Showing 1–50 of 123 results for author: Babbush, R

Observation of disorder-induced superfluidity

Authors: Nicole Ticea, Elias Portoles, Eliott Rosenberg, Alexander Schuckert, Aaron Szasz, Bryce Kobrin, Nicolas Pomata, Pranjal Praneel, Connie Miao, Shashwat Kumar, Ella Crane, Ilya Drozdov, Yuri Lensky, Sofia Gonzalez-Garcia, Thomas Kiely, Dmitry Abanin, Amira Abbas, Rajeev Acharya, Laleh Aghababaie Beni, Georg Aigeldinger, Ross Alcaraz, Sayra Alcaraz, Markus Ansmann, Frank Arute, Kunal Arya , et al. (277 additional authors not shown)

Abstract: The emergence of states with long-range correlations in a disordered landscape is rare, as disorder typically suppresses the particle mobility required for long-range coherence. But when more than two energy levels are available per site, disorder can induce resonances that locally enhance mobility. Here we explore phases arising from the interplay between disorder, kinetic energy, and interaction… ▽ More The emergence of states with long-range correlations in a disordered landscape is rare, as disorder typically suppresses the particle mobility required for long-range coherence. But when more than two energy levels are available per site, disorder can induce resonances that locally enhance mobility. Here we explore phases arising from the interplay between disorder, kinetic energy, and interactions on a superconducting processor with qutrit readout and control. Compressibility measurements distinguish an incompressible Mott insulator from surrounding compressible phases and reveal signatures of glassiness, reflected in non-ergodic behavior. Spatially-resolved two-point correlator measurements identify regions of the phase diagram with a non-vanishing condensate fraction. We also visualize the spectrum by measuring the dynamical structure factor. A linearly-dispersing phonon mode materializes in the superfluid, appearing even when disorder is introduced to the clean Mott insulator. Our results provide strong experimental evidence for disorder-induced superfluidity. △ Less

Submitted 24 December, 2025; originally announced December 2025.

Magic state cultivation on a superconducting quantum processor

Authors: Emma Rosenfeld, Craig Gidney, Gabrielle Roberts, Alexis Morvan, Nathan Lacroix, Dvir Kafri, Jeffrey Marshall, Ming Li, Volodymyr Sivak, Dmitry Abanin, Amira Abbas, Rajeev Acharya, Laleh Aghababaie Beni, Georg Aigeldinger, Ross Alcaraz, Sayra Alcaraz, Trond I. Andersen, Markus Ansmann, Frank Arute, Kunal Arya, Walt Askew, Nikita Astrakhantsev, Juan Atalaya, Ryan Babbush, Brian Ballard , et al. (270 additional authors not shown)

Abstract: Fault-tolerant quantum computing requires a universal gate set, but the necessary non-Clifford gates represent a significant resource cost for most quantum error correction architectures. Magic state cultivation offers an efficient alternative to resource-intensive distillation protocols; however, testing the proposal's assumptions represents a challenging departure from quantum memory experiments… ▽ More Fault-tolerant quantum computing requires a universal gate set, but the necessary non-Clifford gates represent a significant resource cost for most quantum error correction architectures. Magic state cultivation offers an efficient alternative to resource-intensive distillation protocols; however, testing the proposal's assumptions represents a challenging departure from quantum memory experiments. We present an experimental study of magic state cultivation on a superconducting quantum processor. We implement cultivation, including code-switching into a surface code, and develop a fault-tolerant measurement protocol to bound the magic state fidelity. Cultivation reduces the error by a factor of 40, with a state fidelity of 0.9999(1) (retaining 8% of attempts). Our results experimentally establish magic state cultivation as a viable solution to one of quantum computing's most significant challenges. △ Less

Submitted 15 December, 2025; originally announced December 2025.

Quantum-Classical Separation in Bounded-Resource Tasks Arising from Measurement Contextuality

Authors: Shashwat Kumar, Eliott Rosenberg, Alejandro Grajales Dau, Rodrigo Cortinas, Dmitri Maslov, Richard Oliver, Adam Zalcman, Matthew Neeley, Alice Pagano, Aaron Szasz, Ilya Drozdov, Zlatko Minev, Craig Gidney, Noureldin Yosri, Stijn J. de Graaf, Aniket Maiti, Dmitry Abanin, Rajeev Acharya, Laleh Aghababaie Beni, Georg Aigeldinger, Ross Alcaraz, Sayra Alcaraz, Trond I. Andersen, Markus Ansmann, Frank Arute , et al. (258 additional authors not shown)

Abstract: The prevailing view is that quantum phenomena can be harnessed to tackle certain problems beyond the reach of classical approaches. Quantifying this capability as a quantum-classical separation and demonstrating it on current quantum processors has remained elusive. Using a superconducting qubit processor, we show that quantum contextuality enables certain tasks to be performed with success probab… ▽ More The prevailing view is that quantum phenomena can be harnessed to tackle certain problems beyond the reach of classical approaches. Quantifying this capability as a quantum-classical separation and demonstrating it on current quantum processors has remained elusive. Using a superconducting qubit processor, we show that quantum contextuality enables certain tasks to be performed with success probabilities beyond classical limits. With a few qubits, we illustrate quantum contextuality with the magic square game, as well as quantify it through a Kochen--Specker--Bell inequality violation. To examine many-body contextuality, we implement the N-player GHZ game and separately solve a 2D hidden linear function problem, exceeding classical success rate in both. Our work proposes novel ways to benchmark quantum processors using contextuality-based algorithms. △ Less

Submitted 1 December, 2025; originally announced December 2025.

The Grand Challenge of Quantum Applications

Authors: Ryan Babbush, Robbie King, Sergio Boixo, William Huggins, Tanuj Khattar, Guang Hao Low, Jarrod R. McClean, Thomas O'Brien, Nicholas C. Rubin

Abstract: This perspective outlines promising pathways and critical obstacles on the road to developing useful quantum computing applications, drawing on insights from the Google Quantum AI team. We propose a five-stage framework for this process, spanning from theoretical explorations of quantum advantage to the practicalities of compilation and resource estimation. For each stage, we discuss key trends, m… ▽ More This perspective outlines promising pathways and critical obstacles on the road to developing useful quantum computing applications, drawing on insights from the Google Quantum AI team. We propose a five-stage framework for this process, spanning from theoretical explorations of quantum advantage to the practicalities of compilation and resource estimation. For each stage, we discuss key trends, milestones, and inherent scientific and sociological impediments. We argue that two central stages -- identifying concrete problem instances expected to exhibit quantum advantage, and connecting such problems to real-world use cases -- represent essential and currently under-resourced challenges. Throughout, we touch upon related topics, including the promise of generative artificial intelligence for aspects of this research, criteria for compelling demonstrations of quantum advantage, and the future of compilation as we enter the era of early fault-tolerant quantum computing. △ Less

Submitted 4 December, 2025; v1 submitted 12 November, 2025; originally announced November 2025.

The FLuid Allocation of Surface code Qubits (FLASQ) cost model for early fault-tolerant quantum algorithms

Authors: William J. Huggins, Tanuj Khattar, Amanda Xu, Matthew Harrigan, Christopher Kang, Guang Hao Low, Austin Fowler, Nicholas C. Rubin, Ryan Babbush

Abstract: Holistic resource estimates are essential for guiding the development of fault-tolerant quantum algorithms and the computers they will run on. This is particularly true when we focus on highly-constrained early fault-tolerant devices. Many attempts to optimize algorithms for early fault-tolerance focus on simple metrics, such as the circuit depth or T-count. These metrics fail to capture critical… ▽ More Holistic resource estimates are essential for guiding the development of fault-tolerant quantum algorithms and the computers they will run on. This is particularly true when we focus on highly-constrained early fault-tolerant devices. Many attempts to optimize algorithms for early fault-tolerance focus on simple metrics, such as the circuit depth or T-count. These metrics fail to capture critical overheads, such as the spacetime cost of Clifford operations and routing, or miss they key optimizations. We propose the FLuid Allocation of Surface code Qubits (FLASQ) cost model, tailored for architectures that use a two-dimensional lattice of qubits to implement the two-dimensional surface code. FLASQ abstracts away the complexity of routing by assuming that ancilla space and time can be fluidly rearranged, allowing for the tractable estimation of spacetime volume while still capturing important details neglected by simpler approaches. At the same time, it enforces constraints imposed by the circuit's measurement depth and the processor's reaction time. We apply FLASQ to analyze the cost of a standard two-dimensional lattice model simulation, finding that modern advances (such as magic state cultivation and the combination of quantum error correction and mitigation) reduce both the time and space required for this task by an order of magnitude compared with previous estimates. We also analyze the Hamming weight phasing approach to synthesizing parallel rotations, revealing that despite its low T-count, the overhead from imposing a 2D layout and from its use of additional ancilla qubits will make it challenging to benefit from in early fault-tolerance. We hope that the FLASQ cost model will help to better align early fault-tolerant algorithmic design with actual hardware realization costs without demanding excessive knowledge of quantum error correction from quantum algorithmists. △ Less

Submitted 11 November, 2025; originally announced November 2025.

Reinforcement Learning Control of Quantum Error Correction

Authors: Volodymyr Sivak, Alexis Morvan, Michael Broughton, Matthew Neeley, Alec Eickbusch, Dmitry Abanin, Amira Abbas, Rajeev Acharya, Laleh Aghababaie Beni, Georg Aigeldinger, Ross Alcaraz, Sayra Alcaraz, Trond I. Andersen, Markus Ansmann, Frank Arute, Kunal Arya, Walt Askew, Nikita Astrakhantsev, Juan Atalaya, Brian Ballard, Joseph C. Bardin, Hector Bates, Andreas Bengtsson, Majid Bigdeli Karimi, Alexander Bilmes , et al. (269 additional authors not shown)

Abstract: The promise of fault-tolerant quantum computing is challenged by environmental drift that relentlessly degrades the quality of quantum operations. The contemporary solution, halting the entire quantum computation for recalibration, is unsustainable for the long runtimes of the future algorithms. We address this challenge by unifying calibration with computation, granting the quantum error correcti… ▽ More The promise of fault-tolerant quantum computing is challenged by environmental drift that relentlessly degrades the quality of quantum operations. The contemporary solution, halting the entire quantum computation for recalibration, is unsustainable for the long runtimes of the future algorithms. We address this challenge by unifying calibration with computation, granting the quantum error correction process a dual role: its error detection events are not only used to correct the logical quantum state, but are also repurposed as a learning signal, teaching a reinforcement learning agent to continuously steer the physical control parameters and stabilize the quantum system during the computation. We experimentally demonstrate this framework on a superconducting processor, improving the logical error rate stability of the surface code 3.5-fold against injected drift and pushing the performance beyond what is achievable with state-of-the-art traditional calibration and human-expert tuning. Simulations of surface codes up to distance-15 confirm the scalability of our method, revealing an optimization speed that is independent of the system size. This work thus enables a new paradigm: a quantum computer that learns to self-improve directly from its errors and never stops computing. △ Less

Submitted 4 December, 2025; v1 submitted 11 November, 2025; originally announced November 2025.

A simplified version of the quantum OTOC$^{(2)}$ problem

Authors: Robbie King, Robin Kothari, Ryan Babbush, Sergio Boixo, Kostyantyn Kechedzhi, Thomas E. O'Brien, Vadim Smelyanskiy

Abstract: This note presents a simplified version of the OTOC$^{(2)}$ problem that was recently experimentally implemented by Google Quantum AI and collaborators. We present a formulation of the problem for growing input size and hope this spurs further theoretical work on the problem. This note presents a simplified version of the OTOC$^{(2)}$ problem that was recently experimentally implemented by Google Quantum AI and collaborators. We present a formulation of the problem for growing input size and hope this spurs further theoretical work on the problem. △ Less

Submitted 22 October, 2025; originally announced October 2025.

Comments: 2 pages

Quantum computation of molecular geometry via many-body nuclear spin echoes

Authors: C. Zhang, R. G. Cortiñas, A. H. Karamlou, N. Noll, J. Provazza, J. Bausch, S. Shirobokov, A. White, M. Claassen, S. H. Kang, A. W. Senior, N. Tomašev, J. Gross, K. Lee, T. Schuster, W. J. Huggins, H. Celik, A. Greene, B. Kozlovskii, F. J. H. Heras, A. Bengtsson, A. Grajales Dau, I. Drozdov, B. Ying, W. Livingstone , et al. (298 additional authors not shown)

Abstract: Quantum-information-inspired experiments in nuclear magnetic resonance spectroscopy may yield a pathway towards determining molecular structure and properties that are otherwise challenging to learn. We measure out-of-time-ordered correlators (OTOCs) [1-4] on two organic molecules suspended in a nematic liquid crystal, and investigate the utility of this data in performing structural learning task… ▽ More Quantum-information-inspired experiments in nuclear magnetic resonance spectroscopy may yield a pathway towards determining molecular structure and properties that are otherwise challenging to learn. We measure out-of-time-ordered correlators (OTOCs) [1-4] on two organic molecules suspended in a nematic liquid crystal, and investigate the utility of this data in performing structural learning tasks. We use OTOC measurements to augment molecular dynamics models, and to correct for known approximations in the underlying force fields. We demonstrate the utility of OTOCs in these models by estimating the mean ortho-meta H-H distance of toluene and the mean dihedral angle of 3',5'-dimethylbiphenyl, achieving similar accuracy and precision to independent spectroscopic measurements of both quantities. To ameliorate the apparent exponential classical cost of interpreting the above OTOC data, we simulate the molecular OTOCs on a Willow superconducting quantum processor, using AlphaEvolve-optimized [5] quantum circuits and arbitrary-angle fermionic simulation gates. We implement novel zero-noise extrapolation techniques based on the Pauli pathing model of operator dynamics [6], to repeat the learning experiments with root-mean-square error $0.05$ over all circuits used. Our work highlights a computational protocol to interpret many-body echoes from nuclear magnetic systems using low resource quantum computation. △ Less

Submitted 22 October, 2025; originally announced October 2025.

Verifiable Quantum Advantage via Optimized DQI Circuits

Authors: Tanuj Khattar, Noah Shutty, Craig Gidney, Adam Zalcman, Noureldin Yosri, Dmitri Maslov, Ryan Babbush, Stephen P. Jordan

Abstract: Decoded Quantum Interferometry (DQI) provides a framework for superpolynomial quantum speedups by reducing certain optimization problems to reversible decoding tasks. We apply DQI to the Optimal Polynomial Intersection (OPI) problem, whose dual code is Reed-Solomon (RS). We establish that DQI for OPI is the first known candidate for verifiable quantum advantage with optimal asymptotic speedup: sol… ▽ More Decoded Quantum Interferometry (DQI) provides a framework for superpolynomial quantum speedups by reducing certain optimization problems to reversible decoding tasks. We apply DQI to the Optimal Polynomial Intersection (OPI) problem, whose dual code is Reed-Solomon (RS). We establish that DQI for OPI is the first known candidate for verifiable quantum advantage with optimal asymptotic speedup: solving instances with classical hardness $O(2^N)$ requires only $\widetilde{O}(N)$ quantum gates, matching the theoretical lower bound. Realizing this speedup requires highly efficient reversible RS decoders. We introduce novel quantum circuits for the Extended Euclidean Algorithm, the decoder's bottleneck. Our techniques, including a new representation for implicit Bézout coefficient access, and optimized in-place architectures, reduce the leading-order space complexity to the theoretical minimum of $2nb$ qubits while significantly lowering gate counts. These improvements are broadly applicable, including to Shor's algorithm for the discrete logarithm. We analyze OPI over binary extension fields $GF(2^b)$, assess hardness against new classical attacks, and identify resilient instances. Our resource estimates show that classically intractable OPI instances (requiring $>10^{23}$ classical trials) can be solved with approximately 5.72 million Toffoli gates. This is substantially less than the count required for breaking RSA-2048, positioning DQI as a compelling candidate for practical, verifiable quantum advantage. △ Less

Submitted 12 October, 2025; originally announced October 2025.

Comments: 52 pages

Quantum simulation of chemistry via quantum fast multipole method

Authors: Dominic W. Berry, Kianna Wan, Andrew D. Baczewski, Elliot C. Eklund, Arkin Tikku, Ryan Babbush

Abstract: Here we describe an approach for simulating quantum chemistry on quantum computers with significantly lower asymptotic complexity than prior work. The approach uses a real-space first-quantised representation of the molecular Hamiltonian which we propagate using high-order product formulae. Essential for this low complexity is the use of a technique similar to the fast multipole method for computi… ▽ More Here we describe an approach for simulating quantum chemistry on quantum computers with significantly lower asymptotic complexity than prior work. The approach uses a real-space first-quantised representation of the molecular Hamiltonian which we propagate using high-order product formulae. Essential for this low complexity is the use of a technique similar to the fast multipole method for computing the Coulomb operator with $\widetilde{\cal O}(η)$ complexity for a simulation with $η$ particles. We show how to modify this algorithm so that it can be implemented on a quantum computer. We ultimately demonstrate an approach with $t(η^{4/3}N^{1/3} + η^{1/3} N^{2/3} ) (ηNt/ε)^{o(1)}$ gate complexity, where $N$ is the number of grid points, $ε$ is target precision, and $t$ is the duration of time evolution. This is roughly a speedup by ${\cal O}(η)$ over most prior algorithms. We provide lower complexity than all prior work for $N<η^6$ (the regime of practical interest), with only first-quantised interaction-picture simulations providing better performance for $N>η^6$. As with the classical fast multipole method, large numbers $η\gtrsim 10^3$ would be needed to realise this advantage. △ Less

Submitted 8 October, 2025; originally announced October 2025.

Comments: 23 pages, 3 figures

Generative quantum advantage for classical and quantum problems

Authors: Hsin-Yuan Huang, Michael Broughton, Norhan Eassa, Hartmut Neven, Ryan Babbush, Jarrod R. McClean

Abstract: Recent breakthroughs in generative machine learning, powered by massive computational resources, have demonstrated unprecedented human-like capabilities. While beyond-classical quantum experiments can generate samples from classically intractable distributions, their complexity has thwarted all efforts toward efficient learning. This challenge has hindered demonstrations of generative quantum adva… ▽ More Recent breakthroughs in generative machine learning, powered by massive computational resources, have demonstrated unprecedented human-like capabilities. While beyond-classical quantum experiments can generate samples from classically intractable distributions, their complexity has thwarted all efforts toward efficient learning. This challenge has hindered demonstrations of generative quantum advantage: the ability of quantum computers to learn and generate desired outputs substantially better than classical computers. We resolve this challenge by introducing families of generative quantum models that are hard to simulate classically, are efficiently trainable, exhibit no barren plateaus or proliferating local minima, and can learn to generate distributions beyond the reach of classical computers. Using a $68$-qubit superconducting quantum processor, we demonstrate these capabilities in two scenarios: learning classically intractable probability distributions and learning quantum circuits for accelerated physical simulation. Our results establish that both learning and sampling can be performed efficiently in the beyond-classical regime, opening new possibilities for quantum-enhanced generative models with provable advantage. △ Less

Submitted 10 September, 2025; originally announced September 2025.

Quantum algorithm for linear matrix equations

Authors: Rolando D. Somma, Guang Hao Low, Dominic W. Berry, Ryan Babbush

Abstract: We describe an efficient quantum algorithm for solving the linear matrix equation AX+XB=C, where A, B, and C are given complex matrices and X is unknown. This is known as the Sylvester equation, a fundamental equation with applications in control theory and physics. Our approach constructs the solution matrix X/x in a block-encoding, where x is a rescaling factor needed for normalization. This all… ▽ More We describe an efficient quantum algorithm for solving the linear matrix equation AX+XB=C, where A, B, and C are given complex matrices and X is unknown. This is known as the Sylvester equation, a fundamental equation with applications in control theory and physics. Our approach constructs the solution matrix X/x in a block-encoding, where x is a rescaling factor needed for normalization. This allows us to obtain certain properties of the entries of X exponentially faster than would be possible from preparing X as a quantum state. The query and gate complexities of the quantum circuit that implements this block-encoding are almost linear in a condition number that depends on A and B, and depend logarithmically in the dimension and inverse error. We show how our quantum circuits can solve BQP-complete problems efficiently, discuss potential applications and extensions of our approach, its connection to Riccati equation, and comment on open problems. △ Less

Submitted 21 August, 2025; v1 submitted 4 August, 2025; originally announced August 2025.

Comments: 24 pages, 1 figure

Constructive interference at the edge of quantum ergodic dynamics

Authors: Dmitry A. Abanin, Rajeev Acharya, Laleh Aghababaie-Beni, Georg Aigeldinger, Ashok Ajoy, Ross Alcaraz, Igor Aleiner, Trond I. Andersen, Markus Ansmann, Frank Arute, Kunal Arya, Abraham Asfaw, Nikita Astrakhantsev, Juan Atalaya, Ryan Babbush, Dave Bacon, Brian Ballard, Joseph C. Bardin, Christian Bengs, Andreas Bengtsson, Alexander Bilmes, Sergio Boixo, Gina Bortoli, Alexandre Bourassa, Jenna Bovaird , et al. (240 additional authors not shown)

Abstract: Quantum observables in the form of few-point correlators are the key to characterizing the dynamics of quantum many-body systems. In dynamics with fast entanglement generation, quantum observables generally become insensitive to the details of the underlying dynamics at long times due to the effects of scrambling. In experimental systems, repeated time-reversal protocols have been successfully imp… ▽ More Quantum observables in the form of few-point correlators are the key to characterizing the dynamics of quantum many-body systems. In dynamics with fast entanglement generation, quantum observables generally become insensitive to the details of the underlying dynamics at long times due to the effects of scrambling. In experimental systems, repeated time-reversal protocols have been successfully implemented to restore sensitivities of quantum observables. Using a 103-qubit superconducting quantum processor, we characterize ergodic dynamics using the second-order out-of-time-order correlators, OTOC$^{(2)}$. In contrast to dynamics without time reversal, OTOC$^{(2)}$ are observed to remain sensitive to the underlying dynamics at long time scales. Furthermore, by inserting Pauli operators during quantum evolution and randomizing the phases of Pauli strings in the Heisenberg picture, we observe substantial changes in OTOC$^{(2)}$ values. This indicates that OTOC$^{(2)}$ is dominated by constructive interference between Pauli strings that form large loops in configuration space. The observed interference mechanism endows OTOC$^{(2)}$ with a high degree of classical simulation complexity, which culminates in a set of large-scale OTOC$^{(2)}$ measurements exceeding the simulation capacity of known classical algorithms. Further supported by an example of Hamiltonian learning through OTOC$^{(2)}$, our results indicate a viable path to practical quantum advantage. △ Less

Submitted 11 June, 2025; originally announced June 2025.

Comments: See following link: https://zenodo.org/records/15640503, which includes: Circuits used in Fig. 3d, Fig. 3e, Fig. 4a, Fig. 4b of the main text. In addition, OTOC (C^(2)) circuits and data with 95, 40 and 31 qubits are also provided. For system sizes <= 40 qubits, we include exact simulation results. For system sizes > 40, we include experimental data

Quantum simulation with sum-of-squares spectral amplification

Authors: Robbie King, Guang Hao Low, Ryan Babbush, Rolando D. Somma, Nicholas C. Rubin

Abstract: We present sum-of-squares spectral amplification (SOSSA), a framework for improving quantum simulation relevant to low-energy problems. We show how SOSSA can be applied to problems like energy and phase estimation and provide fast quantum algorithms for these problems that significantly improve over prior art. To illustrate the power of SOSSA in applications, we consider the Sachdev-Ye-Kitaev mode… ▽ More We present sum-of-squares spectral amplification (SOSSA), a framework for improving quantum simulation relevant to low-energy problems. We show how SOSSA can be applied to problems like energy and phase estimation and provide fast quantum algorithms for these problems that significantly improve over prior art. To illustrate the power of SOSSA in applications, we consider the Sachdev-Ye-Kitaev model, a representative strongly correlated system, and demonstrate asymptotic speedups over generic simulation methods by a factor of the square root of the system size. Our results reinforce those observed in [G.H. Low \textit{et al.}, arXiv:2502.15882 (2025)], where SOSSA was used to achieve state-of-the-art gate costs for phase estimation of real-world quantum chemistry systems. △ Less

Submitted 2 May, 2025; originally announced May 2025.

Fast quantum simulation of electronic structure by spectrum amplification

Authors: Guang Hao Low, Robbie King, Dominic W. Berry, Qiushi Han, A. Eugene DePrince III, Alec White, Ryan Babbush, Rolando D. Somma, Nicholas C. Rubin

Abstract: The most advanced techniques using fault-tolerant quantum computers to estimate the ground-state energy of a chemical Hamiltonian involve compression of the Coulomb operator through tensor factorizations, enabling efficient block-encodings of the Hamiltonian. A natural challenge of these methods is the degree to which block-encoding costs can be reduced. We address this challenge through the techn… ▽ More The most advanced techniques using fault-tolerant quantum computers to estimate the ground-state energy of a chemical Hamiltonian involve compression of the Coulomb operator through tensor factorizations, enabling efficient block-encodings of the Hamiltonian. A natural challenge of these methods is the degree to which block-encoding costs can be reduced. We address this challenge through the technique of spectrum amplification, which magnifies the spectrum of the low-energy states of Hamiltonians that can be expressed as sums of squares. Spectrum amplification enables estimating ground-state energies with significantly improved cost scaling in the block encoding normalization factor $Λ$ to just $\sqrt{2ΛE_{\text{gap}}}$, where $E_{\text{gap}} \ll Λ$ is the lowest energy of the sum-of-squares Hamiltonian. To achieve this, we show that sum-of-squares representations of the electronic structure Hamiltonian are efficiently computable by a family of classical simulation techniques that approximate the ground-state energy from below. In order to further optimize, we also develop a novel factorization that provides a trade-off between the two leading Coulomb integral factorization schemes -- namely, double factorization and tensor hypercontraction -- that when combined with spectrum amplification yields a factor of 4 to 195 speedup over the state of the art in ground-state energy estimation for models of Iron-Sulfur complexes and a CO$_{2}$-fixation catalyst. △ Less

Submitted 21 February, 2025; originally announced February 2025.

Journal ref: Physical Review X 15, 041016 (2025)

Demonstrating dynamic surface codes

Authors: Alec Eickbusch, Matt McEwen, Volodymyr Sivak, Alexandre Bourassa, Juan Atalaya, Jahan Claes, Dvir Kafri, Craig Gidney, Christopher W. Warren, Jonathan Gross, Alex Opremcak, Nicholas Zobrist, Kevin C. Miao, Gabrielle Roberts, Kevin J. Satzinger, Andreas Bengtsson, Matthew Neeley, William P. Livingston, Alex Greene, Rajeev Acharya, Laleh Aghababaie Beni, Georg Aigeldinger, Ross Alcaraz, Trond I. Andersen, Markus Ansmann , et al. (182 additional authors not shown)

Abstract: A remarkable characteristic of quantum computing is the potential for reliable computation despite faulty qubits. This can be achieved through quantum error correction, which is typically implemented by repeatedly applying static syndrome checks, permitting correction of logical information. Recently, the development of time-dynamic approaches to error correction has uncovered new codes and new co… ▽ More A remarkable characteristic of quantum computing is the potential for reliable computation despite faulty qubits. This can be achieved through quantum error correction, which is typically implemented by repeatedly applying static syndrome checks, permitting correction of logical information. Recently, the development of time-dynamic approaches to error correction has uncovered new codes and new code implementations. In this work, we experimentally demonstrate three time-dynamic implementations of the surface code, each offering a unique solution to hardware design challenges and introducing flexibility in surface code realization. First, we embed the surface code on a hexagonal lattice, reducing the necessary couplings per qubit from four to three. Second, we walk a surface code, swapping the role of data and measure qubits each round, achieving error correction with built-in removal of accumulated non-computational errors. Finally, we realize the surface code using iSWAP gates instead of the traditional CNOT, extending the set of viable gates for error correction without additional overhead. We measure the error suppression factor when scaling from distance-3 to distance-5 codes of $Λ_{35,\text{hex}} = 2.15(2)$, $Λ_{35,\text{walk}} = 1.69(6)$, and $Λ_{35,\text{iSWAP}} = 1.56(2)$, achieving state-of-the-art error suppression for each. With detailed error budgeting, we explore their performance trade-offs and implications for hardware design. This work demonstrates that dynamic circuit approaches satisfy the demands for fault-tolerance and opens new alternative avenues for scalable hardware design. △ Less

Submitted 19 June, 2025; v1 submitted 18 December, 2024; originally announced December 2024.

Comments: 11 pages, 5 figures, Supplementary Information

Scaling and logic in the color code on a superconducting quantum processor

Authors: Nathan Lacroix, Alexandre Bourassa, Francisco J. H. Heras, Lei M. Zhang, Johannes Bausch, Andrew W. Senior, Thomas Edlich, Noah Shutty, Volodymyr Sivak, Andreas Bengtsson, Matt McEwen, Oscar Higgott, Dvir Kafri, Jahan Claes, Alexis Morvan, Zijun Chen, Adam Zalcman, Sid Madhuk, Rajeev Acharya, Laleh Aghababaie Beni, Georg Aigeldinger, Ross Alcaraz, Trond I. Andersen, Markus Ansmann, Frank Arute , et al. (190 additional authors not shown)

Abstract: Quantum error correction is essential for bridging the gap between the error rates of physical devices and the extremely low logical error rates required for quantum algorithms. Recent error-correction demonstrations on superconducting processors have focused primarily on the surface code, which offers a high error threshold but poses limitations for logical operations. In contrast, the color code… ▽ More Quantum error correction is essential for bridging the gap between the error rates of physical devices and the extremely low logical error rates required for quantum algorithms. Recent error-correction demonstrations on superconducting processors have focused primarily on the surface code, which offers a high error threshold but poses limitations for logical operations. In contrast, the color code enables much more efficient logic, although it requires more complex stabilizer measurements and decoding techniques. Measuring these stabilizers in planar architectures such as superconducting qubits is challenging, and so far, realizations of color codes have not addressed performance scaling with code size on any platform. Here, we present a comprehensive demonstration of the color code on a superconducting processor, achieving logical error suppression and performing logical operations. Scaling the code distance from three to five suppresses logical errors by a factor of $Λ_{3/5}$ = 1.56(4). Simulations indicate this performance is below the threshold of the color code, and furthermore that the color code may be more efficient than the surface code with modest device improvements. Using logical randomized benchmarking, we find that transversal Clifford gates add an error of only 0.0027(3), which is substantially less than the error of an idling error correction cycle. We inject magic states, a key resource for universal computation, achieving fidelities exceeding 99% with post-selection (retaining about 75% of the data). Finally, we successfully teleport logical states between distance-three color codes using lattice surgery, with teleported state fidelities between 86.5(1)% and 90.7(1)%. This work establishes the color code as a compelling research direction to realize fault-tolerant quantum computation on superconducting processors in the near future. △ Less

Submitted 18 December, 2024; originally announced December 2024.

Observation of disorder-free localization using a (2+1)D lattice gauge theory on a quantum processor

Authors: Gaurav Gyawali, Shashwat Kumar, Yuri D. Lensky, Eliott Rosenberg, Aaron Szasz, Tyler Cochran, Renyi Chen, Amir H. Karamlou, Kostyantyn Kechedzhi, Julia Berndtsson, Tom Westerhout, Abraham Asfaw, Dmitry Abanin, Rajeev Acharya, Laleh Aghababaie Beni, Trond I. Andersen, Markus Ansmann, Frank Arute, Kunal Arya, Nikita Astrakhantsev, Juan Atalaya, Ryan Babbush, Brian Ballard, Joseph C. Bardin, Andreas Bengtsson , et al. (197 additional authors not shown)

Abstract: Disorder-induced phenomena in quantum many-body systems pose significant challenges for analytical methods and numerical simulations at relevant time and system scales. To reduce the cost of disorder-sampling, we investigate quantum circuits initialized in states tunable to superpositions over all disorder configurations. In a translationally-invariant lattice gauge theory (LGT), these states can… ▽ More Disorder-induced phenomena in quantum many-body systems pose significant challenges for analytical methods and numerical simulations at relevant time and system scales. To reduce the cost of disorder-sampling, we investigate quantum circuits initialized in states tunable to superpositions over all disorder configurations. In a translationally-invariant lattice gauge theory (LGT), these states can be interpreted as a superposition over gauge sectors. We observe localization in this LGT in the absence of disorder in one and two dimensions: perturbations fail to diffuse despite fully disorder-free evolution and initial states. However, Rényi entropy measurements reveal that superposition-prepared states fundamentally differ from those obtained by direct disorder sampling. Leveraging superposition, we propose an algorithm with a polynomial speedup in sampling disorder configurations, a longstanding challenge in many-body localization studies. △ Less

Submitted 6 July, 2025; v1 submitted 9 October, 2024; originally announced October 2024.

Visualizing Dynamics of Charges and Strings in (2+1)D Lattice Gauge Theories

Authors: Tyler A. Cochran, Bernhard Jobst, Eliott Rosenberg, Yuri D. Lensky, Gaurav Gyawali, Norhan Eassa, Melissa Will, Dmitry Abanin, Rajeev Acharya, Laleh Aghababaie Beni, Trond I. Andersen, Markus Ansmann, Frank Arute, Kunal Arya, Abraham Asfaw, Juan Atalaya, Ryan Babbush, Brian Ballard, Joseph C. Bardin, Andreas Bengtsson, Alexander Bilmes, Alexandre Bourassa, Jenna Bovaird, Michael Broughton, David A. Browne , et al. (167 additional authors not shown)

Abstract: Lattice gauge theories (LGTs) can be employed to understand a wide range of phenomena, from elementary particle scattering in high-energy physics to effective descriptions of many-body interactions in materials. Studying dynamical properties of emergent phases can be challenging as it requires solving many-body problems that are generally beyond perturbative limits. Here, we investigate the dynami… ▽ More Lattice gauge theories (LGTs) can be employed to understand a wide range of phenomena, from elementary particle scattering in high-energy physics to effective descriptions of many-body interactions in materials. Studying dynamical properties of emergent phases can be challenging as it requires solving many-body problems that are generally beyond perturbative limits. Here, we investigate the dynamics of local excitations in a $\mathbb{Z}_2$ LGT using a two-dimensional lattice of superconducting qubits. We first construct a simple variational circuit which prepares low-energy states that have a large overlap with the ground state; then we create charge excitations with local gates and simulate their quantum dynamics via a discretized time evolution. As the electric field coupling constant is increased, our measurements show signatures of transitioning from deconfined to confined dynamics. For confined excitations, the electric field induces a tension in the string connecting them. Our method allows us to experimentally image string dynamics in a (2+1)D LGT from which we uncover two distinct regimes inside the confining phase: for weak confinement the string fluctuates strongly in the transverse direction, while for strong confinement transverse fluctuations are effectively frozen. In addition, we demonstrate a resonance condition at which dynamical string breaking is facilitated. Our LGT implementation on a quantum processor presents a novel set of techniques for investigating emergent excitations and string dynamics. △ Less

Submitted 30 June, 2025; v1 submitted 25 September, 2024; originally announced September 2024.

Comments: Main article, methods, and supplemental materials

Journal ref: Nature 642, 315-320 (2025)

Rapid initial state preparation for the quantum simulation of strongly correlated molecules

Authors: Dominic W. Berry, Yu Tong, Tanuj Khattar, Alec White, Tae In Kim, Sergio Boixo, Lin Lin, Seunghoon Lee, Garnet Kin-Lic Chan, Ryan Babbush, Nicholas C. Rubin

Abstract: Studies on quantum algorithms for ground state energy estimation often assume perfect ground state preparation; however, in reality the initial state will have imperfect overlap with the true ground state. Here we address that problem in two ways: by faster preparation of matrix product state (MPS) approximations, and more efficient filtering of the prepared state to find the ground state energy.… ▽ More Studies on quantum algorithms for ground state energy estimation often assume perfect ground state preparation; however, in reality the initial state will have imperfect overlap with the true ground state. Here we address that problem in two ways: by faster preparation of matrix product state (MPS) approximations, and more efficient filtering of the prepared state to find the ground state energy. We show how to achieve unitary synthesis with a Toffoli complexity about $7 \times$ lower than that in prior work, and use that to derive a more efficient MPS preparation method. For filtering we present two different approaches: sampling and binary search. For both we use the theory of window functions to avoid large phase errors and minimise the complexity. We find that the binary search approach provides better scaling with the overlap at the cost of a larger constant factor, such that it will be preferred for overlaps less than about $0.003$. Finally, we estimate the total resources to perform ground state energy estimation of Fe-S cluster systems, including the FeMo cofactor by estimating the overlap of different MPS initial states with potential ground-states of the FeMo cofactor using an extrapolation procedure. {With a modest MPS bond dimension of 4000, our procedure produces an estimate of $\sim 0.9$ overlap squared with a candidate ground-state of the FeMo cofactor, producing a total resource estimate of $7.3 \times 10^{10}$ Toffoli gates; neglecting the search over candidates and assuming the accuracy of the extrapolation, this validates prior estimates that used perfect ground state overlap. This presents an example of a practical path to prepare states of high overlap in a challenging-to-compute chemical system. △ Less

Submitted 18 September, 2024; originally announced September 2024.

Comments: 47 pages, 20 figures

Journal ref: PRX Quantum 6, 020327 (2025)

Expressing and Analyzing Quantum Algorithms with Qualtran

Authors: Matthew P. Harrigan, Tanuj Khattar, Charles Yuan, Anurudh Peduri, Noureldin Yosri, Fionn D. Malone, Ryan Babbush, Nicholas C. Rubin

Abstract: Quantum computing's transition from theory to reality has spurred the need for novel software tools to manage the increasing complexity, sophistication, toil, and fallibility of quantum algorithm development. We present Qualtran, an open-source library for representing and analyzing quantum algorithms. Using appropriate abstractions and data structures, we can simulate and test algorithms, automat… ▽ More Quantum computing's transition from theory to reality has spurred the need for novel software tools to manage the increasing complexity, sophistication, toil, and fallibility of quantum algorithm development. We present Qualtran, an open-source library for representing and analyzing quantum algorithms. Using appropriate abstractions and data structures, we can simulate and test algorithms, automatically generate information-rich diagrams, and tabulate resource requirements. Qualtran offers a standard library of algorithmic building blocks that are essential for modern cost-minimizing compilations. Its capabilities are showcased through the re-analysis of key algorithms in Hamiltonian simulation, chemistry, and cryptography. Architecture-independent resource counts output by Qualtran can be forwarded to our implementation of cost models to estimate physical costs like wall-clock time and number of physical qubits assuming a surface-code architecture. Qualtran provides a foundation for explicit constructions and reproducible analysis, fostering greater collaboration within the growing quantum algorithm development community. △ Less

Submitted 6 September, 2024; originally announced September 2024.

Comments: Code available at https://github.com/quantumlib/Qualtran

Quantum error correction below the surface code threshold

Authors: Rajeev Acharya, Laleh Aghababaie-Beni, Igor Aleiner, Trond I. Andersen, Markus Ansmann, Frank Arute, Kunal Arya, Abraham Asfaw, Nikita Astrakhantsev, Juan Atalaya, Ryan Babbush, Dave Bacon, Brian Ballard, Joseph C. Bardin, Johannes Bausch, Andreas Bengtsson, Alexander Bilmes, Sam Blackwell, Sergio Boixo, Gina Bortoli, Alexandre Bourassa, Jenna Bovaird, Leon Brill, Michael Broughton, David A. Browne , et al. (224 additional authors not shown)

Abstract: Quantum error correction provides a path to reach practical quantum computing by combining multiple physical qubits into a logical qubit, where the logical error rate is suppressed exponentially as more qubits are added. However, this exponential suppression only occurs if the physical error rate is below a critical threshold. In this work, we present two surface code memories operating below this… ▽ More Quantum error correction provides a path to reach practical quantum computing by combining multiple physical qubits into a logical qubit, where the logical error rate is suppressed exponentially as more qubits are added. However, this exponential suppression only occurs if the physical error rate is below a critical threshold. In this work, we present two surface code memories operating below this threshold: a distance-7 code and a distance-5 code integrated with a real-time decoder. The logical error rate of our larger quantum memory is suppressed by a factor of $Λ$ = 2.14 $\pm$ 0.02 when increasing the code distance by two, culminating in a 101-qubit distance-7 code with 0.143% $\pm$ 0.003% error per cycle of error correction. This logical memory is also beyond break-even, exceeding its best physical qubit's lifetime by a factor of 2.4 $\pm$ 0.3. We maintain below-threshold performance when decoding in real time, achieving an average decoder latency of 63 $μ$s at distance-5 up to a million cycles, with a cycle time of 1.1 $μ$s. To probe the limits of our error-correction performance, we run repetition codes up to distance-29 and find that logical performance is limited by rare correlated error events occurring approximately once every hour, or 3 $\times$ 10$^9$ cycles. Our results present device performance that, if scaled, could realize the operational requirements of large scale fault-tolerant quantum algorithms. △ Less

Submitted 24 August, 2024; originally announced August 2024.

Comments: 10 pages, 4 figures, Supplementary Information

Journal ref: Nature 638 (2025) 920-926

Optimization by Decoded Quantum Interferometry

Authors: Stephen P. Jordan, Noah Shutty, Mary Wootters, Adam Zalcman, Alexander Schmidhuber, Robbie King, Sergei V. Isakov, Tanuj Khattar, Ryan Babbush

Abstract: Achieving superpolynomial speedups for optimization has long been a central goal for quantum algorithms. Here we introduce Decoded Quantum Interferometry (DQI), a quantum algorithm that uses the quantum Fourier transform to reduce optimization problems to decoding problems. For approximating optimal polynomial fits over finite fields, DQI achieves a superpolynomial speedup over known classical alg… ▽ More Achieving superpolynomial speedups for optimization has long been a central goal for quantum algorithms. Here we introduce Decoded Quantum Interferometry (DQI), a quantum algorithm that uses the quantum Fourier transform to reduce optimization problems to decoding problems. For approximating optimal polynomial fits over finite fields, DQI achieves a superpolynomial speedup over known classical algorithms. The speedup arises because the problem's algebraic structure is reflected in the decoding problem, which can be solved efficiently. We then investigate whether this approach can achieve speedup for optimization problems that lack algebraic structure but have sparse clauses. These problems reduce to decoding LDPC codes, for which powerful decoders are known. To test this, we construct a max-XORSAT instance where DQI finds an approximate optimum significantly faster than general-purpose classical heuristics, such as simulated annealing. While a tailored classical solver can outperform DQI on this instance, our results establish that combining quantum Fourier transforms with powerful decoding primitives provides a promising new path toward quantum speedups for hard optimization problems. △ Less

Submitted 22 October, 2025; v1 submitted 15 August, 2024; originally announced August 2024.

Comments: 80 pages, 15 figures

Journal ref: Nature 646:831-836, 2025

Shadow Hamiltonian Simulation

Authors: Rolando D. Somma, Robbie King, Robin Kothari, Thomas O'Brien, Ryan Babbush

Abstract: Simulating quantum dynamics is one of the most important applications of quantum computers. Traditional approaches for quantum simulation involve preparing the full evolved state of the system and then measuring some physical quantity. Here, we present a different and novel approach to quantum simulation that uses a compressed quantum state that we call the ``shadow state''. The amplitudes of this… ▽ More Simulating quantum dynamics is one of the most important applications of quantum computers. Traditional approaches for quantum simulation involve preparing the full evolved state of the system and then measuring some physical quantity. Here, we present a different and novel approach to quantum simulation that uses a compressed quantum state that we call the ``shadow state''. The amplitudes of this shadow state are proportional to the time-dependent expectations of a specific set of operators of interest, and it evolves according to its own Schrödinger equation. This evolution can be simulated on a quantum computer efficiently under broad conditions. Applications of this approach to quantum simulation problems include simulating the dynamics of exponentially large systems of free fermions or free bosons, the latter example recovering a recent algorithm for simulating exponentially many classical harmonic oscillators. These simulations are hard for classical methods and also for traditional quantum approaches, as preparing the full states would require exponential resources. Shadow Hamiltonian simulation can also be extended to simulate expectations of more complex operators such as two-time correlators or Green's functions, and to study the evolution of operators themselves in the Heisenberg picture. △ Less

Submitted 20 February, 2025; v1 submitted 31 July, 2024; originally announced July 2024.

Quartic quantum speedups for planted inference

Authors: Alexander Schmidhuber, Ryan O'Donnell, Robin Kothari, Ryan Babbush

Abstract: We describe a quantum algorithm for the Planted Noisy $k$XOR problem (also known as sparse Learning Parity with Noise) that achieves a nearly quartic ($4$th power) speedup over the best known classical algorithm while also only using logarithmically many qubits. Our work generalizes and simplifies prior work of Hastings, by building on his quantum algorithm for the Tensor Principal Component Analy… ▽ More We describe a quantum algorithm for the Planted Noisy $k$XOR problem (also known as sparse Learning Parity with Noise) that achieves a nearly quartic ($4$th power) speedup over the best known classical algorithm while also only using logarithmically many qubits. Our work generalizes and simplifies prior work of Hastings, by building on his quantum algorithm for the Tensor Principal Component Analysis (PCA) problem. We achieve our quantum speedup using a general framework based on the Kikuchi Method (recovering the quartic speedup for Tensor PCA), and we anticipate it will yield similar speedups for further planted inference problems. These speedups rely on the fact that planted inference problems naturally instantiate the Guided Sparse Hamiltonian problem. Since the Planted Noisy $k$XOR problem has been used as a component of certain cryptographic constructions, our work suggests that some of these are susceptible to super-quadratic quantum attacks. △ Less

Submitted 3 June, 2025; v1 submitted 27 June, 2024; originally announced June 2024.

Comments: Short version appeared in SODA 2025 and QIP 2025. Full version published in Phys. Rev. X

Journal ref: Phys. Rev. X 15, 021077 (2025)

Thermalization and Criticality on an Analog-Digital Quantum Simulator

Authors: Trond I. Andersen, Nikita Astrakhantsev, Amir H. Karamlou, Julia Berndtsson, Johannes Motruk, Aaron Szasz, Jonathan A. Gross, Alexander Schuckert, Tom Westerhout, Yaxing Zhang, Ebrahim Forati, Dario Rossi, Bryce Kobrin, Agustin Di Paolo, Andrey R. Klots, Ilya Drozdov, Vladislav D. Kurilovich, Andre Petukhov, Lev B. Ioffe, Andreas Elben, Aniket Rath, Vittorio Vitale, Benoit Vermersch, Rajeev Acharya, Laleh Aghababaie Beni , et al. (202 additional authors not shown)

Abstract: Understanding how interacting particles approach thermal equilibrium is a major challenge of quantum simulators. Unlocking the full potential of such systems toward this goal requires flexible initial state preparation, precise time evolution, and extensive probes for final state characterization. We present a quantum simulator comprising 69 superconducting qubits which supports both universal qua… ▽ More Understanding how interacting particles approach thermal equilibrium is a major challenge of quantum simulators. Unlocking the full potential of such systems toward this goal requires flexible initial state preparation, precise time evolution, and extensive probes for final state characterization. We present a quantum simulator comprising 69 superconducting qubits which supports both universal quantum gates and high-fidelity analog evolution, with performance beyond the reach of classical simulation in cross-entropy benchmarking experiments. Emulating a two-dimensional (2D) XY quantum magnet, we leverage a wide range of measurement techniques to study quantum states after ramps from an antiferromagnetic initial state. We observe signatures of the classical Kosterlitz-Thouless phase transition, as well as strong deviations from Kibble-Zurek scaling predictions attributed to the interplay between quantum and classical coarsening of the correlated domains. This interpretation is corroborated by injecting variable energy density into the initial state, which enables studying the effects of the eigenstate thermalization hypothesis (ETH) in targeted parts of the eigenspectrum. Finally, we digitally prepare the system in pairwise-entangled dimer states and image the transport of energy and vorticity during thermalization. These results establish the efficacy of superconducting analog-digital quantum processors for preparing states across many-body spectra and unveiling their thermalization dynamics. △ Less

Submitted 8 July, 2024; v1 submitted 27 May, 2024; originally announced May 2024.

Triply efficient shadow tomography

Authors: Robbie King, David Gosset, Robin Kothari, Ryan Babbush

Abstract: Given copies of a quantum state $ρ$, a shadow tomography protocol aims to learn all expectation values from a fixed set of observables, to within a given precision $ε$. We say that a shadow tomography protocol is triply efficient if it is sample- and time-efficient, and only employs measurements that entangle a constant number of copies of $ρ$ at a time. The classical shadows protocol based on ran… ▽ More Given copies of a quantum state $ρ$, a shadow tomography protocol aims to learn all expectation values from a fixed set of observables, to within a given precision $ε$. We say that a shadow tomography protocol is triply efficient if it is sample- and time-efficient, and only employs measurements that entangle a constant number of copies of $ρ$ at a time. The classical shadows protocol based on random single-copy measurements is triply efficient for the set of local Pauli observables. This and other protocols based on random single-copy Clifford measurements can be understood as arising from fractional colorings of a graph $G$ that encodes the commutation structure of the set of observables. Here we describe a framework for two-copy shadow tomography that uses an initial round of Bell measurements to reduce to a fractional coloring problem in an induced subgraph of $G$ with bounded clique number. This coloring problem can be addressed using techniques from graph theory known as chi-boundedness. Using this framework we give the first triply efficient shadow tomography scheme for the set of local fermionic observables, which arise in a broad class of interacting fermionic systems in physics and chemistry. We also give a triply efficient scheme for the set of all $n$-qubit Pauli observables. Our protocols for these tasks use two-copy measurements, which is necessary: sample-efficient schemes are provably impossible using only single-copy measurements. Finally, we give a shadow tomography protocol that compresses an $n$-qubit quantum state into a $\text{poly}(n)$-sized classical representation, from which one can extract the expected value of any of the $4^n$ Pauli observables in $\text{poly}(n)$ time, up to a small constant error. △ Less

Submitted 29 April, 2024; originally announced April 2024.

Journal ref: PRX Quantum 6, 010336 (2025)

The discrete adiabatic quantum linear system solver has lower constant factors than the randomized adiabatic solver

Authors: Pedro C. S. Costa, Dong An, Ryan Babbush, Dominic Berry

Abstract: The solution of linear systems of equations is the basis of many other quantum algorithms, and recent results provided an algorithm with optimal scaling in both the condition number $κ$ and the allowable error $ε$ [PRX Quantum \textbf{3}, 040303 (2022)]. That work was based on the discrete adiabatic theorem, and worked out an explicit constant factor for an upper bound on the complexity. Here we s… ▽ More The solution of linear systems of equations is the basis of many other quantum algorithms, and recent results provided an algorithm with optimal scaling in both the condition number $κ$ and the allowable error $ε$ [PRX Quantum \textbf{3}, 040303 (2022)]. That work was based on the discrete adiabatic theorem, and worked out an explicit constant factor for an upper bound on the complexity. Here we show via numerical testing on random matrices that the constant factor is in practice about 1,200 times smaller than the upper bound found numerically in the previous results. That means that this approach is far more efficient than might naively be expected from the upper bound. In particular, it is about an order of magnitude more efficient than using a randomised approach from [arXiv:2305.11352] that claimed to be more efficient. △ Less

Submitted 11 October, 2025; v1 submitted 12 December, 2023; originally announced December 2023.

Comments: 16 pages, 35 figures

Journal ref: Quantum 9, 1887 (2025)

Quantum Simulation of Realistic Materials in First Quantization Using Non-local Pseudopotentials

Authors: Dominic W. Berry, Nicholas C. Rubin, Ahmed O. Elnabawy, Gabriele Ahlers, A. Eugene DePrince III, Joonho Lee, Christian Gogolin, Ryan Babbush

Abstract: This paper improves and demonstrates the usefulness of the first quantized plane-wave algorithms for the quantum simulation of electronic structure, developed by Babbush et al. and Su et al. We describe the first quantum algorithm for first quantized simulation that accurately includes pseudopotentials. We focus on the Goedecker-Tetter-Hutter (GTH) pseudopotential, which is among the most accurate… ▽ More This paper improves and demonstrates the usefulness of the first quantized plane-wave algorithms for the quantum simulation of electronic structure, developed by Babbush et al. and Su et al. We describe the first quantum algorithm for first quantized simulation that accurately includes pseudopotentials. We focus on the Goedecker-Tetter-Hutter (GTH) pseudopotential, which is among the most accurate and widely used norm-conserving pseudopotentials enabling the removal of core electrons from the simulation. The resultant screened nuclear potential regularizes cusps in the electronic wavefunction so that orders of magnitude fewer plane waves are required for a chemically accurate basis. Despite the complicated form of the GTH pseudopotential, we are able to block encode the associated operator without significantly increasing the overall cost of quantum simulation. This is surprising since simulating the nuclear potential is much simpler without pseudopotentials, yet is still the bottleneck. We also generalize prior methods to enable the simulation of materials with non-cubic unit cells, which requires nontrivial modifications. Finally, we combine these techniques to estimate the block-encoding costs for commercially relevant instances of heterogeneous catalysis (e.g. carbon monoxide adsorption on transition metals) and compare to the quantum resources needed to simulate materials in second quantization. We conclude that for computational cells with many particles, first quantization often requires meaningfully less spacetime volume. △ Less

Submitted 24 July, 2024; v1 submitted 12 December, 2023; originally announced December 2023.

Comments: 46 pages, 6 figures, 16 tables

Journal ref: npj Quantum Information 10, 130 (2024)

Quantum computation of stopping power for inertial fusion target design

Authors: Nicholas C. Rubin, Dominic W. Berry, Alina Kononov, Fionn D. Malone, Tanuj Khattar, Alec White, Joonho Lee, Hartmut Neven, Ryan Babbush, Andrew D. Baczewski

Abstract: Stopping power is the rate at which a material absorbs the kinetic energy of a charged particle passing through it -- one of many properties needed over a wide range of thermodynamic conditions in modeling inertial fusion implosions. First-principles stopping calculations are classically challenging because they involve the dynamics of large electronic systems far from equilibrium, with accuracies… ▽ More Stopping power is the rate at which a material absorbs the kinetic energy of a charged particle passing through it -- one of many properties needed over a wide range of thermodynamic conditions in modeling inertial fusion implosions. First-principles stopping calculations are classically challenging because they involve the dynamics of large electronic systems far from equilibrium, with accuracies that are particularly difficult to constrain and assess in the warm-dense conditions preceding ignition. Here, we describe a protocol for using a fault-tolerant quantum computer to calculate stopping power from a first-quantized representation of the electrons and projectile. Our approach builds upon the electronic structure block encodings of Su et al. [PRX Quantum 2, 040332 2021], adapting and optimizing those algorithms to estimate observables of interest from the non-Born-Oppenheimer dynamics of multiple particle species at finite temperature. Ultimately, we report logical qubit requirements and leading-order Toffoli costs for computing the stopping power of various projectile/target combinations relevant to interpreting and designing inertial fusion experiments. We estimate that scientifically interesting and classically intractable stopping power calculations can be quantum simulated with roughly the same number of logical qubits and about one hundred times more Toffoli gates than is required for state-of-the-art quantum simulations of industrially relevant molecules such as FeMoCo or P450. △ Less

Submitted 23 August, 2023; originally announced August 2023.

Journal ref: Proceedings of the National Academy of Sciences Volume 121, Issue 23, 2024

Dynamics of magnetization at infinite temperature in a Heisenberg spin chain

Authors: Eliott Rosenberg, Trond Andersen, Rhine Samajdar, Andre Petukhov, Jesse Hoke, Dmitry Abanin, Andreas Bengtsson, Ilya Drozdov, Catherine Erickson, Paul Klimov, Xiao Mi, Alexis Morvan, Matthew Neeley, Charles Neill, Rajeev Acharya, Richard Allen, Kyle Anderson, Markus Ansmann, Frank Arute, Kunal Arya, Abraham Asfaw, Juan Atalaya, Joseph Bardin, A. Bilmes, Gina Bortoli , et al. (156 additional authors not shown)

Abstract: Understanding universal aspects of quantum dynamics is an unresolved problem in statistical mechanics. In particular, the spin dynamics of the 1D Heisenberg model were conjectured to belong to the Kardar-Parisi-Zhang (KPZ) universality class based on the scaling of the infinite-temperature spin-spin correlation function. In a chain of 46 superconducting qubits, we study the probability distributio… ▽ More Understanding universal aspects of quantum dynamics is an unresolved problem in statistical mechanics. In particular, the spin dynamics of the 1D Heisenberg model were conjectured to belong to the Kardar-Parisi-Zhang (KPZ) universality class based on the scaling of the infinite-temperature spin-spin correlation function. In a chain of 46 superconducting qubits, we study the probability distribution, $P(\mathcal{M})$, of the magnetization transferred across the chain's center. The first two moments of $P(\mathcal{M})$ show superdiffusive behavior, a hallmark of KPZ universality. However, the third and fourth moments rule out the KPZ conjecture and allow for evaluating other theories. Our results highlight the importance of studying higher moments in determining dynamic universality classes and provide key insights into universal behavior in quantum systems. △ Less

Submitted 4 April, 2024; v1 submitted 15 June, 2023; originally announced June 2023.

Journal ref: Science 384, 48-53 (2024)

Stable Quantum-Correlated Many Body States through Engineered Dissipation

Authors: X. Mi, A. A. Michailidis, S. Shabani, K. C. Miao, P. V. Klimov, J. Lloyd, E. Rosenberg, R. Acharya, I. Aleiner, T. I. Andersen, M. Ansmann, F. Arute, K. Arya, A. Asfaw, J. Atalaya, J. C. Bardin, A. Bengtsson, G. Bortoli, A. Bourassa, J. Bovaird, L. Brill, M. Broughton, B. B. Buckley, D. A. Buell, T. Burger , et al. (142 additional authors not shown)

Abstract: Engineered dissipative reservoirs have the potential to steer many-body quantum systems toward correlated steady states useful for quantum simulation of high-temperature superconductivity or quantum magnetism. Using up to 49 superconducting qubits, we prepared low-energy states of the transverse-field Ising model through coupling to dissipative auxiliary qubits. In one dimension, we observed long-… ▽ More Engineered dissipative reservoirs have the potential to steer many-body quantum systems toward correlated steady states useful for quantum simulation of high-temperature superconductivity or quantum magnetism. Using up to 49 superconducting qubits, we prepared low-energy states of the transverse-field Ising model through coupling to dissipative auxiliary qubits. In one dimension, we observed long-range quantum correlations and a ground-state fidelity of 0.86 for 18 qubits at the critical point. In two dimensions, we found mutual information that extends beyond nearest neighbors. Lastly, by coupling the system to auxiliaries emulating reservoirs with different chemical potentials, we explored transport in the quantum Heisenberg model. Our results establish engineered dissipation as a scalable alternative to unitary evolution for preparing entangled many-body states on noisy quantum processors. △ Less

Submitted 5 April, 2024; v1 submitted 26 April, 2023; originally announced April 2023.

Journal ref: Science 383, 1332-1337 (2024)

Phase transition in Random Circuit Sampling

Authors: A. Morvan, B. Villalonga, X. Mi, S. Mandrà, A. Bengtsson, P. V. Klimov, Z. Chen, S. Hong, C. Erickson, I. K. Drozdov, J. Chau, G. Laun, R. Movassagh, A. Asfaw, L. T. A. N. Brandão, R. Peralta, D. Abanin, R. Acharya, R. Allen, T. I. Andersen, K. Anderson, M. Ansmann, F. Arute, K. Arya, J. Atalaya , et al. (160 additional authors not shown)

Abstract: Undesired coupling to the surrounding environment destroys long-range correlations on quantum processors and hinders the coherent evolution in the nominally available computational space. This incoherent noise is an outstanding challenge to fully leverage the computation power of near-term quantum processors. It has been shown that benchmarking Random Circuit Sampling (RCS) with Cross-Entropy Benc… ▽ More Undesired coupling to the surrounding environment destroys long-range correlations on quantum processors and hinders the coherent evolution in the nominally available computational space. This incoherent noise is an outstanding challenge to fully leverage the computation power of near-term quantum processors. It has been shown that benchmarking Random Circuit Sampling (RCS) with Cross-Entropy Benchmarking (XEB) can provide a reliable estimate of the effective size of the Hilbert space coherently available. The extent to which the presence of noise can trivialize the outputs of a given quantum algorithm, i.e. making it spoofable by a classical computation, is an unanswered question. Here, by implementing an RCS algorithm we demonstrate experimentally that there are two phase transitions observable with XEB, which we explain theoretically with a statistical model. The first is a dynamical transition as a function of the number of cycles and is the continuation of the anti-concentration point in the noiseless case. The second is a quantum phase transition controlled by the error per cycle; to identify it analytically and experimentally, we create a weak link model which allows varying the strength of noise versus coherent evolution. Furthermore, by presenting an RCS experiment with 67 qubits at 32 cycles, we demonstrate that the computational cost of our experiment is beyond the capabilities of existing classical supercomputers, even when accounting for the inevitable presence of noise. Our experimental and theoretical work establishes the existence of transitions to a stable computationally complex phase that is reachable with current quantum processors. △ Less

Submitted 21 December, 2023; v1 submitted 21 April, 2023; originally announced April 2023.

Journal ref: Nature 634, 328-333 (2024)

Exponential quantum speedup in simulating coupled classical oscillators

Authors: Ryan Babbush, Dominic W. Berry, Robin Kothari, Rolando D. Somma, Nathan Wiebe

Abstract: We present a quantum algorithm for simulating the classical dynamics of $2^n$ coupled oscillators (e.g., $2^n$ masses coupled by springs). Our approach leverages a mapping between the Schrödinger equation and Newton's equation for harmonic potentials such that the amplitudes of the evolved quantum state encode the momenta and displacements of the classical oscillators. When individual masses and s… ▽ More We present a quantum algorithm for simulating the classical dynamics of $2^n$ coupled oscillators (e.g., $2^n$ masses coupled by springs). Our approach leverages a mapping between the Schrödinger equation and Newton's equation for harmonic potentials such that the amplitudes of the evolved quantum state encode the momenta and displacements of the classical oscillators. When individual masses and spring constants can be efficiently queried, and when the initial state can be efficiently prepared, the complexity of our quantum algorithm is polynomial in $n$, almost linear in the evolution time, and sublinear in the sparsity. As an example application, we apply our quantum algorithm to efficiently estimate the kinetic energy of an oscillator at any time. We show that any classical algorithm solving this same problem is inefficient and must make $2^{Ω(n)}$ queries to the oracle and, when the oracles are instantiated by efficient quantum circuits, the problem is BQP-complete. Thus, our approach solves a potentially practical application with an exponential speedup over classical computers. Finally, we show that under similar conditions our approach can efficiently simulate more general classical harmonic systems with $2^n$ modes. △ Less

Submitted 19 September, 2023; v1 submitted 22 March, 2023; originally announced March 2023.

Comments: 43 pages, 4 figures. v3 changes include improved presentation, discussion of applications related to potential energies, and new appendix discussing relation to prior work

Journal ref: Phys. Rev. X 13, 041041 (2023)

Measurement-induced entanglement and teleportation on a noisy quantum processor

Authors: Jesse C. Hoke, Matteo Ippoliti, Eliott Rosenberg, Dmitry Abanin, Rajeev Acharya, Trond I. Andersen, Markus Ansmann, Frank Arute, Kunal Arya, Abraham Asfaw, Juan Atalaya, Joseph C. Bardin, Andreas Bengtsson, Gina Bortoli, Alexandre Bourassa, Jenna Bovaird, Leon Brill, Michael Broughton, Bob B. Buckley, David A. Buell, Tim Burger, Brian Burkett, Nicholas Bushnell, Zijun Chen, Ben Chiaro , et al. (138 additional authors not shown)

Abstract: Measurement has a special role in quantum theory: by collapsing the wavefunction it can enable phenomena such as teleportation and thereby alter the "arrow of time" that constrains unitary evolution. When integrated in many-body dynamics, measurements can lead to emergent patterns of quantum information in space-time that go beyond established paradigms for characterizing phases, either in or out… ▽ More Measurement has a special role in quantum theory: by collapsing the wavefunction it can enable phenomena such as teleportation and thereby alter the "arrow of time" that constrains unitary evolution. When integrated in many-body dynamics, measurements can lead to emergent patterns of quantum information in space-time that go beyond established paradigms for characterizing phases, either in or out of equilibrium. On present-day NISQ processors, the experimental realization of this physics is challenging due to noise, hardware limitations, and the stochastic nature of quantum measurement. Here we address each of these experimental challenges and investigate measurement-induced quantum information phases on up to 70 superconducting qubits. By leveraging the interchangeability of space and time, we use a duality mapping, to avoid mid-circuit measurement and access different manifestations of the underlying phases -- from entanglement scaling to measurement-induced teleportation -- in a unified way. We obtain finite-size signatures of a phase transition with a decoding protocol that correlates the experimental measurement record with classical simulation data. The phases display sharply different sensitivity to noise, which we exploit to turn an inherent hardware limitation into a useful diagnostic. Our work demonstrates an approach to realize measurement-induced physics at scales that are at the limits of current NISQ processors. △ Less

Submitted 17 October, 2023; v1 submitted 8 March, 2023; originally announced March 2023.

Journal ref: Nature 622, 481-486 (2023)

Fault-tolerant quantum simulation of materials using Bloch orbitals

Authors: Nicholas C. Rubin, Dominic W. Berry, Fionn D. Malone, Alec F. White, Tanuj Khattar, A. Eugene DePrince III, Sabrina Sicolo, Michael Kühn, Michael Kaicher, Joonho Lee, Ryan Babbush

Abstract: The simulation of chemistry is among the most promising applications of quantum computing. However, most prior work exploring algorithms for block-encoding, time-evolving, and sampling in the eigenbasis of electronic structure Hamiltonians has either focused on modeling finite-sized systems, or has required a large number of plane wave basis functions. In this work, we extend methods for quantum s… ▽ More The simulation of chemistry is among the most promising applications of quantum computing. However, most prior work exploring algorithms for block-encoding, time-evolving, and sampling in the eigenbasis of electronic structure Hamiltonians has either focused on modeling finite-sized systems, or has required a large number of plane wave basis functions. In this work, we extend methods for quantum simulation with Bloch orbitals constructed from symmetry-adapted atom-centered orbitals so that one can model periodic \textit{ab initio} Hamiltonians using only a modest number of basis functions. We focus on adapting existing algorithms based on combining qubitization with tensor factorizations of the Coulomb operator. Significant modifications of those algorithms are required to obtain an asymptotic speedup leveraging translational (or, more broadly, Abelian) symmetries. We implement block encodings using known tensor factorizations and a new Bloch orbital form of tensor hypercontraction. Finally, we estimate the resources required to deploy our algorithms to classically challenging model materials relevant to the chemistry of Lithium Nickel Oxide battery cathodes within the surface code. △ Less

Submitted 10 February, 2023; originally announced February 2023.

Journal ref: PRX Quantum 4, 040303 (2023)

Drug design on quantum computers

Authors: Raffaele Santagati, Alan Aspuru-Guzik, Ryan Babbush, Matthias Degroote, Leticia Gonzalez, Elica Kyoseva, Nikolaj Moll, Markus Oppel, Robert M. Parrish, Nicholas C. Rubin, Michael Streif, Christofer S. Tautermann, Horst Weiss, Nathan Wiebe, Clemens Utschig-Utschig

Abstract: Quantum computers promise to impact industrial applications, for which quantum chemical calculations are required, by virtue of their high accuracy. This perspective explores the challenges and opportunities of applying quantum computers to drug design, discusses where they could transform industrial research and elaborates on what is needed to reach this goal. Quantum computers promise to impact industrial applications, for which quantum chemical calculations are required, by virtue of their high accuracy. This perspective explores the challenges and opportunities of applying quantum computers to drug design, discusses where they could transform industrial research and elaborates on what is needed to reach this goal. △ Less

Submitted 10 January, 2023; originally announced January 2023.

Report number: https://www.nature.com/articles/s41567-024-02411-5

Journal ref: Nature Physics 2024

Quantum simulation of exact electron dynamics can be more efficient than classical mean-field methods

Authors: Ryan Babbush, William J. Huggins, Dominic W. Berry, Shu Fay Ung, Andrew Zhao, David R. Reichman, Hartmut Neven, Andrew D. Baczewski, Joonho Lee

Abstract: Quantum algorithms for simulating electronic ground states are slower than popular classical mean-field algorithms such as Hartree-Fock and density functional theory, but offer higher accuracy. Accordingly, quantum computers have been predominantly regarded as competitors to only the most accurate and costly classical methods for treating electron correlation. However, here we tighten bounds showi… ▽ More Quantum algorithms for simulating electronic ground states are slower than popular classical mean-field algorithms such as Hartree-Fock and density functional theory, but offer higher accuracy. Accordingly, quantum computers have been predominantly regarded as competitors to only the most accurate and costly classical methods for treating electron correlation. However, here we tighten bounds showing that certain first quantized quantum algorithms enable exact time evolution of electronic systems with exponentially less space and polynomially fewer operations in basis set size than conventional real-time time-dependent Hartree-Fock and density functional theory. Although the need to sample observables in the quantum algorithm reduces the speedup, we show that one can estimate all elements of the $k$-particle reduced density matrix with a number of samples scaling only polylogarithmically in basis set size. We also introduce a more efficient quantum algorithm for first quantized mean-field state preparation that is likely cheaper than the cost of time evolution. We conclude that quantum speedup is most pronounced for finite temperature simulations and suggest several practically important electron dynamics problems with potential quantum advantage. △ Less

Submitted 3 January, 2023; originally announced January 2023.

Comments: 31 pages, 2 tables, 1 figure

Journal ref: Nat. Comms 14: 4058 (2023)

Purification-based quantum error mitigation of pair-correlated electron simulations

Authors: T. E. O'Brien, G. Anselmetti, F. Gkritsis, V. E. Elfving, S. Polla, W. J. Huggins, O. Oumarou, K. Kechedzhi, D. Abanin, R. Acharya, I. Aleiner, R. Allen, T. I. Andersen, K. Anderson, M. Ansmann, F. Arute, K. Arya, A. Asfaw, J. Atalaya, D. Bacon, J. C. Bardin, A. Bengtsson, S. Boixo, G. Bortoli, A. Bourassa , et al. (151 additional authors not shown)

Abstract: An important measure of the development of quantum computing platforms has been the simulation of increasingly complex physical systems. Prior to fault-tolerant quantum computing, robust error mitigation strategies are necessary to continue this growth. Here, we study physical simulation within the seniority-zero electron pairing subspace, which affords both a computational stepping stone to a ful… ▽ More An important measure of the development of quantum computing platforms has been the simulation of increasingly complex physical systems. Prior to fault-tolerant quantum computing, robust error mitigation strategies are necessary to continue this growth. Here, we study physical simulation within the seniority-zero electron pairing subspace, which affords both a computational stepping stone to a fully correlated model, and an opportunity to validate recently introduced ``purification-based'' error-mitigation strategies. We compare the performance of error mitigation based on doubling quantum resources in time (echo verification) or in space (virtual distillation), on up to $20$ qubits of a superconducting qubit quantum processor. We observe a reduction of error by one to two orders of magnitude below less sophisticated techniques (e.g. post-selection); the gain from error mitigation is seen to increase with the system size. Employing these error mitigation strategies enables the implementation of the largest variational algorithm for a correlated chemistry system to-date. Extrapolating performance from these results allows us to estimate minimum requirements for a beyond-classical simulation of electronic structure. We find that, despite the impressive gains from purification-based error mitigation, significant hardware improvements will be required for classically intractable variational chemistry simulations. △ Less

Submitted 19 October, 2022; originally announced October 2022.

Comments: 10 pages, 13 page supplementary material, 12 figures. Experimental data available at https://doi.org/10.5281/zenodo.7225821

Journal ref: Nat. Phys. (2023)

Non-Abelian braiding of graph vertices in a superconducting processor

Authors: Trond I. Andersen, Yuri D. Lensky, Kostyantyn Kechedzhi, Ilya Drozdov, Andreas Bengtsson, Sabrina Hong, Alexis Morvan, Xiao Mi, Alex Opremcak, Rajeev Acharya, Richard Allen, Markus Ansmann, Frank Arute, Kunal Arya, Abraham Asfaw, Juan Atalaya, Ryan Babbush, Dave Bacon, Joseph C. Bardin, Gina Bortoli, Alexandre Bourassa, Jenna Bovaird, Leon Brill, Michael Broughton, Bob B. Buckley , et al. (144 additional authors not shown)

Abstract: Indistinguishability of particles is a fundamental principle of quantum mechanics. For all elementary and quasiparticles observed to date - including fermions, bosons, and Abelian anyons - this principle guarantees that the braiding of identical particles leaves the system unchanged. However, in two spatial dimensions, an intriguing possibility exists: braiding of non-Abelian anyons causes rotatio… ▽ More Indistinguishability of particles is a fundamental principle of quantum mechanics. For all elementary and quasiparticles observed to date - including fermions, bosons, and Abelian anyons - this principle guarantees that the braiding of identical particles leaves the system unchanged. However, in two spatial dimensions, an intriguing possibility exists: braiding of non-Abelian anyons causes rotations in a space of topologically degenerate wavefunctions. Hence, it can change the observables of the system without violating the principle of indistinguishability. Despite the well developed mathematical description of non-Abelian anyons and numerous theoretical proposals, the experimental observation of their exchange statistics has remained elusive for decades. Controllable many-body quantum states generated on quantum processors offer another path for exploring these fundamental phenomena. While efforts on conventional solid-state platforms typically involve Hamiltonian dynamics of quasi-particles, superconducting quantum processors allow for directly manipulating the many-body wavefunction via unitary gates. Building on predictions that stabilizer codes can host projective non-Abelian Ising anyons, we implement a generalized stabilizer code and unitary protocol to create and braid them. This allows us to experimentally verify the fusion rules of the anyons and braid them to realize their statistics. We then study the prospect of employing the anyons for quantum computation and utilize braiding to create an entangled state of anyons encoding three logical qubits. Our work provides new insights about non-Abelian braiding and - through the future inclusion of error correction to achieve topological protection - could open a path toward fault-tolerant quantum computing. △ Less

Submitted 31 May, 2023; v1 submitted 18 October, 2022; originally announced October 2022.

Quantum Error Mitigation

Authors: Zhenyu Cai, Ryan Babbush, Simon C. Benjamin, Suguru Endo, William J. Huggins, Ying Li, Jarrod R. McClean, Thomas E. O'Brien

Abstract: For quantum computers to successfully solve real-world problems, it is necessary to tackle the challenge of noise: the errors which occur in elementary physical components due to unwanted or imperfect interactions. The theory of quantum fault tolerance can provide an answer in the long term, but in the coming era of `NISQ' machines we must seek to mitigate errors rather than completely remove them… ▽ More For quantum computers to successfully solve real-world problems, it is necessary to tackle the challenge of noise: the errors which occur in elementary physical components due to unwanted or imperfect interactions. The theory of quantum fault tolerance can provide an answer in the long term, but in the coming era of `NISQ' machines we must seek to mitigate errors rather than completely remove them. This review surveys the diverse methods that have been proposed for quantum error mitigation, assesses their in-principle efficacy, and then describes the hardware demonstrations achieved to date. We identify the commonalities and limitations among the methods, noting how mitigation methods can be chosen according to the primary type of noise present, including algorithmic errors. Open problems in the field are identified and we discuss the prospects for realising mitigation-based devices that can deliver quantum advantage with an impact on science and business. △ Less

Submitted 28 December, 2023; v1 submitted 3 October, 2022; originally announced October 2022.

Analyzing Prospects for Quantum Advantage in Topological Data Analysis

Authors: Dominic W. Berry, Yuan Su, Casper Gyurik, Robbie King, Joao Basso, Alexander Del Toro Barba, Abhishek Rajput, Nathan Wiebe, Vedran Dunjko, Ryan Babbush

Abstract: Lloyd et al. were first to demonstrate the promise of quantum algorithms for computing Betti numbers, a way to characterize topological features of data sets. Here, we propose, analyze, and optimize an improved quantum algorithm for topological data analysis (TDA) with reduced scaling, including a method for preparing Dicke states based on inequality testing, a more efficient amplitude estimation… ▽ More Lloyd et al. were first to demonstrate the promise of quantum algorithms for computing Betti numbers, a way to characterize topological features of data sets. Here, we propose, analyze, and optimize an improved quantum algorithm for topological data analysis (TDA) with reduced scaling, including a method for preparing Dicke states based on inequality testing, a more efficient amplitude estimation algorithm using Kaiser windows, and an optimal implementation of eigenvalue projectors based on Chebyshev polynomials. We compile our approach to a fault-tolerant gate set and estimate constant factors in the Toffoli complexity. Our analysis reveals that super-quadratic quantum speedups are only possible for this problem when targeting a multiplicative error approximation and the Betti number grows asymptotically. Further, we propose a dequantization of the quantum TDA algorithm that shows that having exponentially large dimension and Betti number are necessary, but insufficient conditions, for super-polynomial advantage. We then introduce and analyze specific problem examples which have parameters in the regime where super-polynomial advantages may be achieved, and argue that quantum circuits with tens of billions of Toffoli gates can solve seemingly classically intractable instances. △ Less

Submitted 27 September, 2023; v1 submitted 27 September, 2022; originally announced September 2022.

Comments: 54 pages, 7 figures. Added a number of theorems and lemmas to clarify findings and also a discussion in the main text and new appendix about variants of our problems with high Betti numbers that are challenging for recent classical algorithms

Journal ref: PRX Quantum 5, 010319 (2024)

Is there evidence for exponential quantum advantage in quantum chemistry?

Authors: Seunghoon Lee, Joonho Lee, Huanchen Zhai, Yu Tong, Alexander M. Dalzell, Ashutosh Kumar, Phillip Helms, Johnnie Gray, Zhi-Hao Cui, Wenyuan Liu, Michael Kastoryano, Ryan Babbush, John Preskill, David R. Reichman, Earl T. Campbell, Edward F. Valeev, Lin Lin, Garnet Kin-Lic Chan

Abstract: The idea to use quantum mechanical devices to simulate other quantum systems is commonly ascribed to Feynman. Since the original suggestion, concrete proposals have appeared for simulating molecular and materials chemistry through quantum computation, as a potential ``killer application''. Indications of potential exponential quantum advantage in artificial tasks have increased interest in this ap… ▽ More The idea to use quantum mechanical devices to simulate other quantum systems is commonly ascribed to Feynman. Since the original suggestion, concrete proposals have appeared for simulating molecular and materials chemistry through quantum computation, as a potential ``killer application''. Indications of potential exponential quantum advantage in artificial tasks have increased interest in this application, thus, it is critical to understand the basis for potential exponential quantum advantage in quantum chemistry. Here we gather the evidence for this case in the most common task in quantum chemistry, namely, ground-state energy estimation. We conclude that evidence for such an exponential advantage across chemical space has yet to be found. While quantum computers may still prove useful for quantum chemistry, it may be prudent to assume exponential speedups are not generically available for this problem. △ Less

Submitted 14 November, 2022; v1 submitted 3 August, 2022; originally announced August 2022.

Journal ref: Nat Commun 14, 1952 (2023)

Response to "Exponential challenges in unbiasing quantum Monte Carlo algorithms with quantum computers"

Authors: Joonho Lee, David R. Reichman, Ryan Babbush, Nicholas C. Rubin, Fionn D. Malone, Bryan O'Gorman, William J. Huggins

Abstract: A recent preprint by Mazzola and Carleo numerically investigates exponential challenges that can arise for the QC-QMC algorithm introduced in our work, "Unbiasing fermionic quantum Monte Carlo with a quantum computer." As discussed in our original paper, we agree with this general concern. However, here we provide further details and numerics to emphasize that the prospects for practical quantum a… ▽ More A recent preprint by Mazzola and Carleo numerically investigates exponential challenges that can arise for the QC-QMC algorithm introduced in our work, "Unbiasing fermionic quantum Monte Carlo with a quantum computer." As discussed in our original paper, we agree with this general concern. However, here we provide further details and numerics to emphasize that the prospects for practical quantum advantage in QC-QMC remain open. The exponential challenges in QC-QMC are dependent on (1) the choice of QMC methods, (2) the underlying system, and (3) the form of trial and walker wavefunctions. While one can find difficult examples with a specific method, a specific system, and a specific walker/trial form, for some combinations of these choices, the approach is potentially more scalable than other near-term quantum algorithms. Future research should aim to identify examples for which QC-QMC enables practical quantum advantage. △ Less

Submitted 27 July, 2022; originally announced July 2022.

Matchgate Shadows for Fermionic Quantum Simulation

Authors: Kianna Wan, William J. Huggins, Joonho Lee, Ryan Babbush

Abstract: "Classical shadows" are estimators of an unknown quantum state, constructed from suitably distributed random measurements on copies of that state [Nature Physics 16, 1050-1057]. Here, we analyze classical shadows obtained using random matchgate circuits, which correspond to fermionic Gaussian unitaries. We prove that the first three moments of the Haar distribution over the continuous group of mat… ▽ More "Classical shadows" are estimators of an unknown quantum state, constructed from suitably distributed random measurements on copies of that state [Nature Physics 16, 1050-1057]. Here, we analyze classical shadows obtained using random matchgate circuits, which correspond to fermionic Gaussian unitaries. We prove that the first three moments of the Haar distribution over the continuous group of matchgate circuits are equal to those of the discrete uniform distribution over only the matchgate circuits that are also Clifford unitaries; thus, the latter forms a "matchgate 3-design." This implies that the classical shadows resulting from the two ensembles are functionally equivalent. We show how one can use these matchgate shadows to efficiently estimate inner products between an arbitrary quantum state and fermionic Gaussian states, as well as the expectation values of local fermionic operators and various other quantities, thus surpassing the capabilities of prior work. As a concrete application, this enables us to apply wavefunction constraints that control the fermion sign problem in the quantum-classical auxiliary-field quantum Monte Carlo algorithm (QC-AFQMC) [Nature 603, 416-420], without the exponential post-processing cost incurred by the original approach. △ Less

Submitted 24 November, 2023; v1 submitted 27 July, 2022; originally announced July 2022.

Comments: 56 pages, 1 figure; journal version

Journal ref: Comm. Math. Phys. 404, 629-700 (2023)

Suppressing quantum errors by scaling a surface code logical qubit

Authors: Rajeev Acharya, Igor Aleiner, Richard Allen, Trond I. Andersen, Markus Ansmann, Frank Arute, Kunal Arya, Abraham Asfaw, Juan Atalaya, Ryan Babbush, Dave Bacon, Joseph C. Bardin, Joao Basso, Andreas Bengtsson, Sergio Boixo, Gina Bortoli, Alexandre Bourassa, Jenna Bovaird, Leon Brill, Michael Broughton, Bob B. Buckley, David A. Buell, Tim Burger, Brian Burkett, Nicholas Bushnell , et al. (132 additional authors not shown)

Abstract: Practical quantum computing will require error rates that are well below what is achievable with physical qubits. Quantum error correction offers a path to algorithmically-relevant error rates by encoding logical qubits within many physical qubits, where increasing the number of physical qubits enhances protection against physical errors. However, introducing more qubits also increases the number… ▽ More Practical quantum computing will require error rates that are well below what is achievable with physical qubits. Quantum error correction offers a path to algorithmically-relevant error rates by encoding logical qubits within many physical qubits, where increasing the number of physical qubits enhances protection against physical errors. However, introducing more qubits also increases the number of error sources, so the density of errors must be sufficiently low in order for logical performance to improve with increasing code size. Here, we report the measurement of logical qubit performance scaling across multiple code sizes, and demonstrate that our system of superconducting qubits has sufficient performance to overcome the additional errors from increasing qubit number. We find our distance-5 surface code logical qubit modestly outperforms an ensemble of distance-3 logical qubits on average, both in terms of logical error probability over 25 cycles and logical error per cycle ($2.914\%\pm 0.016\%$ compared to $3.028\%\pm 0.023\%$). To investigate damaging, low-probability error sources, we run a distance-25 repetition code and observe a $1.7\times10^{-6}$ logical error per round floor set by a single high-energy event ($1.6\times10^{-7}$ when excluding this event). We are able to accurately model our experiment, and from this model we can extract error budgets that highlight the biggest challenges for future systems. These results mark the first experimental demonstration where quantum error correction begins to improve performance with increasing qubit number, illuminating the path to reaching the logical error rates required for computation. △ Less

Submitted 20 July, 2022; v1 submitted 13 July, 2022; originally announced July 2022.

Comments: Main text: 6 pages, 4 figures. v2: Update author list, references, Fig. S12, Table IV

Journal ref: Nature 614 (2023) 678-681

Formation of robust bound states of interacting microwave photons

Authors: Alexis Morvan, Trond I. Andersen, Xiao Mi, Charles Neill, Andre Petukhov, Kostyantyn Kechedzhi, Dmitry Abanin, Rajeev Acharya, Frank Arute, Kunal Arya, Abraham Asfaw, Juan Atalaya, Ryan Babbush, Dave Bacon, Joseph C. Bardin, Joao Basso, Andreas Bengtsson, Gina Bortoli, Alexandre Bourassa, Jenna Bovaird, Leon Brill, Michael Broughton, Bob B. Buckley, David A. Buell, Tim Burger , et al. (125 additional authors not shown)

Abstract: Systems of correlated particles appear in many fields of science and represent some of the most intractable puzzles in nature. The computational challenge in these systems arises when interactions become comparable to other energy scales, which makes the state of each particle depend on all other particles. The lack of general solutions for the 3-body problem and acceptable theory for strongly cor… ▽ More Systems of correlated particles appear in many fields of science and represent some of the most intractable puzzles in nature. The computational challenge in these systems arises when interactions become comparable to other energy scales, which makes the state of each particle depend on all other particles. The lack of general solutions for the 3-body problem and acceptable theory for strongly correlated electrons shows that our understanding of correlated systems fades when the particle number or the interaction strength increases. One of the hallmarks of interacting systems is the formation of multi-particle bound states. In a ring of 24 superconducting qubits, we develop a high fidelity parameterizable fSim gate that we use to implement the periodic quantum circuit of the spin-1/2 XXZ model, an archetypal model of interaction. By placing microwave photons in adjacent qubit sites, we study the propagation of these excitations and observe their bound nature for up to 5 photons. We devise a phase sensitive method for constructing the few-body spectrum of the bound states and extract their pseudo-charge by introducing a synthetic flux. By introducing interactions between the ring and additional qubits, we observe an unexpected resilience of the bound states to integrability breaking. This finding goes against the common wisdom that bound states in non-integrable systems are unstable when their energies overlap with the continuum spectrum. Our work provides experimental evidence for bound states of interacting photons and discovers their stability beyond the integrability limit. △ Less

Submitted 21 December, 2022; v1 submitted 10 June, 2022; originally announced June 2022.

Comments: 7 pages + 15 pages supplements

Journal ref: Nature 612, 240-245 (2022)

Noise-resilient Edge Modes on a Chain of Superconducting Qubits

Authors: Xiao Mi, Michael Sonner, Murphy Yuezhen Niu, Kenneth W. Lee, Brooks Foxen, Rajeev Acharya, Igor Aleiner, Trond I. Andersen, Frank Arute, Kunal Arya, Abraham Asfaw, Juan Atalaya, Ryan Babbush, Dave Bacon, Joseph C. Bardin, Joao Basso, Andreas Bengtsson, Gina Bortoli, Alexandre Bourassa, Leon Brill, Michael Broughton, Bob B. Buckley, David A. Buell, Brian Burkett, Nicholas Bushnell , et al. (103 additional authors not shown)

Abstract: Inherent symmetry of a quantum system may protect its otherwise fragile states. Leveraging such protection requires testing its robustness against uncontrolled environmental interactions. Using 47 superconducting qubits, we implement the one-dimensional kicked Ising model which exhibits non-local Majorana edge modes (MEMs) with $\mathbb{Z}_2$ parity symmetry. Remarkably, we find that any multi-qub… ▽ More Inherent symmetry of a quantum system may protect its otherwise fragile states. Leveraging such protection requires testing its robustness against uncontrolled environmental interactions. Using 47 superconducting qubits, we implement the one-dimensional kicked Ising model which exhibits non-local Majorana edge modes (MEMs) with $\mathbb{Z}_2$ parity symmetry. Remarkably, we find that any multi-qubit Pauli operator overlapping with the MEMs exhibits a uniform late-time decay rate comparable to single-qubit relaxation rates, irrespective of its size or composition. This characteristic allows us to accurately reconstruct the exponentially localized spatial profiles of the MEMs. Furthermore, the MEMs are found to be resilient against certain symmetry-breaking noise owing to a prethermalization mechanism. Our work elucidates the complex interplay between noise and symmetry-protected edge modes in a solid-state environment. △ Less

Submitted 8 December, 2022; v1 submitted 24 April, 2022; originally announced April 2022.

Journal ref: Science 378, 785 (2022)

Simulating challenging correlated molecules and materials on the Sycamore quantum processor

Authors: Ruslan N. Tazhigulov, Shi-Ning Sun, Reza Haghshenas, Huanchen Zhai, Adrian T. K. Tan, Nicholas C. Rubin, Ryan Babbush, Austin J. Minnich, Garnet Kin-Lic Chan

Abstract: Simulating complex molecules and materials is an anticipated application of quantum devices. With strong quantum advantage demonstrated in artificial tasks, we examine how such advantage translates into modeling physical problems of correlated electronic structure. We simulate static and dynamical electronic structure on a superconducting quantum processor derived from Google's Sycamore architectu… ▽ More Simulating complex molecules and materials is an anticipated application of quantum devices. With strong quantum advantage demonstrated in artificial tasks, we examine how such advantage translates into modeling physical problems of correlated electronic structure. We simulate static and dynamical electronic structure on a superconducting quantum processor derived from Google's Sycamore architecture for two representative correlated electron problems: the nitrogenase iron-sulfur molecular clusters, and $α$-ruthenium trichloride, a proximate spin-liquid material. To do so, we simplify the electronic structure into low-energy spin models that fit on the device. With extensive error mitigation and assistance from classically simulated data, we achieve quantitatively meaningful results deploying about 1/5 of the gate resources used in artificial quantum advantage experiments on a similar architecture. This increases to over 1/2 of the gate resources when choosing a model that suits the hardware. Our work serves to convert artificial measures of quantum advantage into a physically relevant setting. △ Less

Submitted 29 March, 2022; originally announced March 2022.

Comments: 17 pages, 5 figures

Reliably assessing the electronic structure of cytochrome P450 on today's classical computers and tomorrow's quantum computers

Authors: Joshua J. Goings, Alec White, Joonho Lee, Christofer S. Tautermann, Matthias Degroote, Craig Gidney, Toru Shiozaki, Ryan Babbush, Nicholas C. Rubin

Abstract: An accurate assessment of how quantum computers can be used for chemical simulation, especially their potential computational advantages, provides important context on how to deploy these future devices. In order to perform this assessment reliably, quantum resource estimates must be coupled with classical simulations attempting to answer relevant chemical questions and to define the classical sim… ▽ More An accurate assessment of how quantum computers can be used for chemical simulation, especially their potential computational advantages, provides important context on how to deploy these future devices. In order to perform this assessment reliably, quantum resource estimates must be coupled with classical simulations attempting to answer relevant chemical questions and to define the classical simulation frontier. Herein, we explore the quantum and classical resources required to assess the electronic structure of cytochrome P450 enzymes (CYPs) and thus define a classical-quantum advantage boundary. This is accomplished by analyzing the convergence of DMRG+NEVPT2 and coupled cluster singles doubles with non-iterative triples (CCSD(T)) calculations for spin-gaps in models of the CYP catalytic cycle that indicate multireference character. The quantum resources required to perform phase estimation using qubitized quantum walks are calculated for the same systems. Compilation into the surface-code provides runtime estimates to compare directly to DMRG runtimes and to evaluate potential quantum advantage. Both classical and quantum resource estimates suggest that simulation of CYP models at scales large enough to balance dynamic and multiconfigurational electron correlation has the potential to be a quantum advantage problem and emphasizes the important interplay between classical simulations and quantum algorithms development for chemical simulation. △ Less

Submitted 2 February, 2022; originally announced February 2022.