Title:Revisiting MnSe : a Magnetic Semiconductor with Spin-Phonon coupling

Abstract:Spin-phonon interactions in 2D magnetic materials are crucial in advancing next-generation spintronic devices. Therefore, identifying new materials with significant spin-phonon interactions is of great importance. In this context, MnSe, previously recognized as an exemplary non-layered p-type semiconductor emerges in this study as an intriguing material with notable spin-phonon characteristics. The complex magnetism in pristine MnSe, primarily dominated by antiferromagnetism with a weak ferromagnetic component, gives rise to both spontaneous and conventional exchange bias effects at low temperatures. In an effort to understand this intriguing magnetism, we conducted a detailed Raman spectroscopy study, which reveals unconventional deviations from the usual phonon anharmonicity around Neel temperature (170 K), in the self-energies of the P1, P2, and P3 modes. Notably, the P1 mode is most sensitive to spin-phonon coupling, while the P2 mode is particularly responsive to the structural phase transition at 250 K. Therefore, these findings provide comprehensive insights into the phase transitions of pristine MnSe, particularly highlighting the previously unobserved interplay between its magnetic behavior and phonon dynamics.