for physics beyond the Standard Model searches

Authors: Nils-Holger Rehbehn, Lakshmi Priya Kozhiparambil Sajith, Michael K. Rosner, Charles Cheung, Sergey G. Porsev, Marianna S. Safronova, Steven Worm, Dmitry Budker, Thomas Pfeifer, José R. Crespo López-Urrutia, Hendrik Bekker

Abstract: Optical transitions of highly charged ions can be very sensitive to hypothetical beyond-the-Standard-Model phenomena. Those near the $5s-4f$ level crossing, where the $5s$ and $4f$ are degenerate are especially promising. We present predictions from atomic theory and measurements of Os$^{15,16,17+}$ at an electron beam ion trap for identification of several transitions suitable for searches for a… ▽ More Optical transitions of highly charged ions can be very sensitive to hypothetical beyond-the-Standard-Model phenomena. Those near the $5s-4f$ level crossing, where the $5s$ and $4f$ are degenerate are especially promising. We present predictions from atomic theory and measurements of Os$^{15,16,17+}$ at an electron beam ion trap for identification of several transitions suitable for searches for a hypothetical fifth force and possible violations of local Lorentz invariance. The electric quadrupole (E2) transitions of Os$^{16+}$ that were found are especially suitable for frequency metrology due to their small linewidth of 44 $μ$Hz. Our calculations show the need for including enough inner-shell excitations to predict transition rates between configurations, which can otherwise be overestimated. Ultimately, the predicted interconfiguration transitions were too weak to be detected. △ Less

Submitted 8 September, 2025; originally announced September 2025.

Comments: 9 pages, 2 figures

Trapping of electrons and $^{40}\textrm{Ca}^+$ ions in a dual-frequency Paul trap

Authors: Vladimir Mikhailovskii, Natalija Sheth, Guofeng Qu, Michal Hejduk, Niklas Vilhelm Lausti, K. T. Satyajith, Christian Smorra, Günther Werth, Neha Yadav, Qian Yu, Clemens Matthiesen, Hartmut Häffner, Ferdinand Schmidt-Kaler, Hendrik Bekker, Dmitry Budker

Abstract: We demonstrate the operation of a dual-frequency Paul trap and characterize its performance by storing either electrons or calcium ions while applying two quadrupole fields simultaneously which oscillate at $Ω_\textrm{fast} = 2π\times 1.6$ GHz and $Ω_\textrm{slow} = 2π\times 2$ MHz. The particles are loaded and stored in the trap under various conditions followed by detection employing an electron… ▽ More We demonstrate the operation of a dual-frequency Paul trap and characterize its performance by storing either electrons or calcium ions while applying two quadrupole fields simultaneously which oscillate at $Ω_\textrm{fast} = 2π\times 1.6$ GHz and $Ω_\textrm{slow} = 2π\times 2$ MHz. The particles are loaded and stored in the trap under various conditions followed by detection employing an electron multiplier tube. We find that tens of electrons or ions can be trapped for up to ten milliseconds and a small fraction remains trapped even after hundreds of milliseconds. During dual-frequency operation we find that while the number of trapped electrons rapidly decreases with increase of the $Ω_\textrm{slow}$ field amplitude, the number of trapped ions shows no dependence on the $Ω_\textrm{fast}$ field amplitude as supported by our extensive numerical simulations. We aim to use a similar trap for synthesising antihydrogen from antiprotons and positrons. Accordingly, we discuss open challenges such as the co-trapping of oppositely charged species and particle trap duration. △ Less

Submitted 22 August, 2025; originally announced August 2025.

Comments: 11 pages, 13 figures

Journal ref: Phys. Rev. A 113, 043102, April 2026

Solving tricky quantum optics problems with assistance from (artificial) intelligence

Authors: Manas Pandey, Bharath Hebbe Madhusudhana, Saikat Ghosh, Dmitry Budker

Abstract: The capabilities of modern artificial intelligence (AI) as a ``scientific collaborator'' are explored by engaging it with three nuanced problems in quantum optics: state populations in optical pumping, resonant transitions between decaying states (the Burshtein effect), and degenerate mirrorless lasing. Through iterative dialogue, the authors observe that AI models--when prompted and corrected--ca… ▽ More The capabilities of modern artificial intelligence (AI) as a ``scientific collaborator'' are explored by engaging it with three nuanced problems in quantum optics: state populations in optical pumping, resonant transitions between decaying states (the Burshtein effect), and degenerate mirrorless lasing. Through iterative dialogue, the authors observe that AI models--when prompted and corrected--can reason through complex scenarios, refine their answers, and provide expert-level guidance, closely resembling the interaction with an adept colleague. The findings highlight that AI democratizes access to sophisticated modeling and analysis, shifting the focus in scientific practice from technical mastery to the generation and testing of ideas, and reducing the time for completing research tasks from days to minutes. △ Less

Submitted 15 June, 2025; originally announced June 2025.

Comments: 9 pages, 3 figures

The QTF-Backbone: Proposal for a Nationwide Optical Fibre Backbone in Germany for Quantum Technology and Time and Frequency Metrology

Authors: Tara Cubel Liebisch, Peter Kaufmann, Harald Schnatz, Susanne Naegele-Jackson, Jochen Kronjäger, Klaus Blaum, Stefan Kück, Dieter Meschede, Stephan Schiller, Laura Agazzi, Soroosh Alighanbari, Joachim Ankerhold, Georgy V. Astakhov, Stefanie Barz, Ingo Baumann, Rainer Baumgart, Christoph Becher, Hendrik Bekker, Oliver Benson, Paolo Bianco, Ronald Bieber, Immanuel Bloch, Ulrike Blumröder, Rainer Bockholt, Johannes Bouman , et al. (144 additional authors not shown)

Abstract: The recent breakthroughs in the distribution of quantum information and high-precision time and frequency (T&F) signals over long-haul optical fibre networks have transformative potential for physically secure communications, resilience of timing infrastructure (such as that supporting Global Navigation Satellite Systems (GNSS)) and fundamental physics. To date, these capabilities remain confined… ▽ More The recent breakthroughs in the distribution of quantum information and high-precision time and frequency (T&F) signals over long-haul optical fibre networks have transformative potential for physically secure communications, resilience of timing infrastructure (such as that supporting Global Navigation Satellite Systems (GNSS)) and fundamental physics. To date, these capabilities remain confined to isolated testbeds, with quantum and T&F signals accessible, for example in Germany, to only a few institutions. In this white paper we propose the QTF Backbone: a dedicated national fibre-optic infrastructure in Germany for the networked distribution of Quantum and T&F signals using dark fibres and specialised hardware. The QTF Backbone is planned as a four-phase deployment over ten years to ensure scalable, sustainable access for research institutions and industry. The concept builds on successful demonstrations of time and frequency distribution at high Technology Readiness Levels (TRLs) across Europe, including PTB-MPQ links in Germany, REFIMEVE in France, and the Italian LIFT network. The QTF Backbone will enable transformative Research and Development (R&D), support a nationwide QTF ecosystem, and ensure the transition from innovation to deployment. As a national and European hub, it will position Germany and Europe at the forefront of quantum networking, as well as T&F transfer. △ Less

Submitted 16 August, 2026; v1 submitted 4 June, 2025; originally announced June 2025.

Comments: 60 pages, 7 figures This version of the article has been accepted for publication, after peer review (when applicable) but is not the Version of Record and does not reflect post-acceptance improvements, or any corrections. The Version of Record is available online at: https://doi.org/10.1140/epjs/s11734-026-02451-3

Journal ref: Liebisch, T.C., Kaufmann, P., Schnatz, H. et al. The QTF Backbone: proposal for a nationwide optical fibre backbone in Germany for quantum technology and time and frequency metrology. Eur. Phys. J. Spec. Top. 235, 3353-3387 (2026)

Search for a parity-violating long-range spin-dependent interaction

Authors: Xing Heng, Zitong Xu, Xiaofei Huang, Dinghui Gong, Guoqing Tian, Wei Ji, Jiancheng Fang, Dmitry Budker, Kai Wei

Abstract: High-sensitivity quantum sensors are a promising tool for experimental searches for beyond-Standard-Model interactions. Here, we demonstrate an atomic comagnetometer operating under a resonantly-coupled hybrid spin-resonance (HSR) regime to probe P-odd, T-even interactions. The HSR regime enables robust nuclear-electron spin coupling, enhancing measurement bandwidth and stability without compromis… ▽ More High-sensitivity quantum sensors are a promising tool for experimental searches for beyond-Standard-Model interactions. Here, we demonstrate an atomic comagnetometer operating under a resonantly-coupled hybrid spin-resonance (HSR) regime to probe P-odd, T-even interactions. The HSR regime enables robust nuclear-electron spin coupling, enhancing measurement bandwidth and stability without compromising the high sensitivity of spin-exchange relaxation-free magnetometers. To minimize vibration noise from velocity-modulated sources, we implement a multistage vibration isolation system, achieving a vibration noise reduction exceeding 700-fold. We establish new constraints on vector-boson-mediated parity-violating interactions, improving experimental sensitivity by three orders of magnitude compared to previous limits. The new constraints complement existing astrophysical and laboratory studies of potential extensions to the Standard Model. △ Less

Submitted 1 May, 2025; originally announced May 2025.

Levitated Sensor for Magnetometry in Ambient Environment

Authors: Wei Ji, Changhao Xu, Guofeng Qu, Dmitry Budker

Abstract: Levitated particle systems have gained significant attention as a rapidly advancing platform for precision sensing, offering low-loss, highly isolated environments by eliminating mechanical contact and associated noise. Current room-temperature levitation techniques are primarily sensitive to acceleration, with magnetic sensing often relying on the Meissner effect, which is impractical under ambie… ▽ More Levitated particle systems have gained significant attention as a rapidly advancing platform for precision sensing, offering low-loss, highly isolated environments by eliminating mechanical contact and associated noise. Current room-temperature levitation techniques are primarily sensitive to acceleration, with magnetic sensing often relying on the Meissner effect, which is impractical under ambient conditions. Here, we demonstrate a diamagnetically stabilized magnetically levitated magnet magnetometer (LeMaMa), where the motion of the magnet is detected optically. Leveraging strong spin-lattice coupling in the ferromagnet to suppress spin-projection noise and minimizing dissipation through levitation, we achieve a sensitivity of 32 fT $/Hz^{1/2}$. This sensitivity is adequate for a wide range of applications in biology, chemistry, and fundamental physics, matching the performance of leading technologies like SQUIDs and atomic magnetometers, while offering the distinct advantage of operating at room temperature and under Earth's magnetic field. △ Less

Submitted 30 April, 2025; originally announced April 2025.

Search for Axionlike Dark Matter Using Liquid-State Nuclear Magnetic Resonance

Authors: Julian Walter, Olympia Maliaka, Yuzhe Zhang, John Blanchard, Gary Centers, Arian Dogan, Martin Engler, Nataniel L. Figueroa, Younggeun Kim, Derek F. Jackson Kimball, Matthew Lawson, Declan W. Smith, Alexander O. Sushkov, Dmitry Budker, Hendrik Bekker, Arne Wickenbrock

Abstract: We search for dark matter in the form of axionlike particles (ALPs) in the mass range $5.576741 \,\mathrm{neV/c^2}$ - $5.577733\,\mathrm{neV/c^2}$ by probing their possible coupling to fermion spins through the ALP field gradient. This is achieved by performing proton nuclear magnetic resonance spectroscopy on a sample of methanol as a technical demonstration of the Cosmic Axion Spin Precession Ex… ▽ More We search for dark matter in the form of axionlike particles (ALPs) in the mass range $5.576741 \,\mathrm{neV/c^2}$ - $5.577733\,\mathrm{neV/c^2}$ by probing their possible coupling to fermion spins through the ALP field gradient. This is achieved by performing proton nuclear magnetic resonance spectroscopy on a sample of methanol as a technical demonstration of the Cosmic Axion Spin Precession Experiment Gradient (CASPEr-Gradient) Low-Field apparatus. Searching for spin-coupled ALP dark matter in this mass range with associated Compton frequencies in a 240 Hz window centered at 1.348570 MHz resulted in a sensitivity to the ALP-proton coupling constant of $g_{\mathrm{ap}} \approx 3 \times 10^{-2}\,\mathrm{GeV}^{-1}$. This narrow-bandwidth search serves as a proof-of-principle and a commissioning measurement, validating our methodology and demonstrating the experiment's capabilities. CASPEr-Gradient Low-Field will probe the mass range from $4.1\,\mathrm{\peV/c^2}$ to $17\,\mathrm{\neV/c^2}$ with hyperpolarized samples to boost the sensitivity beyond the astronomical limits. △ Less

Submitted 30 August, 2025; v1 submitted 22 April, 2025; originally announced April 2025.

Quantum Magnetic J-Oscillators

Authors: Jingyan Xu, Raphael Kircher, Oleg Tretiak, Dmitry Budker, Danila A. Barskiy

Abstract: We introduce quantum J-oscillators that exploit intrinsic nuclear spin-spin (scalar J) couplings in molecules to produce phase-coherent oscillations. Operated in zero magnetic field and driven by a digital feedback, they operate from sub-hertz to a few tens of hertz frequencies. In a proof-of-principle experiment on [15N]-acetonitrile, the oscillator produced a 337 uHz linewidth over 3000 s, more… ▽ More We introduce quantum J-oscillators that exploit intrinsic nuclear spin-spin (scalar J) couplings in molecules to produce phase-coherent oscillations. Operated in zero magnetic field and driven by a digital feedback, they operate from sub-hertz to a few tens of hertz frequencies. In a proof-of-principle experiment on [15N]-acetonitrile, the oscillator produced a 337 uHz linewidth over 3000 s, more than two orders narrower than in conventional zero-field NMR. This may facilitate precision measurements of J-coupling constants and allows distinguishing mixtures of molecules whose zero-field NMR spectra would otherwise be hard to separate. In addition, the combination of strongly coupled spin systems and programmable feedback turns the J-oscillator into a compact tabletop (and, eventually, chip-scale) platform for exploring nonlinear spin dynamics, including chaos, dynamical phase transitions, and perhaps time-crystal behavior. By uniting high-resolution spectroscopy and controllable quantum dynamics in a single, magnet-free setup, J-oscillators open new opportunities for applications where ultraprecise frequency references or molecular fingerprints are required. △ Less

Submitted 18 June, 2025; v1 submitted 8 April, 2025; originally announced April 2025.

Comments: 39 pages, 15 figures, 2 tables

Degenerate mirrorless lasing in thermal vapors

Authors: Aneesh Ramaswamy, Dmitry Budker, Simon Rochester, Aram Papoyan, Svetlana Shmavonyan, Himadri Parashar, Vladimir V. Malinovsky, Svetlana A. Malinovskaya

Abstract: Theoretical predictions were made for the steady-state gain of an orthogonally polarized probe field in a degenerate two-level alkali atom system driven by a linearly polarized continuous-wave pump field in [Opt. Mem. Neural Networks 32 (Suppl 3), S443-S446 (2023)]. Employing linear response theory, we computed the probe absorption spectrum under conditions where the pump was detuned from resonanc… ▽ More Theoretical predictions were made for the steady-state gain of an orthogonally polarized probe field in a degenerate two-level alkali atom system driven by a linearly polarized continuous-wave pump field in [Opt. Mem. Neural Networks 32 (Suppl 3), S443-S446 (2023)]. Employing linear response theory, we computed the probe absorption spectrum under conditions where the pump was detuned from resonance. The results revealed a sub-natural linewidth dispersive feature near the pump resonance, characterized by both gain and absorption. Furthermore, a distinct pure gain peak emerged at a sideband associated with a dressed-state transition. These phenomena are generally absent outside the ultracold regime due to inhomogeneous broadening, primarily from Doppler effects, which obscure the fine spectral structure. In this paper, it is demonstrated that the sideband gain peak is sustained in the warm vapor regime when both the pump Rabi frequency and detuning exceed the Doppler width, $Ω_P > Δ_P \gg Δ_{Dop}$. Our results can enable degenerate mirrorless lasing in thermal alkali atom vapors, offering a significant enhancement in the signal-to-noise ratio for fluoroscopic remote magnetic sensing applications. The theoretical model studied in this paper is also a complete description of atomic vapors with isolated $J = 2 \to J' = 3$ transitions, such as atomic samarium. △ Less

Submitted 22 February, 2026; v1 submitted 18 March, 2025; originally announced March 2025.

Comments: 14 pages, 6 figures

Constraints on new vector boson mediated electron-nucleus interactions from spectroscopy of polar diatomic molecules

Authors: Konstantin Gaul, Lei Cong, Dmitry Budker

Abstract: A measurement of parity violation in the hyperfine structure of $^{138}$Ba$^{19}$F [E. Altuntaş et al. Phys. Rev. Lett. 120, 142501 (2018)] is reinterpreted with electronic structure calculations in terms of beyond Standard Model vector boson mediated electron-nucleus interactions. Our results set constraints on previously unexplored, new boson mediated axial vector-vector nucleus-electron interac… ▽ More A measurement of parity violation in the hyperfine structure of $^{138}$Ba$^{19}$F [E. Altuntaş et al. Phys. Rev. Lett. 120, 142501 (2018)] is reinterpreted with electronic structure calculations in terms of beyond Standard Model vector boson mediated electron-nucleus interactions. Our results set constraints on previously unexplored, new boson mediated axial vector-vector nucleus-electron interactions. Similar bounds are obtained by analyzing the atomic parity violation experiment with $^{133}$Cs. Moreover, we show that future experiments with cold heavy diatomic molecules like $^{225}$RaF can improve the present sensitivity to axial vector-vector nucleus-electron and nucleon-nucleus interactions by up to five orders of magnitudes. △ Less

Submitted 28 March, 2025; v1 submitted 11 March, 2025; originally announced March 2025.

Comments: 7 pages, 2 figures, supplemental material; more consistent definition of g^A_N, references and acknowledgements updated, minor corrections on the text

Searching for Exotic Interactions between Antimatter

Authors: Lei Cong, Filip Ficek, Pavel Fadeev, Yevgeny V. Stadnik, Dmitry Budker

Abstract: We show that atomic antimatter spectroscopy can be used to search for new bosons that carry spin-dependent exotic forces between antifermions. A comparison of a recent precise measurement of the hyperfine splitting of the $1$S and $2$S electronic levels of antihydrogen and bound-state quantum electrodynamics theory yields the first tests of positron-antiproton exotic interactions, constraining the… ▽ More We show that atomic antimatter spectroscopy can be used to search for new bosons that carry spin-dependent exotic forces between antifermions. A comparison of a recent precise measurement of the hyperfine splitting of the $1$S and $2$S electronic levels of antihydrogen and bound-state quantum electrodynamics theory yields the first tests of positron-antiproton exotic interactions, constraining the dimensionless coupling strengths $g_pg_p$, $g_Vg_V$ and $g_Ag_A$, corresponding to the exchange of a pseudoscalar (axionlike), vector, or axial-vector boson, respectively. We also discuss new tests of CPT invariance with exotic spin-dependent and spin-independent interactions involving antimatter. △ Less

Submitted 10 March, 2025; originally announced March 2025.

Comments: 7 pages, 4 figures

Laser fluence-dependent production of molecular thorium ions in different charge states for trapped-ion experiments

Authors: Jonas Stricker, Jean Velten, Valerii Andriushkov, Lennard M. Arndt, Dmitry Budker, Konstantin Gaul, Dennis Renisch, Ferdinand Schmidt-Kaler, Azer Trimeche, Lars von der Wense, Christoph E. Düllmann

Abstract: Thorium ions and molecules, recognized for their distinctive nuclear and atomic attributes, are central to numerous trapped-ion experiments globally. Our study introduces an effective, compact source of thorium ions produced via laser ablation of microgram-scale, salt-based samples. We thoroughly analyze the variety of ion species and charge states generated at varying laser fluences. Utilizing 10… ▽ More Thorium ions and molecules, recognized for their distinctive nuclear and atomic attributes, are central to numerous trapped-ion experiments globally. Our study introduces an effective, compact source of thorium ions produced via laser ablation of microgram-scale, salt-based samples. We thoroughly analyze the variety of ion species and charge states generated at varying laser fluences. Utilizing 10$μ$g of thorium fluoride crystals and laser fluences between $1.00 - 7.00$ J$\cdot$cm$^{-2}$ we produce thorium molecular ions $^{232}$ThF$_x$$^{n+}$ (with $x= 0 - 3$ and charge states up to $n = 3+$), including ThF$^{2+}$ and ThF$^{3+}$. These species are particularly relevant for spectroscopy; ThF$^{3+}$ is valuable for its stable closed-shell configuration, while ThF$^{2+}$, which is isoelectronic to RaF, offers a unique probe for studying nuclear structure and fundamental symmetries due to its simple electronic structure with a single unpaired electron. Density functional theory calculations of the distribution of positive charge in the produced molecular cations and the simplicity of this setup indicate that this method is easily transferable to other actinide systems. △ Less

Submitted 12 July, 2025; v1 submitted 23 February, 2025; originally announced March 2025.

Hyperfine and Zeeman Optical Pumping and Transverse Laser Cooling of a Thermal Atomic Beam of Dysprosium Using a Single 421 nm Laser

Authors: Rohan Chakravarthy, Jonathan Agil, Arijit Sharma, Jung Bog Kim, Dmitry Budker

Abstract: We demonstrate the effect of Zeeman and hyperfine optical pumping and transverse laser cooling of a dysprosium (Dy) atomic beam on the $4f^{10}6s^2(J = 8) \rightarrow 4f^{10}6s6p(J = 9)$ transition at 421.291 nm. For $^{163}$Dy, an electro-optic modulator is used to generate five frequency sidebands required to pump the atoms to the $F = 10.5$ ground state hyperfine level and the light polarizatio… ▽ More We demonstrate the effect of Zeeman and hyperfine optical pumping and transverse laser cooling of a dysprosium (Dy) atomic beam on the $4f^{10}6s^2(J = 8) \rightarrow 4f^{10}6s6p(J = 9)$ transition at 421.291 nm. For $^{163}$Dy, an electro-optic modulator is used to generate five frequency sidebands required to pump the atoms to the $F = 10.5$ ground state hyperfine level and the light polarization is chosen to pump the atoms to the $m_F = 10.5$ Zeeman sublevel. The atoms are simultaneously laser-cooled using a standing wave orthogonal to the atomic beam. The resulting polarized and cooled atomic beam will be used in fundamental physics experiments taking advantage of the accidental degeneracy of excited states in Dy including the ongoing measurement of parity violation in this system. △ Less

Submitted 15 December, 2025; v1 submitted 24 February, 2025; originally announced February 2025.

Comments: 10 pages, 12 figures

Enhanced multichannel dual-comb spectroscopy of complex systems

Authors: R. Aramyan, O. Tretiak, S. S. Sahoo, D. Budker

Abstract: A multichannel dual-comb spectroscopy (DCS) approach for high-resolution, broadband spectral measurements is presented, demonstrating its effectiveness in studying complex atomic systems. By implementing a photodetector array, we enhance DCS capabilities, addressing the fundamental trade-off between signal-to-noise ratio (SNR) and spectral coverage. To resolve ambiguities in frequency conversion,… ▽ More A multichannel dual-comb spectroscopy (DCS) approach for high-resolution, broadband spectral measurements is presented, demonstrating its effectiveness in studying complex atomic systems. By implementing a photodetector array, we enhance DCS capabilities, addressing the fundamental trade-off between signal-to-noise ratio (SNR) and spectral coverage. To resolve ambiguities in frequency conversion, we introduced a relative offset in the radio frequency (RF) comb teeth, ensuring accurate spectral reconstruction. As a proof of concept, the absorption spectrum of samarium (Sm) vapor is investigated over a 52nm range, and several previously unreported absorption lines are detected. This is a step toward "Spectroscopy 2.0", enabling massively parallel spectroscopic measurements (including those at >100 T magnetic fields) crucial for atomic physics and fundamental interactions research. △ Less

Submitted 13 March, 2025; v1 submitted 19 February, 2025; originally announced February 2025.

New Constraints on Axion Mediated Dipole-Dipole Interactions

Authors: Zitong Xu, Xing Heng, Guoqing Tian, Di Gong, Lei Cong, Wei Ji, Dmitry Budker, Kai Wei

Abstract: The search for axions sits at the intersection of solving critical problems in fundamental physics, including the strong CP problem in QCD, uncovering the nature of dark matter, and understanding the origin of the universe's matter-antimatter asymmetry. The measurement of axion-mediated spin-dependent interactions offers a powerful approach for axion detection. However, it has long been restricted… ▽ More The search for axions sits at the intersection of solving critical problems in fundamental physics, including the strong CP problem in QCD, uncovering the nature of dark matter, and understanding the origin of the universe's matter-antimatter asymmetry. The measurement of axion-mediated spin-dependent interactions offers a powerful approach for axion detection. However, it has long been restricted to regions outside the 'axion window' due to a significant trade-off: the need to effectively suppress the magnetic leakage from highly polarized spin sources while simultaneously detecting sub-femtotesla level exotic physics signals at sub-decimeter-scale distances. In this work, we report new experimental results on axion-mediated exotic spin-spin interactions using an iron-shielded SmCo$_5$ spin source in combination with a specially designed self-compensation comagnetometer. Employing a composite shielding structure, we achieved a suppression of the magnetic field by up to $10^{11}$. This enabled us to establish new constraints on the coupling between electrons and neutrons, surpassing previous experimental limits by more than 10000 times within the axion window. Furthermore, we also set strongest constraints on the coupling between electrons and protons. The proposed method holds substantial potential not only for advancing the search for new physics beyond the Standard Model but also for enabling transformative applications in biological and chemical research. △ Less

Submitted 14 January, 2025; originally announced January 2025.

Towards detection of molecular parity violation via chiral co-sensing: the $^1$H/$^{31}$P model system

Authors: Erik Van Dyke, James Eills, Kirill Sheberstov, John Blanchard, Manfred Wagner, Robert Graf, Andrés Emilio Wedenig, Konstantin Gaul, Robert Berger, Rudolf Pietschnig, Denis Kargin, Danila A. Barskiy, Dmitry Budker

Abstract: Fundamental weak interactions have been shown to violate parity in both nuclear and atomic systems. However, observation of parity violation in a molecular system has proven an elusive target. Nuclear spin dependent contributions of the weak interaction are expected to result in energetic differences between enantiomers manifesting in nuclear magnetic resonance (NMR) spectra as chemical shift diff… ▽ More Fundamental weak interactions have been shown to violate parity in both nuclear and atomic systems. However, observation of parity violation in a molecular system has proven an elusive target. Nuclear spin dependent contributions of the weak interaction are expected to result in energetic differences between enantiomers manifesting in nuclear magnetic resonance (NMR) spectra as chemical shift differences on the order of $10^{-6}$ Hz to $10^{-3}$ Hz for high-$Z$ nuclei. By employing simultaneous measurements of the diastereomeric splittings for a light and a heavy nucleus in solution-state NMR, residual chemical shift differences persisting in non-chiral environment between enantiomers of chiral compounds smaller than the typical linewidth of high-field NMR may be resolved. Sources of error must be identified and minimized to verify that the observed effect is, in fact, due to parity violation and not systematic effects. This paper presents a detailed analysis of a system incorporating \textsuperscript{31}P and \textsuperscript{1}H NMR to elucidate the systematic effects and to guide experiments with higher-$Z$ nuclei where molecular parity violation may be resolved. △ Less

Submitted 30 December, 2024; originally announced December 2024.

Study of NbN as superconducting material for the usage in superconducting radio frequency cavities

Authors: Kristof Schmieden, Tim Schneemann, Matthias Schott, Malavika Unni, Hendrik Bekker, Arne Wickenbrock, Dmitry Budker

Abstract: A new axion-haloscope is setup at the Johannes Gutenberg university of Mainz, named the Supax (a SUPerconducting AXion search) experiment. This setup is used to characterize the behaviour of a NbN coated superconducting cavity in a 2.5T strong magnetic field, at a resonance frequency of 8.4GHz. We observe an increasing surface resistance with increasing magnetic field, leading to a decreasing qual… ▽ More A new axion-haloscope is setup at the Johannes Gutenberg university of Mainz, named the Supax (a SUPerconducting AXion search) experiment. This setup is used to characterize the behaviour of a NbN coated superconducting cavity in a 2.5T strong magnetic field, at a resonance frequency of 8.4GHz. We observe an increasing surface resistance with increasing magnetic field, leading to a decreasing quality factor. The behaviour is similar to that of previously studied cavities using Nb3Tn. △ Less

Submitted 19 December, 2024; originally announced December 2024.

Comments: 7 pages, 6 figures

Towards high-sensitivity magnetometry with nitrogen vacancy centers in diamond using the singlet infrared absorption

Authors: Ali Tayefeh Younesi, Muhib Omar, Arne Wickenbrock, Dmitry Budker, Ronald Ulbricht

Abstract: The negatively-charged nitrogen vacancy (NV$^{-}$) center in diamond is widely used for quantum sensing since the sensitivity of the spin triplet in the electronic ground state to external perturbations such as strain and electromagnetic fields make it an excellent probe for changes in these perturbations. The spin state can be measured through optically detected magnetic resonance (ODMR), which i… ▽ More The negatively-charged nitrogen vacancy (NV$^{-}$) center in diamond is widely used for quantum sensing since the sensitivity of the spin triplet in the electronic ground state to external perturbations such as strain and electromagnetic fields make it an excellent probe for changes in these perturbations. The spin state can be measured through optically detected magnetic resonance (ODMR), which is most commonly achieved by detecting the photoluminescence (PL) after exciting the spin-triplet transition. Recently, methods have been proposed and demonstrated that use the absorption of the infrared singlet transition at 1042 nm instead. These methods however require cryogenic temperatures or external cavities to enhance the absorption signal. Here, we report on our optimization efforts of the magnetometer sensitivity at room temperature and without cavities. We reach sensitivities of 18 pT$/\sqrt{\mathrm{Hz}}$, surpassing previously reported values. We also report on a defect that is native to CVD-grown diamond and thus absent in HPHT diamond, the excitation of which impacts the measured singlet absorption signal. △ Less

Submitted 28 October, 2024; originally announced October 2024.

Comments: 6 pages with 4 figures

Zero- to Ultralow-field Nuclear Magnetic Resonance

Authors: Danila A. Barskiy, John W. Blanchard, Dmitry Budker, James Eills, Szymon Pustelny, Kirill F. Sheberstov, Michael C. D. Tayler, Andreas H. Trabesinger

Abstract: Zero and ultralow-field nuclear magnetic resonance (ZULF NMR) is an NMR modality where experiments are performed in fields at which spin-spin interactions within molecules and materials are stronger than Zeeman interactions. This typically occurs at external fields of microtesla strength or below, considerably smaller than Earth's field. In ZULF NMR, the measurement of spin-spin couplings and spin… ▽ More Zero and ultralow-field nuclear magnetic resonance (ZULF NMR) is an NMR modality where experiments are performed in fields at which spin-spin interactions within molecules and materials are stronger than Zeeman interactions. This typically occurs at external fields of microtesla strength or below, considerably smaller than Earth's field. In ZULF NMR, the measurement of spin-spin couplings and spin relaxation rates provides a nondestructive means for identifying chemicals and chemical fragments, and for conducting sample or process analyses. The absence of the symmetry imposed by a strong external magnetic field enables experiments that exploit terms in the nuclear spin Hamiltonian that are suppressed in high-field NMR, which in turn opens up new capabilities in a broad range of fields, from the search for dark matter to the preparation of hyperpolarized contrast agents for clinical imaging. Furthermore, as in ZULF NMR the Larmor frequencies are typically in the audio band, the nuclear spins can be manipulated with d.c. magnetic field pulses, and highly sensitive magnetometers are used for detection. In contrast to high-field NMR, the low-frequency signals readily pass through conductive materials such as metals, and heterogeneous samples do not lead to resonance line broadening, meaning that high-resolution spectroscopy is possible. Notable practical advantages of ZULF NMR spectroscopy are the low cost and relative simplicity and portability of the spectrometer system. In recent years ZULF NMR has become more accessible, thanks to improvements in magnetometer sensitivity and their commercial availability, and the development of hyperpolarization methods that provide a simple means to boost signal strengths by several orders of magnitude. These topics are reviewed and a perspective on potential future avenues of ZULF-NMR research is presented. △ Less

Submitted 5 February, 2025; v1 submitted 29 August, 2024; originally announced September 2024.

Comments: 72 pages, 44 figures, 433 references

Temperature shift of magnetic-field-dependent photoluminescence features of nitrogen-vacancy ensembles in diamond

Authors: Irena Rodzoń, Xue Zhang, Viktor Ivády, Huijie Zheng, Arne Wickenbrock, Dmitry Budker

Abstract: Recently significant attention has been paid to magnetic-field-dependent photoluminescence (PL) features of the negatively charged nitrogen-vacancy (NV) centers in diamond. These features are used for microwave-free sensing and are indicative of the spin-bath properties in the diamond sample. Examinating the temperature dependence of the PL features allows to identify both temperature dependent an… ▽ More Recently significant attention has been paid to magnetic-field-dependent photoluminescence (PL) features of the negatively charged nitrogen-vacancy (NV) centers in diamond. These features are used for microwave-free sensing and are indicative of the spin-bath properties in the diamond sample. Examinating the temperature dependence of the PL features allows to identify both temperature dependent and independent features, and to utilize them in diamond-based quantum sensing and dynamic nuclear polarization applications. Here, we study the thermal variability of many different features visible in a wide range of magnetic fields. To this end, we first discuss the origin of the features and tentatively assign the previously unidentified features to cross relaxation of NV center containing multi-spin systems. The experimental results are compared with theoretically predicted temperature shifts deduced from a combination of thermal expansion and electron-phonon interactions. A deeper insight into the thermal behavior of a wide array of the features may come with important consequences for various applications in high-precision NV thermometry, gyroscopes, solid-state clocks, and biomagnetic measurements. △ Less

Submitted 23 September, 2024; v1 submitted 5 September, 2024; originally announced September 2024.

Comments: 12 pages, 16 figures

Spin-dependent exotic interactions

Authors: Lei Cong, Wei Ji, Pavel Fadeev, Filip Ficek, Min Jiang, Victor V. Flambaum, Haosen Guan, Derek F. Jackson Kimball, Mikhail G. Kozlov, Yevgeny V. Stadnik, Dmitry Budker

Abstract: Novel interactions beyond the four known fundamental forces in nature (electromagnetic, gravitational, strong and weak interactions), may arise due to "new physics" beyond the standard model, manifesting as a "fifth force". This review is focused on spin-dependent fifth forces mediated by exotic bosons such as spin-0 axions and axionlike particles and spin-1 Z' bosons, dark photons, or paraphotons… ▽ More Novel interactions beyond the four known fundamental forces in nature (electromagnetic, gravitational, strong and weak interactions), may arise due to "new physics" beyond the standard model, manifesting as a "fifth force". This review is focused on spin-dependent fifth forces mediated by exotic bosons such as spin-0 axions and axionlike particles and spin-1 Z' bosons, dark photons, or paraphotons. Many of these exotic bosons are candidates to explain the nature of dark matter and dark energy, and their interactions may violate fundamental symmetries. Spin-dependent interactions between fermions mediated by the exchange of exotic bosons have been investigated in a variety of experiments, particularly at the low-energy frontier. Experimental methods and tools used to search for exotic spin-dependent interactions, such as atomic comagnetometers, torsion balances, nitrogen-vacancy spin sensors, and precision atomic and molecular spectroscopy, are described. A complete set of interaction potentials, derived based on quantum field theory with minimal assumptions and characterized in terms of reduced coupling constants, are presented. A comprehensive summary of existing experimental and observational constraints on exotic spin-dependent interactions is given, illustrating the current research landscape and promising directions of further research. △ Less

Submitted 14 October, 2024; v1 submitted 28 August, 2024; originally announced August 2024.

Comments: 100 pages, 16 figures, Invited review submitted to Reviews of Modern Physics (RMP)

Journal ref: Rev. Mod. Phys. 97, 025005 (2025)

Constraints on exotic interactions from scalar spin-spin coupling in tritium deuteride (DT)

Authors: Lei Cong, Derek F. Jackson Kimball, Mikhail G. Kozlov, Dmitry Budker

Abstract: A comparison of theoretical and experimental values of the scalar spin-spin interaction ($J$-coupling) in tritium deuteride molecules yield constraints for nucleon-nucleon exotic interactions of the dimensionless coupling strengths $g_Vg_V$, $g_Ag_A$ and $g_pg_p$, corresponding to the exchange of an vector, axial-vector, and pseudoscalar (axionlike) boson. The couplings between proton ($p$) and nu… ▽ More A comparison of theoretical and experimental values of the scalar spin-spin interaction ($J$-coupling) in tritium deuteride molecules yield constraints for nucleon-nucleon exotic interactions of the dimensionless coupling strengths $g_Vg_V$, $g_Ag_A$ and $g_pg_p$, corresponding to the exchange of an vector, axial-vector, and pseudoscalar (axionlike) boson. The couplings between proton ($p$) and nucleon ($N$), denoted by $g_V^p g_V^N$, $g_p^p g_p^N$ are constrained to be less than $1.4 \times 10^{-6}$ and $2.7\times 10^{-6}$, respectively, for boson masses around 5 keV. The coupling constant $g_A^p g_A^N$ is constrained to be less than $1.0 \times 10^{-18}$ for boson masses $\leq 100$ eV. It is noteworthy that this study represents the first instance in which constraints on $g_V g_V$ have been established through the analysis of the potential term $V_2 + V_3$ for both tritium deuteride and hydrogen deuteride molecules. △ Less

Submitted 29 August, 2024; v1 submitted 27 August, 2024; originally announced August 2024.

Comments: 6 pages, 4 figures

Improved constraints on exotic interactions between electron and proton in hydrogen

Authors: Lei Cong, Filip Ficek, Pavel Fadeev, Dmitry Budker

Abstract: Atomic spectroscopy can be used to search for new bosons that carry exotic forces between elementary fermions. A comparison of a recent precise measurement [Bullis \textit{et al.}, Phys. Rev. Lett. \textbf{130}, 203001 (2023)] of the hyperfine splitting of the 2S$_{1/2}$ electronic levels of hydrogen and up-to-date bound-state quantum electrodynamics theory yields improved constraints on electron-… ▽ More Atomic spectroscopy can be used to search for new bosons that carry exotic forces between elementary fermions. A comparison of a recent precise measurement [Bullis \textit{et al.}, Phys. Rev. Lett. \textbf{130}, 203001 (2023)] of the hyperfine splitting of the 2S$_{1/2}$ electronic levels of hydrogen and up-to-date bound-state quantum electrodynamics theory yields improved constraints on electron-proton exotic interactions of the dimensionless coupling strengths $g_Ag_A$, $g_pg_p$, and $g_Vg_V$ corresponding to the exchange of a axial-vector, pseudoscalar (axionlike) or vector boson, respectively. △ Less

Submitted 31 May, 2025; v1 submitted 20 August, 2024; originally announced August 2024.

Comments: 3 pages, 3 figures

Journal ref: Phys. Rev. A 112, 052824 (2025)

Search for fast-oscillating fundamental constants with space missions

Authors: Dmitry Budker, Joshua Eby, Marianna S. Safronova, Oleg Tretiak

Abstract: While it is possible to estimate the dark matter density at the Sun distance from the galactic center, this does not give information on actual dark matter density in the Solar system. There can be considerable local enhancement of dark matter density in the vicinity of gravitating centers, including the Sun, the Earth, as well as other planets in the solar system. Generic mechanisms for the forma… ▽ More While it is possible to estimate the dark matter density at the Sun distance from the galactic center, this does not give information on actual dark matter density in the Solar system. There can be considerable local enhancement of dark matter density in the vicinity of gravitating centers, including the Sun, the Earth, as well as other planets in the solar system. Generic mechanisms for the formation of such halos were recently elucidated. In this work, we studies the possible halo dark matter overdensities and corresponding dark matter masses allowed for various objects in the solar system. We explore spacecraft missions to detect such halos with instruments such as quantum clocks, atomic and molecular spectrometers designed to search for fast (tens of hertz to gigahertz) oscillations of fundamental constants, highly sensitive comagnetometers, and other quantum sensors and sensor networks. △ Less

Submitted 19 August, 2024; originally announced August 2024.

Comments: 9 pages, 4 figures

Ramsey interferometry of nuclear spins in diamond using stimulated Raman adiabatic passage

Authors: Sean Lourette, Andrey Jarmola, Jabir Chathanathil, Sebastián C. Carrasco, Dmitry Budker, Svetlana A. Malinovskaya, A. Glen Birdwell, Tony Ivanov, Vladimir S. Malinovsky

Abstract: We report the first experimental demonstration of stimulated Raman adiabatic passage (STIRAP) in nuclear-spin transitions of $^{14}$N within nitrogen-vacancy (NV) color centers in diamond. It is shown that the STIRAP technique suppresses the occupation of the intermediate state, which is a crucial factor for improvements in quantum sensing technology. Building on that advantage, we develop and imp… ▽ More We report the first experimental demonstration of stimulated Raman adiabatic passage (STIRAP) in nuclear-spin transitions of $^{14}$N within nitrogen-vacancy (NV) color centers in diamond. It is shown that the STIRAP technique suppresses the occupation of the intermediate state, which is a crucial factor for improvements in quantum sensing technology. Building on that advantage, we develop and implement a generalized version of the Ramsey interferometric scheme, employing half-STIRAP pulses to perform the necessary quantum-state manipulation with high fidelity. The enhanced robustness of the STIRAP-based Ramsey scheme to variations in the pulse parameters is experimentally demonstrated, showing good agreement with theoretical predictions. Our results pave the way for improving the long-term stability of diamond-based sensors, such as gyroscopes and frequency standards. △ Less

Submitted 22 July, 2024; originally announced July 2024.

Comments: 11 pages, 7 figures

A Multi-Messenger Search for Exotic Field Emission with a Global Magnetometer Network

Authors: Sami S. Khamis, Ibrahim A. Sulai, Paul Hamilton, S. Afach, B. C. Buchler, D. Budker, N. L. Figueroa, R. Folman, D. Gavilán-Martín, M. Givon, Z. D. Grujić, H. Guo, M. P. Hedges, D. F. Jackson Kimball, D. Kim, E. Klinger, T. Kornack, A. Kryemadhi, N. Kukowski, G. Lukasiewicz, H. Masia-Roig, M. Padniuk, C. A. Palm, S. Y. Park, X. Peng , et al. (16 additional authors not shown)

Abstract: Quantum sensor networks in combination with traditional astronomical observations are emerging as a novel modality for multi-messenger astronomy. Here we develop a generic analysis framework that uses a data-driven approach to model the sensitivity of a quantum sensor network to astrophysical signals as a consequence of beyond-the-Standard Model (BSM) physics. The analysis method evaluates correla… ▽ More Quantum sensor networks in combination with traditional astronomical observations are emerging as a novel modality for multi-messenger astronomy. Here we develop a generic analysis framework that uses a data-driven approach to model the sensitivity of a quantum sensor network to astrophysical signals as a consequence of beyond-the-Standard Model (BSM) physics. The analysis method evaluates correlations between sensors to search for BSM signals coincident with astrophysical triggers such as black hole mergers, supernovae, or fast radio bursts. Complementary to astroparticle approaches that search for particlelike signals (e.g. WIMPs), quantum sensors are sensitive to wavelike signals from exotic quantum fields. This analysis method can be applied to networks of different types of quantum sensors, such as atomic clocks, matter-wave interferometers, and nuclear clocks, which can probe many types of interactions between BSM fields and standard model particles. We use this analysis method to carry out the first direct search utilizing a terrestrial network of precision quantum sensors for BSM fields emitted during a black hole merger. Specifically we use the Global Network of Optical Magnetometers for Exotic physics (GNOME) to perform a search for exotic low-mass field (ELF) bursts generated in coincidence with a gravitational wave signal from a binary black hole merger (GW200311 115853) detected by LIGO/Virgo on the 11th of March 2020. The associated gravitational wave heralds the arrival of the ELF burst that interacts with the spins of fermions in the magnetometers. This enables GNOME to serve as a tool for multi-messenger astronomy. Our search found no significant events, and consequently we place the first lab-based limits on combinations of ELF production and coupling parameters. △ Less

Submitted 20 May, 2025; v1 submitted 18 July, 2024; originally announced July 2024.

Comments: 23 pages, 12 figures

Journal ref: Phys. Rev. X 15, 031048 (2025)

Near-zero-field microwave-free magnetometry with nitrogen-vacancy centers in nanodiamonds

Authors: Omkar Dhungel, Mariusz Mrózek, Till Lenz, Viktor Ivády, Adam Gali, Arne Wickenbrock, Dmitry Budker, Wojciech Gawlik, Adam M. Wojciechowski

Abstract: We study the fluorescence of nanodiamond ensembles as a function of static external magnetic field and observe characteristic dip features close to the zero field with potential for magnetometry applications. We analyze the dependence of the features width and contrast of the feature on the size of the diamond (in the range 30 nm to 3 um) and on the strength of a bias magnetic field applied transv… ▽ More We study the fluorescence of nanodiamond ensembles as a function of static external magnetic field and observe characteristic dip features close to the zero field with potential for magnetometry applications. We analyze the dependence of the features width and contrast of the feature on the size of the diamond (in the range 30 nm to 3 um) and on the strength of a bias magnetic field applied transversely to the field being scanned. We also perform optically detected magnetic resonance (ODMR) measurements to quantify the strain splitting of the zero-field ODMR resonance across various nanodiamond sizes and compare it with the width and contrast measurements of the zero-field fluorescence features for both nanodiamonds and bulk samples. The observed properties provide compelling evidence of cross-relaxation effects in the NV system occurring close to zero magnetic fields. Finally, the potential of this technique for use in practical magnetometry is discussed. △ Less

Submitted 6 February, 2024; v1 submitted 16 January, 2024; originally announced January 2024.

Comments: 9 pages, 5 figures

Journal ref: Opt. Express, 32(12), 21936-21945 (2024)

Levitated ferromagnetic magnetometer with energy resolution well below $\hbar$

Authors: Felix Ahrens, Wei Ji, Dmitry Budker, Chris Timberlake, Hendrik Ulbricht, Andrea Vinante

Abstract: A quantum limit on the measurement of magnetic field has been recently pointed out, stating that the so-called Energy Resolution $E_\mathrm{R}$ is bounded to $E_\mathrm{R} \gtrsim \hbar$. This limit holds indeed true for the vast majority of existing quantum magnetometers, including SQUIDs, solid state spins and optically pumped atomic magnetometers. However, it can be surpassed by highly correlat… ▽ More A quantum limit on the measurement of magnetic field has been recently pointed out, stating that the so-called Energy Resolution $E_\mathrm{R}$ is bounded to $E_\mathrm{R} \gtrsim \hbar$. This limit holds indeed true for the vast majority of existing quantum magnetometers, including SQUIDs, solid state spins and optically pumped atomic magnetometers. However, it can be surpassed by highly correlated spin systems, as recently demonstrated with a single-domain spinor Bose-Einstein Condensate. Here we show that similar and potentially much better resolution can be achieved with a hard ferromagnet levitated above a superconductor at cryogenic temperature. We demonstrate $E_\mathrm{R}=\left( 0.064 \pm 0.010 \right) \, \hbar$ and anticipate that $E_\mathrm{R}<10^{-3} \, \hbar$ is within reach with near-future improvements. This finding opens the way to new applications in condensed matter, biophysics and fundamental science. In particular, we propose an experiment to search for axionlike dark matter and project a sensitivity orders of magnitude better than in previous searches. △ Less

Submitted 8 January, 2024; originally announced January 2024.

Comments: 26 pages, 8 figures (including Supplementary Information)

Electric Charging Effects on Insulating Surfaces in Cryogenic Liquids

Authors: Wolfgang Korsch, Mark Broering, Ashok Timsina, Kent K. H. Leung, Joshua Abney, Dmitry Budker, Bradley W. Filippone, Jiachen He, Suman Kandu, Mark McCrea, Murchhana Roy, Christopher Swank, Weijun Yao

Abstract: This paper presents a new technique to study the adsorption and desorption of ions and electrons on insulating surfaces in the presence of strong electric fields in cryoliquids. The experimental design consists of a compact cryostat coupled with a sensitive electro-optical Kerr device to monitor the stability of the electric fields. The behavior of nitrogen and helium ions on a poly(methyl methacr… ▽ More This paper presents a new technique to study the adsorption and desorption of ions and electrons on insulating surfaces in the presence of strong electric fields in cryoliquids. The experimental design consists of a compact cryostat coupled with a sensitive electro-optical Kerr device to monitor the stability of the electric fields. The behavior of nitrogen and helium ions on a poly(methyl methacrylate) (PMMA) surface was compared to a PMMA surface coated with a mixture of deuterated polystyrene and deuterated polybutadiene. Ion accumulation and removal on these surfaces were unambiguously observed. Within the precision of the data, both surfaces behave similarly for the physisorbed ions. The setup was also used to measure the (quasi-)static dielectric constant of PMMA at T = 70 K. The impact of the ion adsorption on the search for a neutron permanent electric dipole moment in a cryogenic environment, like the nEDM@SNS experiment, is discussed. △ Less

Submitted 31 December, 2023; originally announced January 2024.

Microwave-free wide-field magnetometry using nitrogen-vacancy centers

Authors: Joseph Shaji Rebeirro, Muhib Omar, Till Lenz, Omkar Dhungel, Peter Blümler, Dmitry Budker, Arne Wickenbrock

Abstract: A wide-field magnetometer utilizing nitrogen-vacancy (NV) centers in diamond that does not require microwaves is demonstrated. It is designed for applications where microwaves need to be avoided, such as magnetic imaging of biological or conductive samples. The system exploits a magnetically sensitive feature of NV centers near the ground state level anticrossing (GSLAC). An applied test field fro… ▽ More A wide-field magnetometer utilizing nitrogen-vacancy (NV) centers in diamond that does not require microwaves is demonstrated. It is designed for applications where microwaves need to be avoided, such as magnetic imaging of biological or conductive samples. The system exploits a magnetically sensitive feature of NV centers near the ground state level anticrossing (GSLAC). An applied test field from a wire was mapped over an imaging area of $\approx 500 \times 470\,μ\text{m}^2$. Analysis of the GSLAC lineshape allows to extract vector information of the applied field. The device allows micrometer-scale magnetic imaging at a spatial resolution dominated by the thickness of the NV layer (here $50\,μ\text{m}$). For a pixel size of $4\,μ\text{m} \times 3.8\,μ\text{m}$ the estimated sensitivity is $4.8\,μ\text{T}/\sqrt{\text{Hz}}$. Two modalities for visualizing the magnetic fields, static and temporal, are presented along with a discussion of technical limitations and future extensions of the method. △ Less

Submitted 25 October, 2023; originally announced October 2023.

Comments: 8 pages,6 figures

Constraining Ultralight Dark Matter through an Accelerated Resonant Search

Authors: Zitong Xu, Xiaolin Ma, Kai Wei, Yuxuan He, Xing Heng, Xiaofei Huang, Tengyu Ai, Jian Liao, Wei Ji, Jia Liu, Xiao-Ping Wang, Dmitry Budker

Abstract: Experiments aimed at detecting ultralight dark matter typically rely on resonant effects, which are sensitive to the dark matter mass that matches the resonance frequency. In this study, we investigate the nucleon couplings of ultralight axion dark matter using a magnetometer operating in a nuclear magnetic resonance (NMR) mode. Our approach involves the use of a $^{21}$Ne spin-based sensor, which… ▽ More Experiments aimed at detecting ultralight dark matter typically rely on resonant effects, which are sensitive to the dark matter mass that matches the resonance frequency. In this study, we investigate the nucleon couplings of ultralight axion dark matter using a magnetometer operating in a nuclear magnetic resonance (NMR) mode. Our approach involves the use of a $^{21}$Ne spin-based sensor, which features the lowest nuclear magnetic moment among noble-gas spins. This configuration allows us to achieve an ultrahigh sensitivity of 0.73 fT/Hz$^{1/2}$ at around 5 Hz, corresponding to energy resolution of approximately 1.5$\times 10^{-23}\,\rm{eV/Hz^{1/2}}$. Our analysis reveals that under certain conditions it is beneficial to scan the frequency with steps significantly larger than the resonance width. The analytical results are in agreement with experimental data and the scan strategy is potentially applicable to other resonant searches. Further, our study establishes stringent constraints on axion-like particles (ALP) in the 4.5--15.5 Hz Compton-frequency range coupling to neutrons and protons, improving on prior work by several-fold. Within a band around 4.6--6.6 Hz and around 7.5 Hz, our laboratory findings surpass astrophysical limits derived from neutron-star cooling. Hence, we demonstrate an accelerated resonance search for ultralight dark matter, achieving an approximately 30-fold increase in scanning step while maintaining competitive sensitivity. △ Less

Submitted 11 July, 2024; v1 submitted 28 September, 2023; originally announced September 2023.

Comments: 13 pages, 11 figures, accepted by Communications Physics

Journal ref: Commun.Phys. 7 (2024) 1, 226

Remote Detection Optical Magnetometry

Authors: Alexander M. Akulshin, Dmitry Budker, Felipe Pedreros Bustos, Tong Dang, Emmanuel Klinger, Simon M. Rochester, Arne Wickenbrock, Rui Zhang

Abstract: Sensitive magnetometers have been applied in a wide range of research fields, including geophysical exploration, bio-magnetic field detection, ultralow-field nuclear magnetic resonance, etc. Commonly, magnetometers are directly placed at the position where the magnetic field is to be measured. However, in some situations, for example in near space or harsh environments, near nuclear reactors or pa… ▽ More Sensitive magnetometers have been applied in a wide range of research fields, including geophysical exploration, bio-magnetic field detection, ultralow-field nuclear magnetic resonance, etc. Commonly, magnetometers are directly placed at the position where the magnetic field is to be measured. However, in some situations, for example in near space or harsh environments, near nuclear reactors or particle accelerators, it is hard to place a magnetometer directly there. If the magnetic field can be detected remotely, i.e., via stand-off detection, this problem can be solved. As optical magnetometers are based on optical readout, they are naturally promising for stand-off detection. We review various approaches to optical stand-off magnetometry proposed and developed over the years, culminating in recent results on measuring magnetic fields in the mesosphere using laser guide stars, magnetometry with mirrorless-lasing readout, and proposals for satellite-assisted interrogation of atmospheric sodium. △ Less

Submitted 23 October, 2024; v1 submitted 28 September, 2023; originally announced September 2023.